A novel quaternary metal selenide, K2CdSnSe4, was synthesized via a molten-salt reaction at 550 ℃. The compound has a one-dimensional structure containing a chain of ∞^1[CdSnSe4]^2- anions separated by K^＋ cations....A novel quaternary metal selenide, K2CdSnSe4, was synthesized via a molten-salt reaction at 550 ℃. The compound has a one-dimensional structure containing a chain of ∞^1[CdSnSe4]^2- anions separated by K^＋ cations. The crystal belongs to the space group I-4^-2m, with the unit cell parameters a=0.80298（11） nm, b=0.80298（11） nm, c=0.69217（14） nm, α=β=γ=90°. A reflectance spectroscopy study reveals the nature of the semiconductor with an energy gap of 1.7 eV for the compound and it has a strong optical absorotion in a range of 2--5 eV.展开更多
To solve low efficiency,environmental pollution,and toxicity for synthesizing zeolitic imidazolate frameworks(ZIFs)in organic solvents,a KOH-assisted aqueous strategy is proposed to synthesize bimetallic ZIFs polyhedr...To solve low efficiency,environmental pollution,and toxicity for synthesizing zeolitic imidazolate frameworks(ZIFs)in organic solvents,a KOH-assisted aqueous strategy is proposed to synthesize bimetallic ZIFs polyhedrons,which are used as precursors to prepare bimetallic selenide and N-doped carbon(NC)composites.Among them,Fe–Co–Se/NC retains the three-dimensional(3D)polyhedrons with mesoporous structure,and Fe–Co–Se nanoparticles are uniform in size and evenly distributed.When assessed as anode material for lithium-ion batteries,Fe–Co–Se/NC achieves an excellent initial specific capacity of 1165.9 m Ah·g^(-1)at 1.0 A·g^(-1),and the reversible capacity of Fe–Co–Se/NC anode is 1247.4 m Ah·g^(-1)after 550 cycles.It is attributed to that the uniform composite of bimetallic selenides and N-doped carbon can effectively tune redox active sites,the stable 3D structure of Fe–Co–Se/NCs guarantees the structural stability and wettability of the electrolyte,and the uniform distribution of Fe–Co–S nanoparticles in size esuppresses the volume expansion and accelerates the electrochemical reaction kinetics.展开更多
SnSe has attracted extensive attention due to its ultralow thermal conductivity and excellent thermoelectric properties.In this work,pressure-induced thermoelectric properties of Pnma SnSe are investigated via first-p...SnSe has attracted extensive attention due to its ultralow thermal conductivity and excellent thermoelectric properties.In this work,pressure-induced thermoelectric properties of Pnma SnSe are investigated via first-principles calculations.We uncover distinct energy isosurfaces topology transition of conduction band by applying pressure.The newly created conduction band valley caused by pressure has a distinct anisotropic shape compared to the old one.Inducing pressure can greatly enhance the anisotropy of electronic transport properties of the n-type Pnma SnSe.Furthermore,the lattice thermal conductivity also exhibits anisotropic behavior under pressure due to a special collaged phonon mode.The pressure-induced lattice thermal conductivity along the a-axis shows a slower growth trend than that along the b-axis and c-axis.The optimal ZT value of the n-type Pnma SnSe along the a-axis can reach 1.64 at room temperature.These results would be helpful for designing the Pnma SnSe-based materials for the potential thermoelectric and valleytronic applications.展开更多
Antimony selenide(Sb2Se3) films are widely used in phase change memory and solar cells due to their stable switching effect and excellent photovoltaic properties. These properties of the films are affected by the film...Antimony selenide(Sb2Se3) films are widely used in phase change memory and solar cells due to their stable switching effect and excellent photovoltaic properties. These properties of the films are affected by the film thickness. A method combining the advantages of Levenberg–Marquardt method and spectral fitting method(LM–SFM) is presented to study the dependence of refractive index(RI), absorption coefficient, optical band gap, Wemple–Di Domenico parameters, dielectric constant and optical electronegativity of the Sb2Se3films on their thickness. The results show that the RI and absorption coefficient of the Sb2Se3films increase with the increase of film thickness, while the optical band gap decreases with the increase of film thickness. Finally, the reasons why the optical and electrical properties of the film change with its thickness are explained by x-ray diffractometer(XRD), energy dispersive x-ray spectrometer(EDS), Mott–Davis state density model and Raman microstructure analysis.展开更多
The synthesis of crystalline SnSe nanorods was successfully achieved via a chemical reaction between sodium selenosulfate (Na2SeSO3) and SnCl2·2H2O in alkaline aqueous solution in the presence of the complexing a...The synthesis of crystalline SnSe nanorods was successfully achieved via a chemical reaction between sodium selenosulfate (Na2SeSO3) and SnCl2·2H2O in alkaline aqueous solution in the presence of the complexing agent (trisodium citrate) at room temperature under ambient air. The product was characterized by X-ray diffraction (XRD), transmission electron microscopoy (TEM) and X-ray photoelectron spectroscopy (XPS). The results reveal that the SnSe nanorods are well crystalline with an average diameter of 85 nm and the lengths up to 10 μm. The possible mechanism for the formation of SnSe is also discussed.展开更多
基金Supported by the Fund of State Key Laboratoy of Chemical Resource Engineening,China
文摘A novel quaternary metal selenide, K2CdSnSe4, was synthesized via a molten-salt reaction at 550 ℃. The compound has a one-dimensional structure containing a chain of ∞^1[CdSnSe4]^2- anions separated by K^＋ cations. The crystal belongs to the space group I-4^-2m, with the unit cell parameters a=0.80298（11） nm, b=0.80298（11） nm, c=0.69217（14） nm, α=β=γ=90°. A reflectance spectroscopy study reveals the nature of the semiconductor with an energy gap of 1.7 eV for the compound and it has a strong optical absorotion in a range of 2--5 eV.
