The corrosion behavior of 316H stainless steel(SS)in the impure and purified Na Cl–KCl–Mg Cl_(2) salt was investigated at700°C.Results indicate that the main deleterious impurity induced corrosion in the impure...The corrosion behavior of 316H stainless steel(SS)in the impure and purified Na Cl–KCl–Mg Cl_(2) salt was investigated at700°C.Results indicate that the main deleterious impurity induced corrosion in the impure salt was the absorbed moisture,present in the form of Mg Cl_(2)·6H_(2)O.316H SS occurred severe intergranular corrosion with a corrosion depth of 130μm for1000 h in the impure Na Cl–KCl–Mg Cl_(2) salt.In contrast,the purification treatment of molten chloride salt by the dissolved Mg metal can remove the absorbed moisture,and the corresponding reactions were also discussed.As a result,the corrosiveness of Na Cl–KCl–Mg Cl_(2) salt is reduced significantly.316H SS occurred slight uniform corrosion with a depth of less than 5μm for 3000 h in the purified Na Cl–KCl–Mg Cl_(2) salt.展开更多
The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel substrates.The intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by usin...The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel substrates.The intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by using low-pressure cold spray (LPCS) method to improve the salt fog corrosion resistance properties of the supersonic plasma spray (SPS) NiCr-Cr_(3)C_(2) coatings.The friction and wear performance for the double-layer and single-layer NiCr-Cr_(3)C_(2) coatings were carried out by line-contact reciprocating sliding,respectively.Combined with the coating surface analysis techniques,the effect of the salt fog corrosion on the tribological properties of the double-layer coatings was studied.The results showed that the double-layer coatings exhibited better wear resistance than that of the single-layer coatings,due to the better corrosion resistance of the intermediate layer;the wear mass losses of the double-layer coatings was reduced by 70%than that of the single layer coatings and the wear mechanism of coatings after salt fog corrosion conditions is mainly corrosion wear.展开更多
Ceramic coatings were prepared on Ti-6Al-4V alloy in NaAlO2 solution by micro-plasma oxidation (MPO). The salt spray tests of the coated samples and the substrates were carded out in a salt spray test machine. The p...Ceramic coatings were prepared on Ti-6Al-4V alloy in NaAlO2 solution by micro-plasma oxidation (MPO). The salt spray tests of the coated samples and the substrates were carded out in a salt spray test machine. The phase composition and surface morphology of the coatings were investigated by XRD and SEAM. Severe corrosion occurred on the substrate surface, while there were no obvious corrosion phenomena on the coated samples. The coatings were composed of Al2TiO5 and a little α-Al2O3 and mille TiO2, and the salt spray test did not change the composition of the coatings. The weight loss rate of the coatings decreased with increasing MPO time because of the increase in density and thickness of the coatings. The surface morphology of the coatings was influenced by salt spray corrosion test. Among the coated samples, the coating prepared for 2 h has the best corrosion resistance under salt spray test.展开更多
The objective of the present work was to determine the influence of the neutral salt spray corrosion on the wear resistance of HVOF sprayed NiCr-Cr3C2 coating with intermediate layer. Ni-Zn-Al2O3 coatings as interlaye...The objective of the present work was to determine the influence of the neutral salt spray corrosion on the wear resistance of HVOF sprayed NiCr-Cr3C2 coating with intermediate layer. Ni-Zn-Al2O3 coatings as interlayers were prepared by low pressure cold spray(LPCS) between NiCr-Cr3C2 cermet coatings to form a sandwich structure to enhance the corrosion resistance properties. The tribological properties were examined using the UMT-3 fricition and wear tester by line-contact reciprocating sliding under dry and salt spray one week corrosion. The morphology, element distribution, and phase compositions of the coating and worn sufaces were analyzed by using scanning electron microscopy, energy dispersive spectrometry, and X-ray diffraction respectively. The corrosion behavior of the coating was studied by the open-circuit potential, the electrochemical impedance spectroscopy, potentiodynamic polarization, and salt spray corrosion methods. It is found that the sandwich structured coating has better corrosion resistance than the single layer coating. The results show that under dry wear conditions, the wear mechanism is abrasive and adhesive wear, whereas under salt spray corrosion conditions it becomes corrosion wear. The friction coefficient of the sandwich structured coating after salt spray corrosion is slightly lower than the dry friction coefficient, but the weight of the wear loss is lower than that under dry condition.展开更多
