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Shear resistance of assembled bentonite interface after confined water saturation and interfacial self-healing capacity
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作者 Xinxin Dong Yonggui Chen +2 位作者 Xiaohua Bao Weimin Ye Qiong Wang 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第11期4742-4753,共12页
The requisite functions of a bentonite buffer in a deep geological repository depend on the sealing/healing of bentonite interfaces,with particular emphasis on the self-healing(automatic healing upon wetting)of assemb... The requisite functions of a bentonite buffer in a deep geological repository depend on the sealing/healing of bentonite interfaces,with particular emphasis on the self-healing(automatic healing upon wetting)of assembled bentonite-bentonite interfaces.This study determined the shear resistance(including the peak shear strength and secant modulus)of densely compacted Gaomiaozi(GMZ)bentonite and its assembled interface after confined water saturation.The effect of bentonite dry density and saturation time on the shear resistance of saturated healed interfaces was elucidated,and the interfacial self-healing capacity was assessed.The results indicate that the shear resistance of the saturated healed interfaces increased with the bentonite dry density but had a non-monotonic correlation with the saturation time.For a given dry density of the bentonite,the saturated healed interface exhibits a lower peak shear strength than the saturated intact bentonite but a higher peak shear strength than the saturated separated interface.The saturated healed and separated interfaces have comparable shear moduli(secant moduli),which are lower than that of the saturated intact bentonite.The saturated healed interfaces display smooth shear failure planes,while the saturated assembled interfaces and intact bentonite exhibit comparable frictional angles.This indicates that interfacial self-healing plays a pivotal role in enhancing interfacial peak shear strength by facilitating microstructural bonding at the assembled interface.Finally,it can be stated that densely compacted GMZ bentonite has a robust interfacial self-healing capacity in terms of shear resistance.These findings contribute to the design of the bentonite buffer and facilitate the evaluation of its safe operation at specified disposal ages. 展开更多
关键词 Compacted bentonite INTERFACE self-healing Peak shear strength Shear modulus
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The Prediction of Self-Healing Capacity of Bacteria-Based Concrete Using Machine Learning Approaches 被引量:9
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作者 Xiaoying Zhuang Shuai Zhou 《Computers, Materials & Continua》 SCIE EI 2019年第4期57-77,共21页
Advances in machine learning(ML)methods are important in industrial engineering and attract great attention in recent years.However,a comprehensive comparative study of the most advanced ML algorithms is lacking.Six i... Advances in machine learning(ML)methods are important in industrial engineering and attract great attention in recent years.However,a comprehensive comparative study of the most advanced ML algorithms is lacking.Six integrated ML approaches for the crack repairing capacity of the bacteria-based self-healing concrete are proposed and compared.Six ML algorithms,including the Support Vector Regression(SVR),Decision Tree Regression(DTR),Gradient Boosting Regression(GBR),Artificial Neural Network(ANN),Bayesian Ridge Regression(BRR)and Kernel Ridge Regression(KRR),are adopted for the relationship modeling to predict crack closure percentage(CCP).Particle Swarm Optimization(PSO)is used for the hyper-parameters tuning.The importance of parameters is analyzed.It is demonstrated that integrated ML approaches have great potential to predict the CCP,and PSO is efficient in the hyperparameter tuning.This research provides useful information for the design of the bacteria-based self-healing concrete and can contribute to the design in the rest of industrial engineering. 展开更多
关键词 BACTERIA self-healing concrete crack closure percentage machine learning PREDICTION
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Mechanical reliable,NIR light-induced rapid self-healing hydrogel electrolyte towards flexible zinc-ion hybrid supercapacitors with low-temperature adaptability and long service life 被引量:1
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作者 Tengjia Gao Na Li +4 位作者 Yang Yang Jing Li Peng Ji Yunlong Zhou Jianxiong Xu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期63-73,共11页
Hydrogel electrolytes hold great potential in flexible zinc ion supercapacitors(ZICs)due to their high conductivity,good safety,and flexibility.However,freezing of electrolytes at low temperature(subzero)leads to dras... Hydrogel electrolytes hold great potential in flexible zinc ion supercapacitors(ZICs)due to their high conductivity,good safety,and flexibility.However,freezing of electrolytes at low temperature(subzero)leads to drastic reduction in ionic conductivity and mechanical properties that deteriorates the performance of flexible ZICs.Besides,the mechanical fracture during arbitrary deformations significantly prunes out the lifespan of the flexible device.Herein,a Zn^(2+)and Li^(+)co-doped,polypyrrole-dopamine decorated Sb_(2)S_(3)incorporated,and polyvinyl alcohol/poly(N-(2-hydroxyethyl)acrylamide)double-network