A novel utilization way of the sludge from wet calcium-based flue gas desulfurization （FGD） processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calc...A novel utilization way of the sludge from wet calcium-based flue gas desulfurization （FGD） processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calcium sulfate by a hydrothermal salt solution method at atmospheric pressure. Experimental study has been carried out in a batch reactor. Qualitative and quantitative analyses were made by DSC/TG thermal analysis, SEM, XRD, metalloscope and chemical analysis. The experimental results showed that the modification of FGD gypsum was controlled by the dissolution and recrystallization mechanisms. With the introduction of FGD gypsum the salt solution was supersaturated, then crystal nucleus of α-hemihydrate calcium sulfate were produced in the solution. With the submicroscopic structure of FGD gypsum crystal changed, the crystal nucleus grew up into α-hemihydrate calcium sulfate crystals. Thus ,the modification of FGD gypsum was fulfilled.展开更多
采用压力板法、滤纸法和饱和盐溶液法3种方法,对压实桂林红黏土进行全吸力范围内的土-水特性量测,研究干密度对于土-水特征曲线的影响。试验结果表明:干密度1.4 g/cm3的压实桂林红黏土的进气值约为20 k Pa;土-水特征曲线的过渡段与典型...采用压力板法、滤纸法和饱和盐溶液法3种方法,对压实桂林红黏土进行全吸力范围内的土-水特性量测,研究干密度对于土-水特征曲线的影响。试验结果表明:干密度1.4 g/cm3的压实桂林红黏土的进气值约为20 k Pa;土-水特征曲线的过渡段与典型的土-水特征曲线不同,含水率或饱和度与吸力的对数坐标关系不是单一直线,而是出现了3段直线,并且中间一段平缓段下降斜率较小;当吸力增大到367 MPa时,含水率仅为0.74%,可认为如吸力继续增大至106 k Pa时,含水率和饱和度为0;用吸力与含水率关系表示土-水特征曲线时,吸力较大时不同干密度的曲线重合,认为干密度对土-水特征曲线无影响。用吸力与饱和度关系表示土-水特征曲线时,在吸力较小时,干密度越大,对应的土-水特征曲线越高;当吸力较大时,不同干密度的土-水特征曲线几乎重合。展开更多
文摘A novel utilization way of the sludge from wet calcium-based flue gas desulfurization （FGD） processes has been developed in this paper. This study focused on the conversion of the FGD gypsum into α-hemihydrate calcium sulfate by a hydrothermal salt solution method at atmospheric pressure. Experimental study has been carried out in a batch reactor. Qualitative and quantitative analyses were made by DSC/TG thermal analysis, SEM, XRD, metalloscope and chemical analysis. The experimental results showed that the modification of FGD gypsum was controlled by the dissolution and recrystallization mechanisms. With the introduction of FGD gypsum the salt solution was supersaturated, then crystal nucleus of α-hemihydrate calcium sulfate were produced in the solution. With the submicroscopic structure of FGD gypsum crystal changed, the crystal nucleus grew up into α-hemihydrate calcium sulfate crystals. Thus ,the modification of FGD gypsum was fulfilled.
文摘采用压力板法、滤纸法和饱和盐溶液法3种方法,对压实桂林红黏土进行全吸力范围内的土-水特性量测,研究干密度对于土-水特征曲线的影响。试验结果表明:干密度1.4 g/cm3的压实桂林红黏土的进气值约为20 k Pa;土-水特征曲线的过渡段与典型的土-水特征曲线不同,含水率或饱和度与吸力的对数坐标关系不是单一直线,而是出现了3段直线,并且中间一段平缓段下降斜率较小;当吸力增大到367 MPa时,含水率仅为0.74%,可认为如吸力继续增大至106 k Pa时,含水率和饱和度为0;用吸力与含水率关系表示土-水特征曲线时,吸力较大时不同干密度的曲线重合,认为干密度对土-水特征曲线无影响。用吸力与饱和度关系表示土-水特征曲线时,在吸力较小时,干密度越大,对应的土-水特征曲线越高;当吸力较大时,不同干密度的土-水特征曲线几乎重合。
基金the Special Scientific Research Fund of Ministry of Land and Resources of China(201311013)Fundamental Research Funds of Chinese Academy of Geological Sciences(CSJ201607)the large resource investigation project of China(12120113091000)
