A Cu(Ⅰ) complex [Cu(INHPy)(PPh3)2] ·(ClO4)·0.75(C2H5OH) was obtained through self-assembly between [Cu(PPh3)2(MeCN)2]ClO4 and Schiff base 2-pyridylcarboxaldehyde isonicotinoyl hadrazone(INHPy), the structur...A Cu(Ⅰ) complex [Cu(INHPy)(PPh3)2] ·(ClO4)·0.75(C2H5OH) was obtained through self-assembly between [Cu(PPh3)2(MeCN)2]ClO4 and Schiff base 2-pyridylcarboxaldehyde isonicotinoyl hadrazone(INHPy), the structure of which was characterized by elemental analysis, IR spectrum and X-ray diffraction. Single crystal X-ray analysis indicates that this compound crystallizes in triclinic system, space group P1 with parameters: a=1.180 7(2) nm, b=1.330 0(3) nm, c=1.568 6(2) nm. 1.332 g穋m-3, F(000)=1 032, 腎=0.804+23.770C, r=0.995). CCDC: 231388.展开更多
文摘A Cu(Ⅰ) complex [Cu(INHPy)(PPh3)2] ·(ClO4)·0.75(C2H5OH) was obtained through self-assembly between [Cu(PPh3)2(MeCN)2]ClO4 and Schiff base 2-pyridylcarboxaldehyde isonicotinoyl hadrazone(INHPy), the structure of which was characterized by elemental analysis, IR spectrum and X-ray diffraction. Single crystal X-ray analysis indicates that this compound crystallizes in triclinic system, space group P1 with parameters: a=1.180 7(2) nm, b=1.330 0(3) nm, c=1.568 6(2) nm. 1.332 g穋m-3, F(000)=1 032, 腎=0.804+23.770C, r=0.995). CCDC: 231388.
