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Impact of Seasalt Deposition on Acid Soils in Maritime Regions 被引量:2
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作者 ZHANG Zhen-HuaInstitute of Soil and Fertilizer, Jiangsu Academy of Agricultural Sciences, Nanjing 210014 (China), 《Pedosphere》 SCIE CAS CSCD 2003年第4期375-380,共6页
The characteristics of seasalt deposition and its impact on acid soils in maritime regions are reviewed. It is pointed out that studies involving the impact of seasalt deposition on acid soils have been concentrated o... The characteristics of seasalt deposition and its impact on acid soils in maritime regions are reviewed. It is pointed out that studies involving the impact of seasalt deposition on acid soils have been concentrated on short-term effects on soil and water acidification. A deep consideration of long-term effects on soil acidification in maritime regions is still needed. 展开更多
关键词 ACIDIFICATION maritime regions seasalt deposition
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潍河下游地区海咸水入侵动态系统分析 被引量:7
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作者 陈鸿汉 张永祥 +1 位作者 王新民 任仲宇 《地理科学》 CSSCI CSCD 北大核心 1996年第3期224-231,共8页
以潍河下游为研究区,采用趋势面分析等数理统计方法对海咸水入侵历史、现状及其发展规律进行定量研究,指出产生海咸水入侵的根本原因是由于过量开采地下淡水资源,必须科学控制地下淡水资源开采量。
关键词 潍河下游 海咸水入侵 动态系统 趋势面 海洋
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海洋生物生产力的气溶胶表征及其在冰芯研究中的意义 被引量:1
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作者 曹俊忠 李天杰 《极地研究》 CAS CSCD 1997年第4期254-257,共4页
自中国青岛到南极中山站共13个样品粗粒部分S和Cl浓度的分析结果表明海洋气溶胶中的非海盐源S浓度与Cl浓度的分布是相似的,因而说明S和Cl一样都来自海洋并且主要受海洋气溶胶总量的影响。但非海盐硫与Cl比值的经向变化则... 自中国青岛到南极中山站共13个样品粗粒部分S和Cl浓度的分析结果表明海洋气溶胶中的非海盐源S浓度与Cl浓度的分布是相似的,因而说明S和Cl一样都来自海洋并且主要受海洋气溶胶总量的影响。但非海盐硫与Cl比值的经向变化则与海洋初级生产力的空间分布是一致的,更能反映海洋生物的活动强度。本文计算了南极Vostok冰芯中非海盐硫酸根与海盐总量的比值,该比值的变化和冰芯所反映的温度变化是一致的,暖期高于冷期。 展开更多
关键词 海洋 气溶胶 古气候 海洋生物 生产力 冰芯
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Hydrochemistry of the meltwater streams on Fildes Peninsula, King George Island, Antarctica
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作者 YE Liping ZHANG Ruifeng +2 位作者 SUN Qizhen JIN Jie ZHANG Jing 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2018年第6期2181-2193,共13页
King George Island, situated in the South Shetland Islands archipelago, is one of the most visited sites in Antarctica. Antarctica attracts much attention because it is one of the most sensitive areas under the influe... King George Island, situated in the South Shetland Islands archipelago, is one of the most visited sites in Antarctica. Antarctica attracts much attention because it is one of the most sensitive areas under the influence of global warming. To understand its hydrochemistry characteristics, we collected various types of water samples, including samples from streams, meltwaters, ground waters, snow and ice from around the Great Wall Station, Fildes Peninsula, King George Island, from January to February, 2015. Major ions, alkalinities, silicate, pH, dissolved oxygen, temperature, and electric conductivities were measured. Several approaches were applied to identify processes that af fect the hydrochemistry on Fildes Peninsula, including ternary diagrams, principal components analysis and cluster analysis. Our data suggest that atmospheric seasalt deposition is the main factor controlling the hydrochemistry on Fildes Peninsula. After atmospheric influences were corrected for seasalt, we defined the weathering of local rocks to be another important factor on the Peninsula's hydrochemistry. Processes such as Ca dissolution from the Ca-bearing basalt, Si loss through secondary mineralization and biological uptake influence the chemical composition of runof fs on the peninsula. Cluster analysis identified 4 groups of streams based on their hydrochemical features, which reflect their original weathering characters under icecap and the combined effects with melt snow, biological activity and the anthropogenic input. 展开更多
