Synthesis and Coloring Mechanism of Metallic Glaze in R_(2)O-RO-Al_(2)O_(3)-SiO_(2)-P_(2)O_(5)System

A copper-red and silver-white metallic glaze of R_(2)O-RO-Al_(2)O_(3)-SiO_(2)-P_(2)O_(5)system was synthesized by adjusting the firing temperature and glaze components.The coloration mechanism of the metallic glaze was revealed via investigation of the microstructure of the glaze.Our research reveals that the metallic glaze with different colors is mainly due to the amount of Fe_(2)O_(3).The metallic glaze shows a silver-white luster due to a structural color ofα-Fe_(2)O_(3)crystals with a good orientation when the sample contains 0.0939 mol of Fe_(2)O_(3),maintaining temperatures at 1150℃for 0.5 h.The metallic glaze is copper-red which is dominated by the coupling of chemical and structural color ofα-Fe_(2)O_(3)crystals when the sample contains 0.0783 mol of Fe_(2)O_(3).After testing the amount of SiO_(2),we find that 4.0499 mol is the optimal amount to form the ceramic network,and 0.27 mol AlPO_(4)is the best amount to promote phase separation.

Preparation and property of self-sealed plasma electrolytic oxide coating on magnesium alloy

Plasma electrochemical oxidation (PEO) is a surface modification technology to form ceramic coatings on magnesium alloys However,its application is limited due to its defects.This work reports a novel preparation of in-situ sealing of PEO coatings by four-layer voltage and sol addition.The morphology and structure were characterized by scanning electron microscopy (SEM),energy dispersive X-ray spectroscopy (EDS),and X-ray diffractometer (XRD).Image-Pro Plus 6.0 was used to determine the porosity of the coating,which was decreased from 8.53%to 0.51%.Simultaneously,the coating thickness was increased by a factor of four.The anti-corrosion performance of each sample was evaluated using electrochemical tests,and the findings revealed that the corrosion current density of coatings (i_(corr)) of the samples were lowered from 9.152×10^(-2) to 6.152×10^(-4) mA·cm^(-2),and the total resistance (R_(T)) of the samples were enhanced from 2.19×10^(4) to 2.33×10^(5)Ω·cm^(2).The salt spray test used to simulate the actual environment showed that corrosion points appeared on the surface of the coating only at the 336 h.In addition,the mechanism of PEO self-sealing behavior was described in this article.

The Impact of Sun Radiation on the Thermal Comfort in Highly Glazed Buildings Equipped with Floor Heating Systems

Occupants of highly glazed buildings often suffer from thermal discomfort during the mid-seasons when no shadings are used in such buildings,especially when inertial heating systems are used.The present study is devoted to evaluating the impact of long solar beam exposure on the internal thermal discomfort in glazed spaces when heating is implemented through a floor system.A comprehensive experimental study is carried out using an experimental bi-climatic chamber which is fully monitored and controlled,allowing realistic simulations of the dynamic movement of the sun patch on a heated slab.The findings show that a period of discomfort as long as 8 h can occur,and persist far after the sunbeam exposure stops.During this period,the heating slab’s surface temperature,considered from an average point of view,can attain 34°C while the indoor temperature reaches 26°C.Simulations conducted using a previously developed model display a good fit with the measurements.

Sealing capacity evaluation of underground gas storage under intricate geological conditions

