A new nonlinear optical crystal of sodium terbium borate （Na2.67Tb2.11B3O9, Mr = 573.14） was synthesized by solid reaction method. The colorless transparent single crystals were grown from the high temperature solut...A new nonlinear optical crystal of sodium terbium borate （Na2.67Tb2.11B3O9, Mr = 573.14） was synthesized by solid reaction method. The colorless transparent single crystals were grown from the high temperature solution by employing NaBO2 as flux. The structure was deter- mined by single-crystal X-ray diffraction method. The compound crystallizes in the orthorhombic system, space group Amm2 with a = 5.0744（10）, b = 10.990（2）, c = 6.9078（14） A, V = 385.24（13） A3, Dc = 4.941 g/cm3, F（000） = 250, Z = 2, μ= 9.205 mm-1, the final R = 0.0253 and wR = 0.0610. Its three-dimensional network structure is constructed from isolated BO33-, Na（1）O8, Na（2）O6, Na（3）O6 and Tb（1）O9 polyhedra. Variable-temperature magnetic susceptibility measurements show the compound is paramagnetic （μj = 7.04 μb）. The intensity of the second harmonic generation of Na2.67Tb2.11B3O9 is 2.5 times that of KDP.展开更多
The real-time second harmonic generation was employed to investigate the[2＋2]photodimerization of styrylquinoline（SQ） derivatives in Langmuir-Blodgett（LB） monolayers deposited from aqueous subphases with differen...The real-time second harmonic generation was employed to investigate the[2＋2]photodimerization of styrylquinoline（SQ） derivatives in Langmuir-Blodgett（LB） monolayers deposited from aqueous subphases with different acidity.It was discovered that the photodimerization rate constant significantly decreased upon the addition of acid.The additional atomic force microscopy measurements revealed that surface morphologies were correlated to the photodimerization kinetics.These experimental results provide direct evidence for the topo-chemical mechanisms of[2＋2]photodimerization in LB films.The current study demonstrates that the intermolecular interactions and aggregation structures play important roles in the photochemical properties at surfaces.展开更多
基金supported by the National Natural Science Foundation of China (91022025, 51072036)the Natural Science Foundation of Fujian Province (2010J01284)
文摘A new nonlinear optical crystal of sodium terbium borate （Na2.67Tb2.11B3O9, Mr = 573.14） was synthesized by solid reaction method. The colorless transparent single crystals were grown from the high temperature solution by employing NaBO2 as flux. The structure was deter- mined by single-crystal X-ray diffraction method. The compound crystallizes in the orthorhombic system, space group Amm2 with a = 5.0744（10）, b = 10.990（2）, c = 6.9078（14） A, V = 385.24（13） A3, Dc = 4.941 g/cm3, F（000） = 250, Z = 2, μ= 9.205 mm-1, the final R = 0.0253 and wR = 0.0610. Its three-dimensional network structure is constructed from isolated BO33-, Na（1）O8, Na（2）O6, Na（3）O6 and Tb（1）O9 polyhedra. Variable-temperature magnetic susceptibility measurements show the compound is paramagnetic （μj = 7.04 μb）. The intensity of the second harmonic generation of Na2.67Tb2.11B3O9 is 2.5 times that of KDP.
基金supported by the National Natural Science Foundation of China(Nos.21473217,21227802 and 21303216)the Chinese Ministry of Science and Technology(No.2013CB834504)
文摘The real-time second harmonic generation was employed to investigate the[2＋2]photodimerization of styrylquinoline（SQ） derivatives in Langmuir-Blodgett（LB） monolayers deposited from aqueous subphases with different acidity.It was discovered that the photodimerization rate constant significantly decreased upon the addition of acid.The additional atomic force microscopy measurements revealed that surface morphologies were correlated to the photodimerization kinetics.These experimental results provide direct evidence for the topo-chemical mechanisms of[2＋2]photodimerization in LB films.The current study demonstrates that the intermolecular interactions and aggregation structures play important roles in the photochemical properties at surfaces.
