Bamnet Narong is located in northeastern Thailand (Chaiyaphum Province). It is the largest salt mine in the country and has been mined for decades. The landscape in this part of Thailand is characterised by a low plat...Bamnet Narong is located in northeastern Thailand (Chaiyaphum Province). It is the largest salt mine in the country and has been mined for decades. The landscape in this part of Thailand is characterised by a low plateau, which is called the Khorat Plateau. The plateau is divided into two basins by the Phu Phan Range, the Sakhon Nakhon Basin in the north and the Khorat Basin in the south. The analysed potashes and rock salts are deposited in the Maha Sarakham Formation, which represents the salt-bearing strata of the Khorat Basin. The stratigraphic age of this deposit has been debated since the late 1960’s. The assigned ages range from Mid-Cretaceous to Late Cretaceous and up to the Eocene. In this study different isotopic dating systems (Rb-Sr, Sr-Sr, K-Ar and K-Ca) were applied. The stratigraphic age for the time of deposition was confirmed to be Mid Cretaceous (Cenomanian). Furthermore, the homogeneity of the carnallites was investigated in order to trace a possible redistribution of rubidium.展开更多
A water/salt system in an evaporative environment is both a physicochemical region and a biological one. All the parameters of the system, such as the salinity, temperature and CO2 partial pressure, are affected by ha...A water/salt system in an evaporative environment is both a physicochemical region and a biological one. All the parameters of the system, such as the salinity, temperature and CO2 partial pressure, are affected by halophilic bacteria. The system controls salt deposition but is modified by an accompanying ecological system; therefore it should be called a water/salt/biological system. Salt minerals result from accumulation of the remains of bacteria/algae, namely, bacteria/algae formation; whereas biological, biophysical and biochemical processes provide full evidence for organic involvement. Consequently, salt deposits should not be called purely chemical but biological/chemical ones. This new argument supplements and develops the traditional idea and helps perfect the mineralization theory of salts and even general deposits, thus giving guidance to prospecting for salt deposits.展开更多
To investigate the fouling characteristics of the composite insulator surface under the salt fog environment,the FXBW-110/120-2 composite insulator was taken as the research object.Based on the field-induced charge me...To investigate the fouling characteristics of the composite insulator surface under the salt fog environment,the FXBW-110/120-2 composite insulator was taken as the research object.Based on the field-induced charge mechanism,the multi-physical field coupling software COMSOL was used to numerically simulate the fouling characteristics,explored the calculation method of ESDD,and demonstrated its rationality.Based on this method,the pollution characteristics of the composite insulator under the pollution fog environment were studied,and the influence of wind speed,droplet size,and voltage type on the pollution characteristics of the composite insulator was analyzed.The results showed that:with the increase in wind speed,the amount of accumulated pollution of insulator increases in the range of droplet size,and the relationship between wind speed and accumulated pollution is approximately linear;at the same wind speed,the amount of accumulated pollution increases with the increase of droplet size under the action of DC voltage;when there is no voltage,the amount of dirt on the upper surface of the insulator is more than that on the lower surface,while it is the opposite under DC voltage.展开更多
We studied the sedimentary characteristics of a Paleocene-Eocene salt lake in the Jiangling Depression through field core observation,thin section identification,scanning electron microscopy,and X-ray diffraction anal...We studied the sedimentary characteristics of a Paleocene-Eocene salt lake in the Jiangling Depression through field core observation,thin section identification,scanning electron microscopy,and X-ray diffraction analysis.On the basis of sedimentary characteristics we have summarized the petrological and mineralogical characteristics of the salt lake and proposed 9 types of grade IV salt rhythms.The deposition shows a desalting to salting order of halite-argillaceous-mudstone-mud dolostonemud anhydrock-glauberite-halite.The relationship among grade IV rhythms,water salinity and climate fluctuations was analyzed.Based on the analysis of the relationship between boron content and mudstone color and by combining the mineralogy and sedimentary environment characteristics,we propose that the early and late Paleocene Shashi Formation in the Jiangling Depression was a paleolacustrine depositional environment with a high salt content,which is a representation of the shallow water salt lake depositional model.The middle Paleocene Shashi Formation and the early Eocene Xingouzui Formation were salt and brackish sedimentary environments with low salt content in a deep paleolake,which represents a deep salt lake depositional model.展开更多