hydrogel electrolyte is constructed with favorable mechanical reliability,anti-freezing,and self-healing ability.In addition,it delivers ultra-high ionic conductivity of 8.6 and 3.7 S m^(-1)at 20 and−30°C,respectively,and displays excellent mechanical properties to withstand tensile stress of 1.85 MPa with tensile elongation of 760%,together with fracture energy of 5.14 MJ m^(-3).Notably,the fractured hydrogel electrolyte can recover itself after only 90 s of infrared illumination,while regaining 83%of its tensile strain and almost 100%of its ionic conductivity during−30–60°C.Moreover,ZICs coupled with this hydrogel electrolyte not only show a wide voltage window(up to 2 V),but also provide high energy density of 230 Wh kg^(-1)at power density of 500 W kg^(-1)with a capacity retention of 86.7%after 20,000 cycles under 20°C.Furthermore,the ZICs are able to retain excellent capacity even under various mechanical deformation at−30°C.This contribution will open up new insights into design of advanced wearable flexible electronics with environmental adaptability and long-life span. 展开更多
关键词 Flexible zinc ion supercapacitor Hydrogel electrolyte self-healing Anti-freezing
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A comparison study on structure-function relationship of polysaccharides obtained from sea buckthorn berries using different methods:antioxidant and bile acid-binding capacity 被引量:5
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作者 Qiaoyun Li Zuman Dou +5 位作者 Qingfei Duan Chun Chen Ruihai Liu Yueming Jiang Bao Yang Xiong Fu 《Food Science and Human Wellness》 SCIE CSCD 2024年第1期494-505,共12页
In this study,the structural characters,antioxidant activities and bile acid-binding ability of sea buckthorn polysaccharides(HRPs)obtained by the commonly used hot water(HRP-W),pressurized hot water(HRP-H),ultrasonic... In this study,the structural characters,antioxidant activities and bile acid-binding ability of sea buckthorn polysaccharides(HRPs)obtained by the commonly used hot water(HRP-W),pressurized hot water(HRP-H),ultrasonic(HRP-U),acid(HRP-C)and alkali(HRP-A)assisted extraction methods were investigated.The results demonstrated that extraction methods had significant effects on extraction yield,monosaccharide composition,molecular weight,particle size,triple-helical structure,and surface morphology of HRPs except for the major linkage bands.Thermogravimetric analysis showed that HRP-U with filamentous reticular microstructure exhibited better thermal stability.The HRP-A with the lowest molecular weight and highest arabinose content possessed the best antioxidant activities.Moreover,the rheological analysis indicated that HRPs with higher galacturonic acid content and molecular weight showed higher viscosity and stronger crosslinking network(HRP-C,HRP-W and HRP-U),which exhibited stronger bile acid binding capacity.The present findings provide scientific evidence in the preparation technology of sea buckthorn polysaccharides with good antioxidant and bile acid binding capacity which are related to the structure affected by the extraction methods. 展开更多
关键词 Sea buckthorn Extraction method STRUCTURE Rheological properties Antioxidant activity Bile acid binding capacity
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Free radicals trigger the closure of open pores in lignin-derived hard carbons toward improved sodium-storage capacity 被引量:1
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作者 Wen-Jun Ji Zong-Lin Yi +8 位作者 Ming-Xin Song Xiao-Qian Guo Yi-Lin Wang Yi-Xuan Mao Fang-Yuan Su Jing-Peng Chen Xian-Xian Wei Li-Jing Xie Cheng-Meng Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第7期551-559,共9页
The chemical activation of various precursors is effective for creating additional closed pores in hard carbons for sodium storage.However,the formation mechanism of closed pores under the influence of pore-forming ag... The chemical activation of various precursors is effective for creating additional closed pores in hard carbons for sodium storage.However,the formation mechanism of closed pores under the influence of pore-forming agents is not well understood.Herein,an effective chemical activation followed by a high-temperature self-healing strategy is employed to generate interconnected closed pores in lignin-derived hard carbon(HCs).By systematic experimental design combined with electron paramagnetic res-onance spectroscopy,it can be found that the content of free radicals in the carbon matrix influences the closure of open pores at high temperatures.Excessively high activation temperature(>700 C)leads to a low free radical concentration,making it difficult to achieve self-healing of open pores at high tempera-tures.By activation at 700°C,a balance between pore making and self-healing is achieved in the final hard carbon.A large number of free radicals triggers rapid growth and aggregation of carbon microcrys-tals,blocking pre-formed open micropores and creating additional interconnected closed pores in as-obtained hard carbons.As a result,the optimized carbon anode(LK-700-1300)delivers a high reversible capacity of 330.8 mA h g^(-1) at 0.03 A g^(-1),which is an increase of 86 mA h g^(-1) compared to the pristine lignin-derived carbon anode(L-700-1300),and exhibits a good rate performance(202.1 mA h g^(-1) at 1 A g^(-1)).This work provides a universal and effective guidance for tuning closed pores of hard carbons from otherprecursors. 展开更多
