Per-and polyfluoroalkyl substances(PFASs)are emerging persistent organic pollutants(POPs).In this study,47 surface sediment samples were collected from the Yellow River Delta wetland(YRDW)to investigate the occurrence...Per-and polyfluoroalkyl substances(PFASs)are emerging persistent organic pollutants(POPs).In this study,47 surface sediment samples were collected from the Yellow River Delta wetland(YRDW)to investigate the occurrence,spatial distribution,potential sources,and ecological risks of PFASs.Twenty-three out of 26 targeted PFASs were detected in surface sediment samples from the YRDW,with totalΣ23PFASs concentrations ranging from 0.23 to 16.30 ng g^(-1) dw and a median value of 2.27 ng g^(-1) dw.Perfluorooctanoic acid(PFOA),perfluorobutanoic acid(PFBA)and perfluorooctanesulfonic acid(PFOS)were the main contaminants.The detection frequency and concentration of perfluoroalkyl carboxylic acids(PFCAs)were higher than those of perfluoroal-kanesulfonic acids(PFSAs),while those of long-chain PFASs were higher than those of short-chain PFASs.The emerging PFASs substitutes were dominated by 6:2 chlorinated polyfluoroalkyl ether sulfonic acid(6:2 Cl-PFESA).The distribution of PFASs is significantly influenced by the total organic carbon content in the sediments.The concentration of PFASs seems to be related to human activities,with high concentration levels of PFASs near locations such as beaches and villages.By using a positive matrix factorization model,the potential sources of PFASs in the region were identified as metal plating mist inhibitor and fluoropolymer manufacturing sources,metal plating industry and firefighting foam and textile treatment sources,and food packaging material sources.The risk assessment indicated that PFASs in YRDW sediments do not pose a significant ecological risk to benthic organisms in the region overall,but PFOA and PFOS exert a low to moderate risk at individual stations.展开更多
Natural radionuclides are powerful tools for understanding the sources and fate of suspended particulate matter(SPM).Particulate matter with different particle sizes behaves differently with respect to adsorption and ...Natural radionuclides are powerful tools for understanding the sources and fate of suspended particulate matter(SPM).Particulate matter with different particle sizes behaves differently with respect to adsorption and desorption.We analyzed the activi-ties and distribution characteristics of multiple natural radionuclides(238U,226Ra,40K,228Ra,7Be and 210Pbex)on size-fractionated SPM at the Lijin Hydrographic Station(Huanghe or Yellow River)every month over a one-year period.Results showed that medium silt(16–32µm)was the main component.As expected,the activity of each radionuclide decreased with an increase of particle size.We examined the sources of SPM with different particle sizes using activity ratios of 226Ra/238U,228Ra/226Ra,40K/238U and 7Be/210Pbex,and concluded that SPM with different particle sizes originated from different sources.Our results indicate that fine SPM(<32µm)was mainly from the erosion of soil along the lower reaches of the Yellow River,while coarse SPM(>32µm)was mainly derived from resuspension of riverbed sediment.During high runoff periods,the concentration of SPM increased significantly,and the pro-portion of fine particles originating upstream increased.Naturally occurring radioactive isotopes,especially on size-fractionated par-ticles,are therefore seen as useful tracers to understand the sources and behaviors of riverine particles transported from land to sea.展开更多
The implementation of the water sediment regulation scheme(WSRS)is a typical example of artificially controlling land-source input.During WSRS,the water discharge of the Yellow River will increase significantly,and so...The implementation of the water sediment regulation scheme(WSRS)is a typical example of artificially controlling land-source input.During WSRS,the water discharge of the Yellow River will increase significantly,and so will the input of terri-genous materials.In this study,we used a natural geochemical tracer 222Rn to quantify terrestrial inputs under the influence of the 2014 WSRS in the Yellow River Estuary.The results indicated that during WSRS the concentration of 222Rn in the estuary increased by about four times than in the period before WSRS.The high-level 222Rn plume disappeared quickly after WSRS,indicating that 222Rn has a very short‘memory effect’in the estuary.Based on the investigation conducted from 2015 to 2016,the concentration of 222Rn tended to be stable in the lower reaches of the Yellow River.During WSRS,the concentrations of 222Rn in the river water in-creased sharply at about 3–5 times greater than in the non-WSRS period.Based on the 222Rn mass balance model,the fluxes of 222Rn caused by submarine groundwater discharge(SGD)were estimated to be(3.5±1.7)×10^(3),(11±3.9)×10^(3),and(5.2±1.9)×10^(3)dpm m^(-2)d^(-1)in the periods before,during,and after WSRS,respectively.This finding indicated that SGD was the major source of 222Rn in the Yellow River Estuary,which can be significantly increased during WSRS.Furthermore,the SGD-associated nutrient fluxes were estimated to be 9.8×10^(3),2.5×102,and 1.1×10^(4)μmolm^(-2)d^(-1)for dissolved inorganic nitrogen,phosphorus,and silicon,respectively,during WSRS or about 2–40 times greater than during the non-WSRS period.展开更多
The Yellow River cut through Sanmenxia Gorge and discharged into the sea via the North China Plain in 150 ka BP; since then, around 86 000 × 108 t sediment has been transported passing Sanmenxia Gorge. Based on l...The Yellow River cut through Sanmenxia Gorge and discharged into the sea via the North China Plain in 150 ka BP; since then, around 86 000 × 108 t sediment has been transported passing Sanmenxia Gorge. Based on land use and land cover changes in Loess Plateau and other available evidence, an estimate of the Yellow River sediment budget is presented here: about 72% of the sedimentary material was trapped in the North China Plain and the remainder(i.e., 26%) escaped to the sea. At the present stage, 〈 0.2×108 t/a suspended sediment of the Yellow River enter the northern Yellow Sea. The transport pattern is determined mainly by the shelf current system. Annually 0.2×108–0.3×108 t of suspended particles are carried to the East China Sea; the materials are derived mainly from coastal and subaqueous delta erosion associated with the abandoned Yellow River on the Jiangsu coast. Since 1972, the lower Yellow River started to have a situation of continuous no-flow. During 1996–2000, the annual water flow and sediment discharge are only 19%, as compared with normal years(i.e., average for 1950–1979). In response to global warming and increase of water diversion from the Yellow River for industrial and urban use, the sediment flux of the Yellow River to the sea will most likely remain small in the next two to three decades.展开更多
In order to find out the variation process of water-sediment and its effect on the Yellow River Delta, the water discharge and sediment load at Lijin from 1950 to 2007 and the decrease of water discharge and sediment ...In order to find out the variation process of water-sediment and its effect on the Yellow River Delta, the water discharge and sediment load at Lijin from 1950 to 2007 and the decrease of water discharge and sediment load in the Yellow River Basin caused by human disturbances were analyzed by means of statistics. It was shown that the water discharge and sediment load into the sea were decreasing from 1950 to 2007 with serious fluctuation. The human activities were the main cause for decrease of water discharge and sediment load into the sea. From 1950 to 2005, the average annual reduction of water discharge and sediment load by means of water-soil conservation practices were 2.02×10^9 m^3 and 3.41×10^8 t respectively, and the average annual volume by water abstraction for industry and agriculture were 2.52×10^10 m^3 and 2.42×10^8 t respectively. The average sediment trapped by Sanmenxia Reservoir was 1.45×10^8 t from 1960 to 2007, and the average sediment retention of Xiaolangdi Reservoir was 2.398×10^8t from 1997 to 2007. Compared to the data records at Huanyuankou, the water discharge and sediment load into the sea decreased with siltation in the lower reaches and increased with scouring in the lower reaches. The coastline near river mouth extended and the delta area increased when the ratio of accumulative sediment load and accumulative water discharge into the sea (SSCT) is 25.4-26.0 kg/m^3 in different time periods. However, the sharp decrease of water discharge and sediment load into the sea in recent years, especially the Yellow River into the sea at Qing 8, the entire Yellow River Delta has turned into erosion from siltation, and the time for a reversal of the state was about 1997.展开更多