This study was designed to solve the problem of magnesium hazards due to potash extraction in the salt lake region.Using basalt fiber(BF)as the reinforcement material and magnesium oxychloride cement(MOC)as the gellin...This study was designed to solve the problem of magnesium hazards due to potash extraction in the salt lake region.Using basalt fiber(BF)as the reinforcement material and magnesium oxychloride cement(MOC)as the gelling material,a BF/MOC composite material was prepared.Firstly,the effect of BF addition content on the basic mechanical properties of the composites was investigated.Then,through the salt spray corrosion test,the durability damage deterioration evaluation analysis was carried out from both macroscopic and microscopic aspects using mass change,relative dynamic modulus of elasticity(RDME)change,SEM analysis and FT-IR analysis.Finally,a GM(1,1)-Markov model was established to predict the durability life of composite materials by using durability evaluation indicators.The results show that:when the BF content is 0.10%(by volumetric content),the composites have the best mechanical properties and resistance to salt spray corrosion.However,when the volume of BF content exceeds 0.10%,a large number of magnesium salt crystallization products are observed from the microscopic point of view,and the corrosion of the main strength phase of MOC is more serious.The prediction results of the GM(1,1)-Markov model are highly identical with the raw data.In addition,using the change of RDME as a predictor,RDME is more sensitive to environmental factor compared to the change of mass.Predictions using the change of RDME as a threshold indicate that MOC-BF0.10 has the longest durability life,which is 836 days.The model is important to promote the application of MOC composites in the salt lake region and to promote the healthy development of green building materials.展开更多
The corrosion failure mechanism of M152 was studied using the neutral salt-spray test to better understand the corrosion behavior of 1Cr12Ni3Mo2VN(M152), provide a basis for the optimization of material selection, a...The corrosion failure mechanism of M152 was studied using the neutral salt-spray test to better understand the corrosion behavior of 1Cr12Ni3Mo2VN(M152), provide a basis for the optimization of material selection, and prevent the occurrence of failure. Moreover, the mechanism was investigated using the mass loss method, polarization curves, electrochemical impedance spectroscopy(EIS), stereology microscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy(EDS). The results show that M152 steel suffers severe corrosion, especially pitting corrosion, in a high-salt-spray environment. In the early stage of the experiment, the color of the corrosion products was mainly orange. The products then gradually evolved into a dense, brown substance, which coincided with a decrease of corrosion rate. Correspondingly, the EIS spectrum of M152 in the late test also exhibited three time constants and presented Warburg impedance at low frequencies.展开更多
From a safety point of view, it is important to study the damages and reliability of molten salt reactor structural alloy materials, which are subjected to extreme environments due to neutron irradiation, molten salt ...From a safety point of view, it is important to study the damages and reliability of molten salt reactor structural alloy materials, which are subjected to extreme environments due to neutron irradiation, molten salt corrosion, fission product attacks, thermal stress, and even combinations of these. In the past few years, synchrotron radiation-based materials characterization techniques have proven to be effective in revealing the microstructural evolution and failure mechanisms of the alloys under surrogating operation conditions. Here, we review the recent progress in the investigations of molten salt corrosion,tellurium(Te) corrosion, and alloy design. The valence states and distribution of chromium(Cr) atoms, and the diffusion and local atomic structure of Te atoms near the surface of corroded alloys have been investigated using synchrotron radiation techniques, which considerably deepen the understandings on the molten salt and Te corrosion behaviors. Furthermore, the structure and size distribution of the second phases in the alloys have been obtained, which are helpful for the future development of new alloy materials.展开更多