关键词 HYDROCHEMISTRY runoffs seasalt water-rock INTERACTION Fildes PENINSULA ANTARCTICA
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海盐沉降对森林沼泽土交换性阳离子组成和交换过程的影响(英文)
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作者 张振华 FARRELLEP 《江苏农业学报》 CSCD 北大核心 1999年第3期167-172,共6页
1996年1月至1997年3月,每月1次在爱尔兰 Galw ay 县 Cloosh 林地采集土壤样品,并分析其交换性阳离子( Ca2 + 、 Mg2 + 、 K+ 、 Na+ 、 Fe3 + 、 M n2+ 、 Al3 + 和 H+ )的... 1996年1月至1997年3月,每月1次在爱尔兰 Galw ay 县 Cloosh 林地采集土壤样品,并分析其交换性阳离子( Ca2 + 、 Mg2 + 、 K+ 、 Na+ 、 Fe3 + 、 M n2+ 、 Al3 + 和 H+ )的浓度。结果显示:在沼泽土0~60 cm 土层中,交换性阳离子主要为 Mg2+ 和 Na+ ,表现了海盐沉降对其的影响,但在森林土壤表层的 O1 层中,交换性阳离子主要为 Ca2 + ,说明其受森林及管理的影响;交换性阳离子的分布随土层深度和森林生长、休眠季节的更替而发生变化,体现了营养元素在森林生态系统中的迁移性和循环性。海盐沉降较小时,将会对土壤阳离子交换过程产生一定影响。可以推测,海盐沉降较大或特大时,土壤中交换性阳离子的分布则将产生明显变化。 展开更多
关键词 海盐沉降 交换性阳离子 阳离子交换 森林沼泽土
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Heterogeneous reaction mechanism of gaseous HNO3 with solid NaCI: a density functional theory study 被引量:1
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作者 Nan ZHAO Qingzhu ZHANG Wenxing WANG 《Frontiers of Environmental Science & Engineering》 SCIE EI CAS CSCD 2016年第5期49-58,共10页
Sea salt particles containing NaCl are among the most abundant particulate masses in coastal atmosphere. Reactions involving sea salt particles potentially generate Cl radicals, which are released into coastal atmosph... Sea salt particles containing NaCl are among the most abundant particulate masses in coastal atmosphere. Reactions involving sea salt particles potentially generate Cl radicals, which are released into coastal atmosphere. Cl radicals play an important role in the nitrogen and O3 cycles, sulfitr chemistry and particle formation in the troposphere of the polluted coastal regions. This paper aimed at .the heterogeneous reaction between gaseous HNO3 .and solid NaCl. The mech.anis.m was in.vestigatedby density functional theory (DFT). The results imply that water molecules induce the surface reconstruction, which is essential for the heterogeneous reaction. The surface reconstruction on the defective (710) surface has a barrier of 10.24 kcal.mol-1 and is endothermic by 9.69 kcal.mol-1, whereas the reconstruction on the clean (100) surface has a barrier of 18.46 kcal.mol-1 and isendothermic by 12.96 kcal.mol-1. The surface reconstruction involved in water-adsorbed (710) surface is more energetically favorable. In comparison, water molecules adsorbed on NaCl (100) surface likely undergo water diffusion or desorption. Further, it reveals that the coordination number of the Cl-out is reduced after the surface reconstruction, which assists Clout to accept the proton from HNO3. HCl is released from heterogeneous reactions between gaseous HNO3 and solid NaCl and can react with OH free radicals to produce atomic Cl radicals. The results will offer further insights into the impact of gaseous HNO3 on the air quality of the coastal areas. 展开更多
关键词 seasalt particles NACL HNO3 Heterogeneous reaction Reaction mechanism Density functional theory
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