Hydroxyquinone compounds, such as 1,4-dihydroxyanthraquinone and alizarin sulfonate, are widely used in dye manufacturing, pharmaceutical manufacturing, and other industries. However, the treatment of hydroxyquinone-c...Hydroxyquinone compounds, such as 1,4-dihydroxyanthraquinone and alizarin sulfonate, are widely used in dye manufacturing, pharmaceutical manufacturing, and other industries. However, the treatment of hydroxyquinone-containing wastewater has seldom been examined. This study used a precipitation method with barium salt to treat nano-silver industrial wastewater. The results show that barium chloride was a suitable reagent for significantly degrading COD and color from nano-silver wastewater. When the initial pH value was 10.5, 8 g of BaCl2·2H2O were added to 100 mL of wastewater. After reaction at 15℃ for 1 h, the removal efficiencies of COD and color in the nano-silver wastewater were 85.6% and 97.1%, respectively. Simulated wastewater containing sodium alizarin-3-sulfonate (ARS) or purpurin was used to further investigate the removal mechanism of hydroxyquinone compounds. Fourier transform infrared spectroscopy, X-ray diffraction, and some related experiments showed that hydroxyquinone compounds can directly react with barium ions in the solution so as to transfer from wastewater to precipitate. In addition, the newly produced barium sulfate particles have positive surface charges, which can improve the removal efficiency of hydroxyquinone compounds due to electrostatic attraction.展开更多
Due to the high energy consumption for separation of salt containing methanol wastewater, in this work, the multi-effect evaporation coupled with mechanical vapor recompression (MVR) heat pump and thermal integration ...Due to the high energy consumption for separation of salt containing methanol wastewater, in this work, the multi-effect evaporation coupled with mechanical vapor recompression (MVR) heat pump and thermal integration technologies were raised for the first time. The ELECNRTL thermodynamic model is used to simulate and optimize the evaporation rectification process. Energy consumption and total annual cost (TAC) are taken as objective functions. The results show that multi-effect evaporation coupled with conventional distillation process can save energy consumption and TAC by 44.12% and 39.14%. The multi-effect evaporation coupled with distillation process based on MVR heat pump technology can save energy consumption and TAC by 55.27% and 47.49%, which is super to three-effect evaporation coupled with conventional distillation process. The three-effect evaporation coupled with MVR heat integration process can save energy consumption and TAC by 81.32% and 58.55%, which is more economical than other processes. It can be clearly seen that three-effect evaporation coupled with MVR heat integration process is more competitive to deal with the salt containing methanol wastewater.展开更多
Photocatalysis-assisted removal of uranium has been proven as an effective method for the elimination of radioactive pollution from wastewater.In this work,carbon nitride materials were synthesized in potassium hydrox...Photocatalysis-assisted removal of uranium has been proven as an effective method for the elimination of radioactive pollution from wastewater.In this work,carbon nitride materials were synthesized in potassium hydroxide(KOH)molten salt and applied to photocatalytic uranyl extraction.Obtained materials were confirmed to possess the triazine-s-heptazine structure by NMR,XPS and UV-Vis characterization,and exhibited a wider visible light absorption than graphitic carbon nitride(g-C_(3)N_(4)).The photocatalytic activity of the carbon nitride materials was tailored by varying the precursor mass fractions.The carbon nitride obtained at 80%melamine as precursor(K-CN-80)exhibited the highest photocatalytic extraction ability and its photocatalytic reaction rate is 6.6 times faster than that of g-C_(3)N_(4).The influence of sacrificial agents was studied and the results showed that triethanolamine inhibited U(Ⅵ)photoreduction,but methanol can accelerate U(Ⅵ)photoreduction by consuming photogenerated holes.This unary KOH molten salt synthesis method has exceptional potential applications in the preparation of carbon nitrides,and the obtained products showed potential in extracting U(Ⅵ)from aqueous solutions for use in nuclear fuel industry and for U(Ⅵ)environmental pollution cleanup.展开更多