The ammonium salt corrosion is a typical failure mode for the hydrogenation reaction effluent air cooler(REAC) system. In order to investigate the corrosion characteristics in the REAC system, numerical simulations we...The ammonium salt corrosion is a typical failure mode for the hydrogenation reaction effluent air cooler(REAC) system. In order to investigate the corrosion characteristics in the REAC system, numerical simulations were performed by using the mixture model, the heating transfer model, and the particles tracking model. The results show that the differences between the temperature and the velocity at each cross section of the first-row and second-row tubes are small. The inertia of the particles plays an important role in the particle’s deposition, and the smaller particles distribute more uniformly in the air cooler. However, for larger particles, they prefer falling from the inner side of the vertical elbow, and preferentially depositing at the inlet header and pipes before saturation. In the heat exchanger tubes, the particle deposition number is larger in the second-row tubes than that in the first-row tubes, and the high-risk tubes mainly concentrate on the middle and right side of the air cooler. The kinetic parameters of the particles are in accordance with the blocking-prone position in many real operating conditions.展开更多
Reinforcement corrosion directly affects the mechanical behavior of reinforced concrete structures.An electric corrosion test was conducted on a reinforced concrete test specimen,and a finite element model of the rein...Reinforcement corrosion directly affects the mechanical behavior of reinforced concrete structures.An electric corrosion test was conducted on a reinforced concrete test specimen,and a finite element model of the reinforcement corrosion damage was established.In addition,the damage behavior of reinforced concrete under different corrosion sediment distribution characteristics and different corrosion rates was studied.It was noted that when corrosion sediments are in a“semiellipse+semicircle”distribution,the results of numerical calculation are consistent with those obtained experimentally,reflecting the damage characteristics of reinforced concrete test specimens.Further,the results showed that the distribution characteristics of corrosion sediments greatly influence the damage behavior of reinforced concrete.In particular,when the corrosion sediments demonstrate a“semiellipse”distribution,reinforced concrete members may easily suffer from reinforcement damages.In the case of“semiellipse+semicircle”and“circle”distributions,the cohesive force between the reinforcements and concrete decreases:With the same corrosion rate,the damaged area expands with the increase in the number of reinforcements,which indicates a reduction in the cohesive force and thus,a reduction in the damage in the reinforcement area.This paper analyzes in-depth the effects of reinforcement corrosion expansion on the concrete damage behavior,provides references for practical engineering.展开更多
The corrosion behavior of ZL104 alloy at different states (as-cast and heattreatment) in salt spray corrosion (SSC) was studied. The results show that the sample treated afterrefinement and modification has the least ...The corrosion behavior of ZL104 alloy at different states (as-cast and heattreatment) in salt spray corrosion (SSC) was studied. The results show that the sample treated afterrefinement and modification has the least corrosive resistance compared with the sample bearingas-cast structure at the beginning of the corrosion. As the corrosion process continued, however,the trend reversed itself. After 44 h continuous corrosion, the corrosive rates of all samples tendto be stable. After experiments, the sample bearing as-cast structure had the most corrosiveproducts on the surface whereas the sample being refined and modified had the least products. TheFourier transformation infrared spectroscopy (FTIR) analyses of the corrosion products show thatthese products are composed of hydroxyl-containing substances.展开更多
Galvanic corrosion on samples of AZ91D magnesium alloy coupled with 2A12 aluminum alloy during neutral salt spray test was investigated.The variations of the surface potential were measured using scanning kelvin probe...Galvanic corrosion on samples of AZ91D magnesium alloy coupled with 2A12 aluminum alloy during neutral salt spray test was investigated.The variations of the surface potential were measured using scanning kelvin probe(SKP).The results showed that galvanic effect on the corrosion of AZ91D magnesium alloy is closely related to the potential difference between the anodic and cathodic materials.In the initial period,corrosion only occurred in a narrow area at the coupling interface because of the limited distance galvanic current.Then,the corrosion rate of 2A12 aluminum alloy was accelerated due to its poor stability in strong alkali environment,which was attributed to the strong alkalization caused by the corrosion of AZ91D magnesium alloy.With the increase of the potential of 2A12 aluminum alloy as a result of the continuous covering of corrosion products,the potential difference between the two materials was enlarged,which enhanced the galvanic corrosion.展开更多