The well-documented decrease in the discharge of sediment into the Yellow River has attracted considerable attention in recent years. The present study analyzed the spatial and temporal variation of sediment yield bas...The well-documented decrease in the discharge of sediment into the Yellow River has attracted considerable attention in recent years. The present study analyzed the spatial and temporal variation of sediment yield based on data from 46 hydrological stations in the sediment-rich region of the Yellow River from 1955 to 2010. The results showed that since 1970 sediment yield in the region has clearly decreased at different rates in the 45 sub-areas controlled by hydrological stations. The decrease in sediment yield was closely related to the intensity and extent of soil erosion control measures and rainstorms that occurred in different periods and sub-areas. The average sediment delivery modulus(SDM) in the study area decreased from 7,767.4 t/(km^2·a) in 1951–1969 to 980.5 t/(km^2·a) in 2000–2010. Our study suggested that 65.5% of the study area with the SDM below 1,000 t/(km^2·a) is still necessary to control soil deterioration caused by erosion, and soil erosion control measures should be further strengthened in the areas with the SDM above 1,000 t/(km^2·a).展开更多
Since 2002, an artificial water and sediment regulation(AWSR) has been carried out, which largely reduced water and sediment discharged from the Yellow River into the Bohai Sea. Although the sediment transport in the ...Since 2002, an artificial water and sediment regulation(AWSR) has been carried out, which largely reduced water and sediment discharged from the Yellow River into the Bohai Sea. Although the sediment transport in the Yellow River Mouth(YRM) has been observed and modeled intensively since AWSR, but preferentially for the non-storm conditions. In this study, a three-dimensional current-wave-sediment coupled model, DHI-MIKE numerical model, was used to examine the seasonal suspended-sediment transport in the YRM after the AWSR. Results show that the seasonal distribution of suspended-sediments in the YRM is dominated by wind and wave rather than river input. The major transport pathway of suspended-sediments is from the western Laizhou Bay to the Bohai Strait during the winter monsoon, especially in storm events. In addition, about 66% of the river sediments deposit within 30 km of the YRM, which is smaller than previous estimations. It suggests that the YRM has been eroded in recent decades.展开更多
A comparative comparative study on the detrital mineral composition of stream sediments of the Yangtze River (Changjiang) and Yellow River (Huanghe) shows that, light minerals of the Yangtze River basin were mainly qu...A comparative comparative study on the detrital mineral composition of stream sediments of the Yangtze River (Changjiang) and Yellow River (Huanghe) shows that, light minerals of the Yangtze River basin were mainly quartz, feldspar, and detritus, the compositional characteristics of light minerals differed among tributaries, the main stream had a generally higher maturity index than tributaries;heavy mineral content tended to decrease progressively from the upper stream to lower stream of the Yangtze River, the primary assemblage was magnetite-hornblende-augite-garnet-epidote, and diagnostic minerals of different river basins were capable of indicating the nature and distribution of the source rock. Detrital mineral assemblages in sediments of tributaries and the main stream of the Yellow River were basically similar, Primary heavy mineral assemblage was opaque mineral-garnet-epidote-carbonate mineral and alteration mineral. Variations in the contents of garnet, opaque mineral, and hornblende mainly reflected the degree of sedimentary differentiation in suspended sediment and the hydrodynamic intensity of a drainage system. The heavy mineral differentiation index F revealed sedimentary differentiation of diagnostic detrital mineral composition due to changes in regional hydrodynamic intensity and can serve as an indicator for studying the dynamic sedimentary environment of a single-provenance river and the degree of sedimentary differentiation of its detrital minerals. Changes in detrital mineral content of the Yellow River was not completely controlled by provenance but reflected gravity sorting of the detrital mineral due to variations in the ephemeral river hydrodynamic intensity and sedimentary environment, however the index changing of Yangtze River were mainly influenced by the complex sediment sources. Therefore caution must be exercised in using the detrital mineral composition of marginal sea to determine the contribution of the Yangtze River and Yellow River.展开更多
Five diagnostic experiments with a 3D baroclinic hydrodynamic and sediment transport model ECOMSED in couple with the third generation wave model SWAN and the Grant-Madsen bottom boundary layer model driven by the mon...Five diagnostic experiments with a 3D baroclinic hydrodynamic and sediment transport model ECOMSED in couple with the third generation wave model SWAN and the Grant-Madsen bottom boundary layer model driven by the monthly sediment load of the Yellow River, were conducted to separately diagnose effects of different hydrodynamic factors on transport of suspended sediment discharged from the Yellow River in the Bohai Sea. Both transport and spatio-temporal distribution of suspended sediment concentration in the Bohai Sea were numerially simulated. It could be from the Yellow River cannot be delivered in concluded that suspended sediment discharged long distance under the condition of tidal current. Almost all of sediments from the Yellow River are deposited outside the delta under the condition of wind-driven current, and only very small of them are transported faraway. On the basis of wind forcing, sediments from the Yellow River are mainly transported north-northwestward, and others which are first delivered to the Laizhou Bay are continuously moved northward. An obvious 3D structure characteristic of sediment transport is produced in the wind-driven and tide-induced residual circulation condition. Transport patterns at all layers are generally consistent with circulation structure, but there is apparent deviation between the depth-averaged sediment flux and the circulation structure. The phase of temporal variation of sediment concentration is consistent with that of the bottom shear stress, both of which are proved to have a ten-day cycle in wave and current condition.展开更多