Evaluating underground gas storage(UGS)sealing capacity is essential for its safe construction and operational efficiency.This involves evaluating both the static sealing capacity of traps during hydrocarbon accumulation and the dynamic sealing capacity of UGS under intensive gas injection and withdrawal,and alternating loads.This study detailed the methodology developed by Sinopec.The approach merges disciplines like geology,geomechanics,and hydrodynamics,employing both dynamic-static and qualitative-quantitative analyses.Sinopec's evaluation methods,grounded in the in situ stress analysis,include mechanistic studies,laboratory tests,geological surveys,stress analysis,and fluid-solid interactions.Through tests on the static and dynamic sealing capacity of UGS,alongside investigations into sealing mechanisms and the geological and geomechanical properties of cap rocks and faults,A geomechanics-rock damage-seepage mechanics dynamic coupling analysis method has been developed to predict in situ stress variations relative to pore pressure changes during UGS operations and evaluate fault sealing capacity and cap rock integrity,thereby setting the maximum operational pressures.Utilizing this evaluation technique,Sinopec has defined performance metrics and criteria for evaluating the sealing capacity of depleted gas reservoirs,enabling preliminary sealing capacity evaluations at UGS sites.These evaluations have significantly informed the design of UGS construction schemes and the evaluation of fault sealing capacity and cap rock integrity during UGS operations.

The Application of Bilayer Artificial Dermis Combined with VSD Technology in Chronic Wounds

Background: Bilayer artificial dermis promotes wound healing and offers a treatment option for chronic wounds. Aim: Examine the clinical efficacy of bilayer artificial dermis combined with Vacuum Sealing Drainage (VSD) technology in the treatment of chronic wounds. Method: From June 2021 to December 2023, our hospital treated 24 patients with chronic skin tissue wounds on their limbs using a novel tissue engineering product, the bilayer artificial dermis, in combination with VSD technology to repair the wounds. The bilayer artificial dermis protects subcutaneous tissue, blood vessels, nerves, muscles, and tendons, and also promotes the growth of granulation tissue and blood vessels to aid in wound healing when used in conjunction with VSD technology for wound dressing changes in chronic wounds. Results: In this study, 24 cases of chronic wounds with exposed bone or tendon larger than 1.0 cm2 were treated with a bilayer artificial skin combined with VSD dressing after wound debridement. The wounds were not suitable for immediate skin grafting. At 2 - 3 weeks post-treatment, good granulation tissue growth was observed. Subsequent procedures included thick skin grafting or wound dressing changes until complete wound healing. Patients were followed up on average for 3 months (range: 1 - 12 months) post-surgery. Comparative analysis of the appearance, function, skin color, elasticity, and sensation of the healed chronic wounds revealed superior outcomes compared to traditional skin fl repairs, resulting in significantly higher satisfaction levels among patients and their families. Conclusion: The application of bilayer artificial dermis combined with VSD technology for the repair of chronic wounds proves to be a viable method, yielding satisfactory therapeutic effects compared to traditional skin flap procedures.

Interfacial friction effects on sealing performances of elastomer packer

Elastomer sealing performance is of critical importance for downhole tools application including the use of fracturing(Frac)plugs during multi-stage hydraulic fracking.In practice sealing performances of such plugs are normally evaluated through pressure tests,and in numerical simulation studies,maximum contact stress,average contact stress and contact length data are used to determine sealing quality between a packer and casing.In previous studies,the impact of friction forces on sealing performance is often overlooked.This work aims to fill this knowledge gap in determining the influence of friction forces on elastomer packer sealing performances.We first determined the most appropriate constitutive hyperelastic model for the elastomers used in frac plug.Then we compared analytical calculation results with Finite Element Analysis simulation using a simplified tubular geometry and showed the significant influences on interfacial friction on elastomer packer stress distribution,deformation,and contact stress after setting.With the demonstration of validity of FEA method,we conducted systematic numerical simulation studies to show how the interfacial friction coefficients can affect the maximum contact stress,average contact stress,contact stress distribution,and maximum mises stress for an actual packer used in plug products.In addition,we also demonstrated how the groove in a packer can affect packer deformation and evolvement during setting with the consideration of interfacial stress.This study underscores the critical role that friction forces play in Frac plug performance and provides a new dimension for optimizing packer design by controlling interfacial interactions at the packer contact surfaces.