关键词 Hard carbon Chemical activation Free radical self-healing Closed pores Sodium ion batteries
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Durable K-ion batteries with 100% capacity retention up to 40,000 cycles 被引量:1
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作者 Xianlu Lu Zhao Liang +6 位作者 Zhi Fang Dongdong Zhang Yapeng Zheng Qiao Liu Dingfa Fu Jie Teng Weiyou Yang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第5期201-212,共12页
Currently,the major challenge in terms of research on K-ion batteries is to ensure that they possess satisfactory cycle stability and specific capacity,especially in terms of the intrinsically sluggish kinetics induce... Currently,the major challenge in terms of research on K-ion batteries is to ensure that they possess satisfactory cycle stability and specific capacity,especially in terms of the intrinsically sluggish kinetics induced by the large radius of K+ions.Here,we explore high-performance K-ion half/full batteries with high rate capability,high specific capacity,and extremely durable cycle stability based on carbon nanosheets with tailored N dopants,which can alleviate the change of volume,increase electronic conductivity,and enhance the K+ion adsorption.The as-assembled K-ion half-batteries show an excellent rate capability of 468 mA h g^(−1) at 100 mA g^(−1),which is superior to those of most carbon materials reported to date.Moreover,the as-assembled half-cells have an outstanding life span,running 40,000 cycles over 8 months with a specific capacity retention of 100%at a high current density of 2000 mA g^(−1),and the target full cells deliver a high reversible specific capacity of 146 mA h g^(−1) after 2000 cycles over 2 months,with a specific capacity retention of 113%at a high current density of 500 mA g^(−1),both of which are state of the art in the field of K-ion batteries.This study might provide some insights into and potential avenues for exploration of advanced K-ion batteries with durable stability for practical applications. 展开更多
关键词 carbon nanosheet cycle stability K-ion batteries rate performance specific capacity
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A comparative study of data-driven battery capacity estimation based on partial charging curves 被引量:1
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作者 Chuanping Lin Jun Xu +5 位作者 Delong Jiang Jiayang Hou Ying Liang Xianggong Zhang Enhu Li Xuesong Mei 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第1期409-420,I0010,共13页
With its generality and practicality, the combination of partial charging curves and machine learning(ML) for battery capacity estimation has attracted widespread attention. However, a clear classification,fair compar... With its generality and practicality, the combination of partial charging curves and machine learning(ML) for battery capacity estimation has attracted widespread attention. However, a clear classification,fair comparison, and performance rationalization of these methods are lacking, due to the scattered existing studies. To address these issues, we develop 20 capacity estimation methods from three perspectives:charging sequence construction, input forms, and ML models. 22,582 charging curves are generated from 44 cells with different battery chemistry and operating conditions to validate the performance. Through comprehensive and unbiased comparison, the long short-term memory(LSTM) based neural network exhibits the best accuracy and robustness. Across all 6503 tested samples, the mean absolute percentage error(MAPE) for capacity estimation using LSTM is 0.61%, with a maximum error of only 3.94%. Even with the addition of 3 m V voltage noise or the extension of sampling intervals to 60 s, the average MAPE remains below 2%. Furthermore, the charging sequences are provided with physical explanations related to battery degradation to enhance confidence in their application. Recommendations for using other competitive methods are also presented. This work provides valuable insights and guidance for estimating battery capacity based on partial charging curves. 展开更多
关键词 Lithium-ion battery Partial charging curves capacity estimation DATA-DRIVEN Sampling frequency
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Sealing capacity evaluation of underground gas storage under intricate geological conditions 被引量:1
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作者 Guangquan Zhang Sinan Zhu +4 位作者 Daqian Zeng Yuewei Jia Lidong Mi Xiaosong Yang Junfa Zhang 《Energy Geoscience》 EI 2024年第3期234-243,共10页
Evaluating underground gas storage(UGS)sealing capacity is essential for its safe construction and operational efficiency.This involves evaluating both the static sealing capacity of traps during hydrocarbon accumulat... Evaluating underground gas storage(UGS)sealing capacity is essential for its safe construction and operational efficiency.This involves evaluating both the static sealing capacity of traps during hydrocarbon accumulation and the dynamic sealing capacity of UGS under intensive gas injection and withdrawal,and alternating loads.This study detailed the methodology developed by Sinopec.The approach merges disciplines like geology,geomechanics,and hydrodynamics,employing both dynamic-static and qualitative-quantitative analyses.Sinopec's evaluation methods,grounded in the in situ stress analysis,include mechanistic