Carbon fiber-reinforced silicon carbide(C/SiC) composites are significantly important candidates for thermal protection materials. The corrosion mechanism of C/SiC composite materials is the basis of their optimizatio...Carbon fiber-reinforced silicon carbide(C/SiC) composites are significantly important candidates for thermal protection materials. The corrosion mechanism of C/SiC composite materials is the basis of their optimization and application. In this study, structural evolution of C/SiC composites fabricated by chemical vapor infiltration was investigated in the salt-fog storage environment. Furthermore, the effect of salt-fog on their ablation behaviors under oxyacetylene flame environment was studied. The ablation morphologies and corrosion mechanisms of C/SiC composites were analyzed and discussed. The results indicated that silica layer with size of c.a. 20 nm was formed on the surface of composite. The extent of corrosion in salt fog was limited, and it had little effect on the ablation behavior of the C/SiC composites,as well on the tensile strength and bending strength.展开更多
The commercialisation of molten salts reactors(MSRs)is hindered by the lack of structural materials capable of withstanding the corrosive environment therein.To address this problem,we herein prepared1 wt%Y_(2)O_(3)md...The commercialisation of molten salts reactors(MSRs)is hindered by the lack of structural materials capable of withstanding the corrosive environment therein.To address this problem,we herein prepared1 wt%Y_(2)O_(3)mdispersion-strengthened Ni Mo-based alloys using powder metallurgy and evaluated their potential as structural materials for MSRs based on their mechanical properties,He swelling behaviour,and molten salt corrosion resistance.In view of the strengthening provided by homogenously dispersed Y_(2)O_(3)particles,all NiMo-Y_(2)O_(3)samples exhibited ultimate tensile strengths and yield strengths exceeding those of the Hastelloy N alloy,a state-of-the-art structural material for MSRs.Moreover,the volume fraction of He bubbles in the NiMo-Y_(2)O_(3)samples(~0.3%)was lower than that in the Hastelloy N alloy(0.58%),which showed that the introduction of Y_(2)O_(3)nanoparticles effectively inhibited He swelling.All NiMo-Y_(2)O_(3)samples showed excellent resistance to molten salt corrosion(as reflected by the absence of obvious holes therein),thus holding great promise for the development of irradiation-and molten salt corrosion-resistant structural materials for high-temperature MSRs.展开更多
It is imperative to develop multifunctional erosion and corrosion resistant coatings for compressor blades of aircraft engines in harsh environment.PVD(Physical Vapor Deposition)technology has the advances in processi...It is imperative to develop multifunctional erosion and corrosion resistant coatings for compressor blades of aircraft engines in harsh environment.PVD(Physical Vapor Deposition)technology has the advances in processing erosion-resistant coatings;however,the performance of PVD coatings to combat corrosion depends on various coating defects.Determining and comparing the corrosion performances of PVD TiN/Ti coating and uncoated TC4 alloy was the main objective of present work.The 960 h salt spray corrosion and 116 h hot corrosion tests were conducted to simulate the grounding and working environments of the aircraft compressors.The corrosion mechanisms due to the coating defects such as pinhole,columnar boundary and large grain were analyzed based on the OM,Confocal microscope,electrochemical measurements,SEM,XRD and EDS results.Owing to the disordered state associated with the columnar boundary and the coating defect,nitrogen could be easily replaced by oxygen in the hot corrosion process,these structures were channels for fast diffusion of oxygen.Moreover,the Gibbs energy changes of Ti oxidation and TiN oxidation were thermodynamically calculated according to the working condition of aircraft compressors,and considerable research effort was focused on mapping out the phase diagram of Ti,TiN and high pressure gases.The findings of this research can provide insights into developing multifunctional coatings for future aircraft engines.展开更多
基金supported by the National Science Foundation of Shanghai(No.22ZR1474600)the National Natural Science Foundation of China(No.12175302)+1 种基金the“Thorium Molten Salt Reactor Nuclear Energy System”Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA 02040000)the“Transformational Technologies for Clean Energy and Demonstration,”Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA 21000000)。
文摘The corrosion behavior of 316H stainless steel(SS)in the impure and purified Na Cl–KCl–Mg Cl_(2) salt was investigated at700°C.Results indicate that the main deleterious impurity induced corrosion in the impure salt was the absorbed moisture,present in the form of Mg Cl_(2)·6H_(2)O.316H SS occurred severe intergranular corrosion with a corrosion depth of 130μm for1000 h in the impure Na Cl–KCl–Mg Cl_(2) salt.In contrast,the purification treatment of molten chloride salt by the dissolved Mg metal can remove the absorbed moisture,and the corresponding reactions were also discussed.As a result,the corrosiveness of Na Cl–KCl–Mg Cl_(2) salt is reduced significantly.316H SS occurred slight uniform corrosion with a depth of less than 5μm for 3000 h in the purified Na Cl–KCl–Mg Cl_(2) salt.
