Capacity Titration Technique for Determining the Solid Diffusion Coefficient of Intercalary Species within Insertion-host Materials

In this paper, the capacity titration technique （CT technique） was developed on basis of the RPG （ratio of potentio-charge capacity to galvano-charge capacity） method to continuously determine the solid diffusion coefficient D of the intercalary species within insertion-host materials with a small voltage region. The linear equations of D vs. q （value of ratio of the potentio-charge capacity to the galvano-charge capacity） were given in different range of q. By the CT technique,the Li^＋ solid diffusion coefficients D within LiMn2O4 at different voltages were determined. The results showed that the values of D varied from 3.447×10^-9 cm^2/s to 7.60×10^-11 cm^2/s in the voltage range of charge from 3.3V to 4.3V as a function of voltage with “W” shape.

Investigating the Efficiency Coefficient of Pile Group in Clay Under Two-Way Lateral Load

This research investigates the behavior of a 2×2 pile group under two-directional lateral loads in addition to the vertical load.Through three-dimensional numerical modeling based on Flac 3D software,the study examines the total bearing capacity and efficiency coefficient of the pile group,considering factors such as the angle of lateral load,relative pile spacing,and relative stiffness of the pile-soil system.The findings highlight the significance of these factors in understanding and predicting the response of pile groups to changing lateral load directions.The results reveal that increasing the angle of the lateral load from 0°to 45°enhances both the maximum total lateral load and the efficiency coefficient of the pile group.When the relative stiffness of the pile-soil system significantly increases,soil stiffening occurs and reducing the relative spacing of the piles from 7 to 3 times the diameter of the piles diminishes the influence of the pile group.Consequently,the response of the pile group to lateral loads becomes more linear,with only a slight alteration in the maximum total lateral load and the efficiency coefficient when the lateral load is angled from 0°to 45°.Conversely,increasing the relative distance between the piles,specifically from 3 to 7 times the diameter of the piles,amplifies the influence of the pile group.Both the maximum total lateral load and the efficiency coefficient of the pile group exhibit an observed increase.These provide insights for designing pile groups and optimizing their performance under lateral loading conditions.

Comparison of Absorption Capacity of Different Flue-cured Tobacco Cultivars for Six Kinds of Heavy Metals

[Objective] This study aimed to analyze the differences in absorption capacity of different flue-cured tobacco cultivars for chromium （Cr）, arsenic （As）, cadmium （Cd）, lead （Pb）, mercury （Hg） and copper （Cu）. [Method] With 4 flue-cured tobacco cultivars as the experimental materials, their absorption capacity for 6 kinds of heavy metals was compared by pot experiment. [Result] There were great differences in absorption capacity of different flue-cured tobacco cultivars for the six kinds of heavy metals. According to the absorption capacity of different flue-cured tobacco cultivars for the heavy metals, the six heavy metals could be classified into three categories. The first category included only Cd with average enrichment coefficient of 8.564; the second category included Hg with average enrichment coefficient of 0.753; and the third category included Cr, As, Pb and Cu with average enrichment coefficients below or equivalent to 0.114. [Conclusion] The absorption capacity of different flue-cured tobacco cultivars for heavy metals was grasped by this study, thereby providing reference data for screening of high-yielding and high-quality flue-cured tobacco cultivars.