studies,laboratory tests,geological surveys,stress analysis,and fluid-solid interactions.Through tests on the static and dynamic sealing capacity of UGS,alongside investigations into sealing mechanisms and the geological and geomechanical properties of cap rocks and faults,A geomechanics-rock damage-seepage mechanics dynamic coupling analysis method has been developed to predict in situ stress variations relative to pore pressure changes during UGS operations and evaluate fault sealing capacity and cap rock integrity,thereby setting the maximum operational pressures.Utilizing this evaluation technique,Sinopec has defined performance metrics and criteria for evaluating the sealing capacity of depleted gas reservoirs,enabling preliminary sealing capacity evaluations at UGS sites.These evaluations have significantly informed the design of UGS construction schemes and the evaluation of fault sealing capacity and cap rock integrity during UGS operations. 展开更多
关键词 Underground gas storage Sealing capacity GEOMECHANICS Maximum operational pressure
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Mechanically skin-like and water-resistant self-healing bioelastomer for high-tension wound healing
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作者 Jinyi Huang Hongying Chen +7 位作者 Zenghui Jia Xingqi Song Sinan Wang Baoshuai Bai Jian Wang Junfeng Zhang Guangdong Zhou Dong Lei 《Bioactive Materials》 SCIE CSCD 2024年第9期443-455,共13页
The biomedical application of self-healing materials in wet or(under)water environments is quite challenging because the insulation and dissociation effects of water molecules significantly reduce the reconstruction o... The biomedical application of self-healing materials in wet or(under)water environments is quite challenging because the insulation and dissociation effects of water molecules significantly reduce the reconstruction of material–interface interactions.Rapid closure with uniform tension of high-tension wounds is often difficult,leading to further deterioration and scarring.Herein,a new type of thermosetting water-resistant self-healing bioelastomer(WRSHE)was designed by synergistically incorporating a stable polyglycerol sebacate(PGS)covalent crosslinking network and triple hybrid dynamic networks consisting of reversible disulfide metathesis(SS),and dimethylglyoxime urethane(Dou)and hydrogen bonds.And a resveratrol-loaded WRSHE(Res@WRSHE)was developed by a swelling,absorption,and crosslinked network locking strategy.WRSHEs exhibited skin-like mechanical properties in terms of nonlinear modulus behavior,biomimetic softness,high stretchability,and good elasticity,and they also achieved ultrafast and highly efficient self-healing in various liquid environments.For wound-healing applications of high-tension full-thickness skin defects,the convenient surface assembly by self-healing of WRSHEs provides uniform contraction stress to facilitate tight closure.Moreover,Res@WRSHEs gradually release resveratrol,which helps inflammatory response reduction,promotes blood vessel regeneration,and accelerates wound repair. 展开更多
关键词 Underwater self-healing Dynamic bonds BIOELASTOMER High-tension wounds RESVERATROL
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A Self-Healing Optoacoustic Patch with High Damage Threshold and Conversion Efficiency for Biomedical Applications
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作者 Tao Zhang Cheng-Hui Li +7 位作者 Wenbo Li Zhen Wang Zhongya Gu Jiapu Li Junru Yuan Jun Ou-Yang Xiaofei Yang Benpeng Zhu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第7期31-45,共15页
Compared with traditional piezoelectric ultrasonic devices,optoacoustic devices have unique advantages such as a simple preparation process,anti-electromagnetic interference,and wireless long-distance power supply.How... Compared with traditional piezoelectric ultrasonic devices,optoacoustic devices have unique advantages such as a simple preparation process,anti-electromagnetic interference,and wireless long-distance power supply.However,current optoacoustic devices remain limited due to a low damage threshold and energy conversion efficiency,which seriously hinder their widespread applications.In this study,using a self-healing polydimethylsiloxane(PDMS,Fe-Hpdca-PDMS)and carbon nanotube composite,a flexible optoacoustic patch is developed,which possesses the self-healing capability at room temperature,and can even recover from damage induced by cutting or laser irradiation.Moreover,this patch can generate high-intensity ultrasound(>25 MPa)without the focusing structure.The laser damage threshold is greater than 183.44 mJ cm^(-2),and the optoacoustic energy conversion efficiency reaches a major achievement at 10.66×10^(-3),compared with other carbon-based nanomaterials and PDMS composites.This patch is also been successfully examined in the application of acoustic flow,thrombolysis,and wireless energy harvesting.All findings in this study provides new insight into designing and fabricating of novel ultrasound devices for biomedical applications. 展开更多
关键词 Optoacoustic self-healing PDMS Acoustic flow THROMBOLYTIC Wireless energy harvesting
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Insight into the capacity degradation and structural evolution of single-crystal Ni-rich cathodes
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作者 Xiaodong Zhang Jiao Lin +5 位作者 Ersha Fan Qingrong Huang Su Ma Renjie Chen Feng Wu Li Li 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期68-76,I0003,共10页
