Magnetic entropy change and magnetic phase transition of LaFe11.4Al1.6Cx （x=0-0.8） compounds

The unit cell volume and phase transition temperature of LaFe11.4Al1.6Cx compounds have been studied. The magnetic entropy change, refrigerant capacity and the type of magnetic phase transition are investigated in detail for LaFe11.4Al1.6Cx with x=0.1, All the LaFe11.4Al1.6Cx （x=0-0.8） compounds have the cubic NaZn13-type structure. The addition of carbon atoms brings about a considerable increase in the lattice parameter. The bulk expansion results in the change of phase transition temperature （Tc）, Tc increases from 187K to 269 K with x varying from 0.1 to 0.8, Meanwhile an increase in the lattice parameter can also cause a change of the magnetic ground state from antiferromagnetic to ferromagnetic. Large magnetic entropy change IASI is found over a large temperature range around Tc and the refrigerant capacity is about 322J/kg for LaFe11.4Al1.6C0.1. The magnetic phase transition belongs in weakly first-order one for x=0.1.

Tunable Electronic and Magnetic Properties from Structure Phase Transition of Layered Vanadium Diselenide

The atomic geometry, structure stability, electronic and magnetic properties of VSe2 were systematically investigated based on the density functional theory（DFT）. Varying from 3D to 2D four VSe2 structures, bulk 2H-VSe2 and 1T-VSe2, monolayer H-VSe2 and T-VSe2 are all demonstrated as thermodynamically stable by lattice dynamic calculations. More interestingly, the phase transition temperature is dramatically different due to the lattice size. Finally, owing to different crystal structures, H-VSe2 is semimetallic whereas T-VSe2 is totally metallic and also they have different magnetic moments. Our main argument is that being exfoliated from bulk to monolayer, 2H-VSe2 transforms to T-VSe2, accompanied by both semimetallic-metallic transition and dramatic magnetic moment variation. Our calculations provide a novel structure phase transition and an efficient way to modulate the electronic structure and magnetic moment of layered VSe2, which suggests potential applications as high-performance functional nanomaterial.

Chiral phase transition of quark matter in the background of parallel electric and magnetic fields

We report on our results about spontaneous chiral symmetry breaking for quark matter in the background of static and homogeneous parallel electric field,E,and magnetic field,B.A Nambu–Jona–Lasinio model is used to compute the dependence of the chiral condensate at finite temperature,E and B.We study the effect of this background on inverse catalysis of chiral symmetry breaking for E and B of the same order of magnitude.We also consider the effect of equilibration of chiral density,n_5,produced by axial anomaly on the critical temperature.The equilibration of n_5 allows for the introduction of the chiral chemical potential,u_5,which is computed selfconsistently as a function of temperature and field strength.We find that even if the chiral medium is produced by the fields the thermodynamics,with particular reference to the inverse catalysis induced by the external fields,it is not very affected by n_5 at least if the average u_5,at equilibrium is not too large.

Field-induced Magnetic Phase Transitions in FerrimagnetGdMn_2Ge_2: H-T Magnetic Phase Diagrams

Magnetic properties of a two sublattice ferrimagnet with antiferromagnetic exchange interaction inside one of the sublattices are calculated within the framework of the molecular field theory taking into account the anisotropy of unstable sublattice. The magnetization curves of single crystal GdMn 2Ge 2 for the magnetic field parallel and perpendicular to the c axis at different temperatures are calculated. Field induced magnetic phase transitions in GdMn 2Ge 2 are discussed. Calculated H T magnetic phase diagrams are in fair agreement with experimental data.

Pressure induced magnetic and semiconductor–metal phase transitions in Cr_2MoO_6

We investigate magnetic ordering and electronic structures of Cr2MoO6under hydrostatic pressure. To overcome the band gap problem, the modified Becke and Johnson exchange potential is used to investigate the electronic structures of Cr2MoO6. The insulating nature at the experimental crystal structure is produced, with a band gap of 1.04 eV, and the magnetic moment of the Cr atom is 2.50 μB, compared to an experimental value of about 2.47 μB. The calculated results show that an antiferromagnetic inter-bilayer coupling–ferromagnetic intra-bilayer coupling to a ferromagnetic inter-bilayer coupling–antiferromagnetic intra-bilayer coupling phase transition is produced with the pressure increasing. The magnetic phase transition is simultaneously accompanied by a semiconductor–metal phase transition. The magnetic phase transition can be explained by the Mo–O hybridization strength, and ferromagnetic coupling between two Cr atoms can be understood by empty Mo-d bands perturbing the nearest O-p orbital.