基金Fundamental Research Funds for Central Universities Project (No. 1CX05021A)Shandong Provincial Key R&D Plan Project (No. 2GHY15108)Shandong Postdoctoral Innovation Project and Qingdao Postdoctoral Applied Research Project。
文摘The double-layer NiCr-Cr_(3)C_(2)/Ni-Zn-Al_(2)O_(3) coatings with sufficient corrosion and wear resistance were prepared on low carbon steel substrates.The intermediate layers Ni-Zn-Al_(2)O_(3) were fabricated by using low-pressure cold spray (LPCS) method to improve the salt fog corrosion resistance properties of the supersonic plasma spray (SPS) NiCr-Cr_(3)C_(2) coatings.The friction and wear performance for the double-layer and single-layer NiCr-Cr_(3)C_(2) coatings were carried out by line-contact reciprocating sliding,respectively.Combined with the coating surface analysis techniques,the effect of the salt fog corrosion on the tribological properties of the double-layer coatings was studied.The results showed that the double-layer coatings exhibited better wear resistance than that of the single-layer coatings,due to the better corrosion resistance of the intermediate layer;the wear mass losses of the double-layer coatings was reduced by 70%than that of the single layer coatings and the wear mechanism of coatings after salt fog corrosion conditions is mainly corrosion wear.
基金the National Natural Science Foundation of China (No. 50171026)the Natu-ral Science Foundation of Heilongjiang Province, China (No. E2007-36).
文摘Ceramic coatings were prepared on Ti-6Al-4V alloy in NaAlO2 solution by micro-plasma oxidation (MPO). The salt spray tests of the coated samples and the substrates were carded out in a salt spray test machine. The phase composition and surface morphology of the coatings were investigated by XRD and SEAM. Severe corrosion occurred on the substrate surface, while there were no obvious corrosion phenomena on the coated samples. The coatings were composed of Al2TiO5 and a little α-Al2O3 and mille TiO2, and the salt spray test did not change the composition of the coatings. The weight loss rate of the coatings decreased with increasing MPO time because of the increase in density and thickness of the coatings. The surface morphology of the coatings was influenced by salt spray corrosion test. Among the coated samples, the coating prepared for 2 h has the best corrosion resistance under salt spray test.
基金Funded by the High-Tech Research and Development Program of China(No.2012AA09A203)the Fundmental Research Funds for the Central Universities(No.15CX06061A)the Postgraduate Innovation Project of China University of Petroleum(East China)(No.YCXJ2016059)
文摘The objective of the present work was to determine the influence of the neutral salt spray corrosion on the wear resistance of HVOF sprayed NiCr-Cr3C2 coating with intermediate layer. Ni-Zn-Al2O3 coatings as interlayers were prepared by low pressure cold spray(LPCS) between NiCr-Cr3C2 cermet coatings to form a sandwich structure to enhance the corrosion resistance properties. The tribological properties were examined using the UMT-3 fricition and wear tester by line-contact reciprocating sliding under dry and salt spray one week corrosion. The morphology, element distribution, and phase compositions of the coating and worn sufaces were analyzed by using scanning electron microscopy, energy dispersive spectrometry, and X-ray diffraction respectively. The corrosion behavior of the coating was studied by the open-circuit potential, the electrochemical impedance spectroscopy, potentiodynamic polarization, and salt spray corrosion methods. It is found that the sandwich structured coating has better corrosion resistance than the single layer coating. The results show that under dry wear conditions, the wear mechanism is abrasive and adhesive wear, whereas under salt spray corrosion conditions it becomes corrosion wear. The friction coefficient of the sandwich structured coating after salt spray corrosion is slightly lower than the dry friction coefficient, but the weight of the wear loss is lower than that under dry condition.