Observation and experimental analysis of soluble salt deposit along four profiles across the strata deposited in Nihewan paleolake basin enabled us to recognize the nature and evolution stages of the Nihewan paleolake...Observation and experimental analysis of soluble salt deposit along four profiles across the strata deposited in Nihewan paleolake basin enabled us to recognize the nature and evolution stages of the Nihewan paleolake and its significance in stratigraphical division and pa-leo-environmental reconstruction. The Nihewan paleolake was at least a weak-saline to semi-saline lake and represents an intracontinental lake in the semi-arid region. The lower member of sedimentary strata in the paleolake contains gypsum layer and gypsum lamellae. Soluble salt is mainly composed of SO42- and Ca2+ ions, representing a trend of the paleolake evolvinginto a stage of sulfate lake. The upper member of the strata has predominantly Cl-, K+, and Na+ ions in soluble salt, indicating a starting development of the paleolake to chlorite lake, but no salt rock was deposited, indicating a drying trend of the area.展开更多
Magnesium based alloys with aluminum and zinc were obtained through electrochemical co-deposition from LiCl-NaCl-MgCl2 melt. The possibility of electrochemical co-deposition was discussed in detail by electro-analytic...Magnesium based alloys with aluminum and zinc were obtained through electrochemical co-deposition from LiCl-NaCl-MgCl2 melt. The possibility of electrochemical co-deposition was discussed in detail by electro-analytical methods including cyclic voltametry,square wave voltametry,and chronopotentiometry. The co-deposition happens when the concentration of aluminum and zinc ions is kept at low value and the current density is high enough. The components of alloy elements can be controlled by fixing the components of the feeding salts. A laboratory experiment of the preparation by step-current co-deposition was also performed and certain compositions of the Mg-Al,and Mg-Zn were obtained. The alloys obtained from the co-deposition show a typical as-cast microstructure. The best conditions of electrolysis such as temperature,amount of addition and mode of feeding were discussed in detail.展开更多
Da Qaidam salt lake is known for its both liquid and solid boron resource.Data from previous investigation of the Da Qaidam salt lake provided a comparable framework for this study that focused on investigating the se...Da Qaidam salt lake is known for its both liquid and solid boron resource.Data from previous investigation of the Da Qaidam salt lake provided a comparable framework for this study that focused on investigating the section beneath the bottom of the perennial salt lake,including the timing,展开更多
China has unique salt lake resources, and they are distributed in the east of Eurasian salt lake subzone of the Northern Hemisphere Salt Lake Zone, mainly concentrated in the regions with modern mean annual precipitat...China has unique salt lake resources, and they are distributed in the east of Eurasian salt lake subzone of the Northern Hemisphere Salt Lake Zone, mainly concentrated in the regions with modern mean annual precipitation lower than 500 mm. This paper preliminarily reviews the progress made in salt lake research in China for the past 60 years. In the research of Paleoclimate and paleoenvironment from salt lake sediments, a series of salts have been proposed to be indicators of paleoclimate, and have been well accepted by scholars. The chloride-sulfate depositional regions of the west Qaidam and the east Tarim have been revealed to be the drought center of China since the Quaternary, and more than 6 spreading stages of arid climate (salt forming) have been identified. Five pan-lake periods with highstands have been proved to exist during the late Quaternary on the Tibetan Plateau. In mineral resource prospecting and theories of the forming of salt deposits: the atlas (1:2500000) of hydrochemical zoning of salt lakes on the Tibetan Plateau has been compiled for the first time, revealing the zonal distribution and transition from carbonate type to chloride type from south to north and presenting corresponding mineral assemblages for different type of salt lakes; several large continental salt deposits have been discovered and the theory of continental potash deposition has been developed, including the salt deposition in deep basins surrounded by high mountains, the mineral deposition from multistage evolution through chains of moderate or shallow lakes with multilevels, the origin of potassium rich brines in gravel layers, and the forming of potassium deposits through the inheriting from ancient salt deposits, thus establishing the framework of "Continental Potash Deposition Theory"; several new types of Mg-borate deposits have been discovered, including the ulexite and pinnoite bed in Da Qaidam Lake, Qinghai, the