Single-crystal Ni-rich cathodes are a promising candidate for high-energy lithium-ion batteries due to their higher structural and cycling stability than polycrystalline materials.However,the phase evolution and capac... Single-crystal Ni-rich cathodes are a promising candidate for high-energy lithium-ion batteries due to their higher structural and cycling stability than polycrystalline materials.However,the phase evolution and capacity degradation of these single-crystal cathodes during continuous lithation/delithation cycling remains unclear.Understanding the mapping relationship between the macroscopic electrochemical properties and the material physicochemical properties is crucial.Here,we investigate the correlation between the physical-chemical characteristics,phase transition,and capacity decay using capacity differential curve feature identification and in-situ X-ray spectroscopic imaging.We systematically clarify the dominant mechanism of phase evolution in aging cycling.Appropriately high cut-off voltages can mitigate the slow kinetic and electrochemical properties of single-crystal cathodes.We also find that second-order differential capacity discharge characteristic curves can be used to identify the crystal structure disorder of Ni-rich cathodes.These findings constitute a step forward in elucidating the correlation between the electrochemical extrinsic properties and the physicochemical intrinsic properties and provide new perspectives for failure analysis of layered electrode materials. 展开更多
关键词 Single-crystal cathodes capacity decay Phase transition Differential capacity analysis
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Multifunctional phase change film with high recyclability, adjustable thermal responsiveness, and intrinsic self-healing ability for thermal energy storage
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作者 Bo Yang Xuelai Zhang +2 位作者 Jun Ji Weisan Hua Miaomiao Jiang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第10期216-227,I0005,共13页
Phase change materials(PCMs) present promising potential for guaranteeing safety in thermal management systems.However,most reported PCMs have a single application in energy storage for thermal management systems,whic... Phase change materials(PCMs) present promising potential for guaranteeing safety in thermal management systems.However,most reported PCMs have a single application in energy storage for thermal management systems,which does not meet the growing demand for multi-functional materials.In this paper,the flexible material and hydrogen-bonding function are innovatively combined to design and prepare a novel multi-functional flexible phase change film(PPL).The 0.2PPL-2 film exhibits solid-solid phase change behavior with energy storage density of 131.8 J/g at the transition temperature of42.1℃,thermal cycling stability(500 cycles),wide-temperature range flexibility(0-60℃) and selfhealing property.Notably,the PPL film can be recycled up to 98.5% by intrinsic remodeling.Moreover,the PPL film can be tailored to the desired colors and configurations and can be cleverly assembled on several thermal management systems at ambient temperature through its flexibility combined with shape-memory properties.More interestingly,the transmittance of PPL will be altered when the ambient temperature changes(60℃),conveying a clear thermal signal.Finally,the thermal energy storage performance of the PPL film is successfully tested by human thermotherapy and electronic device temperature control experiments.The proposed functional integration strategy provides innovative ideas to design PCMs for multifunctionality,and makes significant contributions in green chemistry,highefficiency thermal management,and energy sustainability. 展开更多
关键词 Phase change film Multifunctional material Energy storage self-healing RECYCLABILITY
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Flexible,thermal processable,self-healing,and fully bio-based starch plastics by constructing dynamic imine network
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作者 Xiaoqian Zhang Haishan Zhang +2 位作者 Guowen Zhou Zhiping Su Xiaohui Wang 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第10期1610-1618,共9页
The serious environmental threat caused by petroleum-based plastics has spurred more researches in developing substitutes from renewable sources.Starch is desirable for fabricating bioplastic due to its abundance and ... The serious environmental threat caused by petroleum-based plastics has spurred more researches in developing substitutes from renewable sources.Starch is desirable for fabricating bioplastic due to its abundance and renewable nature.However,limitations such as brittleness,hydrophilicity,and thermal properties restrict its widespread application.To overcome these issues,covalent adaptable network was constructed to fabricate a fully bio-based starch plastic with multiple advantages via Schiff base reactions.This strategy endowed starch plastic with excellent thermal processability,as evidenced by a low glass transition temperature(T_(g)=20.15℃).Through introducing Priamine with long carbon chains,the starch plastic demonstrated superior flexibility(elongation at break=45.2%)and waterproof capability(water contact angle=109.2°).Besides,it possessed a good thermal stability and self-adaptability,as well as solvent resistance and chemical degradability.This work provides a promising method to fabricate fully bio-based plastics as alternative to petroleum-based plastics. 展开更多