Accurate assessment of surface suspended sediment concentration (SSSC) in estuary is essential to address several important issues: erosion, water pollution, human health risks, etc. In this study, an empirical cub...Accurate assessment of surface suspended sediment concentration (SSSC) in estuary is essential to address several important issues: erosion, water pollution, human health risks, etc. In this study, an empirical cubic retrieval model was developed for the retrieval of SSSC from Yellow River Estuary. Based on sediments and seawater collected from the Yellow River and southeastern Laizhou Bay, SSSC conditions were reproduced in the laboratory at increasing concentrations within a range common to field observations. Continu- ous spectrum measurements of the various SSSCs ranging from 1 to 5700 mg/1 were carried out using an AvaField-3 spectrometer. The results indicated the good correlation between water SSSC and spectral reflectance (Rrs) was obtained in the spectral range of 726-900 nm. At SSSC greater than 2700 mg/L, the 740-900 nm spectral range was less susceptible to the effects of spectral reflectance saturation and more suitable for retrieval of high sediment concentrations. The best correlations were obtained for the reflectance ratio of 820 nm to 490 nm. Informed by the correlation between Rrs and SSSC, a retrieval model was developed (R2 = 0.992). The novel cubic model, which used the ratio of a near-infrared (NIR) band (740-900 nm) to a visible band (400-600 nm) as factors, provided robust quantifica- tion of high SSSC water samples. Two high SSSC centers, with an order of 103 mg/1, were found in the inversion results around the abandoned Diaokou River mouth, the present Yellow River mouth to the abandoned Qingshuigou River mouth. There was little sedi- ment exchange between the two high SSSC centers due to the directions of the residual currents and vertical mixing.展开更多
Relocation of the Yellow River estuary has significant impacts on not only terrestrial environment and human activities, but also sedimentary and ecological environments in coastal seas. The responses of regional geoc...Relocation of the Yellow River estuary has significant impacts on not only terrestrial environment and human activities, but also sedimentary and ecological environments in coastal seas. The responses of regional geochemical characteristics to the relocation event, however, have not been well studied. In the present study, we performed detailed geochemical elemental analyses of a sediment core from the northern Yellow Sea and studied their geochemical responses to the 1855AD relocation of the Yellow River estuary. The results show that TOC/TN, Co/A1203, Cr/A1203, Ni/A1203 and Se/A1203 ratios all decreased abruptly after 1855 AD, and similar decreases are observed in the sediments of the mud area southwest off the Cheju Island. These abrupt changes are very likely caused by the changes in source materials due to the relocation of the Yellow River estuary from the southern Yellow Sea to the Bohai Sea, which the corresponding decreasing trends caused by the changes in main source materials from those transported by the Liaohe River, the Haihe River and the Luanhe River to those by the Yellow River. Because the events have precise ages recorded in historical archives, these obvious changes in elemental geochemistry of sediments can be used to calibrate age models of related coastal sea sediments.展开更多
Dongping Lake area,located in the lower reaches of Yellow River,is an ideal place to study the changes of modern river and lake sedimentary environment.The sediment samples of Dawen River,Yellow River,and Dongping Lak...Dongping Lake area,located in the lower reaches of Yellow River,is an ideal place to study the changes of modern river and lake sedimentary environment.The sediment samples of Dawen River,Yellow River,and Dongping Lake were collected,and the major elements,trace elements and organic matter geochemical composition of the samples were analyzed.Cluster analysis,characteristic element ratio method and graphic method were used to explore the geochemical characteristics of sediments and their environmental implication.The results show that the contents of SiO_(2),Na_(2)O,TiO_(2) and Zr in sediments of Dawen River and Yellow River are relatively high,and the contents of iron and manganese oxides,organic matter,CaO,P2O5 and Sr in lake sediments are relatively high.That reveals the differences of sedimentary environments between the rivers and the lake.The contents of Sr and Zr in Dawen River are affected by the rapid migration of clastic materials in the upstream carbonate source area during the flood season;the δCe,ΣREE and REE’s ratios in the sediments of the Yellow River reflect the influence of the Loess source;and the distribution of elements changes along the flow direction during the flood season.The characteristics of pH,element composition and LREE&HREE fractionation of the lake sediments indicate that the sediment source is complex,and the lake environment is affected by the flood season.The study shows that the geochemical content and its variation characteristics of sediments effectively reveal the sedimentary environment,material composition and characteristics of flood season of rivers and the lake in the study area.展开更多
The Huanghe (Yellow) River, with annual sediment discharge about 11 ×108tons, contributes about 17% of the fluvial sediment discharge of world’s 21 major rivers to the ocean because its middle reaches flow acros...The Huanghe (Yellow) River, with annual sediment discharge about 11 ×108tons, contributes about 17% of the fluvial sediment discharge of world’s 21 major rivers to the ocean because its middle reaches flow across the great Loess Plateau of China. Sediment discharge of the Huanghe River has a widespread and profound effect on sedimentation of the sea. The remarkable shift of its outlet in 1128-1855 A.D. to the South Yellow Sea formed a large subaqueous delta and provided the substrate for an extensive submarine ridge field.The shift of its outlet in the modern delta every 10 years is the main reason why with an extremely heavy sediment input and a micro- tidal environment, the Huanghe River has not succeeded in building a birdfoot delta like the Mississippi. The Huanghe River has consistently brought heavy sediment input to sea at least since 0.7 myr.B.P. Paleochannels, paleosols, cheniers and fossils on the sea bottom indicate that the Yellow Sea was exposed during the late Quaternary glacial low-sea展开更多
Significant differences are noticed in major and trace element compositions between the Yangtze River and the Yellow River surface sediments. The former sediments are rich in some major elements such as K, Fe, Mg, Al,...Significant differences are noticed in major and trace element compositions between the Yangtze River and the Yellow River surface sediments. The former sediments are rich in some major elements such as K, Fe, Mg, Al, and most of the trace elements which show wide variations in element concentrations, whereas the Yellow River sediments only have higher Ca, Na, Sr, Ba, Th, Ga, Zr, Hf contents and show slight variations in element contents. In the Yangtze River Basin are widely distributed intermediate\|acid igneous rocks and complicated source rocks together with strong chemical weathering which determine the elemental compositions of the Yangtze River sediments, while the elemental compositions of the Yellow River sediments are decided by the chemical composition of loess from the Loess Plateau and intense physical weathering. Cu, Zn, Sc, Ti, Fe, V, Ni, Cr, Co, Li and Be can be used to distinguish the Yangtze River sediments from the Yellow River sediments and be treated as tracers for both the sediments to study the processes of their mixing and diffusion in the coastal zones of China.展开更多
