NaCl aqueous solution（15 wt%） was used as the quenching medium to prepare amorphous Lithium-Zinc ferrite hollow microspheres（LiZn FHMs） based on self-reactive quenching technology. Investigations by scanning elect...NaCl aqueous solution（15 wt%） was used as the quenching medium to prepare amorphous Lithium-Zinc ferrite hollow microspheres（LiZn FHMs） based on self-reactive quenching technology. Investigations by scanning electro microscope, X-ray diffraction, electron diffraction of transmission electron microscope, and differential scanning calorimetry prove that LiZn FHMs are susceptible to amorphization. It is indicated that NaCl aqueous solution（15 wt%） has ultra-fast quenching speed, and the growth rate of crystals on LiZn FHMs is so large that the formation and growth of the crystal nucleus are significantly restrained. This is the main reason for the formation of amorphous LiZn FHMs.展开更多
Fe–Fe2O3–MnO2–sucrose–epoxy resin and O2 as reaction system and feed gas,separately,were used to prepare micro-nano hollow multiphase ceramic microspheres containing MnFe2O4absorbent by self-reactive quenching met...Fe–Fe2O3–MnO2–sucrose–epoxy resin and O2 as reaction system and feed gas,separately,were used to prepare micro-nano hollow multiphase ceramic microspheres containing MnFe2O4absorbent by self-reactive quenching method which is integrated with flame jet,selfpropagating high-temperature synthesis(SHS),and rapidly solidification.The morphologies and phase compositions of hollow microspheres were studied by scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),and energy dispersive spectroscopy.The results show that the quenching products are regular spherical substantially with hollow structure,particle size is between few hundreds nanometers and 5 lm.Phase compositions are diphase of Fe3O4,Mn3O4,and MnFe2O4,and the spinel soft magnetic ferrite MnFe2O4 with microwave magnetic properties is in majority.Collisions with each other,burst as well as‘‘refinement’’of agglomerate powders in flame field may be the main reasons for the formation of micro-nano hollow multiphase ceramic microspheres containing MnFeOabsorbent.展开更多
基金Funded by the National Natural Science Foundation of China(No.51172282)the Hebei Natural Science Foundation of China(E2015506011)
文摘NaCl aqueous solution（15 wt%） was used as the quenching medium to prepare amorphous Lithium-Zinc ferrite hollow microspheres（LiZn FHMs） based on self-reactive quenching technology. Investigations by scanning electro microscope, X-ray diffraction, electron diffraction of transmission electron microscope, and differential scanning calorimetry prove that LiZn FHMs are susceptible to amorphization. It is indicated that NaCl aqueous solution（15 wt%） has ultra-fast quenching speed, and the growth rate of crystals on LiZn FHMs is so large that the formation and growth of the crystal nucleus are significantly restrained. This is the main reason for the formation of amorphous LiZn FHMs.
基金supported by the ational Natural Science Foundation of China (No. 51172282)
文摘Fe–Fe2O3–MnO2–sucrose–epoxy resin and O2 as reaction system and feed gas,separately,were used to prepare micro-nano hollow multiphase ceramic microspheres containing MnFe2O4absorbent by self-reactive quenching method which is integrated with flame jet,selfpropagating high-temperature synthesis(SHS),and rapidly solidification.The morphologies and phase compositions of hollow microspheres were studied by scanning electron microscope(SEM),transmission electron microscope(TEM),X-ray diffraction(XRD),and energy dispersive spectroscopy.The results show that the quenching products are regular spherical substantially with hollow structure,particle size is between few hundreds nanometers and 5 lm.Phase compositions are diphase of Fe3O4,Mn3O4,and MnFe2O4,and the spinel soft magnetic ferrite MnFe2O4 with microwave magnetic properties is in majority.Collisions with each other,burst as well as‘‘refinement’’of agglomerate powders in flame field may be the main reasons for the formation of micro-nano hollow multiphase ceramic microspheres containing MnFeOabsorbent.
基金Natural Science Foundation of Shanxi(201901D111310,201801D221057)Postgraduate Educational reform and research program in Shanxi province(2022YJJG255)Natural Science Foundation of Shanxi Datong University(2022K23).