基金the financial support provided by National Natural Science Foundation of China(Grant Nos.52178216,51868044).
文摘This study was designed to solve the problem of magnesium hazards due to potash extraction in the salt lake region.Using basalt fiber(BF)as the reinforcement material and magnesium oxychloride cement(MOC)as the gelling material,a BF/MOC composite material was prepared.Firstly,the effect of BF addition content on the basic mechanical properties of the composites was investigated.Then,through the salt spray corrosion test,the durability damage deterioration evaluation analysis was carried out from both macroscopic and microscopic aspects using mass change,relative dynamic modulus of elasticity(RDME)change,SEM analysis and FT-IR analysis.Finally,a GM(1,1)-Markov model was established to predict the durability life of composite materials by using durability evaluation indicators.The results show that:when the BF content is 0.10%(by volumetric content),the composites have the best mechanical properties and resistance to salt spray corrosion.However,when the volume of BF content exceeds 0.10%,a large number of magnesium salt crystallization products are observed from the microscopic point of view,and the corrosion of the main strength phase of MOC is more serious.The prediction results of the GM(1,1)-Markov model are highly identical with the raw data.In addition,using the change of RDME as a predictor,RDME is more sensitive to environmental factor compared to the change of mass.Predictions using the change of RDME as a threshold indicate that MOC-BF0.10 has the longest durability life,which is 836 days.The model is important to promote the application of MOC composites in the salt lake region and to promote the healthy development of green building materials.
基金financially supported by the Major State Basic Research Development Program of China (No. 2014CB643300)
文摘The corrosion failure mechanism of M152 was studied using the neutral salt-spray test to better understand the corrosion behavior of 1Cr12Ni3Mo2VN(M152), provide a basis for the optimization of material selection, and prevent the occurrence of failure. Moreover, the mechanism was investigated using the mass loss method, polarization curves, electrochemical impedance spectroscopy(EIS), stereology microscopy, scanning electron microscopy, and energy-dispersive X-ray spectroscopy(EDS). The results show that M152 steel suffers severe corrosion, especially pitting corrosion, in a high-salt-spray environment. In the early stage of the experiment, the color of the corrosion products was mainly orange. The products then gradually evolved into a dense, brown substance, which coincided with a decrease of corrosion rate. Correspondingly, the EIS spectrum of M152 in the late test also exhibited three time constants and presented Warburg impedance at low frequencies.
基金supported by the National key research and development program of China(Nos.2016YFB0700401 and 2016YFB0700404)Natural Science Foundation of Shanghai(Nos.19ZR1468200 and 18ZR1448000)+2 种基金National Natural Science Foundation of China(Nos.51671154,51601213 and 51671122)Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA02004210)Youth Innovation Promotion Association,Chinese Academy of Science(No.2019264)
文摘From a safety point of view, it is important to study the damages and reliability of molten salt reactor structural alloy materials, which are subjected to extreme environments due to neutron irradiation, molten salt corrosion, fission product attacks, thermal stress, and even combinations of these. In the past few years, synchrotron radiation-based materials characterization techniques have proven to be effective in revealing the microstructural evolution and failure mechanisms of the alloys under surrogating operation conditions. Here, we review the recent progress in the investigations of molten salt corrosion,tellurium(Te) corrosion, and alloy design. The valence states and distribution of chromium(Cr) atoms, and the diffusion and local atomic structure of Te atoms near the surface of corroded alloys have been investigated using synchrotron radiation techniques, which considerably deepen the understandings on the molten salt and Te corrosion behaviors. Furthermore, the structure and size distribution of the second phases in the alloys have been obtained, which are helpful for the future development of new alloy materials.