Influence of Methane-Hydrogen Mixture Characteristics on Compressor Vibrations

A transition to clean hydrogen energy will not be possible until the issues related to its production, transportation,storage, etc., are adequately resolved. Currently, however, it is possible to use methane-hydrogen mixtures.Natural gas can be transported using a pipeline system with the required pressure being maintained by gascompression stations. This method, however, is affected by some problems too. Compressors emergency stopscan be induced by vibrations because in some cases, mechanical methods are not able to reduce the vibrationamplitude. As an example, it is known that a gas-dynamic flow effect in labyrinth seals can lead to increasedvibrations. This paper presents the numerical simulation of rotor oscillations taking into account a gas-dynamicload. The influence of a transported mixture on the oscillatory process is investigated. Mixtures consisting ofmethane and hydrogen in various proportions and an air mixture are considered. The results are discussed forvarious operating pressures and include the rotor motion trajectories and oscillation frequency spectra obtainednumerically. It is shown that the gas mixture composition has a significant effect on the oscillations and theiroccurrence. Hydrogen as a working fluid reduces the vibration amplitude. Operating a compressor with hydrogenleads to a decrease in the resonant frequency, bringing it closer to the operating one. However, the operatingpressure at which maximum oscillations are observed depends slightly on the gas mixture composition.

Evolution and Application of Sealing Ability of Gypsum Caprocks under Temperature-Pressure Coupling:An Example of the ZS5 Well in the Tazhong Area of the Tarim Basin

Gypsum caprocks'sealing ability is affected by temperature-pressure coupling.Due to the limitations of experimental conditions,there is still a lack of triaxial stress-strain experiments that simultaneously consider changes in temperature and pressure conditions,which limits the accuracy of the comprehensive evaluation of the brittle plastic evolution and sealing ability of gypsum rocks using temperature pressure coupling.Triaxial stress-strain tests were utilized to investigate the differences in the evolution of the confinement capacity of gypsum rocks under coupled temperaturepressure action and isothermal-variable pressure action on the basis of sample feasibility analysis.According to research,the gypsum rock's peak and residual strengths decrease under simultaneous increases in temperature and pressure over isothermal pressurization experimental conditions,and it becomes more ductile.This reduces the amount of time it takes for the rock to transition from brittle to plastic.When temperature is taken into account,both the brittle–plastic transformation's depth limit and the lithological transformation of gypsum rocks become shallower,and the evolution of gypsum rocks under variable temperature and pressure conditions is more complicated than that under isothermal pressurization.The sealing ability under the temperature-pressure coupling is more in line with the actual geological context when the application results of the Well#ZS5 are compared.This provides a theoretical basis for precisely determining the process of hydrocarbon accumulation and explains why the early hydrocarbon were not well preserved.

Innovative approach to boosting the chemical stability of AZ31 magnesium alloy using polymer-modified hybrid metal oxides

Meeting the demands of complex and advanced applications requires the development of high-performance hybrid materials with unique properties.However,the integration of polymeric frameworks with MgO/WO_(3) composite layers faces challenges due to the lack of understanding of the formation mechanism and the challenge of determining the impact of self-assembled architecture on anticorrosive properties.In this study,we aimed to enhance the corrosion resistance of the MgO layer produced by plasma electrolysis(PE)of AZ31 Mg alloy by incorporating WO_(3) with partially phosphorated poly(vinyl alcohol)(PPVA).Two types of porous MgO layers were produced using the PE process with an alkaline-phosphate electrolyte,one with and one without WO_(3) nanoparticles,which were subsequently immersed in an aqueous solution of PPVA.Incorporating PPVA into the WO_(3)-MgO layer resulted in hybrids being deposited in a fragmented manner,creating a“laminar reef-like structure”that sealed most of the structural defects in the layer.The PPVA-sealed WO_(3)-based coating exhibited superior corrosion resistance compared to the other samples.Computational analyses were employed to explore the mechanism underlying the formation of PPVA/WO_(3) hybrids on the MgO layer.These findings suggest that PPVA-WO_(3)-MgO hybrid coatings can potentially improve corrosion resistance in various fields.

