Improving Impact Toughness of Polylactide/Ethylene-co-vinyl-acetate Blends via Adding Fumed Silica Nanoparticles:Effects of Specific Surface Area-dependent Interfacial Selective Distribution of Silica

Adding fumed silica(Si0_(2))has been considered as an effective method for tailoring the phase morphology and performance of elastomer-toughened plastic binary blends.It has been demonstrated that the selective distribution of SiO_(2) plays a decisive role in the mechanical properties of plastic/elastomer/SiO_(2)nanocomposites,especially for the impact toughness.In this work,we aim to illuminate the role of specific surface area in controlling their selective distribution of fumed SiO_(2) and consequent mechanical properties of plastic/elastomer binary blends.Three types of SiO_(2) with different specific surface areas were incorporated into polylactide/ethylene-co-vinyl-acetate(PLA/EVA)model blends by melt blending directly.It was found that the selective distribution of SiO_(2) is largely determined by their specific surface areas,i.e.SiO_(2) nanoparticles with low specific surface area has a stronger tendency to be located at the interface between PLA matrix and EVA dispersed phase as compared to those with high specific surface area.The specific surface area-dependent interfacial selective distribution of SiO_(2) is mainly attributed to the extent of increased viscosity of EVA dispersed phase in which SiO_(2)nanoparticles are initially dispersed and resultant migration rate of SiO_(2) nanoparticles.The interfacial localized SiO_(2) nanoparticles induce an obvious enhancement in the impact toughness with strength and modulus well maintained.More importantly,in the case of the same interfacial distribution,toughening efficiency is increased with the specific surface area of SiO_(2).Therefore,this is an optimum specific surface area of SiO_(2) for the toughening.This work not only provides a novel way to manipulate the selective distribution of SiO_(2) in elastomer-toughened plastic blends toward high-performance,but also gives a deep insight into the role of interfacial localized nanoparticles in the toughening mechanism.

Preparation of porous polyamide 6(PA6)membrane with copper oxide(CuO)nanoparticles selectively localized at the wall of the pores via reactive extrusion

In this study,CuO nanoparticles are pre-modified with styrene-maleic anhydride copolymers(SMAs)of different molecular weights and MAH contents.Then the pre-modified CuO nanoparticles(CuO-SMAs)are added to the PA6/SEBS(Styrene Ethylene Butylene Styrene copolymer)(40/60 wt/wt)polymer blends with a co-continuous morphology.When SMA3(MAH=8 wt%,M_(n)=250000 g/mol)is used to modify CuO nanoparticles,and the grafting degree of SMA3 on the surface of CuO reaches 2.74 wt%,90.71%of the added mCuO-SMA3 nanoparticles can be located at the interface of PA6 and SEBS.A porous PA6 membrane with CuO nanoparticles located at the pore walls can be obtained after the SEBS phase is etched with xylene.The catalytic reaction velocity constant(k)for the reduction of p-nitrophenol in NaBH_(4)solutions with the PA6/mCuO-SMA3 porous membrane can reach 1.0040 min^(-1).This work provides a feasible and straightforward method for the preparation of porous polymer membranes with functional nanoparticles located at the wall of the pores.

Fabrication of 32 Gb/s Electroabsorption Modulated Distributed Feedback Lasers by Selective Area Growth Technology

A 32 Gb/s monolithically integrated electroabsorption modulated laser is fabricated by selective area growth technology. The threshold current of the device is below 13mA. The output power exceeds 10mW at 0V bias when the injection current of the distributed feedback laser is 100mA at 25℃. The side mode suppression ratio is over 50 dB. A 32Gb/s eye diagram is measured with a 3.SVpp nonreturn-to-zero pseudorandom modulation signal at -2.3 V bias. A clearly opening eyediagram with a dynamic extinction ratio of 8.01 dB is obtained.

无限协作网络中一种高效的分布式安全中继选择方法(英文)

Cloud computing is always adopted to enhance the computing capability of mobile systems, especially when the mobile users prefer to use some computation intensive applications. Consequently, the distributed wireless relay infrastructure should be deployed to aid the traffic transmission. To further enhance the QoS provisioning goals of wireless cooperative network, this paper puts forward a multi-objective approach for distributed optimal relay selection, which takes Bit Error Rate (BER) and Secrecy Capacity (SC) into account simultaneously. Firstly, our proposal partitions the channel state into several levels according to the received signal-to-noise ratio (SNR) and describes the time-varying Rayleigh fading channel characteristics by using first order finite-state Markov model. Secondly, we model the relay selection as Restless Multi-armed Bandit optimal solution problem with respect to the channel state and the state transition probability. Finally, simulation results demonstrate the efficiency of the proposed approach which outperforms the existing ones.

Symbol Error Probability of Incremental Relaying with Distributed/Centralized Relay Selection

In this paper,we derive the Symbol Error Probability(SEP)of cooperative systems with incremental relaying and Distributed Relay Selection(DRS).The relays remain idle when the Signal to Noise Ratio(SNR)between the source and destination is larger than T.Otherwise,we activate a relay using DRS.Relay nodes transmit only if their SNR is larger than thresholdβ.If the SNRs of more than two relays is larger thanβ,there is a collision and the destination uses only the received signal from the source.If all relays have SNR less thanβ,no relay is chosen.Thresholdβis optimized to yield the lowest SEP at the destination.Our results are compared to centralized relay selection using opportunistic Amplify and Forward(OAF),Partial and Reactive Relay Selection(PRS and RRS).We compare our results to computer simulations for Rayleigh fading channels.

Type selection and maintenance of the control system of large-scale air separation units

Based on the practice of Baosteel＇ s 60000 m3/h air separation unit （ASU） ,which is the first domestically- integrated unit of such a scale, this paper studies the principles of type selection of the distribution control system （DCS）. It discusses the design of the unit＇s control system,which involves a compressor system,a purification system （molecular sieving）, a turbo expansion system and an air separation system. The final part of the paper discusses the maintenance and future development of the ASU control system at Baosteel.