Experimental study on discharge coefficient of a gear-shaped weir

This study focused on hydraulic characteristics around a gear-shaped weir in a straight channel. Systematic experiments were carried out for weirs with two different gear heights and eight groups of geometrical parameters. The impacts of various geometrical parameters of gear-shaped weirs on the discharge capacity were investigated. The following conclusions are drawn from the experimental study:(1) The discharge coefficient(m_c) was influenced by the size of the gear: at a constant discharge, the weir with larger values of a/b(a is the width of the gear, and b is the width between the two neighboring gears) and a/c(c is the height of the gear) had a smaller value of m_c. The discharge capacity of the gear-shaped weir was influenced by the water depth in the weir.(2) For type C1 with a gear height of 0.01 m, when the discharge was less than 60m^3/h and H_1=P < 1.0(H_1 is the water depth at the low weir crest, and P is the weir height), m_c significantly increased with the discharge and H_1=P; with further increases of the discharge and H_1=P, m_cshowed insignificant decreases and fluctuated within small ranges. For type C2 with a gear height of 0.02 m, when the discharge was less than 60m^3/h and H_1=P < 1.0, m_csignificantly increased with the discharge and H_1=P; when the discharge was larger than 60m^3/h and H_1=P > 1.0, m_c slowly decreased with the increases of the discharge and H_1=P for a=b 1.0 and a=c 1.0, and slowly increased with the discharge and H_1=P for a=b > 1.0 and a=c > 1.0.(3) A formula of m_cfor gear-shaped weirs was established based on the principle of weir flow, with consideration of the water depth in the weir, the weir height and width, and the height of the gear.

Study of the Bearing Capacity at the Variable Cross-Section of A Riser- Surface Casing Composite Pile

Reducing the cost of offshore platform construction is an urgent issue for marginal oilfield development.The offshore oil well structure includes a riser and a surface casing.The riser,surface casing and oil well cement can be considered special variable cross-section piles.Replacing or partially replacing the steel pipe pile foundation with a variable cross-section pile to provide the required bearing capacity for an offshore oil platform can reduce the cost of foundation construction and improve the economic efficiency of production.In this paper,the finite element analysis method is used to investigate the variable cross-section bearing mode of composite piles composed of a riser and a surface casing in saturated clay under a vertical load.The calculation formula of the bearing capacity at the variable section is derived based on the theory of spherical cavity expansion,the influencing factors of the bearing capacity coefficient N_(c) are revealed,and the calculation method of N_(c) is proposed.By comparing the calculation results with the results of the centrifuge test,the accuracy and applicability of the calculation method are verified.The results show that the riser composite pile has a rigid core in the soil under the variable cross-section,which increases the bearing capacity at the variable cross-section.

Limit analysis of ultimate uplift capacity and failure mechanism ofshallow plate anchors in multi-layered soils

Considering the fact that in some complex cases,plate anchors are buried in multi-layered geotechnical materials,the ultimate dynamic analysis was performed to investigate the uplift capacity and failure mechanism of shallow strips and circular plate anchors in multi-layered soils.The nonlinear strength criterion and non-associated flow rule of geotechnical materials were introduced to investigate the influence of nonuniformity on the pullout performance and failure mechanism of shallow plate anchors.The expressions of the detaching curves or surfaces were obtained to reflect the failure mechanism,which can be used to figure out the ultimate uplift capacity and failure range.The results are generally in agreement with the numerical simulations and previous research.The effects of various parameters on the ultimate uplift capacity and failure mechanism of plate anchors in multi-layered soils were investigated,and it is found that the ultimate uplift capacity and failure range of shallow anchors increase with the increase of initial cohesion and dilatancy coefficient,but decrease with the unit weight,axial tensile stress and nonlinear coefficient.

Evaluation of optimal UPFC allocation for improving transmission capacity

A unified power flow controller(UPFC)combines the advantages of various flexible alternating current transmission system(FACTS)devices into a powerful format.Using a 500 kV power grid,this study evaluates the selection and use of a UPFC to improve transmission capacity.The"UPFC unit capacity control proportionality coefficient"is introduced to quantify the control effect of the UPFC,and an optimal calculation method for the UPFC capacity is presented.Following the proposal of a UPFC site selection process,the data of an existing power grid is used to conduct simulations.The simulation results show that the UPFC has a strong ability to improve transmission capacity,and its use is greatly advantageous.Additionally,by applying the proposed selection method,the control effect and economic benefits of the UPFC can be comprehensively considered during project site selection.These findings have a guiding significance for UPFC site selection in ultra-high voltage power grids.