Crystal structures, phase relationships, and magnetic phase transitions of R_5M_4 compounds (R = rare earths, M = Si, Ge)

Our recent studies of the crystal structures, phase transitions, and magnetic properties of intermetallic compounds RsM4 （R = rare earths; M = Si, Ge） are reviewed briefly. First, crystal structures, phase relationships, and magnetic prop- erties of several 5：4 compounds, including Nd5 Si4-xGex, Pr5 Si4_xGex, Gds-xLaxGe4, La5 Si4, and Gd5 Sn4, are presented. In particular, the canted spin structures as well as the magnetic phase transitions in PrsSi2Ge2 and PrsGe4 investigated by neutron powder diffractions and small-angle neutron scattering are reviewed. Second, the crystal structures and magnetic properties of the most studied compounds Gds（Si,Ge）4 are summarized. The focus is on the parent compound GdsGe4, which is an amazing material exhibiting magnetic anisotropy, angular dependent spin-flop transition, metastable magnetic response, Griffiths-like phase, thermal effect under pulsed fields, antiferromagnetic and ferromagnetic resonances, pro- nounced effects of impurities, and high-field induced magnetic transitions.

MAGNETIC PHASE TRANSITIONS AND MAGNETIC PROPERTIES OF Nd_3(Fe,Mo)_(29) COMPOUND AND ITS NITRIDE

ＭＡＧＮＥＴＩＣＰＨＡＳＥＴＲＡＮＳＩＴＩＯＮＳＡＮＤＭＡＧＮＥＴＩＣＰＲＯＰＥＲＴＩＥＳＯＦＮｄ３（Ｆｅ，Ｍｏ）２９ＣＯＭＰＯＵＮＤＡＮＤＩＴＳＮＩＴＲＩＤＥ①ＰａｎＨｏｎｇｇｅ，ＷａｎｇＸｉｎｈｕａ，ＣｈｅｎＹｕｎａｎｄＣｈｅｎＣｈａｎｇｐｉｎＤ...

Deconfinement Phase Transition with External Magnetic Field in the Friedberg-Lee Model

The deconfinement phase transition with external magnetic field is investigated in the Friedberg-Lee model. We expand the potentiM around the two locM minima of the first-order deconfinement phase transition and extract the ground state of the system in the frame of functional renormalization group. By solving the flow equations we find that the magnetic field displays a catalysis effect and it becomes more difficult to break through the confinement.

Chiral Magnetic Effect and Chiral Phase Transition

We study the influence of the chiral phase transition on the chiral magnetic effect. The azimuthal charge-particle correlations as functions of the temperature are calculated. It is found that there is a pronounced cusp in the correlations as the temperature reaches its critical value for the QCD phase transition. It is predicted that there will be a drastic suppression of the charge-particle correlations as the collision energy in RHIC decreases to below a critical value. We show then the azimuthal charge-particle correlations can be the signal to identify the occurrence of the QCD phase transitions in RHIC energy scan experiments.

Phase transition in bilayer quantum Hall system with opposite magnetic field

We construct a mapped bilayer quantum Hall system to realize the proposal that two nearly flatbands have opposite Chern numbers.For the C=±1 case,the two Landau levels of the bilayer experience opposite magnetic fields.We consider a mapped bilayer quantum Hall system at total fillingν_(t)=1/2+1/2where the intralayer interaction is repulsive and the interlayer interaction is attractive.We take exact diagonalization(ED)calculations on a torus to study the phase transition when the separation distance d/l_(B)is driven.The critical point at d_(c)/l_(B)=0.68 is characterized by a collapse of degeneracy and a crossing of energy levels.In the region d/l_(B)<d_(c)/l_(B),the states of each level are highly degenerate.The pair-correlation function indicates electrons with opposite pseudo-spins are strong correlated at r=0.We find an exciton stripe phase composed of bound pairs.The ferromagnetic ground state is destroyed by the strong effective attractive potential.An electron composite-Fermion(eCF)and a hole composite Fermion(hCF)are tightly bound.In the region d/lB>d_(c)/l_(B),a crossover from the d→d_(c)limit to the large d limit is observed.The electron and hole composite Fermion liquids(CFL)are realized by composite Fermions(CF)which attach opposite fluxes,respectively.

A review on 3d transition metal dilute magnetic REIn_(3) intermetallic compounds

The dilute magnetic intermetallic compound(DMIC) is an extended study of the dilute magnetic semiconductor. The giant magnetic effect and room temperature ferromagnetism are induced by doping minor 3d transition metal into REIn_(3) intermetallic compound. Owing to the metallic processability, the REIn_(3)-based DMIC might have the potential application as magnetoelectric device. In this review, the structural stability, magnetic and electric transport properties of REIn_(3-x)T_(x)(RE = rare earth;T = Co, Mn, Fe;x = 0–0.3) have been systematically summarized and analyzed.