基金supported by the National Key R&D Program of China(Grant No.2017YFF0210403)the Zhejiang Provincial Natural Science Foundation of China(Grant No.LY17E060008)the Talent Project of Zhejiang Association for Science and Development Project of SINOPEC(No.318023-2)
文摘The ammonium salt corrosion is a typical failure mode for the hydrogenation reaction effluent air cooler(REAC) system. In order to investigate the corrosion characteristics in the REAC system, numerical simulations were performed by using the mixture model, the heating transfer model, and the particles tracking model. The results show that the differences between the temperature and the velocity at each cross section of the first-row and second-row tubes are small. The inertia of the particles plays an important role in the particle’s deposition, and the smaller particles distribute more uniformly in the air cooler. However, for larger particles, they prefer falling from the inner side of the vertical elbow, and preferentially depositing at the inlet header and pipes before saturation. In the heat exchanger tubes, the particle deposition number is larger in the second-row tubes than that in the first-row tubes, and the high-risk tubes mainly concentrate on the middle and right side of the air cooler. The kinetic parameters of the particles are in accordance with the blocking-prone position in many real operating conditions.
基金We appreciate the support from National Natural Science Foundation of China Projects(Numbers 11672101,11372099 and 11132003)National Key Research and Development Program Project(Number:2017YFC1502603)Natural Science Foundation of Jiangsu Province(Number:BK20151493).
文摘Reinforcement corrosion directly affects the mechanical behavior of reinforced concrete structures.An electric corrosion test was conducted on a reinforced concrete test specimen,and a finite element model of the reinforcement corrosion damage was established.In addition,the damage behavior of reinforced concrete under different corrosion sediment distribution characteristics and different corrosion rates was studied.It was noted that when corrosion sediments are in a“semiellipse+semicircle”distribution,the results of numerical calculation are consistent with those obtained experimentally,reflecting the damage characteristics of reinforced concrete test specimens.Further,the results showed that the distribution characteristics of corrosion sediments greatly influence the damage behavior of reinforced concrete.In particular,when the corrosion sediments demonstrate a“semiellipse”distribution,reinforced concrete members may easily suffer from reinforcement damages.In the case of“semiellipse+semicircle”and“circle”distributions,the cohesive force between the reinforcements and concrete decreases:With the same corrosion rate,the damaged area expands with the increase in the number of reinforcements,which indicates a reduction in the cohesive force and thus,a reduction in the damage in the reinforcement area.This paper analyzes in-depth the effects of reinforcement corrosion expansion on the concrete damage behavior,provides references for practical engineering.
基金The work was financially supported by the Open Laboratory Funds ofTsinghua University.
文摘The corrosion behavior of ZL104 alloy at different states (as-cast and heattreatment) in salt spray corrosion (SSC) was studied. The results show that the sample treated afterrefinement and modification has the least corrosive resistance compared with the sample bearingas-cast structure at the beginning of the corrosion. As the corrosion process continued, however,the trend reversed itself. After 44 h continuous corrosion, the corrosive rates of all samples tendto be stable. After experiments, the sample bearing as-cast structure had the most corrosiveproducts on the surface whereas the sample being refined and modified had the least products. TheFourier transformation infrared spectroscopy (FTIR) analyses of the corrosion products show thatthese products are composed of hydroxyl-containing substances.