关键词 Bioplastic Covalent adaptable networks Schiff base chemistry Thermal processability self-healing
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High performance photodegradation resistant PVA@TiO_(2)/carboxyl-PES self-healing reactive ultrafiltration membrane
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作者 Yu Liang Yuanfang Fan +5 位作者 Zhongmin Su Mingxin Huo Xia Yang Hongliang Huo Chi Wang Zhi Geng 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期31-39,共9页
The occurrence of ultrafiltration(UF)membrane fouling frequently hampers the sustainable advancement of UF technology.Reactive self-cleaning UF membranes can effectively alleviate the problem of membrane fouling.Never... The occurrence of ultrafiltration(UF)membrane fouling frequently hampers the sustainable advancement of UF technology.Reactive self-cleaning UF membranes can effectively alleviate the problem of membrane fouling.Nevertheless,the self-cleaning process may accelerate membrane aging.Addressing these concerns,we present an innovative design concept for composite self-healing materials based on self-cleaning UF membranes.To begin,TiO_(2)nanoparticles were incorporated into the polymer molecular structure via molecular design,resulting in the synthesis of TiO_(2)/carboxyl-polyether sulfone(PES)hybrid materials.Subsequently,the nonsolvent-induced phase inversion technique was employed to prepare a novel of UF membrane.Lastly,a polyvinyl alcohol(PVA)hydrogel coating was applied to the hybrid UF membrane surface to create PVA@TiO_(2)/carboxyl-PES self-healing reactive UF membranes.By establishing a covalent bond,the TiO_(2)nanoparticles were effectively and uniformly dispersed within the UF membrane,leading to exceptional self-cleaning properties.Furthermore,the water-absorbing and swelling properties of PVA hydrogel,along with its capacity to form hydrogen bonds with water molecules,resulted in UF membranes with improved hydrophilicity and active self-healing abilities.The results demonstrated that the water contact angle of PVA@5%TiO_(2)/carboxyl-PES UF membrane was 43.1°.Following a 1-h exposure to simulated solar exposure,the water flux recovery ratio increased from 48.16%to 81.03%.Moreover,even after undergoing five cycles of 12-h simulated sunlight exposure,the UF membranes exhibited a consistent retention rate of over 97%,thus fully demonstrating their exceptional self-cleaning,antifouling,and selfhealing capabilities.We anticipate that the self-healing reactive UF membrane system will serve as a pioneering and comprehensive solution for the self-cleaning antifouling challenges encountered in UF membranes while also effectively mitigating the aging effects of reactive UF membranes. 展开更多
关键词 Ultrafiltration membrane SELF-CLEANING self-healing Poly(aryl ether sulfone)
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An intrinsically self-healing and anti-freezing molecular chains induced polyacrylamide-based hydrogel electrolytes for zinc manganese dioxide batteries
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作者 Haiyang Liao Wenzhao Zhong +8 位作者 Chen Li Jieling Han Xiao Sun Xinhui Xia Ting Li Abolhassan Noori Mir F.Mousavi Xin Liu Yongqi Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期565-578,I0013,共15页
The anti-freezing strategy of hydrogels and their self-healing structure are often contradictory,it is vital to break through the molecular structure to design and construct hydrogels with intrinsic anti-freezing/self... The anti-freezing strategy of hydrogels and their self-healing structure are often contradictory,it is vital to break through the molecular structure to design and construct hydrogels with intrinsic anti-freezing/self-healing for meeting the rapid development of flexible and wearable devices in diverse service conditions.Herein,we design a new hydrogel electrolyte(AF/SH-Hydrogel)with intrinsic anti-freezing/self-healing capabilities by introducing ethylene glycol molecules,dynamic chemical bonding(disulfide bond),and supramolecular interaction(multi-hydrogen bond)into the polyacrylamide molecular chain.Thanks to the exceptional freeze resistance(84%capacity retention at-20℃)and intrinsic self-healing capabilities(95%capacity retention after 5 cutting/self-healing cycles),the obtained AF/SH-Hydrogel makes the zinc||manganese dioxide cell an economically feasible battery for the state-of-the-art applications.The Zn||AF/SH-Hydrogel||MnO_(2)device offers a near-theoretical specific capacity of 285 m A h g^(-1)at 0.1 A g^(-1)(Coulombic efficiency≈100%),as well as good self-healing capability and mechanical flexibility in an ice bath.This work provides insight that can be utilized to develop multifunctional hydrogel electrolytes for application in next generation of self-healable and freeze-resistance smart aqueous energy storage devices. 展开更多
关键词 Flexible aqueous battery Hydrogel electrolyte ANTI-FREEZING self-healing Dual-dynamic reversible bond
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Effect of Trimetazidine on Functional Capacity in Patient with Ischaemic Cardiomyopathy (TOFCAPI)