The modern Yellow River delta is formed near the estuary of the Yellow River with the characteristics of short formation time, efficient sedimentation rate and loose structure which make sediments prone to be compacte...The modern Yellow River delta is formed near the estuary of the Yellow River with the characteristics of short formation time, efficient sedimentation rate and loose structure which make sediments prone to be compacted and consolidate under the geostatic stress and overburden stress. It is one of the key areas with land subsidence disasters in China, bringing a series of safety hazards to production and living. Based on the data of massive surface cores and ten drill holes ranging from 12 to 40 m obtained from the northern modern Yellow River subaqueous delta, the inversion method suitable for the calculation of consolidation settlement characteristics of the modern Yellow River subaqueous delta is discussed, and the consolidation settlement characteristics of the delta sediments are inversed and predicted in this paper. The actual void ratio of the delta sediments at the depth from 3 to 15 m shows a significant power function relationship with the depth, while the void ratio of the sediments below 15 m changes little with depth. The pre-consolidation settlement(from deposition to sampling) of the delta sediments is between 0.91 and 1.96 m, while the consolidation settlement of unit depth is between 9.6 and 14.0 cm m^(-1). The post-consolidation settlement(from sampling to stable) of the subaqueous delta sediments is between 0.65 and 1.56 m in the later stage, and the consolidation settlement of unit depth is between 7.6 and 13.1 cm m^(-1) under the overburden stress. The delta sediments with a buried depth of 3 to 7 m contribute the most to the possible consolidation settlement in the later stage.展开更多
Effective management of a river reach requires a sound understanding of flow and sediment transport generated by varying natural and artificial runoff conditions. Flow and sediment transport within the Ning-Meng reach...Effective management of a river reach requires a sound understanding of flow and sediment transport generated by varying natural and artificial runoff conditions. Flow and sediment transport within the Ning-Meng reach of the Yellow River(NMRYR), northern China are controlled by a complex set of factors/processes, mainly including four sets of factors:(1) aeolian sediments from deserts bordering the main stream;(2) inflow of water and sediment from numerous tributaries;(3) impoundment of water by reservoir/hydro-junction; and(4) complex diversion and return of irrigation water. In this study, the 1-D flow & sediment transport model developed by the Yellow River Institute of Hydraulic Research was used to simulate the flow and sediment transport within the NMRYR from 2001 to 2012. All four sets of factors that primarily control the flow and sediment transport mentioned above were considered in this model. Compared to the measured data collected from the hydrological stations along the NMRYR, the simulated flow and sediment transport values were generally acceptable, with relative mean deviation between measured and simulated values of 〈15%. However, simulated sediment concentration and siltation values within two sub-reaches(i.e., Qingtongxia Reservoir to Bayan Gol Hydrological Station and Bayan Gol Hydrological Station to Toudaoguai Hydrological Station) for some periods exhibited relatively large errors(the relative mean deviations between measured and simulated values of 18% and 25%, respectively). These errors are presumably related to the inability to accurately determine the quantity of aeolian sediment influx to the river reach and the inflow of water from the ten ephemeral tributaries. This study may provide some valuable insights into the numerical simulations of flow and sediment transport in large watersheds and also provide a useful model for the effective management of the NMRYR.展开更多
In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analy...In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analyzed their specific amino acids(AA),DOC,POC,and bacteria abundance.Summarized by 14 specific AA,the total hydrolysable AA(THAA),particulate AA(PAA),and sediment AA(SAA)varied in ranges of 2.29-9.05μmol L^-1,5.22-22.96μmol L^-1,and 81.7-137.19μg g^-1 dry weight.After the regulation,dissolved free AA(DFAA)decreased by 29%while DCAA increased by 72%.These variations suggested that DFAA were further degraded,while DCAA molecules were further activated.Meanwhile,PAA increased almost 4 times as many as those before regulation,and SAA increased as well.After regulation,the amounts of bioactive amino acids(Asp,Glu and Gly)increased in THAA but decreased in PAA,with little changes in SAA.The ratios of Asp/Gly in different phases increased after regulation,indicating the AA contributions were promoted by calcareous organisms rather than by siliceous organisms.Multiple correlation analysis showed that PAA was primary representatives of AA and organic carbon,followed by DCAA and POC.Moreover,bacterial reproduction played a key role in shaping the AA compositions and properties,followed by the redox condition and acid-base balance.The results of this study provided a clear evidence for the effects of water-sediment regulation on regional biogeochemistry of organic carbon in the middle-lower Yellow River.展开更多
Elemental(TOC,TN,C/N)and stable carbon isotopic(δ^13C)compositions and long-chain alkane(n C16-38)concentrations were measured for eight major plants and a sediment core collected from the Yellow River estuarine wetl...Elemental(TOC,TN,C/N)and stable carbon isotopic(δ^13C)compositions and long-chain alkane(n C16-38)concentrations were measured for eight major plants and a sediment core collected from the Yellow River estuarine wetlands.Our results indicate that both C3(-25.4‰to-29.6‰)and C4(-14.2‰to-15.0‰)plants are growing in the wetlands and C3 plants are the predominant species.The biomass of the wetland plants had similar organic carbon(35.5-45.8%)but very different organic nitrogen(0.35-4.15%)contents.Both C3 and C4 plants all contained long-chain alkanes with strong odd-to-even carbon numbered chain predominance.Phragmites australis,a dominant C3 plant contained mainly n C29 and n C31 homologues.Aeluropus littoralis,an abundant C4 plant were concentrated with n C27 and n C29 homologues.Organic matter preserved in the Yellow River estuarine sediments showed strong terrestrial signals(C/N=11-16,δ^13C=-22.0‰to-24.3‰).The distribution of long-chain n-alkanes in sediments also showed strong odd-to-even carbon chain predominance with n C29 and n C31 being the most abundant homologues.These results suggest that organic matter preserved in the Yellow River estuarine sediments were influenced by the wetland-derived organic matter,mainly C3 plants.The Yellow River estuarine wetland plants could play important role affecting both the carbon and nutrient cycling in the estuary and adjacent coastal waters.展开更多
The sediment content of the Yellow River is resulted from the interactions of natural, economic, and social factors, so it includes some evolutive information of the Yellow River Basin system. Sediment contents from 1...The sediment content of the Yellow River is resulted from the interactions of natural, economic, and social factors, so it includes some evolutive information of the Yellow River Basin system. Sediment contents from 1952 to 2007 on Toudaoguai, Tongguan, Huayuankou and Lijin sections along the river are chosen as the study time series, and correlation dimensions (D2), Kolmogorov entropies (K2), and Hurst indexes (H) of the time series were calculated. Correlation dimensions on Toudaoguai, Tongguan, Huayuankou, and Lijin sections are 3.24, 5.69, 6.57 and 7.34 respectively, and the Kolmogorov entropies are 0.13, 0.37, 0.40 and 0.38 respectively, which indicates that the systems controlled by different sections along the Yellow River are chaotic systems and the chaotic degrees increase gradually from the upper to lower section. The average predictable period of the sediment contents is 8 years on Toudaoguai section and 3 years on the other sections with the reciprocals of the Kolmogorov entropies. The more obvious the chaotic degree is, the shorter the average predictable period is. Hurst indexes on the sections are above 0.5, with the maximum of 0.86 on Tongguan section and the minimum of 0.68 on Toudaoguai section, which indicates that the time series have persistent trends in the average predictable period. Eight state variables and two control parameters are necessary to construct the dynamic model of the Yellow River Basin system.展开更多
基金financially supported by the National Natural Science Foundation of China(NSFC)(No.42377217)the Cooperation Fund between Dongying City and Universities(No.SXHZ-2023-02-6).