基金Funded by the National Natural Science Foundation of China(No.51271032)
文摘Galvanic corrosion on samples of AZ91D magnesium alloy coupled with 2A12 aluminum alloy during neutral salt spray test was investigated.The variations of the surface potential were measured using scanning kelvin probe(SKP).The results showed that galvanic effect on the corrosion of AZ91D magnesium alloy is closely related to the potential difference between the anodic and cathodic materials.In the initial period,corrosion only occurred in a narrow area at the coupling interface because of the limited distance galvanic current.Then,the corrosion rate of 2A12 aluminum alloy was accelerated due to its poor stability in strong alkali environment,which was attributed to the strong alkalization caused by the corrosion of AZ91D magnesium alloy.With the increase of the potential of 2A12 aluminum alloy as a result of the continuous covering of corrosion products,the potential difference between the two materials was enlarged,which enhanced the galvanic corrosion.
文摘Carbon fiber-reinforced silicon carbide(C/SiC) composites are significantly important candidates for thermal protection materials. The corrosion mechanism of C/SiC composite materials is the basis of their optimization and application. In this study, structural evolution of C/SiC composites fabricated by chemical vapor infiltration was investigated in the salt-fog storage environment. Furthermore, the effect of salt-fog on their ablation behaviors under oxyacetylene flame environment was studied. The ablation morphologies and corrosion mechanisms of C/SiC composites were analyzed and discussed. The results indicated that silica layer with size of c.a. 20 nm was formed on the surface of composite. The extent of corrosion in salt fog was limited, and it had little effect on the ablation behavior of the C/SiC composites,as well on the tensile strength and bending strength.
基金supported by the National Natural Science Foundation of China(Grant Nos.11975304,12022515,11805261,11805256)Youth Innovation Promotion Association,Chinese Academy of Sciences(Grant No.Y202063)。
文摘The commercialisation of molten salts reactors(MSRs)is hindered by the lack of structural materials capable of withstanding the corrosive environment therein.To address this problem,we herein prepared1 wt%Y_(2)O_(3)mdispersion-strengthened Ni Mo-based alloys using powder metallurgy and evaluated their potential as structural materials for MSRs based on their mechanical properties,He swelling behaviour,and molten salt corrosion resistance.In view of the strengthening provided by homogenously dispersed Y_(2)O_(3)particles,all NiMo-Y_(2)O_(3)samples exhibited ultimate tensile strengths and yield strengths exceeding those of the Hastelloy N alloy,a state-of-the-art structural material for MSRs.Moreover,the volume fraction of He bubbles in the NiMo-Y_(2)O_(3)samples(~0.3%)was lower than that in the Hastelloy N alloy(0.58%),which showed that the introduction of Y_(2)O_(3)nanoparticles effectively inhibited He swelling.All NiMo-Y_(2)O_(3)samples showed excellent resistance to molten salt corrosion(as reflected by the absence of obvious holes therein),thus holding great promise for the development of irradiation-and molten salt corrosion-resistant structural materials for high-temperature MSRs.
基金supported by National Science and Technology Major Project of China(2017-VII-0012-0107)National Natural Science Foundation of China(No.51405506)Natural Science Basic Research Plan in Shaanxi Province of China(No.2019JQ-309)。
文摘It is imperative to develop multifunctional erosion and corrosion resistant coatings for compressor blades of aircraft engines in harsh environment.PVD(Physical Vapor Deposition)technology has the advances in processing erosion-resistant coatings;however,the performance of PVD coatings to combat corrosion depends on various coating defects.Determining and comparing the corrosion performances of PVD TiN/Ti coating and uncoated TC4 alloy was the main objective of present work.The 960 h salt spray corrosion and 116 h hot corrosion tests were conducted to simulate the grounding and working environments of the aircraft compressors.The corrosion mechanisms due to the coating defects such as pinhole,columnar boundary and large grain were analyzed based on the OM,Confocal microscope,electrochemical measurements,SEM,XRD and EDS results.Owing to the disordered state associated with the columnar boundary and the coating defect,nitrogen could be easily replaced by oxygen in the hot corrosion process,these structures were channels for fast diffusion of oxygen.Moreover,the Gibbs energy changes of Ti oxidation and TiN oxidation were thermodynamically calculated according to the working condition of aircraft compressors,and considerable research effort was focused on mapping out the phase diagram of Ti,TiN and high pressure gases.The findings of this research can provide insights into developing multifunctional coatings for future aircraft engines.