Investigation was made on the efficiency of two commercial membranes in removing via forward osmosis(FO)the low molecular weight organic compounds typical of coking wastewater. The membranes were supplied by Poten and...Investigation was made on the efficiency of two commercial membranes in removing via forward osmosis(FO)the low molecular weight organic compounds typical of coking wastewater. The membranes were supplied by Poten and HTI companies. The organics in the simulated coking water were indole and pyrridine. Under FO mode, the rejection to the organics by Poten membrane was around 50%, whereas that for HTI membrane was obviously higher, ranging from 65% to 74%. The response of the two membranes in terms of Water flux and reverse salt flux(RSF) towards changing feed/draw solution(DS) flow rates in FO mode showed similar tendency,but different degree. Generally, the flux in FO using HTI membranes was lower. For HTI membrane, FO operated with pressure retarded osmosis(PRO) mode was also performed and the overall rejection of the organics was slightly lower than that in FO mode. In the long term FO test within 15 days, both Poten and HTI membranes displayed flux reduction and rejection enhancement. But the variation with Poten membrane was much more obvious. Discussion was carried out about the reasons and the mechanisms behind the FO performance difference between two membranes and the variation in flux and rejection with operation conditions. Characterizations by SEM, FTIR, AFM, XRD and XPS were tried to support the proposed explanations.展开更多
[ Objective ] The study aimed to discuss the optimal conditions for the treatment of enzymolysis wastewater by centrifugation - coagu- lation - Fenton reagent oxidation - adsorption process. [ Metbod] According to the...[ Objective ] The study aimed to discuss the optimal conditions for the treatment of enzymolysis wastewater by centrifugation - coagu- lation - Fenton reagent oxidation - adsorption process. [ Metbod] According to the water-quality characteristics of wastewater from a heparin so- dium production factory of Jiangsu Province, enzymolysis wastewater was segregated from intestinal lavage wastewater and treated through cen- trifugation- coagulation- Fenton reagent oxidation-adsorption process, and the optimal technical parameters were determined. E Resultl After enzymolysis wastewater was centrifuged at a speed of 4 000 rpm, 0.6 g/L CTS as the coagulant was added to the supematant. Hereafter, pH of the coagulated effluent was adjusted to 3, and then 1.5% (V/V) H2O2 was added to the coagulated effluent; a certain amount of ferrous sul- fate (n H2O2-.n FeSO4 . 7H2O =8:1 ) was added to the mixture; the reaction conducted for 30 min, and then solution pH was adjusted to about 9. Finally, the oxidized effluent flowed through a resin red until the adsorptive capacity reached 240 BV, and COD of the effluent water was lower than 100 mg/L, meeting the Grade-I standard of Comprehensive Discharge Standard of Sewage (GB8978-1996). [Condusio] The research could provide a new process for the treatment of enzymolysis wastewater.展开更多
Based on the characteristics of pickling wastewater in the cold-rolling production of stainless steel, a new processing route, featuring source sludge reduction, wastewater two-stage treatment, heavy metal-contained s...Based on the characteristics of pickling wastewater in the cold-rolling production of stainless steel, a new processing route, featuring source sludge reduction, wastewater two-stage treatment, heavy metal-contained sludge and calcium salt sludge separating recovery, was proposed. As shown by the research results, after the two-stage process treatment, the effluent water can steadily reach the emission standards, the sludge yield can be decreased by more than 8% ; within the heavy metal-contained sludge, the recovery rates of Fc,Cr and Ni can either reach or surpass 95% ,and the total content ofF and S can drop to around 3%. Therefore,the sludge in the front part can be used as ferric dust. In the calcium salt sludge ,the recovery rate of F can either reach or surpass 85% ,and the total contents of Fe,Cr and Ni can fall below 0.5%. So the sludge in the rear part can be used as fluorgypsum or fluorite. Meanwhile,the results of the analysis on heavy metals leaching toxicity and morphologic distribution indicate that the two kinds of sectionalized sludge are not classified as hazardous wastes, which have a stable behavior and better utilization values compared with the former mixed- sludge.展开更多
