Effect of ECAP processing on distribution of second phase particles,hardness and electrical conductivity of Cu-0.81Cr-0.07Zr alloy

The effect of equal-channel angular pressing(ECAP)processing at room temperature and 300℃on the distribution of the second phase particles and its influence on hardness and electrical conductivity of the commercial Cu-0.81Cr-0.07Zr alloy were investigated.Microstructural characterization indicated that the area fraction of coarse Cr-rich particles decreased after ECAP processing.This reduction was attributed to the Cr dissolution induced by plastic deformation.The electrical conductivity of the alloy decreased by 12%after 4 ECAP passes at room temperature due to the increase of electrons scattering caused by higher Cr content in solid solution and higher density of defects in the matrix.These results were supported by the reduction of the Cu lattice parameter and by the exothermic reactions,during differential scanning calorimetry(DSC)analysis,observed only in the samples subjected to ECAP processing.Aging heat treatment after ECAP processing promoted an additional hardening effect and the complete recuperation of the electrical conductivity,caused by the re-precipitation of the partially dissolved particles.The better combination of hardness(191 HV)and electrical conductivity(83.5%(IACS))was obtained after 4 ECAP passes at room temperature and subsequent aging at 380℃for 1 h.

Phase-field study of the second phase particle effect on texture evolution of polycrystalline material

The second phase particle effect on texture evolution of polycrystalline material is studied through phase-field method. A unique field variable is introduced into the phase-field model to represent the second phase particles. Elastic interaction between particles and grains is also considered. Results indicate that in the presence of second phase particles the average particle diameter turns smaller than in the absence of these particles and retards texture formation by pinning effect. The second phase particles change the strain energy profile, which tremendously influences the pinning effect.

Monte Carlo study on abnormal growth of Goss grains in Fe-3%Si steel induced by second-phase particles

The selective abnormal growth of Goss grains in magnetic sheets of Fe-3%Si （grade Hi-B） induced by second-phase particles （AlN and MnS） was studied using a modified Monte Carlo Ports model. The starting microstructures for the simulations were generated from electron backscatter diffraction （EBSD） orientation imaging maps of recrystallized samples. In the simulation, second-phase particles were assumed to be randomly distributed in the initial microstructures and the Zener drag effect of particles on Goss grain boundaries was assumed to be selectively invalid because of the unique properties of Goss grain boundaries. The simulation results suggest that normal growth of the matrix grains stagnates because of the pinning effect of particles on their boundaries. During the onset of abnormal grain growth, some Goss grains with concave boundaries in the initial microstructure grow fast abnormally and other Goss grains with convex boundaries shrink and eventually disappear.

Grain growth simulation with the second phase particle pinning for heat-affected zone of microalloyed steel welds

The second phase particle dispersed in microalloyed steel has different effects on grain growth depending on their size and volume fiaction of the second phase particles which will change during welding thermal cycles. The particle coarsening and dissolution kinetics model was analyzed for continuous heating and cooling. In addition, based on experimental data, the coupled equation of grain growth was established by introducing limited size of grain growth with the consideration of the second phase particles pinning effects. Using Monte Carlo method based on experimental data model, the grain growth simulation for heat-affected zone of microalloyed steel welds was achieved. The calculating results were well in agreement with that of experiments.

Microstructure and mechanical properties of Mg-Gd-Y-Zr alloy processed by equal channel angular pressing

Microstructure evolution and texture development and their effects on mechanical properties of a Mg-Gd-Y-Zr alloy during equal channel angular pressing（ECAP） were investigated.It is found that the microstructure is still inhomogeneous after four passes,and two zones,namely the fine grain zone（FGZ） and the coarse grain zone（CGZ） are formed.The grain refinement occurs mainly by particle-stimulated nucleation（PSN） mechanism,which led to a more random texture after four passes of ECAP.In the ECAP-processed alloy,the strength did not increase while the ductility was enhanced dramatically compared with the as-received condition.The change of ductility of this alloy was discussed in terms of texture and second phase particles.

OUT-OF-PILE CORROSION RESISTANCE OF NEW ZIRCONIUM ALLOYS IN 500 ℃/10 3MPa STEAM

he out of pile corrosion resistance of new Zirconium alloys in 500℃/10 3MPa steam has been investigated and the effect of alloying elements, Sn,Nb,Fe,Cr on the property has been analyzed. The results show that the new alloys have better corrosion resistance than Zircaloy 4. That no nodular corrosion is found during test cycles shows the nodular corrosion resistance can be dramatically improved by addition of alloying elements Nb. The Fe/Cr ratio should be properly controlled if there is Cr addition in the alloys when developing new alloys.

Effect of cooling conditions on corrosion resistance of friction stir welded 2219-T62 aluminum alloy thick plate joint

Friction stir welding (FSW) with water cooling and air cooling was used to weld 2219-T62 aluminum alloy joints with a thickness of 20 mm. The effect of cooling conditions on the corrosion resistance of joints in 3.5% NaCl solution was investigated using the open circuit potential (OCP), the potentiodynamic polarization, and the corrosion morphology after immersing for different time. And the precipitates distribution was characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results reveal that the weld nugget zone (WNZ) owning positive potential, lower corrosion current density and fine and uniform precipitates, is much more difficult to corrode than the heat affected zone (HAZ) and the base metal (BM). Compared with air-cooled joint, the water-cooled joint has better corrosion resistance. In addition, the results of microstructure observation show that the potential, distribution and size of second phase particles determine the corrosion resistance of FSW AA2219 alloy joints in chlorine-contained solution.