基金financially supported by the National Natural Science Foundation of China(No.52102100)the Natural Science Foundation of Jiangsu Province(No.BK20181469)the Guangdong Basic and Applied Basic Research Foundation,China(No.2020A1515110035)。
文摘To solve low efficiency,environmental pollution,and toxicity for synthesizing zeolitic imidazolate frameworks(ZIFs)in organic solvents,a KOH-assisted aqueous strategy is proposed to synthesize bimetallic ZIFs polyhedrons,which are used as precursors to prepare bimetallic selenide and N-doped carbon(NC)composites.Among them,Fe–Co–Se/NC retains the three-dimensional(3D)polyhedrons with mesoporous structure,and Fe–Co–Se nanoparticles are uniform in size and evenly distributed.When assessed as anode material for lithium-ion batteries,Fe–Co–Se/NC achieves an excellent initial specific capacity of 1165.9 m Ah·g^(-1)at 1.0 A·g^(-1),and the reversible capacity of Fe–Co–Se/NC anode is 1247.4 m Ah·g^(-1)after 550 cycles.It is attributed to that the uniform composite of bimetallic selenides and N-doped carbon can effectively tune redox active sites,the stable 3D structure of Fe–Co–Se/NCs guarantees the structural stability and wettability of the electrolyte,and the uniform distribution of Fe–Co–S nanoparticles in size esuppresses the volume expansion and accelerates the electrochemical reaction kinetics.
基金support of the project from the National Natural Science Foundation of China(Grant No.91963207,12122408,12074292)National Key R&D Program of China(Grant No.2021YFA0718700)Suzhou Key Industrial Technology Innovation project(Grant No.SYG201921).
文摘SnSe has attracted extensive attention due to its ultralow thermal conductivity and excellent thermoelectric properties.In this work,pressure-induced thermoelectric properties of Pnma SnSe are investigated via first-principles calculations.We uncover distinct energy isosurfaces topology transition of conduction band by applying pressure.The newly created conduction band valley caused by pressure has a distinct anisotropic shape compared to the old one.Inducing pressure can greatly enhance the anisotropy of electronic transport properties of the n-type Pnma SnSe.Furthermore,the lattice thermal conductivity also exhibits anisotropic behavior under pressure due to a special collaged phonon mode.The pressure-induced lattice thermal conductivity along the a-axis shows a slower growth trend than that along the b-axis and c-axis.The optimal ZT value of the n-type Pnma SnSe along the a-axis can reach 1.64 at room temperature.These results would be helpful for designing the Pnma SnSe-based materials for the potential thermoelectric and valleytronic applications.
基金supported by the National Natural Science Foundation of China (Grant Nos. 62075109, 62135011, 62075107, and 61935006)K. C. Wong Magna Fund in Ningbo University。
文摘Antimony selenide(Sb2Se3) films are widely used in phase change memory and solar cells due to their stable switching effect and excellent photovoltaic properties. These properties of the films are affected by the film thickness. A method combining the advantages of Levenberg–Marquardt method and spectral fitting method(LM–SFM) is presented to study the dependence of refractive index(RI), absorption coefficient, optical band gap, Wemple–Di Domenico parameters, dielectric constant and optical electronegativity of the Sb2Se3films on their thickness. The results show that the RI and absorption coefficient of the Sb2Se3films increase with the increase of film thickness, while the optical band gap decreases with the increase of film thickness. Finally, the reasons why the optical and electrical properties of the film change with its thickness are explained by x-ray diffractometer(XRD), energy dispersive x-ray spectrometer(EDS), Mott–Davis state density model and Raman microstructure analysis.
文摘The synthesis of crystalline SnSe nanorods was successfully achieved via a chemical reaction between sodium selenosulfate (Na2SeSO3) and SnCl2·2H2O in alkaline aqueous solution in the presence of the complexing agent (trisodium citrate) at room temperature under ambient air. The product was characterized by X-ray diffraction (XRD), transmission electron microscopoy (TEM) and X-ray photoelectron spectroscopy (XPS). The results reveal that the SnSe nanorods are well crystalline with an average diameter of 85 nm and the lengths up to 10 μm. The possible mechanism for the formation of SnSe is also discussed.