不同温度下柔性刷丝HVOF涂层摩擦磨损及氧化行为研究

目的研究不同温度下柔性刷丝HVOF涂层接触界面的摩擦磨损行为。方法在销盘摩擦磨损试验机上采用法向载荷2 N,转速900 r/min,对L605刷丝材料与HVOF涂层配副进行不同温度下的摩擦磨损试验,分别利用扫描电镜(SEM)、能谱仪(EDX)和X射线光电子能谱仪(XPS)对摩擦试验后不同温度(200~600℃)下的刷丝端面进行观察,并对其表面化学成分的价态进行分析。结果柔性刷丝界面的摩擦因数在0.5~0.9之间,且摩擦因数随着温度的升高而降低,摩擦因数曲线的波动程度则随温度的升高而加剧。随温度的升高,柔性刷丝界面的摩擦磨损状态由三体磨损逐渐转向二体磨损。摩擦界面EDX分析表明,接触界面的氧含量分布存在差异,随温度升高,刷丝表面氧含量增加,且XPS结果表明,不同温度工况下摩擦磨损界面氧元素的结合能并不相同。结论柔性刷丝接触界面的磨损机制以氧化磨损为主,在400℃以下,柔性刷丝界面的磨损机制主要表现为氧化磨损和磨粒磨损,再转变为氧化磨损与黏着磨损共同作用。此外,柔性刷丝界面形成不同的磨损氧化产物,当温度高于400℃时,氧元素的结合能呈现双峰。

Fracture sealing performance of granular lost circulation materials at elevated temperature:A theoretical and coupled CFD-DEM simulation study

Lost circulation is a common downhole problem of drilling in geothermal and high-temperature,high-pressure(HTHP)formations.Lost circulation material(LCM)is a regular preventive and remedial measure for lost circulation.However,conventional LCMs seem ineffective in high-temperature formations.This may be due to the changes in the mechanical properties of LCMs and their sealing performance under high-temperature conditions.To understand how high temperature affects the fracture sealing performance of LCMs,we developed a coupled computational fluid dynamics-discrete element method(CFD-DEM)model to simulate the behavior of granular LCMs in fractures.We summarized the literature on the effects of high temperature on the mechanical properties of LCMs and the rheological properties of drilling fluid.We conducted sensitivity analyses to investigate how changing LCM slurry properties affected the fracture sealing efficiency at increasing temperatures.The results show that high temperature reduces the size,strength,and friction coefficient of LCMs as well as the drilling fluid viscosity.Smaller,softer,and less frictional LCM particles have lower bridging probability and slower bridging initiation.Smaller particles tend to form dual-particle bridges rather than single-particle bridges.These result in a deeper,tighter,but unstable sealing zone.Reduced drilling fluid viscosity leads to faster and shallower sealing zones.

Dynamic evaluation on sealing capacity of caprocks of the Meso-Neoproterozoic reservoirs in Ordos Basin,China

The Meso-Neoproterozoic is a new play in the Ordos Basin.A deeper understanding about the dynamic relationship between the caprocks and the source rocks is needed.Based on the comprehensive analysis of hydrocarbon source development characteristics of the Meso-Neoproterozoic and its overlying strata,as well as the formation contact relationships,lithology characteristics and exploratory drilling data,it is recognized that the Meso-Neoproterozoic contains two types of petroleum accumulation assemblage,that is,the“self-sourced indigenous”and“upper source rock-lower reservoir”assemblages.The former is mainly controlled by the development and distribution of source rocks of the Changcheng System,with the Lower Cambrian shale sequence as its caprock.The later is controlled by the superposition between the Meso-Neoproterozoic and its overlying source rocks and this assemblage is mainly distributed in Hangjinqi and Pingliang areas with the Carboniferous-Permian shale sequence as its caprock.The dynamic evaluation on the displacement pressure serves to reconstruct the displacement pressure history of the caprock.The results show that the shale sequence of the Cambrian Maozhuang Formation in well XY 1 in the southern Ordos Basin has possibly acquired the ability of sealing natural gas since the early of Late Triassic.Its displacement pressure increased rapidly up to 20 MPa during the Late Triassic-Jurassic and keeps at 9.2 MPa at present,indicating fair sealing ability.The Carboniferous-Permian caprocks in Hangjinqi area could have acquired the ability to seal natural gas in the Late Jurassic-Early Cretaceous,and the present-day displacement pressure is 9e12 MPa,indicating good sealing ability.The upper Paleozoic caprock in Pingliang area has been able to seal natural gas since the Early Jurassic,with a maximum displacement pressure of 23 MPa during the Cretaceous period and a current value of 17 e20 MPa,indicative of strong ability to seal natural gas.The sealing ability of caprocks of both the“selfsourced indigenous”and“upper source rock-lower reservoir”assemblages has come into being earlier than or at least no later than the peak gas generation of the source rocks and therefore the caprocks are dynamically effective in geohistory.The Meso-Neoproterozoic reservoirs in the Ordos Basin are well preserved and probabally of better potential for exploration in terms of the caprock-source rock combination.