Effects of rare earth Ce addition on microstructure and mechanical properties of impure copper containing Pb

The effects of rare earth Ce on the microstructure and mechanical properties of impure copper containing Pb were investigated using OM,SEM,EPMA,TEM and tensile testing.TEM and EDS analysis reveal that spherical CePb3 particles form after Ce addition.CePb3 particles,with average size of^3.6μm,homogenously distribute in the Cu matrix.Due to small lattice misfit(~4.62%)with Cu matrix,CePb3 particles can act as effective nucleation sites beneficial to the grain refinement.Pb at grain boundaries seriously deteriorates the mechanical properties of Cu.The tensile strength and the elongation of Cu-0.1 Pb are decreased by 43.1%and 56.7%compared with those of pure copper,respectively.Ce can purify grain boundaries,cause the precipitation of CePb3 particles and refine grain sizes,which contribute to significant improvement of the mechanical properties of Cu.Compared with Cu-0.1Pb,the tensile strength(179 MPa)and the elongation(38.5%)of Cu-0.1Pb-0.3Ce are increased by 117.6%and 151.6%,respectively.

Kinetics of Precipitation Behavior of Second Phase Particles in Ferritic Ti-Mo Microalloyed Steel

Two types of stress relaxation tests were carried out to investigate the incubation time for incipient precipi-tation of Ti（C,N） in deformed austenite and （Ti,Mo）C in ferrite of ferritic Ti-Mo microalloyed steel The size dis-tribution, amount and chemical composition of precipitates were obtained by using physicochemical phase analysis, and calculated according to thermodynamics and kinetics. The experimental results demonstrated that the incubation time was reduced with increasing Ti content, and prolonged with the addition of Mo. After 30 % deformation at 850 ℃, the nucleation of strain-induced Ti（C,N） was a relatively slow process. On the other hand, the temperature where the nucleation rate of （Ti, Mo）C in ferrite was the highest descended first and then ascended with increasing Ti content, and so did the temperature where the incubation time was the shortest. The key point is that the tempera-ture of steel containing about 0.09 % Ti is the lowest. The mass fraction of MC-type particles with size smaller than 10 nm in steel containing 0.09% Ti and 0.2% Mo reached 73.7%. The size distributions of precipitates in steel containing 0.09% Ti were relatively concentrated compared with that in steel containing 0.07% Ti.

Inhibition of Abnormal Grain Growth in Stir Zone via In‑Situ Intermetallic Particle Formation During Friction Stir Welding of AA6061

Abnormal grain growth(AGG)has been widely observed in many friction stir welded(FSWed)joints during post-weld heat treatment(PWHT).The coarse grain structure not only reduces the strength of the joint but also limits its usage in superplastic forming.Several methods have been reported in previous studies to inhibit AGG,but all of them can only mitigate AGG.Complete inhibition of AGG was not achieved.In the current research,AGG was widely observed during the PWHT of friction stir welded AA6061.Multi-pass FSW enhanced the thermal stability of the as-welded grain structure but did not eliminate the occurrence of AGG.A new welding method was developed with the ball-milled Al–Ti powder mixture introduced into the stir zone and proved effective in inhibiting AGG in FSWed AA6061 during PWHT.The adoption of 5-pass FSW with an alternate rotation mode succeeded in producing an AGG-free sample.Microscopic characterizations conducted in the stir zone showed an evolution of Al–Ti powder mixture into different particle formations and Al3Ti new phase.Quantitative analysis of the second phase particles(SPPs)in the stir zone confirmed the increases in both particle number and average size.The quantitative results fit well with Humphreys’grain growth model,which theoretically explains the mechanism for AGG inhibition,i.e.,the significantly enhanced particle pinning effect.

Effect of heat treatment on the Nb distribution and corrosion resistance of Zr-Sn-Nb-Fe zirconium alloy

After being treated in different ways, Zr-Sn-Nb-Fe alloy specimens are exposed in 0.01mol/L LiOH aqueous solution at 350℃ under 16.8 MPa. The examination of microstructures and second phase particles （SPPs） of these specimens was carried out by high-resolution transmission electron microscopy （HR-TEM）. The specimens treated at 800℃ before the final cold rolling have a better corrosion resistance than those treated at 680℃, and the specimens treated at 500℃, after the final cold rolling, have a better corrosion resistance than those treated at 560℃. TEM examination shows that the SPPs existing in the 800℃/500℃ specimen, which has the best corrosion resistance, contains a lot of Nb element, which results in the reduction of the niobium content in the α-Zr solid solution.

A study on welded joint toughness of X-60 steel

Charpy impact test and COD test were performed on the specimens subjected to simulated welded thermal cycle and the specimens taken from welded joint. The optical microscope, TEM, SEM, EDAX and XRD analysis have been used to investigate the behaviors of second phase particles and the effects of microstructure on toughness separately. The results are as follows. The dispersed second phase particles can effectively retard the growth of austenite grain in the coarse grained HAZ (CGHAZ), and improve the toughness. When t 8/5 is different, the behaviors of the particles are also different in dissolving, coarsening and re precipitating. The ability of retarding the growth of austenite grain will be affected. When t 8/5 increases from 10 s to 70 s , the microstructure of CGHAZ will transform from upper bainite and granular bainite to granular bainite, and the size of austenite grain will grow a little, thus the toughness of the materials decreases slightly.