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作者 Mohsin Ahmed Golam Morshed +7 位作者 Mahmood Hasan Khan Md. Arifur Rahman Muhammed Aminur Razzaque Shariful Islam Sayeedur Rahman Khan Chowdhury Md. Kudrat-E-Khuda Salahuddin Anis Shiblee Md. Habibur Rahman 《International Journal of Clinical Medicine》 CAS 2024年第2期55-67,共13页
Objective: This study aimed to evaluate the efficacy of trimetazidine on exercise capacity via a six-minute walk test in patients with ischaemic cardiomyopathy and also evaluate the effect of trimetazidine on left ven... Objective: This study aimed to evaluate the efficacy of trimetazidine on exercise capacity via a six-minute walk test in patients with ischaemic cardiomyopathy and also evaluate the effect of trimetazidine on left ventricular function via echocardiography in the same population. Methods: This prospective observational study, conducted at the National Institute of Cardiovascular Diseases in Dhaka, Bangladesh, enrolled 200 patients with ischaemic cardiomyopathy and a depressed left ventricular ejection fraction (LVEF Results: In this study (n = 200) of ischaemic cardiomyopathy patients, the mean age was 58 years, with 76% of the patients being male. All study subjects received GDMT (Guideline-Directed Medical Therapy) for angina and heart failure. Those who received the modified released form of trimetazidine developed lesions during the 1st and 2nd follow-ups, during which the LVEF, LVIDd, and six-minute walk distance significantly improved (p Conclusion: The findings of the present study demonstrated that the addition of modified-release trimetazidine to GDMT can improve exercise capacity and left ventricular function in patients with ischaemic cardiomyopathy. 展开更多
关键词 BANGLADESH Heart Failure Exercise capacity TRIMETAZIDINE Ischaemic Cardiomyopathy
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Effect of Cardiac Rehabilitation on Physical Capacity of Heart Failure Patients in Senegal
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作者 Ngoné Diaba Gaye Aliou Alassane Ngaidé +5 位作者 Joseph Mingou Fatou Aw Mame Madjiguène Ka Aimé Mbaye Sy Zakaria Naji Lamrani Abdoul Kane 《World Journal of Cardiovascular Diseases》 CAS 2024年第8期447-458,共12页
Background: Heart failure is a chronic and severe condition that often results from various heart diseases. Cardiac rehabilitation (CR) is currently a crucial component in managing this condition. The aim was to asses... Background: Heart failure is a chronic and severe condition that often results from various heart diseases. Cardiac rehabilitation (CR) is currently a crucial component in managing this condition. The aim was to assess the effects of cardiac rehabilitation on physical capacity of heart failure patients. Methods: This was a cross-sectional study conducted from February 1, 2021, to June 30, 2023. We included all patients with heart failure who underwent cardiac rehabilitation. Data analysis was performed using SPSS software version 24.0, with a significance level set at p Results: The study included 87 heart failure patients, with a male-to-female ratio of 1.8. Mean age was 57.10 years (±11.75). Coronary artery disease was the primary cause of heart failure, accounting for 75.9% of cases. Atrial fibrillation was present in 4.7% of cases. Following cardiac rehabilitation, Left Ventricular Ejection Fraction increased from 40.15% to 49.48% (p = 0.001). Resting heart rate decreased significantly from 81.4 bpm to 68.3 bpm (p = 0.000), and the number of METS increased from 4.3 to 6.57 (+56.8%;p = 0.000). The mean distance covered in the 6-minute walk test significantly increased from 337.8 meters to 522.7 meters (p = 0.000), reflecting a gain of 183.5 meters. Moreover, the increase in the number of METS was more pronounced in females (p = 0.001), non-obese individuals (p = 0.000), non-diabetics (p = 0.001), non-sedentary individuals (p = 0.000), and non-smokers (p = 0.000). The study reported a low readmissions rate of 2.2% and a mortality rate of 1.1%. Conclusion: Our study demonstrates that cardiac rehabilitation is beneficial for black African heart failure patients, resulting in significant improvements in symptoms, physical and capacity. 展开更多
关键词 Cardiac Rehabilitation Chronic Heart Failure Physical capacity Senegal
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Functional Capacity of Patients with Venous Thromboembolic Disease Six to Twelve Months after Treatment
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作者 Hamadou Bâ Chris-Nadège Nganou-Gnindjio +3 位作者 Alexis Noé S. Guiakam Kemnang Yemele Honore Danwe Dieudonné Guy S. Wafeu 《World Journal of Cardiovascular Diseases》 CAS 2024年第2期88-98,共11页
Background: Venous thromboembolism (VTE) is among the leading causes of hospital-related disability-adjusted life years lost. We aimed to determine the prevalence and determinants of functional capacity impairment six... Background: Venous thromboembolism (VTE) is among the leading causes of hospital-related disability-adjusted life years lost. We aimed to determine the prevalence and determinants of functional capacity impairment six to twelve months after an acute VTE event. Methods: This was a cross-sectional study conducted between January and April 2021 in two referral hospitals of Yaoundé, including consenting adult patients admitted to these hospitals six to twelve months ago for VTE. We excluded dead patients and those with any comorbidity or symptoms limiting physical activity. The functional outcome was assessed with the six-minute walk test. Functional capacity impairment was defined as walking distance lower than the expected value. Results: We included 27 cases in this study with a mean age of 53.2 ± 14.4 years. The prevalence of functional capacity impairment was 29.6% (95% CI: 14.8 - 48.1). Factors associated with poor functional outcome were obesity (OR: 59.5;95% CI: 4.6 - 767.2;p - 207.4;p = 0.017), massive PE (OR: 30;95% CI: 2.5 - 354;p = 0.004), and poor adherence to treatment (OR: 30.3;95% CI: 2.5 - 333.3;p = 0.004). Conclusion: Functional capacity impairment is common in the medium-term after VTE and factors associated with this poor outcome are obesity, the severity of the VTE, and poor adherence to treatment. 展开更多