pinnoite and kurnakovite bed in Chagcam Caka, Tibet, the kurnakovite bed in Lake Nyer, and the corresponding model of borate deposition from the cooling and dissolution of boron rich brines was proposed based on principles of geology, physics and chemistry. The anti-floatation-cold crystallization method developed independently has improved the capacity of KCI production to 3 million tons per year for the Qarham, serving the famous brand of potash fertilizer products. One 1.2 million ton K-sulfate production line, the biggest in the world, has been built in Lop Nor, and K-sulfate of about 1.6 million tons was produced in 2015. Supported by the new technology, i.e. brine preparation in winter-cooling-solarization-isolation-lithium deposition from salt gradient solar pond" the highest lithium production base at Zabuye Lake (4421 m), Tibet, has been established, which is the first lithium production base in China that reaches the year production of 5000 tons of lithium carbonate. The concept of Salt lake agriculture (Salt land agriculture) has been established based on the mass growth of Dunaliella and other bacillus-algae and the occurrence of various halophytes in saltmarsh and salt saline-alkali lands, finding a new way to increase arable lands and develop related green industry in salt rich environments. Finally this paper presents some new thoughts for the further research and development on salt science, and the further progress in salt science and technology will facilitate the maturing of the interdisciplinary science "Salinology".展开更多
The primary purpose of underground gas storages is to provide gas for seasonal consumptions or strategic reserve.The periodical operations of gas injection and extraction lead to cyclic loading on the walls and surrou...The primary purpose of underground gas storages is to provide gas for seasonal consumptions or strategic reserve.The periodical operations of gas injection and extraction lead to cyclic loading on the walls and surrounding rocks of gas storages.To investigate the mechanical behaviors of different host rocks in bedded salt deposit,laboratory experiments were conducted on the samples of rock salt,thenardite,glauberite and gypsum.The mechanical properties of rock samples under monotonic and cyclic loadings were studied.Testing results show that,under monotonic loading,the uniaxial compressive stress(UCS) of glauberite is the largest(17.3 MPa),while that of rock salt is the smallest(14.0 MPa).The UCSs of thenardite and gypsum are 16.3 and 14.6 MPa,respectively.The maximum strain at the peak strength of rock salt(halite) is much greater than those of the other three rocks.The elastic moduli of halite,thenardite,glauberite and gypsum are 3.0,4.2,5.1 and 6.8 GPa,respectively.Under cyclic loading,the peak strengths of the rock specimens are deteriorated except for rock salt.The peak strengths of thenardite,glauberite and gypsum decrease by 33.7%,19.1% and 35.5%,respectively;and the strains of the three rocks at the peak strengths are almost the same.However,the strain of rock salt at the peak strength increases by 1.98%,twice more than that under monotonic loading.Under monotonic loading,deformation of the tested rock salt,thenardite and glauberite shows in an elastoplastic style.However,it changes to a ductile style under cyclic loading.Brittle deformation and failure are only observed for gypsum.The results should be helpful for engineering design and operation of gas storage in bedded salt deposit.展开更多
Fused salt accelerated hot corrosion is quite common in gas turbines, fossil fuelled devices, waste inclinators, pyrochemical systems, etc. Presence of fused salt on metal surface dissolves their existing oxide layer....Fused salt accelerated hot corrosion is quite common in gas turbines, fossil fuelled devices, waste inclinators, pyrochemical systems, etc. Presence of fused salt on metal surface dissolves their existing oxide layer. This results in an increase in oxidation rate of the metal. Since, zirconia coating is well recognized for corrosion protection under high temperature oxidative environment, we have developed zirconia coating on 9Cr1Mo ferritic steel and their oxidation performance was evaluated in LiCl-NaCl and Na2SO4-K2SO4 salts deposit system in air atmosphere at 650?C and 850?C, respectively. Before coating development, zirconium based sol was synthesized using zirconium (IV) propoxide as a precursor. Oxidation test results indicated that the zirconia coated specimens shows more than two times higher corrosion resistance in LiCl-NaCl and three time higher corrosion resistance in Na2SO4-K2SO4 salt deposit, respectively.展开更多
A conversion film was obtained on zinc deposit by immersing zinc coated specimens in a mischmetal salt solution. Several factors affecting the anticorrosive efficiency of the conversion film were studied. The suitabl...A conversion film was obtained on zinc deposit by immersing zinc coated specimens in a mischmetal salt solution. Several factors affecting the anticorrosive efficiency of the conversion film were studied. The suitable technological conditions were established. The composition and the thickness of the conversion film were determined by Auger electron spectroscopy(AES).展开更多