Influence of pressure disturbance wave on dynamic response characteristics of liquid film seal for multiphase pump

Slug flow or high GVF(Gas Volume Fraction)conditions can cause pressure disturbance waves and alternating loads at the boundary of mechanical seals for multiphase pumps,endangering the safety of multiphase pump units.The mechanical seal model is simplified by using periodic boundary conditions and numerical calculations are carried out based on the Zwart-Gerber-Belamri cavitation model.UDF(User Define Function)programs such as structural dynamics equations,alternating load equations,and pressure disturbance equations are embedded in numerical calculations,and the dynamic response characteristics of mechanical seal are studied using layered dynamic mesh technology.The results show that when the pressure disturbance occurs at the inlet,as the amplitude and period of the disturbance increase,the film thickness gradually decreases.And the fundamental reason for the hysteresis of the film thickness change is that the pressure in the high-pressure area cannot be restored in a timely manner.The maximum value of leakage and the minimum value of axial velocity are independent of the disturbance period and determined by the disturbance amplitude.The mutual interference between enhanced waves does not have a significant impact on the film thickness,while the front wave in the attenuated wave has a promoting effect on the subsequent film thickness changes,and the fluctuation of the liquid film cavitation rate and axial velocity under the attenuated wave condition deviates from the initial values.Compared with pressure disturbance conditions,alternating load conditions have a more significant impact on film thickness and leakage.During actual operation,it is necessary to avoid alternating load conditions in multiphase pump mechanical seals.

Preparation and property of seal coating for gas turbine compressor

Double-layer structure of seal coating which consisted of a Ni5Al bond coating and a Ni25 graphite top coating were prepared on steel substrate of gas turbine compressor cylinder block.Bond coating was prepared by atmospheric plasma spraying and top coating was prepared by flame spraying.The microstructure,mechanical properties and abradability of the coating were characterized by scanning elec-tron microscope(SEM),hardness tester,universal testing machine,thermal shock testing machine and abradability testing machine.The res-ults show that the overall spraying structure of the seal coating is uniform,the nickel metal phase is the skeleton supporting the entire coat-ing,and the coating is well bonded without separation.The seal coating has a bonding strength of not less than 7.7 MPa,excellent thermal stability,and thermal shock resistance cycle numbers at 500℃more than 50;the scratch length,deepest invasion depth and wear amount of the coating increase with rise of test temperature,with almost no coating adhesion,indicating that the seal coating has excellent abradability.

Evaluation of the injection and plugging ability of a novel epoxy resin in cement cracks

