Bipolar membrane electrodialysis integrated with in-situ CO_(2)absorption for simulated seawater concentrate utilization,carbon storage and production of sodium carbonate

In the context of carbon capture,utilization,and storage,the high-value utilization of carbon storage presents a significant challenge.To address this challenge,this study employed the bipolar membrane electrodialysis integrated with carbon utilization technology to prepare Na_(2)CO_(3)products using simulated seawater concentrate,achieving simultaneous saline wastewater utilization,carbon storage and high-value production of Na_(2)CO_(3).The effects of various factors,including concentration of simulated seawater concentrate,current density,CO_(2)aeration rate,and circulating flow rate of alkali chamber,on the quality of Na_(2)CO_(3)product,carbon sequestration rate,and energy consumption were investigated.Under the optimal condition,the CO_(3)^(2-)concentration in the alkaline chamber reached a maximum of 0.817 mol/L with 98 mol%purity.The resulting carbon fixation rate was 70.50%,with energy consumption for carbon sequestration and product production of 5.7 k Whr/m^(3)CO_(2)and1237.8 k Whr/ton Na_(2)CO_(3),respectively.This coupling design provides a triple-win outcome promoting waste reduction and efficient utilization of resources.

Effect of dissolved oxygen on electrochemical corrosion behavior of 2205 duplex stainless steel in hot concentrated seawater

The corrosion behavior of 2205 duplex stainless steel was investigated in hot concentrated seawater with different dissolved oxygen(DO) concentration by electrochemical measurement techniques and surface analysis methods. DO obviously enhances the cathodic reaction process, the formation of passive film and polarization resistance. With increasing the DO concentration from 0.34 to 3.06 mg L^(-1), the relative contents of Fe_(2)O_(3) and Cr_(2)O_(3) and the Cr-enrichment gradually enlarge in the passive film. The higher DO concentrations result in lower defect densities and thicker of space charge layers in the passive films,whichmayeffectively inhibit the intrusion of aggressive chloride ions. The increment inDOconcentration clearly increases the pitting potential, but decreases the repassivation potential. It may weaken both the occurrence and repassviation tendencies of stable pitting corrosion.

Effect of Vacuum Pressure on the Initiation and Propagation of Pitting Corrosion of 2205 Duplex Stainless Steel in Concentrated Seawater

Pitting initiation and stable propagation behaviors of 2205 duplex stainless steel were investigated in the hot concentrated seawater under vacuum pressures by potentiostatic polarization. Both applied potentials and vacuum pressures greatly influence the pitting corrosion. Higher potentials lead to much faster stable pitting initiation and growth rates in both static(101.3 kPa) and dynamic(28.4 kPa) solutions. The pressure reduction can also accelerate the pitting initiation rate. However, the boiling of solution can influence the pitting propagation mechanism. The dynamic actions of boiling bubbles are unfavorable to the pit propagation and result in the formation of relatively smooth pit bottom without secondary pits.

Passivation Behavior of 2507 Super Duplex Stainless Steel in Hot Concentrated Seawater:Influence of Temperature and Seawater Concentration

The electrochemical behavior and passivation properties of 2507 super duplex stainless steel(SDSS)in the hot concentrated seawater with different concentrations at different temperatures are characterized by electrochemical methods and X-ray photoelectron spectroscopy.The passive film formed on 2507 SDSS belongs to n-type semiconductor and mainly composed of hydroxides and oxides of Fe and Cr under all circumstances.The protectiveness of the passive film decreases with the increase in temperature mainly because of the increase in defect density in the passive film.The corrosion resistance of 2507 decreases with the increase in seawater concentration,and the critical pitting temperature also decreases.