The origin of boron in boron-rich salt lakes in the Tibetan Plateau has long been the subject of debate.The Damzung Co Salt Lake in central Tibet has high boron concentrations(B=276–313 mg/L)and is an ideal site for
文摘Bamnet Narong is located in northeastern Thailand (Chaiyaphum Province). It is the largest salt mine in the country and has been mined for decades. The landscape in this part of Thailand is characterised by a low plateau, which is called the Khorat Plateau. The plateau is divided into two basins by the Phu Phan Range, the Sakhon Nakhon Basin in the north and the Khorat Basin in the south. The analysed potashes and rock salts are deposited in the Maha Sarakham Formation, which represents the salt-bearing strata of the Khorat Basin. The stratigraphic age of this deposit has been debated since the late 1960’s. The assigned ages range from Mid-Cretaceous to Late Cretaceous and up to the Eocene. In this study different isotopic dating systems (Rb-Sr, Sr-Sr, K-Ar and K-Ca) were applied. The stratigraphic age for the time of deposition was confirmed to be Mid Cretaceous (Cenomanian). Furthermore, the homogeneity of the carnallites was investigated in order to trace a possible redistribution of rubidium.
文摘A water/salt system in an evaporative environment is both a physicochemical region and a biological one. All the parameters of the system, such as the salinity, temperature and CO2 partial pressure, are affected by halophilic bacteria. The system controls salt deposition but is modified by an accompanying ecological system; therefore it should be called a water/salt/biological system. Salt minerals result from accumulation of the remains of bacteria/algae, namely, bacteria/algae formation; whereas biological, biophysical and biochemical processes provide full evidence for organic involvement. Consequently, salt deposits should not be called purely chemical but biological/chemical ones. This new argument supplements and develops the traditional idea and helps perfect the mineralization theory of salts and even general deposits, thus giving guidance to prospecting for salt deposits.
文摘To investigate the fouling characteristics of the composite insulator surface under the salt fog environment,the FXBW-110/120-2 composite insulator was taken as the research object.Based on the field-induced charge mechanism,the multi-physical field coupling software COMSOL was used to numerically simulate the fouling characteristics,explored the calculation method of ESDD,and demonstrated its rationality.Based on this method,the pollution characteristics of the composite insulator under the pollution fog environment were studied,and the influence of wind speed,droplet size,and voltage type on the pollution characteristics of the composite insulator was analyzed.The results showed that:with the increase in wind speed,the amount of accumulated pollution of insulator increases in the range of droplet size,and the relationship between wind speed and accumulated pollution is approximately linear;at the same wind speed,the amount of accumulated pollution increases with the increase of droplet size under the action of DC voltage;when there is no voltage,the amount of dirt on the upper surface of the insulator is more than that on the lower surface,while it is the opposite under DC voltage.
基金Supported by the National Basic Research Program of China(973 Program)(No.20011CB403007)the National Natural Science Foundation for Young Scientists of China(Nos.41502089,41202059)+1 种基金the Central Public Welfare Scientific Research Basic Scientific Research Business Expenses(No.K1415)the Geological Survey(No.1212010011808)
文摘We studied the sedimentary characteristics of a Paleocene-Eocene salt lake in the Jiangling Depression through field core observation,thin section identification,scanning electron microscopy,and X-ray diffraction analysis.On the basis of sedimentary characteristics we have summarized the petrological and mineralogical characteristics of the salt lake and proposed 9 types of grade IV salt rhythms.The deposition shows a desalting to salting order of halite-argillaceous-mudstone-mud dolostonemud anhydrock-glauberite-halite.The relationship among grade IV rhythms,water salinity and climate fluctuations was analyzed.Based on the analysis of the relationship between boron content and mudstone color and by combining the mineralogy and sedimentary environment characteristics,we propose that the early and late Paleocene Shashi Formation in the Jiangling Depression was a paleolacustrine depositional environment with a high salt content,which is a representation of the shallow water salt lake depositional model.The middle Paleocene Shashi Formation and the early Eocene Xingouzui Formation were salt and brackish sedimentary environments with low salt content in a deep paleolake,which represents a deep salt lake depositional model.