A Discusion on Limited Load-Carrying Capacity of Rectangular Plates

The elastic-plastic method is often used in designing the inner flat bulkhead plates of submarines, and the upper structure of ships and drilling platforms. Such bulkhead plates can bear the load only once. For the improvement of the load-carrying capacity or the reduction of the weight of plates, the yield line analytical method is employed in this paper to design the bulkhead plate to improve economy and increase the effiective load. Besides, a further sutdy of this method has been made theoretically and experimentally, and the data of the limited load-carrying capacity of the plate have been obtained. Furthermore, the safety coefficients for such a method are presented, which can be used as reference for related departments and staffs.

QSRR Study on the Relationship between the Chromatographic Capacity Factor and Lipophilicity and Structure Parameters of Halogenated Thiophenols

The capacity factors （k＇） of fourteen types ofhalogenated thiophenols in different phases of methanol-water eluent were determined by reversed phased high-performance liquid chromatography （RP-HPLC） and the relationships between the logarithm of capacity factor lgK＇ and methanol ratio ψ were analyzed. A fair linear relationship is found between lgK＇ and ψ, and the correlation coefficients R2 of the constructed linear equations are all greater than 0.990. Relationship between the chromatographic data lgKw＇ when extrapolated to pure water and n-octanol/water partition coefficient lgKow obtained by the group contribution method has shown a good linear correlation with R2= 0.956. The structure parameters of fourteen halogenated thiophenols were calculated by using DFT, and the correlation equation of lgKw＇ and structure parameters was obtained by using SPSS, lgKw＇ = -0.409 ＋ 0.039a and R2 = 0.981, meaning that lgKw＇ is mainly determined by the polarizability α.

Research on VSG Frequency Characteristics and Energy Storage Device Capacity and Charge-Discharge Characteristics Based on Feedforward Branch

Renewable energy is connected to the grid through the inverter,which in turn reduces the inertia and stability of the power grid itself.The traditional grid-connected inverter does not have the function of voltage regulation and frequency regulation and can therefore no longer adapt to the new development.The virtual synchronous generator(VSG)has the function of voltage regulation and frequency regulation,which has more prominent advantages than traditional inverters.Based on the principle of VSG,the relationship between the frequency characteristics and the energy storage capacity of the feedforward branch-based virtual synchronous machine(FVSG)is derived when the input power and grid frequency change.Reveal the relationship between the virtual inertia coefficient,damping coefficient,and frequency characteristics of VSG and energy storage capacity.An energy storage configuration method that meets the requirements of frequency variation characteristics is proposed.A mathematical model is established,and the Matlab/Simulink simulation software is used for modeling.The simulation results verify the relationship between the inertia coefficient,damping coefficient,and energy storage demand of the FVSG.

Linear Regression Relationship between Lychee Juice Content and Buffering Capacity

Juice drinks are an important commercialization alternative for lychee, a tropical and subtropical fruit. Although the lychee juice content is important when assessing the quality of a drink, there are no published methods to determine it, particularly simple ones for the routine inspection of juice drinks. Lychee juice drinks contain ingredients with buffering capacity including proteins and ions such as phosphate, citrate, lactate, carbonate, acetate and propionate. The relationship between their buffering capacity and lychee juice content was studied. Citric acid was added to pure lychee dilutions in distilled water containing 100%, 90%, 80%, 70%, 60%, 50%, 40%, 30%, 20% and 10% lychee juice. The pH of the dilutions was measured to obtain a linear model for the molar H+ concentration as a function of the added citric acid (g/L) amount LC = (BC-494.2)/12,031, where LC was the lychee juice content and BC was defined as the juice buffering coefficient.

The revision on heat capacity of Einstein’s solid model

This paper is based on Einstein’s supposition about crystal lattice vibration, which states that when Einstein’s temperature ΘE is not less than the crystal temperature T but less than 2T, the expression of crystal molar heat capacity changes to the Dulong-Petit equation Cv=3R. Thereby this equation can explain why crystal molar heat capacity equals about 3R not only at low temperatures but also at normal temperatures for many kinds of metals. It can be calculated that the nonlinear interaction among atoms contributes to the molar heat capacity using the coefficient of expansion β and the Grüneisen constant γ. The result is that the relative error between the theoretical and the experimental value of the molar heat capacity is reduced greatly for many kinds of metals, especially for metals of IA. The relative error can be cut by about 17%.