基金supported by the National Natural Science Foundation of China(Grant No.51868029)the Yunnan Applied Basic Research Projects(Grant No.2016FB093)
文摘Hydroxyquinone compounds, such as 1,4-dihydroxyanthraquinone and alizarin sulfonate, are widely used in dye manufacturing, pharmaceutical manufacturing, and other industries. However, the treatment of hydroxyquinone-containing wastewater has seldom been examined. This study used a precipitation method with barium salt to treat nano-silver industrial wastewater. The results show that barium chloride was a suitable reagent for significantly degrading COD and color from nano-silver wastewater. When the initial pH value was 10.5, 8 g of BaCl2·2H2O were added to 100 mL of wastewater. After reaction at 15℃ for 1 h, the removal efficiencies of COD and color in the nano-silver wastewater were 85.6% and 97.1%, respectively. Simulated wastewater containing sodium alizarin-3-sulfonate (ARS) or purpurin was used to further investigate the removal mechanism of hydroxyquinone compounds. Fourier transform infrared spectroscopy, X-ray diffraction, and some related experiments showed that hydroxyquinone compounds can directly react with barium ions in the solution so as to transfer from wastewater to precipitate. In addition, the newly produced barium sulfate particles have positive surface charges, which can improve the removal efficiency of hydroxyquinone compounds due to electrostatic attraction.
文摘Due to the high energy consumption for separation of salt containing methanol wastewater, in this work, the multi-effect evaporation coupled with mechanical vapor recompression (MVR) heat pump and thermal integration technologies were raised for the first time. The ELECNRTL thermodynamic model is used to simulate and optimize the evaporation rectification process. Energy consumption and total annual cost (TAC) are taken as objective functions. The results show that multi-effect evaporation coupled with conventional distillation process can save energy consumption and TAC by 44.12% and 39.14%. The multi-effect evaporation coupled with distillation process based on MVR heat pump technology can save energy consumption and TAC by 55.27% and 47.49%, which is super to three-effect evaporation coupled with conventional distillation process. The three-effect evaporation coupled with MVR heat integration process can save energy consumption and TAC by 81.32% and 58.55%, which is more economical than other processes. It can be clearly seen that three-effect evaporation coupled with MVR heat integration process is more competitive to deal with the salt containing methanol wastewater.
基金financially supported by the National Natural Science Foundation of China(Nos.22376059 and 21976104)the Young Elite Scientists Sponsorship Program of China Association for Science and Technology(No.2021QNRC001)the Brain Pool program funded by the Ministry of Science and ICT through the National Research Foundation of Korea(No.NRF-2022H1D3A2A02051548).
文摘Photocatalysis-assisted removal of uranium has been proven as an effective method for the elimination of radioactive pollution from wastewater.In this work,carbon nitride materials were synthesized in potassium hydroxide(KOH)molten salt and applied to photocatalytic uranyl extraction.Obtained materials were confirmed to possess the triazine-s-heptazine structure by NMR,XPS and UV-Vis characterization,and exhibited a wider visible light absorption than graphitic carbon nitride(g-C_(3)N_(4)).The photocatalytic activity of the carbon nitride materials was tailored by varying the precursor mass fractions.The carbon nitride obtained at 80%melamine as precursor(K-CN-80)exhibited the highest photocatalytic extraction ability and its photocatalytic reaction rate is 6.6 times faster than that of g-C_(3)N_(4).The influence of sacrificial agents was studied and the results showed that triethanolamine inhibited U(Ⅵ)photoreduction,but methanol can accelerate U(Ⅵ)photoreduction by consuming photogenerated holes.This unary KOH molten salt synthesis method has exceptional potential applications in the preparation of carbon nitrides,and the obtained products showed potential in extracting U(Ⅵ)from aqueous solutions for use in nuclear fuel industry and for U(Ⅵ)environmental pollution cleanup.