文摘Per-and polyfluoroalkyl substances(PFASs)are emerging persistent organic pollutants(POPs).In this study,47 surface sediment samples were collected from the Yellow River Delta wetland(YRDW)to investigate the occurrence,spatial distribution,potential sources,and ecological risks of PFASs.Twenty-three out of 26 targeted PFASs were detected in surface sediment samples from the YRDW,with totalΣ23PFASs concentrations ranging from 0.23 to 16.30 ng g^(-1) dw and a median value of 2.27 ng g^(-1) dw.Perfluorooctanoic acid(PFOA),perfluorobutanoic acid(PFBA)and perfluorooctanesulfonic acid(PFOS)were the main contaminants.The detection frequency and concentration of perfluoroalkyl carboxylic acids(PFCAs)were higher than those of perfluoroal-kanesulfonic acids(PFSAs),while those of long-chain PFASs were higher than those of short-chain PFASs.The emerging PFASs substitutes were dominated by 6:2 chlorinated polyfluoroalkyl ether sulfonic acid(6:2 Cl-PFESA).The distribution of PFASs is significantly influenced by the total organic carbon content in the sediments.The concentration of PFASs seems to be related to human activities,with high concentration levels of PFASs near locations such as beaches and villages.By using a positive matrix factorization model,the potential sources of PFASs in the region were identified as metal plating mist inhibitor and fluoropolymer manufacturing sources,metal plating industry and firefighting foam and textile treatment sources,and food packaging material sources.The risk assessment indicated that PFASs in YRDW sediments do not pose a significant ecological risk to benthic organisms in the region overall,but PFOA and PFOS exert a low to moderate risk at individual stations.
基金financially supported by the National Natural Science Foundation of China(Nos.U22A20580,42130410,and U1906210)the Fundamental Research Funds for the Central Universities(No.201962003).
文摘Natural radionuclides are powerful tools for understanding the sources and fate of suspended particulate matter(SPM).Particulate matter with different particle sizes behaves differently with respect to adsorption and desorption.We analyzed the activi-ties and distribution characteristics of multiple natural radionuclides(238U,226Ra,40K,228Ra,7Be and 210Pbex)on size-fractionated SPM at the Lijin Hydrographic Station(Huanghe or Yellow River)every month over a one-year period.Results showed that medium silt(16–32µm)was the main component.As expected,the activity of each radionuclide decreased with an increase of particle size.We examined the sources of SPM with different particle sizes using activity ratios of 226Ra/238U,228Ra/226Ra,40K/238U and 7Be/210Pbex,and concluded that SPM with different particle sizes originated from different sources.Our results indicate that fine SPM(<32µm)was mainly from the erosion of soil along the lower reaches of the Yellow River,while coarse SPM(>32µm)was mainly derived from resuspension of riverbed sediment.During high runoff periods,the concentration of SPM increased significantly,and the pro-portion of fine particles originating upstream increased.Naturally occurring radioactive isotopes,especially on size-fractionated par-ticles,are therefore seen as useful tracers to understand the sources and behaviors of riverine particles transported from land to sea.
基金funded by the National Natural Science Foundation of China(Nos.42130410,41876075,and 41576075).
文摘The implementation of the water sediment regulation scheme(WSRS)is a typical example of artificially controlling land-source input.During WSRS,the water discharge of the Yellow River will increase significantly,and so will the input of terri-genous materials.In this study,we used a natural geochemical tracer 222Rn to quantify terrestrial inputs under the influence of the 2014 WSRS in the Yellow River Estuary.The results indicated that during WSRS the concentration of 222Rn in the estuary increased by about four times than in the period before WSRS.The high-level 222Rn plume disappeared quickly after WSRS,indicating that 222Rn has a very short‘memory effect’in the estuary.Based on the investigation conducted from 2015 to 2016,the concentration of 222Rn tended to be stable in the lower reaches of the Yellow River.During WSRS,the concentrations of 222Rn in the river water in-creased sharply at about 3–5 times greater than in the non-WSRS period.Based on the 222Rn mass balance model,the fluxes of 222Rn caused by submarine groundwater discharge(SGD)were estimated to be(3.5±1.7)×10^(3),(11±3.9)×10^(3),and(5.2±1.9)×10^(3)dpm m^(-2)d^(-1)in the periods before,during,and after WSRS,respectively.This finding indicated that SGD was the major source of 222Rn in the Yellow River Estuary,which can be significantly increased during WSRS.Furthermore,the SGD-associated nutrient fluxes were estimated to be 9.8×10^(3),2.5×102,and 1.1×10^(4)μmolm^(-2)d^(-1)for dissolved inorganic nitrogen,phosphorus,and silicon,respectively,during WSRS or about 2–40 times greater than during the non-WSRS period.
文摘The Yellow River cut through Sanmenxia Gorge and discharged into the sea via the North China Plain in 150 ka BP; since then, around 86 000 × 108 t sediment has been transported passing Sanmenxia Gorge. Based on land use and land cover changes in Loess Plateau and other available evidence, an estimate of the Yellow River sediment budget is presented here: about 72% of the sedimentary material was trapped in the North China Plain and the remainder(i.e., 26%) escaped to the sea. At the present stage, 〈 0.2×108 t/a suspended sediment of the Yellow River enter the northern Yellow Sea. The transport pattern is determined mainly by the shelf current system. Annually 0.2×108–0.3×108 t of suspended particles are carried to the East China Sea; the materials are derived mainly from coastal and subaqueous delta erosion associated with the abandoned Yellow River on the Jiangsu coast. Since 1972, the lower Yellow River started to have a situation of continuous no-flow. During 1996–2000, the annual water flow and sediment discharge are only 19%, as compared with normal years(i.e., average for 1950–1979). In response to global warming and increase of water diversion from the Yellow River for industrial and urban use, the sediment flux of the Yellow River to the sea will most likely remain small in the next two to three decades.