关键词 Functional capacity Venous Thromboembolism Six-Minute Walk Test Cameroon
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Dust-Holding Capacity and Bio-Chemical Changes of Plant Species Growing in an Around Opencast Mining Area of Bundelkhand Region of Uttar Pradesh, India
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作者 Priyanka Singh Amit Pal 《American Journal of Plant Sciences》 CAS 2024年第8期677-698,共22页
The present study has been carried out on a total of 50 available plant species to assess their dust-capturing capacity and biochemical performances in and around open cast granite mine areas of Jhansi district and Bu... The present study has been carried out on a total of 50 available plant species to assess their dust-capturing capacity and biochemical performances in and around open cast granite mine areas of Jhansi district and Bundelkhand University campus treated as control site. Plant species existing under a polluted environment for a long time may be considered as potentially resistant species and recommended for green belt design in mining areas, especially to cope with dust pollution. Results showed the pollution level, especially of mining-originated dust particles holding capacity of leaves and effects of different biochemical parameters (Total Chlorophyll, Protein and Carotenoid) of existing plant species both from mining areas as well as from Bundelkhand University campus. Based on their performances, Tectona grandis L., Ficus hispida L., Calotropis procera Aiton., Butea monosperma Lam. and Ficus benghalensis L., etc. are highly tolerant species while Ficus infectoria L., Artocarpus heterophyllus Lam., Ipomoea purpurea L., Allianthus excelsa Roxb. and Bauhinia variegata L. are intermediate tolerant species. T. grandis had shown the highest dust-holding capacity (2.566 ± 0.0004 mg/cm2) whereas Albizia procera (0.018 ± 0.0002 mg/cm2) was found to be the lowest dust-holding capacity. Our findings also showed that the T. grandis and F. hispida have significant dust deposition with minimal effect of dust on their leaf chlorophyll (17.447 ± 0.019 mg/g and 14.703 ± 0.201 mg/g), protein (0.699 ± 0.001 mg/g and 0.604 ± 0.002 mg/g) and carotenoid (0.372 ± 0.003 mg/g and 0.354 ± 0.003 mg/g) content respectively among all selected plant species. Therefore, in the present investigation, plant species with high tolerance to high dust-holding capacity on their leaf surfaces are preferable for green corridors as open cast granite mines and their adjacent areas. 展开更多
关键词 Bundelkhand Region Biochemical Changes Dust-Holding capacity Chlorophyll Content Open Cast Granite Mining
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Stochastic Air Traffic Flow Management for Demand and Capacity Balancing Under Capacity Uncertainty
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作者 CHEN Yunxiang XU Yan ZHAO Yifei 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2024年第5期656-674,共19页
This paper introduces an innovative approach to the synchronized demand-capacity balance with special focus on sector capacity uncertainty within a centrally controlled collaborative air traffic flow management(ATFM)f... This paper introduces an innovative approach to the synchronized demand-capacity balance with special focus on sector capacity uncertainty within a centrally controlled collaborative air traffic flow management(ATFM)framework.Further with previous study,the uncertainty in capacity is considered as a non-negligible issue regarding multiple reasons,like the impact of weather,the strike of air traffic controllers(ATCOs),the military use of airspace and the spatiotemporal distribution of nonscheduled flights,etc.These recessive factors affect the outcome of traffic flow optimization.In this research,the focus is placed on the impact of sector capacity uncertainty on demand and capacity balancing(DCB)optimization and ATFM,and multiple options,such as delay assignment and rerouting,are intended for regulating the traffic flow.A scenario optimization method for sector capacity in the presence of uncertainties is used to find the approximately optimal solution.The results show that the proposed approach can achieve better demand and capacity balancing and determine perfect integer solutions to ATFM problems,solving large-scale instances(24 h on seven capacity scenarios,with 6255 flights and 8949 trajectories)in 5-15 min.To the best of our knowledge,our experiment is the first to tackle large-scale instances of stochastic ATFM problems within the collaborative ATFM framework. 展开更多
关键词 air traffic flow management demand and capacity balancing flight delays sector capacity uncertainty ground delay programs probabilistic scenario trees
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