Precessing Ball Solitons as Self-Organizing Systems during a Phase Transition in a Ferromagnet

Precessing ball solitons (PBS) in a ferromagnet during the first order phase transition is induced by a magnetic field directed along the axis of anisotropy, while the action of the periodic field perpendicular to the main magnetic field has been analyzed. Under these conditions, the characteristics of arising equilibrium PBS are uniquely determined by the frequency of the periodic field, but the solitons with other frequencies are impossible. For such structure, the entropy increase connected with dissipation is compensated by the decrease of the entropy due to the external periodic field. It is shown that the equilibrium PBS are essentially the “self-organizing systems” that can arise spotaneously in a metastable state of ferromagnet.

Magnetic and electronic properties of La-doped hexagonal 4H-SrMnO_(3)

As typical strongly correlated electronic materials, manganites show rich magnetic phase diagrams and electronic structures depending on the doped carrier density. Most previous relevant studies of doped manganites rely on the cubic/orthorhombic structures, while the hexagonal structure is much less studied. Here first-principles calculations are employed to investigate the magnetic and electronic structures of La-doped 4H-SrMnO_(3). By systematically analyzing the two kinds of La-doped positions, our calculations predict that the doped electron with lattice distortion would prefer to form polarons, which contribute to the local magnetic phase transition, nonzero net magnetization, and semiconducting behavior. In addition, the energy gap decreases gradually with increasing doping concentration, indicating a tendency of insulator–metal transition.

Anomalous bond lengthening in compressed magnetic doped semiconductor Ba(Zn_(0.95)Mn_(0.05))_(2)As_(2)

Applying pressure has been evidenced as an effective method to control the properties of semiconductors,owing to its capability to modify the band configuration around Fermi energy.Correspondingly,structural evolutions under external pres-sures are required to analyze the mechanisms.Herein high-pressure structure of a magnetic doped semiconductor Ba(Zn_(0.95)Mn_(0.05))_(2)As_(2)is studied with combination of in-situ synchrotron X-ray diffractions and diamond anvil cells.The materials become ferromagnetic with Curie temperature of 105 K after further 20%K doping.The title material undergoes an isostruc-tural phase transition at around 19 GPa.Below the transition pressure,it is remarkable to find lengthening of Zn/Mn-As bond within Zn/MnAs layers,since chemical bonds are generally shortened with applying pressures.Accompanied with the bond stretch,interlayer As-As distances become shorter and the As-As dimers form after the phase transition.With further compres-sion,Zn/Mn-As bond becomes shortened due to the recovery of isotropic compression on the Zn/MnAs layers.

Structural phase transition, precursory electronic anomaly, and strong-coupling superconductivity in quasi-skutterudite (Sr1-xCax)3Ir4Sn13 and Ca3Rh4Sn13

The interplay between superconductivity and structural phase transition has attracted enormous interest in recent years. For example, in Fe-pnictide high temperature superconductors, quantum fluctuations in association with structural phase transition have been proposed to lead to many novel physical properties and even the superconductivity itself. Here we report a finding that the quasi-skutterudite superconductors （Sr1-xCax）3Ir4Sn13 （x = 0, 0.5, 1） and Ca3Rh4Snl3 show some unusual properties similar to the Fe-pnictides, through 119Sn nuclear magnetic resonance （NMR） measurements. In （Sr1-xCax）3Ir4Sn13, the NMR linewidth increases below a temperature T＊ that is higher than the structural phase transition temperature Ts. The spin-lattice relaxation rate （1/T1 ） divided by temperature （T）, 1/TI T and the Knight shift K increase with decreasing T down to T＊, but start to decrease below T＊, and followed by more distinct changes at Ts. In contrast, none of the anomalies is observed in Ca3Rh4Sn13 that does not undergo a structural phase transition. The precursory phenomenon above the structural phase transition resembles that occurring in Fe-pnictides. In the superconducting state of Ca3Ir4Sn13, 1/T1 decays as exp（-△/kBT） with a large gap △ = 2.21kBTc, yet without a Hebel-Slichter coherence peak, which indicates strong-coupling superconductivity. Our results provide new insight into the relationship between superconductivity and the electronic-structure change associated with structural phase transition.