基金National Natural Science Foundation of China(Project no.21176265)Hunan Provincial Science and Technology Plan(Project no.2014GK3106).
文摘Investigation was made on the efficiency of two commercial membranes in removing via forward osmosis(FO)the low molecular weight organic compounds typical of coking wastewater. The membranes were supplied by Poten and HTI companies. The organics in the simulated coking water were indole and pyrridine. Under FO mode, the rejection to the organics by Poten membrane was around 50%, whereas that for HTI membrane was obviously higher, ranging from 65% to 74%. The response of the two membranes in terms of Water flux and reverse salt flux(RSF) towards changing feed/draw solution(DS) flow rates in FO mode showed similar tendency,but different degree. Generally, the flux in FO using HTI membranes was lower. For HTI membrane, FO operated with pressure retarded osmosis(PRO) mode was also performed and the overall rejection of the organics was slightly lower than that in FO mode. In the long term FO test within 15 days, both Poten and HTI membranes displayed flux reduction and rejection enhancement. But the variation with Poten membrane was much more obvious. Discussion was carried out about the reasons and the mechanisms behind the FO performance difference between two membranes and the variation in flux and rejection with operation conditions. Characterizations by SEM, FTIR, AFM, XRD and XPS were tried to support the proposed explanations.
基金Supported by the Project of Practical Innovation Training Program of Undergraduates in Jiangsu Province in 2012(232)Project of Visiting Engineers of Nanjing College of Chemical Technology in 2012
文摘[ Objective ] The study aimed to discuss the optimal conditions for the treatment of enzymolysis wastewater by centrifugation - coagu- lation - Fenton reagent oxidation - adsorption process. [ Metbod] According to the water-quality characteristics of wastewater from a heparin so- dium production factory of Jiangsu Province, enzymolysis wastewater was segregated from intestinal lavage wastewater and treated through cen- trifugation- coagulation- Fenton reagent oxidation-adsorption process, and the optimal technical parameters were determined. E Resultl After enzymolysis wastewater was centrifuged at a speed of 4 000 rpm, 0.6 g/L CTS as the coagulant was added to the supematant. Hereafter, pH of the coagulated effluent was adjusted to 3, and then 1.5% (V/V) H2O2 was added to the coagulated effluent; a certain amount of ferrous sul- fate (n H2O2-.n FeSO4 . 7H2O =8:1 ) was added to the mixture; the reaction conducted for 30 min, and then solution pH was adjusted to about 9. Finally, the oxidized effluent flowed through a resin red until the adsorptive capacity reached 240 BV, and COD of the effluent water was lower than 100 mg/L, meeting the Grade-I standard of Comprehensive Discharge Standard of Sewage (GB8978-1996). [Condusio] The research could provide a new process for the treatment of enzymolysis wastewater.
文摘Based on the characteristics of pickling wastewater in the cold-rolling production of stainless steel, a new processing route, featuring source sludge reduction, wastewater two-stage treatment, heavy metal-contained sludge and calcium salt sludge separating recovery, was proposed. As shown by the research results, after the two-stage process treatment, the effluent water can steadily reach the emission standards, the sludge yield can be decreased by more than 8% ; within the heavy metal-contained sludge, the recovery rates of Fc,Cr and Ni can either reach or surpass 95% ,and the total content ofF and S can drop to around 3%. Therefore,the sludge in the front part can be used as ferric dust. In the calcium salt sludge ,the recovery rate of F can either reach or surpass 85% ,and the total contents of Fe,Cr and Ni can fall below 0.5%. So the sludge in the rear part can be used as fluorgypsum or fluorite. Meanwhile,the results of the analysis on heavy metals leaching toxicity and morphologic distribution indicate that the two kinds of sectionalized sludge are not classified as hazardous wastes, which have a stable behavior and better utilization values compared with the former mixed- sludge.