Determination of Li+ solid diffusion coefficient in LiMn2O4 by CITT

The capacity intermittent titration technique (CITT) was developed based on the ratio of potentio-charge capacity to galvano-charge capacity (RPG) method, to continuously determine the solid diffusion coefficient (D) of the intercalary species within insertion-host materials with a small voltage region. The linear equations of D vs the value of ratio of the potentio-charge capacity to the galvano-charge capacity (q) were given. By the CITT technique,the Li+ solid diffusion coefficients within LiMn2 O4 at different voltages were determined. The results show that the values of D varied from 3. 447× 10-9 to 7.60× 10-11 cm2/s in the voltage range of charge from 3.3 to 4.3 V as a function of voltage with "W" shape.

Study on Ecological Carrying Capacity of Land in Henan Province

In order to explore the technical methods to improve the ecological carrying capacity of regional land under the premise of limited land use area,an open ecological footprint model is established based on the traditional ecological footprint model.Using the two models,this paper evaluates the ecological carrying capacity of Henan Province in 2017.The results indicate that the ecological productive footprint of cultivated land in Henan Province is much larger than the ecological carrying capacity,but the ecological consumption footprint is lower than the ecological carrying capacity.The open ecological footprint model can clearly distinguish the internal and the external ecological consumption footprint after corrected by the consumption adjustment coefficient and the land-use structure adjustment coefficient.Based on the open ecological footprint model,the ecological carrying capacity evaluation results of Henan Province are more realistic.The comprehensive ecological carrying capacity in Henan Province has a surplus,but there are significant differences among different land use types.The cultivated land has the largest ecological carrying capacity surplus,while the fossil energy land has a larger ecological carrying capacity deficit.In the process of achieving sustainable development,Henan Province should focus on reducing energy consumption and improving the ecological carrying capacity of fossil energy land.The paper concludes that the open ecological footprint model can simulate the ecological carrying capacity under different land use structures and different consumption structures.According to the simulation results,the technical methods to improve the ecological carrying capacity under the premise of limited land use scale can be proposed.The research can provide reference for land use structure adjustment,land use planning and land protection in Henan Province.It can also provide scientific basis for ecological protection and high-quality development of the Yellow River basin.

基于系统动力学模型的郑州市水资源承载力动态模拟

水资源问题制约着缺水城市的可持续发展,近年来郑州市社会经济高速发展,其水资源有限的现状与用水需求快速增长之间的矛盾愈加凸显。为科学研究郑州市水资源承载力远期发展情况,根据郑州市经济社会现状的水资源供需和发展状况,采用多系统综合的系统动力学方法(System Dynamics,SD),结合水资源、生态、经济社会、水利工程四个子系统,构建郑州市水资源承载力研究的SD模型。将2010-2019年的历史数据与SD方法的模拟数据进行比较,平均误差均小于10%,具有较高的可信度,可用来预测郑州市未来的水资源承载力发展情况。在此基础上,通过设定现状延续、控污节流、开源控污和开源节流4种不同方案,对2020-2030年水资源承载力系数进行动态模拟预测。结果表明:2030年4种方案下的水资源承载力系数分别为1.24、1.18、1.00、0.89,现状延续和控污节流方案下的郑州市水资源承载力随着时间的推移呈现严重超载状态,无法承载郑州市经济社会的快速发展;开源控污方案在预测期内的水资源承载力超载状态会对经济社会发展产生较大阻力。故开源节流方案为最佳方案,水资源承载力系数小于1,在研究期内未出现超载状态,可有利缓解郑州市的缺水状况,促进经济社会的发展。结合4种方案的优点,提出有利于郑州市水资源可持续发展的建议与对策。