基金Special Expenses Program of Scientific Research in Marine Commonweal Industry, No.200805063Scien-tific Research Program of State Key Laboratory of Estuarine and Coastal Research, No.2008KYYW06Open-end Foundation of State Oceanic Administration Key Laboratory of Marine Sedimentology & Envi-ronmental Geology, No.MASEG200608
文摘In order to find out the variation process of water-sediment and its effect on the Yellow River Delta, the water discharge and sediment load at Lijin from 1950 to 2007 and the decrease of water discharge and sediment load in the Yellow River Basin caused by human disturbances were analyzed by means of statistics. It was shown that the water discharge and sediment load into the sea were decreasing from 1950 to 2007 with serious fluctuation. The human activities were the main cause for decrease of water discharge and sediment load into the sea. From 1950 to 2005, the average annual reduction of water discharge and sediment load by means of water-soil conservation practices were 2.02×10^9 m^3 and 3.41×10^8 t respectively, and the average annual volume by water abstraction for industry and agriculture were 2.52×10^10 m^3 and 2.42×10^8 t respectively. The average sediment trapped by Sanmenxia Reservoir was 1.45×10^8 t from 1960 to 2007, and the average sediment retention of Xiaolangdi Reservoir was 2.398×10^8t from 1997 to 2007. Compared to the data records at Huanyuankou, the water discharge and sediment load into the sea decreased with siltation in the lower reaches and increased with scouring in the lower reaches. The coastline near river mouth extended and the delta area increased when the ratio of accumulative sediment load and accumulative water discharge into the sea (SSCT) is 25.4-26.0 kg/m^3 in different time periods. However, the sharp decrease of water discharge and sediment load into the sea in recent years, especially the Yellow River into the sea at Qing 8, the entire Yellow River Delta has turned into erosion from siltation, and the time for a reversal of the state was about 1997.
基金funded by the Major Programs of the Chinese Academy of Sciences (KZZD-EW-04-03-04)the National Science-technology Support Plan Project (2006BAD09B10)the Knowledge Innovation Program of the Chinese Academy of Sciences (KZCX2-EW-406)
文摘The well-documented decrease in the discharge of sediment into the Yellow River has attracted considerable attention in recent years. The present study analyzed the spatial and temporal variation of sediment yield based on data from 46 hydrological stations in the sediment-rich region of the Yellow River from 1955 to 2010. The results showed that since 1970 sediment yield in the region has clearly decreased at different rates in the 45 sub-areas controlled by hydrological stations. The decrease in sediment yield was closely related to the intensity and extent of soil erosion control measures and rainstorms that occurred in different periods and sub-areas. The average sediment delivery modulus(SDM) in the study area decreased from 7,767.4 t/(km^2·a) in 1951–1969 to 980.5 t/(km^2·a) in 2000–2010. Our study suggested that 65.5% of the study area with the SDM below 1,000 t/(km^2·a) is still necessary to control soil deterioration caused by erosion, and soil erosion control measures should be further strengthened in the areas with the SDM above 1,000 t/(km^2·a).
基金supported by the National Natural Science Foundation of China (Nos. 41476030, U1706215, and 41406081)the Project of Taishan Scholar
文摘Since 2002, an artificial water and sediment regulation(AWSR) has been carried out, which largely reduced water and sediment discharged from the Yellow River into the Bohai Sea. Although the sediment transport in the Yellow River Mouth(YRM) has been observed and modeled intensively since AWSR, but preferentially for the non-storm conditions. In this study, a three-dimensional current-wave-sediment coupled model, DHI-MIKE numerical model, was used to examine the seasonal suspended-sediment transport in the YRM after the AWSR. Results show that the seasonal distribution of suspended-sediments in the YRM is dominated by wind and wave rather than river input. The major transport pathway of suspended-sediments is from the western Laizhou Bay to the Bohai Strait during the winter monsoon, especially in storm events. In addition, about 66% of the river sediments deposit within 30 km of the YRM, which is smaller than previous estimations. It suggests that the YRM has been eroded in recent decades.
基金jointly supported by the National Natural Science Foundation of China (41876059, 41730531)China Geological Survey (GZH201400201, DD20160137, DD20190208, DD20190377)+1 种基金China-ASEAN Maritime Cooperation Fund (121201005000151110)Open Found of Shandong Provincial Key Laboratory of Depositional Mineralization&Sedimentary Mineral (DMSM2017024).
文摘A comparative comparative study on the detrital mineral composition of stream sediments of the Yangtze River (Changjiang) and Yellow River (Huanghe) shows that, light minerals of the Yangtze River basin were mainly quartz, feldspar, and detritus, the compositional characteristics of light minerals differed among tributaries, the main stream had a generally higher maturity index than tributaries;heavy mineral content tended to decrease progressively from the upper stream to lower stream of the Yangtze River, the primary assemblage was magnetite-hornblende-augite-garnet-epidote, and diagnostic minerals of different river basins were capable of indicating the nature and distribution of the source rock. Detrital mineral assemblages in sediments of tributaries and the main stream of the Yellow River were basically similar, Primary heavy mineral assemblage was opaque mineral-garnet-epidote-carbonate mineral and alteration mineral. Variations in the contents of garnet, opaque mineral, and hornblende mainly reflected the degree of sedimentary differentiation in suspended sediment and the hydrodynamic intensity of a drainage system. The heavy mineral differentiation index F revealed sedimentary differentiation of diagnostic detrital mineral composition due to changes in regional hydrodynamic intensity and can serve as an indicator for studying the dynamic sedimentary environment of a single-provenance river and the degree of sedimentary differentiation of its detrital minerals. Changes in detrital mineral content of the Yellow River was not completely controlled by provenance but reflected gravity sorting of the detrital mineral due to variations in the ephemeral river hydrodynamic intensity and sedimentary environment, however the index changing of Yangtze River were mainly influenced by the complex sediment sources. Therefore caution must be exercised in using the detrital mineral composition of marginal sea to determine the contribution of the Yangtze River and Yellow River.
基金National Natural Science Foundation of China, No.40771030 No.40571020
文摘Five diagnostic experiments with a 3D baroclinic hydrodynamic and sediment transport model ECOMSED in couple with the third generation wave model SWAN and the Grant-Madsen bottom boundary layer model driven by the monthly sediment load of the Yellow River, were conducted to separately diagnose effects of different hydrodynamic factors on transport of suspended sediment discharged from the Yellow River in the Bohai Sea. Both transport and spatio-temporal distribution of suspended sediment concentration in the Bohai Sea were numerially simulated. It could be from the Yellow River cannot be delivered in concluded that suspended sediment discharged long distance under the condition of tidal current. Almost all of sediments from the Yellow River are deposited outside the delta under the condition of wind-driven current, and only very small of them are transported faraway. On the basis of wind forcing, sediments from the Yellow River are mainly transported north-northwestward, and others which are first delivered to the Laizhou Bay are continuously moved northward. An obvious 3D structure characteristic of sediment transport is produced in the wind-driven and tide-induced residual circulation condition. Transport patterns at all layers are generally consistent with circulation structure, but there is apparent deviation between the depth-averaged sediment flux and the circulation structure. The phase of temporal variation of sediment concentration is consistent with that of the bottom shear stress, both of which are proved to have a ten-day cycle in wave and current condition.