Sustained casing pressure(SCP)is a crucial issue in the oil and gas production lifecycle.Epoxy resins,exhibiting exceptional compressive strength,ductility,and shear bonding strength,have the potential to form reliable barriers.The injectivity and sealing capacity of the epoxy resin is crucial parameters for the success of shallow remediation operations.This study aimed to develop and assess a novel solid-free resin sealant as an alternative to Portland cement for mitigating fluid leakage.The investigation evaluated the viscosity,compressive strength,and brittleness index of the epoxy resin sealant,as well as its tangential and normal shear strengths in conjunction with casing steel.The flow characteristics and sealing abilities of conventional cement and epoxy resin were comparatively analyzed in cracks.The results showed that the application of a viscosity reducer facilitated control over the curing time of the epoxy resin,ranging from 1.5 to 6 h,and reduced the initial viscosity from 865.53 to 118.71 m Pa,s.The mechanical properties of the epoxy resin initially increased with a rise in curing agent content before experiencing a minor decrease.The epoxy resin containing 30%curing agent exhibited optimal mechanical properties.After a 14-day curing period,the epoxy resin's compressive strength reached81.37 MPa,2.12 times higher than that of cement,whereas the elastic modulus of cement was 2.99 times greater than that of the epoxy resin.The brittleness index of epoxy resin is only 3.42,demonstrating high flexibility and toughness.The tangential and normal shear strengths of the epoxy resin exceeded those of cement by 3.17 and 2.82 times,respectively.In a 0.5 mm-wide crack,the injection pressure of the epoxy resin remained below 0.075 MPa,indicating superior injection and flow capabilities.Conversely,the injection pressure of cement surged dramatically to 2.61 MPa within 5 min.The breakthrough pressure of0.5 PV epoxy resin reached 7.53 MPa,decreasing the crack's permeability to 0.02 D,a mere 9.49%of the permeability observed following cement plugging.Upon sealing a 2 mm-wide crack using epoxy resin,the maximum breakthrough pressure attained 5.47 MPa,3.48 times of cement.These results suggest that epoxy resin sealant can be employed safely and effectively to seal cracks in the cement.

Calculation of high-speed abrasion forces for ceramic coatings based on the Hertzian contact model

Aero engine seal coatings can effectively improve the air tightness of aircraft engines and increase fuel efficiency.However,due to the frictional forces between the blades and the coating,the coating often flakes off,resulting in damage to the blades and causing eco-nomic losses.Therefore,it is necessary to analyze the friction between the blades and the coating.In this paper,three ceramic-based high-temperature seal coatings with different polyphenylene ester contents and a pure Yttria-stabilised zirconia coating were prepared by atmo-spheric plasma spraying(APS).The hardness and modulus of elasticity of the coated surfaces were obtained by hardness and modulus of elasticity tests,and the coatings were subjected to high-speed touch abrasion tests.The Hertzian contact model was used to calculate the maximum normal contact load on the coating during the process.The test values were compared with the theoretical values and it was found that the calculated values were always greater than the test values.In order to make the Hertzian contact model more accurate in calculating the touching and abrasion forces,the contact coefficients in the Hertzian contact model were optimized.Substituting the optimized coeffi-cients into the Hertzian contact model,the results show that the calculated results after optimizing the coefficients are much closer to the test values,with deviations from the test values ranging from 1%to 38%.

Mechanism of slag pellets sticking on the wall of reduction pot in magnesium production by Pidgeon process

In the preparation of magnesium by Pidgeon process,the phenomenon slag pellets sticking on the wall of reduction pot always appear,and the glaze sticking on the inner wall of the reduction pot is difficult to remove.The mechanism of this phenomenon is studied in this work by X-ray fluorescence spectrometer(XRF)measurement,electron probe microanalyzer scanning(EPMA)analysis,differential scanning calorimetry(DSC)analysis,and thermodynamic calculations.The main components of the glaze are MgO,Ca_(12)Al_(14)F_(2)O_(32),CaF_(2),CaO,and a small amount of Ca_(4)Si_(2)O_(7)F_(2).The solid-liquid transition temperature of Ca_(12)Al_(14)F_(2)O_(32)and CaF_(2)is close to the production temperature of Pidgeon process,which leads to the bonding between the slag pellets and the pot wall.The loss of CaF_(2)in glaze layer will reduce the total amount of liquid phase and increase the temperature at which Ca_(12)Al_(14)F_(2)O_(32)is completely transformed into liquid phase,which causes glaze layer sticking on the inner wall of the reduction pot.