砂土中冲刷条件下三筒基础水平承载特性研究

通过开展小比尺三筒基础承载力模型试验,研究冲刷条件下三筒基础水平承载特性,建立数值模型对模型试验结果进行验证与扩展,分析水平和弯矩荷载下,冲刷率e和相对筒间距S/D对极限承载力的影响,提出三筒基础极限承载力的冲刷修正系数dhe、dme的计算方法;采用固定荷载比方法,通过数值模型计算M-H加载条件下三筒基础的破坏包络线,分析冲刷率e和相对筒间距S/D对复合加载特性的影响,提出冲刷条件下三筒基础M-H破坏包络线公式。研究结果表明:冲刷条件下的三筒基础受水平和弯矩作用直至破坏的过程,经历弹性变形—塑性变形—失稳破坏3个阶段;三筒基础的水平极限承载力随冲刷率e的增大而下降,且下降速率逐渐增大,相同长径比的三筒基础的水平极限承载力随相对筒间距的减小而降低;随着冲刷率e的提高,三筒基础的M-H破坏包络线向内移动,随着相对筒间距S/D增大,归一化破坏包络线呈上凸的趋势。

三维土工网边坡防护水土保持能力研究

路基边坡防护工程可减轻降雨对坡面土体的侵蚀作用,为深入研究坡面防护材料水土保持能力的定量表征方法,通过室内人工降雨边坡侵蚀模型试验,分析不同降雨强度和不同三维土工网防护下路基边坡的降雨侵蚀规律,提出三维土工网水土保持能力的试验测定方法及相关系数计算公式。研究结果表明:三维土工网防护边坡泥沙流失干质量明显小于相同条件下不设防边坡泥沙流失干质量,土工网防护在减少边坡侵蚀量的同时,有利于边坡侵蚀进程的快速稳定,但土工网的水土保持能力随雨强增大急剧下降。泥沙流失速度随着降雨的持续而逐渐减小,后期趋于收敛稳定,侵蚀历程采用指数函数拟合具有较好的相关性。建议设防边坡的试验降雨时间不少于70 min,不设防的边坡试验降雨时间不小于100 min。水土保持能力系数随雨强的增大呈对数函数关系减小,雨强超过100 mm/h时水土保持能力系数实测值与对数函数拟合值差异较大,建议在测定材料水土保持能力系数时雨强取20~100 mm/h,可取50 mm/h作为标准试验雨强。泡面类三维土工网水土保持能力显著优于普通三维土工网,而双泡面的三维土工网优于单泡面三维土工网。试验条件下凹凸泡面三维土工网的水土保持能力系数主要分布在1.71~3.03,建议50 mm/h雨强三维土工网水土保持能力系数不应小于1.5。

木材老化对古建筑木梁抗弯性能的影响分析

为研究木材老化对古建筑木梁抗弯性能的影响,分析了木材的老化机理,采用等效截面法并结合国内木梁老化深度经验公式,提出了老化木梁抗弯承载力退化模型,并对某古建筑的木梁进行了承载力退化评估。对未老化与老化木梁进行了单调加载数值模拟,并通过试验验证了模型的合理性;在此基础上,进一步分析了老化均匀度与老化深度对木梁抗弯性能的影响。结合《木结构设计标准》(GB 50005—2017)中受弯构件的承载力计算公式,提出了考虑老化影响的木梁抗弯承载力折减系数计算公式。结果表明:老化对木梁抗弯承载力的影响与老化均匀度呈线性相关,与老化深度呈一元二次多项式关系。老化深度越深且老化均匀度越大,木梁承载力越低。

高陡岩质临坡地基承载力试验研究与数值模拟

针对高陡岩质临坡地基开展了不同坡角、坡距下承载力试验。结合深废矿坑工程采用数值模拟对高陡岩质临坡地基承载力影响因素进行了模拟计算与分析。研究结果表明:(1)承载力系数(η)随坡角(β)的增大而逐渐减小,随坡距(B)的增大呈非线性增长,当B超过一定距离时,η几乎不再增长且接近1.0;(2)相较β,地质强度指标(GSI)对η的影响更大,二者呈非线性同步增长;(3)锚索可提高η,设置4道锚索对η的提升效果较好,继续增加锚索数量对η的影响较小。