基金Under the auspices of National Key R&D Program of China(No.2017YFC0505902)Project of the Cultivation Plan of Superior Discipline Talent Teams of Universities in Shandong Province,National Natural Science Foundation of China(No.41471005,41271016)
文摘Accurate assessment of surface suspended sediment concentration (SSSC) in estuary is essential to address several important issues: erosion, water pollution, human health risks, etc. In this study, an empirical cubic retrieval model was developed for the retrieval of SSSC from Yellow River Estuary. Based on sediments and seawater collected from the Yellow River and southeastern Laizhou Bay, SSSC conditions were reproduced in the laboratory at increasing concentrations within a range common to field observations. Continu- ous spectrum measurements of the various SSSCs ranging from 1 to 5700 mg/1 were carried out using an AvaField-3 spectrometer. The results indicated the good correlation between water SSSC and spectral reflectance (Rrs) was obtained in the spectral range of 726-900 nm. At SSSC greater than 2700 mg/L, the 740-900 nm spectral range was less susceptible to the effects of spectral reflectance saturation and more suitable for retrieval of high sediment concentrations. The best correlations were obtained for the reflectance ratio of 820 nm to 490 nm. Informed by the correlation between Rrs and SSSC, a retrieval model was developed (R2 = 0.992). The novel cubic model, which used the ratio of a near-infrared (NIR) band (740-900 nm) to a visible band (400-600 nm) as factors, provided robust quantifica- tion of high SSSC water samples. Two high SSSC centers, with an order of 103 mg/1, were found in the inversion results around the abandoned Diaokou River mouth, the present Yellow River mouth to the abandoned Qingshuigou River mouth. There was little sedi- ment exchange between the two high SSSC centers due to the directions of the residual currents and vertical mixing.
基金supported by the National Basic Research Program of China(2010CB428902)National Natural Science Foundation of China(40876088)
文摘Relocation of the Yellow River estuary has significant impacts on not only terrestrial environment and human activities, but also sedimentary and ecological environments in coastal seas. The responses of regional geochemical characteristics to the relocation event, however, have not been well studied. In the present study, we performed detailed geochemical elemental analyses of a sediment core from the northern Yellow Sea and studied their geochemical responses to the 1855AD relocation of the Yellow River estuary. The results show that TOC/TN, Co/A1203, Cr/A1203, Ni/A1203 and Se/A1203 ratios all decreased abruptly after 1855 AD, and similar decreases are observed in the sediments of the mud area southwest off the Cheju Island. These abrupt changes are very likely caused by the changes in source materials due to the relocation of the Yellow River estuary from the southern Yellow Sea to the Bohai Sea, which the corresponding decreasing trends caused by the changes in main source materials from those transported by the Liaohe River, the Haihe River and the Luanhe River to those by the Yellow River. Because the events have precise ages recorded in historical archives, these obvious changes in elemental geochemistry of sediments can be used to calibrate age models of related coastal sea sediments.
基金This study was supported by Opening Fund of Provincial Key Lab of Applied Nuclear Techniques in Geosciences(No.201904)Key Scientific and Technological Project(No.KY201957)of Shandong Bureau of Geology and Mineral Resources.
文摘Dongping Lake area,located in the lower reaches of Yellow River,is an ideal place to study the changes of modern river and lake sedimentary environment.The sediment samples of Dawen River,Yellow River,and Dongping Lake were collected,and the major elements,trace elements and organic matter geochemical composition of the samples were analyzed.Cluster analysis,characteristic element ratio method and graphic method were used to explore the geochemical characteristics of sediments and their environmental implication.The results show that the contents of SiO_(2),Na_(2)O,TiO_(2) and Zr in sediments of Dawen River and Yellow River are relatively high,and the contents of iron and manganese oxides,organic matter,CaO,P2O5 and Sr in lake sediments are relatively high.That reveals the differences of sedimentary environments between the rivers and the lake.The contents of Sr and Zr in Dawen River are affected by the rapid migration of clastic materials in the upstream carbonate source area during the flood season;the δCe,ΣREE and REE’s ratios in the sediments of the Yellow River reflect the influence of the Loess source;and the distribution of elements changes along the flow direction during the flood season.The characteristics of pH,element composition and LREE&HREE fractionation of the lake sediments indicate that the sediment source is complex,and the lake environment is affected by the flood season.The study shows that the geochemical content and its variation characteristics of sediments effectively reveal the sedimentary environment,material composition and characteristics of flood season of rivers and the lake in the study area.
文摘The Huanghe (Yellow) River, with annual sediment discharge about 11 ×108tons, contributes about 17% of the fluvial sediment discharge of world’s 21 major rivers to the ocean because its middle reaches flow across the great Loess Plateau of China. Sediment discharge of the Huanghe River has a widespread and profound effect on sedimentation of the sea. The remarkable shift of its outlet in 1128-1855 A.D. to the South Yellow Sea formed a large subaqueous delta and provided the substrate for an extensive submarine ridge field.The shift of its outlet in the modern delta every 10 years is the main reason why with an extremely heavy sediment input and a micro- tidal environment, the Huanghe River has not succeeded in building a birdfoot delta like the Mississippi. The Huanghe River has consistently brought heavy sediment input to sea at least since 0.7 myr.B.P. Paleochannels, paleosols, cheniers and fossils on the sea bottom indicate that the Yellow Sea was exposed during the late Quaternary glacial low-sea
文摘Significant differences are noticed in major and trace element compositions between the Yangtze River and the Yellow River surface sediments. The former sediments are rich in some major elements such as K, Fe, Mg, Al, and most of the trace elements which show wide variations in element concentrations, whereas the Yellow River sediments only have higher Ca, Na, Sr, Ba, Th, Ga, Zr, Hf contents and show slight variations in element contents. In the Yangtze River Basin are widely distributed intermediate\|acid igneous rocks and complicated source rocks together with strong chemical weathering which determine the elemental compositions of the Yangtze River sediments, while the elemental compositions of the Yellow River sediments are decided by the chemical composition of loess from the Loess Plateau and intense physical weathering. Cu, Zn, Sc, Ti, Fe, V, Ni, Cr, Co, Li and Be can be used to distinguish the Yangtze River sediments from the Yellow River sediments and be treated as tracers for both the sediments to study the processes of their mixing and diffusion in the coastal zones of China.
基金financially supported by the Laboratory for Marine Geology, Qingdao National Laboratory for Marine Science and Technology (No. MGQNLM-KF20 1715)the National Natural Science Foundation of ChinaShandong Joint Fund for Marine Science Research Centers (No. U1606401)+1 种基金the Special Fund of Chinese Central Government for Basic Scientific Research Operations in Commonweal Research Institutes (No. 2015G08)the National Science Foundation for Young Scientists of China (No. 41206054)
文摘The modern Yellow River delta is formed near the estuary of the Yellow River with the characteristics of short formation time, efficient sedimentation rate and loose structure which make sediments prone to be compacted and consolidate under the geostatic stress and overburden stress. It is one of the key areas with land subsidence disasters in China, bringing a series of safety hazards to production and living. Based on the data of massive surface cores and ten drill holes ranging from 12 to 40 m obtained from the northern modern Yellow River subaqueous delta, the inversion method suitable for the calculation of consolidation settlement characteristics of the modern Yellow River subaqueous delta is discussed, and the consolidation settlement characteristics of the delta sediments are inversed and predicted in this paper. The actual void ratio of the delta sediments at the depth from 3 to 15 m shows a significant power function relationship with the depth, while the void ratio of the sediments below 15 m changes little with depth. The pre-consolidation settlement(from deposition to sampling) of the delta sediments is between 0.91 and 1.96 m, while the consolidation settlement of unit depth is between 9.6 and 14.0 cm m^(-1). The post-consolidation settlement(from sampling to stable) of the subaqueous delta sediments is between 0.65 and 1.56 m in the later stage, and the consolidation settlement of unit depth is between 7.6 and 13.1 cm m^(-1) under the overburden stress. The delta sediments with a buried depth of 3 to 7 m contribute the most to the possible consolidation settlement in the later stage.
