Based on the theory of pH evolution of sea water and the balance between the seawater and the atmosphere the authors discussed the problems about (i) the method ofcalculating P_(CO_2) in the ancient atmosphere with th...Based on the theory of pH evolution of sea water and the balance between the seawater and the atmosphere the authors discussed the problems about (i) the method ofcalculating P_(CO_2) in the ancient atmosphere with the associations of sedimentary miner-als; (ii) the evolution of P_(CO_2) values in the geologic history; (iii) the relations of thepH evolution of sea water with carbonate precipitations; and (iv) calculation of the pHlimit for some associations of sedimentary minerals and its corresponding P_(CO_2) valuesin the atmosphere. The authors pointed out that though carbonates had deposited little in the Archaean,the content of CO_2 gas in the Archaean atmosphere was very high and was gradually go-ing up to form a thick CO_2 atmosphere. Up to 2600 Ma ago, the P_(CO_2) had reached a gradeof 10- 50 atm. There was a general trend of evolution that from the early Proterozoicera to the present the depositional horizon of carbonate layers was gradually risingand finally surpassed the horizons of clay minerals and sulfides. The corresponding P_(CO_2)in the atmosphere was lowering from the thick CO_2 atmosphere to the present 0.03%atm. On the basis of the calculated P_(CO_2) sizes and its fluctuation characteristics thehistory of P_(CO_2) evolution can be divided into three major stages.展开更多
As a potential mineral resource, the clay minerals enriched in rare earth elements including yttrium（REY） in the deep sea have been attracting great attention. However, the enrichment mechanism of REY remains unclea...As a potential mineral resource, the clay minerals enriched in rare earth elements including yttrium（REY） in the deep sea have been attracting great attention. However, the enrichment mechanism of REY remains unclear. To understand the geochemical characteristics and factors controlling REY enrichment in zeolite clay in the deep sea, we conducted mineral identification by XRD, major and trace element measurements by XRF and REY analyses by ICP-MS on a 1.4-m-long sediment core（GC02） located in the Central Indian Oceanic Basin（CIOB）. The main findings include：（1） the core sediments in GC02 possess elevated REY contents and exhibited a strong negative Ce anomaly, an apparent MREE bulge and positive Y anomaly. These were comparable with typical REY-rich clays in the Pacific Ocean, indicating the similar REY enrichment mechanism and the presence of REY-rich clays in the CIOB;（2） in comparison with the dataset from the Wharton Basin and DSDP site 213, the higher content of REY and stronger PAAS（Post Archean Australian Shale） normalization patterns in the GC02 sediments were likely caused by the weaker impact of terrigenous materials of GC02. The CIOB was suggested to be a promising place hosting REY rich pelagic sediments.展开更多
文摘Based on the theory of pH evolution of sea water and the balance between the seawater and the atmosphere the authors discussed the problems about (i) the method ofcalculating P_(CO_2) in the ancient atmosphere with the associations of sedimentary miner-als; (ii) the evolution of P_(CO_2) values in the geologic history; (iii) the relations of thepH evolution of sea water with carbonate precipitations; and (iv) calculation of the pHlimit for some associations of sedimentary minerals and its corresponding P_(CO_2) valuesin the atmosphere. The authors pointed out that though carbonates had deposited little in the Archaean,the content of CO_2 gas in the Archaean atmosphere was very high and was gradually go-ing up to form a thick CO_2 atmosphere. Up to 2600 Ma ago, the P_(CO_2) had reached a gradeof 10- 50 atm. There was a general trend of evolution that from the early Proterozoicera to the present the depositional horizon of carbonate layers was gradually risingand finally surpassed the horizons of clay minerals and sulfides. The corresponding P_(CO_2)in the atmosphere was lowering from the thick CO_2 atmosphere to the present 0.03%atm. On the basis of the calculated P_(CO_2) sizes and its fluctuation characteristics thehistory of P_(CO_2) evolution can be divided into three major stages.
基金supported by the National Natural Science Foundation of China(41773005)China Ocean Mineral Resources R&D Association(COMRA)Research Program(DY125-11-R-01,DY125-22-02),the Research Center for Air Pollution and Health(RCAPH)of Zhejiang University
文摘As a potential mineral resource, the clay minerals enriched in rare earth elements including yttrium（REY） in the deep sea have been attracting great attention. However, the enrichment mechanism of REY remains unclear. To understand the geochemical characteristics and factors controlling REY enrichment in zeolite clay in the deep sea, we conducted mineral identification by XRD, major and trace element measurements by XRF and REY analyses by ICP-MS on a 1.4-m-long sediment core（GC02） located in the Central Indian Oceanic Basin（CIOB）. The main findings include：（1） the core sediments in GC02 possess elevated REY contents and exhibited a strong negative Ce anomaly, an apparent MREE bulge and positive Y anomaly. These were comparable with typical REY-rich clays in the Pacific Ocean, indicating the similar REY enrichment mechanism and the presence of REY-rich clays in the CIOB;（2） in comparison with the dataset from the Wharton Basin and DSDP site 213, the higher content of REY and stronger PAAS（Post Archean Australian Shale） normalization patterns in the GC02 sediments were likely caused by the weaker impact of terrigenous materials of GC02. The CIOB was suggested to be a promising place hosting REY rich pelagic sediments.