文摘Observation and experimental analysis of soluble salt deposit along four profiles across the strata deposited in Nihewan paleolake basin enabled us to recognize the nature and evolution stages of the Nihewan paleolake and its significance in stratigraphical division and pa-leo-environmental reconstruction. The Nihewan paleolake was at least a weak-saline to semi-saline lake and represents an intracontinental lake in the semi-arid region. The lower member of sedimentary strata in the paleolake contains gypsum layer and gypsum lamellae. Soluble salt is mainly composed of SO42- and Ca2+ ions, representing a trend of the paleolake evolvinginto a stage of sulfate lake. The upper member of the strata has predominantly Cl-, K+, and Na+ ions in soluble salt, indicating a starting development of the paleolake to chlorite lake, but no salt rock was deposited, indicating a drying trend of the area.
基金Project(50374012) supported by the National Natural Science Foundation of China
文摘Magnesium based alloys with aluminum and zinc were obtained through electrochemical co-deposition from LiCl-NaCl-MgCl2 melt. The possibility of electrochemical co-deposition was discussed in detail by electro-analytical methods including cyclic voltametry,square wave voltametry,and chronopotentiometry. The co-deposition happens when the concentration of aluminum and zinc ions is kept at low value and the current density is high enough. The components of alloy elements can be controlled by fixing the components of the feeding salts. A laboratory experiment of the preparation by step-current co-deposition was also performed and certain compositions of the Mg-Al,and Mg-Zn were obtained. The alloys obtained from the co-deposition show a typical as-cast microstructure. The best conditions of electrolysis such as temperature,amount of addition and mode of feeding were discussed in detail.
文摘Da Qaidam salt lake is known for its both liquid and solid boron resource.Data from previous investigation of the Da Qaidam salt lake provided a comparable framework for this study that focused on investigating the section beneath the bottom of the perennial salt lake,including the timing,
基金supported by the National Science Foundation of China and joint foundation(grants DD20160054 and 21422036)projects of China Geological Survey(grants U1407207)
文摘China has unique salt lake resources, and they are distributed in the east of Eurasian salt lake subzone of the Northern Hemisphere Salt Lake Zone, mainly concentrated in the regions with modern mean annual precipitation lower than 500 mm. This paper preliminarily reviews the progress made in salt lake research in China for the past 60 years. In the research of Paleoclimate and paleoenvironment from salt lake sediments, a series of salts have been proposed to be indicators of paleoclimate, and have been well accepted by scholars. The chloride-sulfate depositional regions of the west Qaidam and the east Tarim have been revealed to be the drought center of China since the Quaternary, and more than 6 spreading stages of arid climate (salt forming) have been identified. Five pan-lake periods with highstands have been proved to exist during the late Quaternary on the Tibetan Plateau. In mineral resource prospecting and theories of the forming of salt deposits: the atlas (1:2500000) of hydrochemical zoning of salt lakes on the Tibetan Plateau has been compiled for the first time, revealing the zonal distribution and transition from carbonate type to chloride type from south to north and presenting corresponding mineral assemblages for different type of salt lakes; several large continental salt deposits have been discovered and the theory of continental potash deposition has been developed, including the salt deposition in deep basins surrounded by high mountains, the mineral deposition from multistage evolution through chains of moderate or shallow lakes with multilevels, the origin of potassium rich brines in gravel layers, and the forming of potassium deposits through the inheriting from ancient salt deposits, thus establishing the framework of "Continental Potash Deposition Theory"; several new types of Mg-borate deposits have been discovered, including the ulexite and pinnoite bed in Da Qaidam Lake, Qinghai, the pinnoite and kurnakovite bed in Chagcam Caka, Tibet, the kurnakovite bed in Lake Nyer, and the corresponding model of borate deposition from the cooling and dissolution of boron rich brines was proposed based on principles of geology, physics and chemistry. The anti-floatation-cold crystallization method developed independently has improved the capacity of KCI production to 3 million tons per year for the Qarham, serving the famous brand of potash fertilizer products. One 1.2 million ton K-sulfate production line, the biggest in the world, has been built in Lop Nor, and K-sulfate of about 1.6 million tons was produced in 2015. Supported by the new technology, i.e. brine preparation in winter-cooling-solarization-isolation-lithium deposition from salt gradient solar pond" the highest lithium production base at Zabuye Lake (4421 m), Tibet, has been established, which is the first lithium production base in China that reaches the year production of 5000 tons of lithium carbonate. The concept of Salt lake agriculture (Salt land agriculture) has been established based on the mass growth of Dunaliella and other bacillus-algae and the occurrence of various halophytes in saltmarsh and salt saline-alkali lands, finding a new way to increase arable lands and develop related green industry in salt rich environments. Finally this paper presents some new thoughts for the further research and development on salt science, and the further progress in salt science and technology will facilitate the maturing of the interdisciplinary science "Salinology".