基金financially supported by the National Natural Science Foundation of China(51579113,51309111,51309113)
文摘Effective management of a river reach requires a sound understanding of flow and sediment transport generated by varying natural and artificial runoff conditions. Flow and sediment transport within the Ning-Meng reach of the Yellow River(NMRYR), northern China are controlled by a complex set of factors/processes, mainly including four sets of factors:(1) aeolian sediments from deserts bordering the main stream;(2) inflow of water and sediment from numerous tributaries;(3) impoundment of water by reservoir/hydro-junction; and(4) complex diversion and return of irrigation water. In this study, the 1-D flow & sediment transport model developed by the Yellow River Institute of Hydraulic Research was used to simulate the flow and sediment transport within the NMRYR from 2001 to 2012. All four sets of factors that primarily control the flow and sediment transport mentioned above were considered in this model. Compared to the measured data collected from the hydrological stations along the NMRYR, the simulated flow and sediment transport values were generally acceptable, with relative mean deviation between measured and simulated values of 〈15%. However, simulated sediment concentration and siltation values within two sub-reaches(i.e., Qingtongxia Reservoir to Bayan Gol Hydrological Station and Bayan Gol Hydrological Station to Toudaoguai Hydrological Station) for some periods exhibited relatively large errors(the relative mean deviations between measured and simulated values of 18% and 25%, respectively). These errors are presumably related to the inability to accurately determine the quantity of aeolian sediment influx to the river reach and the inflow of water from the ten ephemeral tributaries. This study may provide some valuable insights into the numerical simulations of flow and sediment transport in large watersheds and also provide a useful model for the effective management of the NMRYR.
基金supported by the National Key Research and Development Program of China(No.2018YFC1407 601)the National Natural Science Foundation of China(No.41176064)
文摘In order to examine the impacts of water-sediment regulation on regional carbon cycling,we collected water,particulate and sediment samples from the middle-lower Yellow River in late June and early July,2015 and analyzed their specific amino acids(AA),DOC,POC,and bacteria abundance.Summarized by 14 specific AA,the total hydrolysable AA(THAA),particulate AA(PAA),and sediment AA(SAA)varied in ranges of 2.29-9.05μmol L^-1,5.22-22.96μmol L^-1,and 81.7-137.19μg g^-1 dry weight.After the regulation,dissolved free AA(DFAA)decreased by 29%while DCAA increased by 72%.These variations suggested that DFAA were further degraded,while DCAA molecules were further activated.Meanwhile,PAA increased almost 4 times as many as those before regulation,and SAA increased as well.After regulation,the amounts of bioactive amino acids(Asp,Glu and Gly)increased in THAA but decreased in PAA,with little changes in SAA.The ratios of Asp/Gly in different phases increased after regulation,indicating the AA contributions were promoted by calcareous organisms rather than by siliceous organisms.Multiple correlation analysis showed that PAA was primary representatives of AA and organic carbon,followed by DCAA and POC.Moreover,bacterial reproduction played a key role in shaping the AA compositions and properties,followed by the redox condition and acid-base balance.The results of this study provided a clear evidence for the effects of water-sediment regulation on regional biogeochemistry of organic carbon in the middle-lower Yellow River.
基金Financial support for this work was provided by the National Natural Science Foundation of China (Grants # 41476057, 41521064)
文摘Elemental(TOC,TN,C/N)and stable carbon isotopic(δ^13C)compositions and long-chain alkane(n C16-38)concentrations were measured for eight major plants and a sediment core collected from the Yellow River estuarine wetlands.Our results indicate that both C3(-25.4‰to-29.6‰)and C4(-14.2‰to-15.0‰)plants are growing in the wetlands and C3 plants are the predominant species.The biomass of the wetland plants had similar organic carbon(35.5-45.8%)but very different organic nitrogen(0.35-4.15%)contents.Both C3 and C4 plants all contained long-chain alkanes with strong odd-to-even carbon numbered chain predominance.Phragmites australis,a dominant C3 plant contained mainly n C29 and n C31 homologues.Aeluropus littoralis,an abundant C4 plant were concentrated with n C27 and n C29 homologues.Organic matter preserved in the Yellow River estuarine sediments showed strong terrestrial signals(C/N=11-16,δ^13C=-22.0‰to-24.3‰).The distribution of long-chain n-alkanes in sediments also showed strong odd-to-even carbon chain predominance with n C29 and n C31 being the most abundant homologues.These results suggest that organic matter preserved in the Yellow River estuarine sediments were influenced by the wetland-derived organic matter,mainly C3 plants.The Yellow River estuarine wetland plants could play important role affecting both the carbon and nutrient cycling in the estuary and adjacent coastal waters.
基金National Natural Science Foundation of China, No.40601105 Key Project of Science and Technology of Henan Province, No.0721021500
文摘The sediment content of the Yellow River is resulted from the interactions of natural, economic, and social factors, so it includes some evolutive information of the Yellow River Basin system. Sediment contents from 1952 to 2007 on Toudaoguai, Tongguan, Huayuankou and Lijin sections along the river are chosen as the study time series, and correlation dimensions (D2), Kolmogorov entropies (K2), and Hurst indexes (H) of the time series were calculated. Correlation dimensions on Toudaoguai, Tongguan, Huayuankou, and Lijin sections are 3.24, 5.69, 6.57 and 7.34 respectively, and the Kolmogorov entropies are 0.13, 0.37, 0.40 and 0.38 respectively, which indicates that the systems controlled by different sections along the Yellow River are chaotic systems and the chaotic degrees increase gradually from the upper to lower section. The average predictable period of the sediment contents is 8 years on Toudaoguai section and 3 years on the other sections with the reciprocals of the Kolmogorov entropies. The more obvious the chaotic degree is, the shorter the average predictable period is. Hurst indexes on the sections are above 0.5, with the maximum of 0.86 on Tongguan section and the minimum of 0.68 on Toudaoguai section, which indicates that the time series have persistent trends in the average predictable period. Eight state variables and two control parameters are necessary to construct the dynamic model of the Yellow River Basin system.