ENHANCEMENT OF DAMPING PERFORMANCE OF POLYMERS BY FUNCTIONAL SMALL MOLECULES

The addition effects of organic small molecular substances N,N'-dicyclohexyl-benzothiazyl-2-sulfenamide (DZ) and 3,9-bis{1,1-dimethyl-2[beta-(3-tert-butyl-4-hydroxy-5-methylphenyl)propionyloxy]ethyl}-2,4,8,10-tetraoxaspiro[5,5]-undecane (AO-80) on the dynamic mechanical properties of chlorinated polyethylene (CPE), chlorinated polypropylene (CPP), acrylate rubber (ACM) and their blends were investigated. In the case of compatible systems such as CPE/DZ and ACM/AO-80, the height of the loss tangent (tandelta) peak of a matrix polymer (CPE or ACM) increases, and its peak position shifts to a higher temperature with the addition of DZ or AO-80. By contrast, for incompatible CPE/AO-80, a novel transition appeared above the glass transition temperature of CPE. This additional transition was assigned to dissociation of the intermolecular hydrogen bond between the alpha-hydrogen of CPE and the hydroxyl groups of AO-80 within the AO-80-rich domain. This will provide a new concept for developing damping material. However, the minimum value between two tandelta peaks is lower. It was found that the temperature dependence of tandelta could be improved by adding chlorinated paraffin (CP) or ACM to CPE/AO-80. In addition, another ternary system of ACM/CPP with more AO-80 was found to be a very good self-adhesive damping material because of the appearance of a novel transition due to an interfacial layer of ACM/CPP.

Spatial Planning of the Water Ecosystem with Resilience in the Small Town

The water ecosystem with self-restoration and self-regulation capabilities is the goal pursued by modern urban planning and construction. In this paper, GIS technology was employed to identify local characteristics, and the present topography was used to optimize the landscape ecosystem and establish an ecological water network that coupled the water system with the ecosystem to enhance the ecological resilience of the water ecosystem.

以色列严重退化旱地长期恢复对土壤和植被的影响

Land degradation affects extensive drylands around the world.Due to long-term misuse,the Israeli Sde Zin dryland site has faced severe degradation.The study objective was to assess the feasibility of passive restoration in recovering the site.The study was conducted in four land-units along a preservation-degradation continuum:(1)an area that has not faced anthropogenic disturbances(Ecological land);(2)an area that was proclaimed as a national park in the 1970s(Rehabilitation);(3)an area that was prone,until recently,to moderate anthropogenic pressures(Triangle);and(4)a dirt road that was subjected to long-term off-road traffic(Dirtroad).Soil was sampled and analyzed for its properties.The soil physical quality followed the trend of Ecological land>Rehabilitation>Triangle>Dirtroad.Specifically,high soil salinity in the latter three land-units is attributed to long-term erosional processes that exposed the underlying salic horizons.Herbaceous and shrubby vegetation cover was also monitored.The herbaceous vegetation cover followed the trend of Ecological land(86.4%)>Rehabilitation(40.3%)>Triangle(26.2%)>Dirtroad(2.1%),while the shrubby cover was 2.8%in the Ecological land-unit,and practically zero in the other land-units.It seems that despite the effectiveness of passive restoration in recovering the soil’s physical properties,the recovery of vegetation is limited by the severe soil salinity.