喀斯特流域是岩石风化碳汇的关键区域,同时也是CO_(2)逸散研究的热点区域。为探究喀斯特地下河涌出后CO_(2)分压(pCO_(2))及其逸散通量的时空变化格局,选择喀斯特流域巴马盘阳河为对象,分析水体的pH、碱度、总溶解性固体(TDS)、溶解无机...喀斯特流域是岩石风化碳汇的关键区域,同时也是CO_(2)逸散研究的热点区域。为探究喀斯特地下河涌出后CO_(2)分压(pCO_(2))及其逸散通量的时空变化格局,选择喀斯特流域巴马盘阳河为对象,分析水体的pH、碱度、总溶解性固体(TDS)、溶解无机碳(DIC)、溶解有机碳(DOC)、pCO_(2)的时空变化特征,探讨pCO_(2)的调控因素并估算了CO_(2)逸散通量。结果表明,流域内地下水碱度、TDS、DIC和pCO_(2)显著高于地表水,表明喀斯特碳酸盐风化释放大量DIC进入地下水,地下水涌出后产生CO_(2)逸散降低了地表水DIC含量和pCO_(2)。在时间尺度上,旱季常规地表、地下水的碱度、TDS、DIC、pCO_(2)、CO_(2)逸散通量均显著高于雨季,主要归结于雨季雨水的稀释效应。然而次降雨事件下地表、地下水的pH、碱度、TDS、DIC、DOC、pCO_(2)无显著性差异,可能由于降雨量不足或降雨持续时间短。研究期间,巴马盘阳河流域地表水、地下水CO_(2)逸散通量范围分别为-0.10~9.20 kg C m^(-2)year^(-1),-0.12~17.28kg C m^(-2)year^(-1),平均CO_(2)逸散通量分别为1.06±1.46 kg C m^(-2)year^(-1)和2.40±3.14 kg C m^(-2)year^(-1),远高于全球主要大型流域的平均CO_(2)逸散通量(0.64 kg Cm^(-2)year^(-1))。阐明喀斯特流域的CO_(2)逸散通量及其时空变化特征对准确评估河流碳收支状况与评估岩石风化碳汇具有重要意义。展开更多
Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expec...Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expected to improve the uncertainty existing in these estimates. In the present study,the annual global sea-air CO2 flux is estimated with the sea-state-dependent-k parameterization proposed by Woolf(2005) ,using NOAA/NCEP reanalysis wind speed and hindcast wave data from 1998 to 2006,and a new estimate,-2.18 Gt C year-1,is obtained,which is comparable with previous estimates with biochemical methods. It is interesting to note that the averaged value of previous estimates with various wind-dependent-k parameterizations is almost identical to that of previous estimates with biochemical methods by various authors,and that the new estimate is quite consistent with these averaged estimates.展开更多
文摘喀斯特流域是岩石风化碳汇的关键区域,同时也是CO_(2)逸散研究的热点区域。为探究喀斯特地下河涌出后CO_(2)分压(pCO_(2))及其逸散通量的时空变化格局,选择喀斯特流域巴马盘阳河为对象,分析水体的pH、碱度、总溶解性固体(TDS)、溶解无机碳(DIC)、溶解有机碳(DOC)、pCO_(2)的时空变化特征,探讨pCO_(2)的调控因素并估算了CO_(2)逸散通量。结果表明,流域内地下水碱度、TDS、DIC和pCO_(2)显著高于地表水,表明喀斯特碳酸盐风化释放大量DIC进入地下水,地下水涌出后产生CO_(2)逸散降低了地表水DIC含量和pCO_(2)。在时间尺度上,旱季常规地表、地下水的碱度、TDS、DIC、pCO_(2)、CO_(2)逸散通量均显著高于雨季,主要归结于雨季雨水的稀释效应。然而次降雨事件下地表、地下水的pH、碱度、TDS、DIC、DOC、pCO_(2)无显著性差异,可能由于降雨量不足或降雨持续时间短。研究期间,巴马盘阳河流域地表水、地下水CO_(2)逸散通量范围分别为-0.10~9.20 kg C m^(-2)year^(-1),-0.12~17.28kg C m^(-2)year^(-1),平均CO_(2)逸散通量分别为1.06±1.46 kg C m^(-2)year^(-1)和2.40±3.14 kg C m^(-2)year^(-1),远高于全球主要大型流域的平均CO_(2)逸散通量(0.64 kg Cm^(-2)year^(-1))。阐明喀斯特流域的CO_(2)逸散通量及其时空变化特征对准确评估河流碳收支状况与评估岩石风化碳汇具有重要意义。
文摘Although the annual global sea-air CO2 flux has been estimated extensively with various wind-dependent-k parameterizations,uncertainty still exists in the estimates. The sea-state-dependent-k parameterization is expected to improve the uncertainty existing in these estimates. In the present study,the annual global sea-air CO2 flux is estimated with the sea-state-dependent-k parameterization proposed by Woolf(2005) ,using NOAA/NCEP reanalysis wind speed and hindcast wave data from 1998 to 2006,and a new estimate,-2.18 Gt C year-1,is obtained,which is comparable with previous estimates with biochemical methods. It is interesting to note that the averaged value of previous estimates with various wind-dependent-k parameterizations is almost identical to that of previous estimates with biochemical methods by various authors,and that the new estimate is quite consistent with these averaged estimates.