基金Supported by the Program for New Century Excellent Talents in University of China (NCET-07-0594)the National Natural Science Foundation of China (50874078 and 50804033)the Special Support for National Excellent Ph.D.Thesis (200959)
文摘The primary purpose of underground gas storages is to provide gas for seasonal consumptions or strategic reserve.The periodical operations of gas injection and extraction lead to cyclic loading on the walls and surrounding rocks of gas storages.To investigate the mechanical behaviors of different host rocks in bedded salt deposit,laboratory experiments were conducted on the samples of rock salt,thenardite,glauberite and gypsum.The mechanical properties of rock samples under monotonic and cyclic loadings were studied.Testing results show that,under monotonic loading,the uniaxial compressive stress(UCS) of glauberite is the largest(17.3 MPa),while that of rock salt is the smallest(14.0 MPa).The UCSs of thenardite and gypsum are 16.3 and 14.6 MPa,respectively.The maximum strain at the peak strength of rock salt(halite) is much greater than those of the other three rocks.The elastic moduli of halite,thenardite,glauberite and gypsum are 3.0,4.2,5.1 and 6.8 GPa,respectively.Under cyclic loading,the peak strengths of the rock specimens are deteriorated except for rock salt.The peak strengths of thenardite,glauberite and gypsum decrease by 33.7%,19.1% and 35.5%,respectively;and the strains of the three rocks at the peak strengths are almost the same.However,the strain of rock salt at the peak strength increases by 1.98%,twice more than that under monotonic loading.Under monotonic loading,deformation of the tested rock salt,thenardite and glauberite shows in an elastoplastic style.However,it changes to a ductile style under cyclic loading.Brittle deformation and failure are only observed for gypsum.The results should be helpful for engineering design and operation of gas storage in bedded salt deposit.
文摘Fused salt accelerated hot corrosion is quite common in gas turbines, fossil fuelled devices, waste inclinators, pyrochemical systems, etc. Presence of fused salt on metal surface dissolves their existing oxide layer. This results in an increase in oxidation rate of the metal. Since, zirconia coating is well recognized for corrosion protection under high temperature oxidative environment, we have developed zirconia coating on 9Cr1Mo ferritic steel and their oxidation performance was evaluated in LiCl-NaCl and Na2SO4-K2SO4 salts deposit system in air atmosphere at 650?C and 850?C, respectively. Before coating development, zirconium based sol was synthesized using zirconium (IV) propoxide as a precursor. Oxidation test results indicated that the zirconia coated specimens shows more than two times higher corrosion resistance in LiCl-NaCl and three time higher corrosion resistance in Na2SO4-K2SO4 salt deposit, respectively.
文摘A conversion film was obtained on zinc deposit by immersing zinc coated specimens in a mischmetal salt solution. Several factors affecting the anticorrosive efficiency of the conversion film were studied. The suitable technological conditions were established. The composition and the thickness of the conversion film were determined by Auger electron spectroscopy(AES).
基金supported jointly by the China Geological Survey (Grant no. 1212011085524)by the National Science Foundation of China (Grant no. 41203012)
文摘The origin of boron in boron-rich salt lakes in the Tibetan Plateau has long been the subject of debate.The Damzung Co Salt Lake in central Tibet has high boron concentrations(B=276–313 mg/L)and is an ideal site for