Particle Density in Zero Temperature Symmetry Restoring Phase Transitions in Four-Fermion Interaction Models

By means of critical behaviors of the dynamical fermion mass in four-fermion interaction models, we show by explicit calculations that when T = 0 the particle density will have a discontinuous jumping across the critical chemical potential μc in 2D and 3D Gross-Neveu (GN) model and these physically explain the first-order feature of the corresponding symmetry restoring phase transitions. For the second-order phase transitions in the 3D GN model when T → 0 and in 4D Nambu–Jona–Lasinio (NJL) model when T = 0, it is proven that the particle density itself will be continuous across μc but its derivative over the chemical potential μ will have a discontinuous jumping. The results give a physical explanation of implications of the tricritical point in the 3D GN model. The discussions also show effectiveness of the critical analysis approach of phase transitions.

A Puzzle of Quantum Phase Transition on Gd-IMC by Tuning of Conduction Electron Concentration

Based on the critical unstable of both crystal and magnetic structure of Gd-intermetallic compound near the competition of two strongly independent subsystem （＂local 4f7＂ and ＂conduction electron concentration＂）, a new QPT （quantum point transition） is predicted by calculation of： （1） The band structure and density of state by density functional theory where a strong narrowing fluidity of fermions around EF with shifted to negative value ＂-0.8 eV ＂is observable in the Gd-intermetalliccompound system while in the Y-case, it is not dominated. An antiferromagnetic state on the fluidity of conduction band can be investigated; （2） The internal magnetic field due to short range exchange interaction Jij between the nearest neighbor of local magnetic moment of stable s-state of Gd （L = 0） through the mean field approximation and of Eigenvalue-Eigenfunction ~.（k） are calculated. While a strong negative value of Jy is predicted, the eigenvalue L（k） of the system shows a strong antiferromagnetic phase in the reciprocal lattice direction 〈010〉, 〈001〉 in the correlation length 3.38 ~A. Although the antiferromagnetic state at Rc 〈_ 3.38 °A is a puzzle but it is completely dominated at Rc = 9 °A after passing through the competition between ）.λmin（O） and λmin（π） in the ranger of 3.2 °A 〈 Rc 〈 9 °A. Since both of the antiferromagnetic subsystems are sensitive to the predicted KF, the effect of decreasing of conduction electron is proposed to investigate, the change of the antiferromagnetic ordering state to the competition of ferromagnetic state （in direction 〈010〉） and antiferromagnetic state （in direction 〈001 〉 and 〈 100〉） resulted to paramagnetic state in the long range Rc = 9 °A.

Influence of high-pressure heat treatment on magnetocaloric effects and magnetic phase transition in single crystal Gd_(3)Ga_5O_(12)

The magnetic properties and magnetic phase transition critical behavior of Gd_(3)Ga_5O_(12)single crystals subjected to high-pressure heat treatment were investigated.The results show that high-pressure heat treatment reduces the Curie temperature and magnetization of the sample.Under a magnetic field change of 5 T,the maximum isothermal magnetic entropy of the sample is approximately 19.73 J/(kg·K).High-pressure heat treatment increases the phase transition temperature range and leads to an increase in the magnetic refrigeration power.Both Gd_(3)Ga_(5)O_(12)single crystals and the high-pressure heat-treated sample undergo a second-order phase transition.The critical behavior of the samples aligns with the mean field model acquired via critical model fitting.This indicates that the samples exhibit long-range exchange interactions in the system near the Curie temperature.Thus,this material can be used as a magnetic refrigerant for low-temperature applications.

Anisotropic magnetism and band evolution induced by ferromagnetic phase transition in titanium-based kagome ferromagnet SmTi_3Bi_4

Kagome magnets with diverse topological quantum responses are crucial for next-generation topological engineering.The anisotropic magnetism and band evolution induced by ferromagnetic phase transition(FMPT)is reported in a newly discovered titanium-based kagome ferromagnet Sm Ti3Bi4,which features a distorted Ti kagome lattice and Sm atomic zig-zag chains.Temperature-dependent resistivity,heat capacity,and magnetic susceptibility reveal a ferromagnetic ordering temperature Tc of23.2 K.A large magnetic anisotropy,observed by applying the magnetic field along three crystallographic axes,identifies the b axis as the easy axis.Angle-resolved photoemission spectroscopy with first-principles calculations unveils the characteristic kagome motif,including the Dirac point at the Fermi level and multiple van Hove singularities.Notably,a band splitting and gap closing attributed to FMPT is observed,originating from the exchange coupling between Sm 4 f local moments and itinerant electrons of the kagome Ti atoms,as well as the time-reversal symmetry breaking induced by the long-range ferromagnetic order.Considering the large in-plane magnetization and the evolution of electronic structure under the influence of ferromagnetic ordering,such materials promise to be a new platform for exploring the intricate electronic properties and magnetic phases based on the kagome lattice.