Study on Sealing Characteristics of Sliding Seal Assembly of Aircraft Hydraulic Actuator

The hydraulic actuator,known as the"muscle"of military aircraft,is responsible for flight attitude adjustment,trajectory control,braking turn,landing gear retracting and other actions,which directly affect its flight efficiency and safety.However,the sealing assembly often has the situation of over-aberrant aperture fit clearance or critical over-aberrant clearance,which increases the failure probability and degree of movable seal failure,and directly affects the flight efficiency and safety of military aircraft.In this paper,the simulation model of hydraulic actuator seal combination is established by ANSYS software,and the sealing principle is described.The change curve of contact width and contact pressure of combination seal under the action of high-pressure fluid is drawn.The effects of different oil pressure,fit clearance and other parameters on the sealing performance are analyzed.Finally,the accelerated life test of sliding seal components is carried out on the hydraulic actuator accelerated life test rig,and the surface morphology is compared and analyzed.The research shows that the O-ring is the main sealing element and the role of the check ring is to protect and support the O-ring to prevent damage caused by squeezing into the fit clearance,so the check ring bears a large load and is prone to shear failure.Excessive fit clearance is the main factor affecting the damage of the check ring,and the damage parts are mainly concentrated at the edge of the sealing surface.This paper provides a theoretical basis for the design of hydraulic actuator and the improvement of sealing performance.

Application of Choquet Integral-Importance-Performance Analysis and TOPSIS Methods in Approaching the Preference Factors of Calligraphy and Seal Engraving Imagery

Classical Chinese characters,presented through calligraphy,seal engraving,or painting,can exhibit different aesthetics and essences of Chinese characters,making them the most important asset of the Chinese people.Calligraphy and seal engraving,as two closely related systems in traditional Chinese art,have developed through the ages.Due to changes in lifestyle and advancements in modern technology,their original functions of daily writing and verification have gradually diminished.Instead,they have increasingly played a significant role in commercial art.This study utilizes the Evaluation Grid Method(EGM)and the Analytic Hierarchy Process(AHP)to research the key preference factors in the application of calligraphy and seal engraving imagery.Different from the traditional 5-point equal interval semantic questionnaire,this study employs a non-equal interval semantic questionnaire with a golden ratio scale,distinguishing the importance ratio of adjacent semantic meanings and highlighting the weighted emphasis on visual aesthetics.Additionally,the study uses Importance-Performance Analysis(IPA)and Technique for Order Preference by Similarity to Ideal Solution(TOPSIS)to obtain the key preference sequence of calligraphy and seal engraving culture.Plus,the Choquet integral comprehensive evaluation is used as a reference for IPA comparison.It is hoped that this study can provide cultural imagery references and research methods,injecting further creativity into industrial design.

BaO-CaO-Al_(2)O_(3)-B_(2)O_(3)-SiO_(2)中温SOFC封接玻璃的失效性分析与性能改进研究

热稳定性及致密度是影响中温固体氧化物燃料电池封接玻璃实际应用的两大重要因素。通过传统固相熔融退火法制备32.96BaO-14.45CaO-4.87Al_(2)O_(3)-14.62B_(2)O_(3)-33.10SiO_(2)(BCS1)基础玻璃,采用X射线衍射分析、扫描电镜、高温显微镜等表征手段来探究其封接失效原因,并提出改进方法,以获得性能稳定的致密封接材料。结果表明,BCS1基础玻璃中的六方BaAl_(2)SiO_(8),经1073 K热处理会转变为低膨胀单斜相,造成基础玻璃与Ni-YSZ阳极的热膨胀系数不匹配,再者BCS1玻璃易过烧发泡,内部存在的大量孔隙容易引发气体泄漏。通过额外增加Al_(2)O_(3)含量,可以提高封接玻璃的热稳定性、热匹配性和致密性,并使封接玻璃与Ni-YSZ阳极具有良好的界面结合。该研究为中温固体氧化物燃料电池封接玻璃的性能改进提供了有效的途径,有助于推动该领域技术的发展和应用。