期刊文献+
共找到114,083篇文章
< 1 2 250 >
每页显示 20 50 100
Semi-analytic Solution of Steady Temperature Fields During Thin Plate Welding
1
作者 DAI Yao TAN Wei +1 位作者 SUN Qi SUN Chang-qing 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2006年第B12期248-251,共4页
Usually, it is very difficult to find out an analytical solution to thermal conduction problems during high temperature welding. Therefore, as an important numerical approach, the method of lines (MOLs) is introduce... Usually, it is very difficult to find out an analytical solution to thermal conduction problems during high temperature welding. Therefore, as an important numerical approach, the method of lines (MOLs) is introduced to solve the temperature field characterized by high gradients. The basic idea of the method is to semi-discretize the governing equation of the problem into a system of ordinary differential equations (ODEs) defined on discrete lines by means of the finite difference method, by which the thermal boundary condition with high gradients are directly embodied in formulation. Thus the temperature field can be obtained by solving the ODEs. As a numerical example, the variation of an axisymmetrical temperature field along the plate thickness can be obtained. 展开更多
关键词 steady temperature field method of lines thin plate welding semi-analytic solution high gradient
下载PDF
Semi-analytic solution of Eringen's two-phase local/nonlocal model for Euler-Bernoulli beam with axial force
2
作者 Licheng MENG Dajun ZOU +4 位作者 Huan LAI Zili GUO Xianzhong HE Zhijun XIE Cunfa GAO 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2018年第12期1805-1824,共20页
Eringen’s two-phase local/nonlocal model is applied to an Euler-Bernoulli nanobeam considering the bending-induced axial force, where the contribution of the axial force to bending moment is calculated on the deforme... Eringen’s two-phase local/nonlocal model is applied to an Euler-Bernoulli nanobeam considering the bending-induced axial force, where the contribution of the axial force to bending moment is calculated on the deformed state. Basic equations for the corresponding one-dimensional beam problem are obtained by degenerating from the three-dimensional nonlocal elastic equations. Semi-analytic solutions are then presented for a clamped-clamped beam subject to a concentrated force and a uniformly distributed load, respectively. Except for the traditional essential boundary conditions and those required to be satisfied by transferring an integral equation to its equivalent differential form, additional boundary conditions are needed and should be chosen with great caution, since numerical results reveal that non-unique solutions might exist for a nonlinear problem if inappropriate boundary conditions are used. The validity of the solutions is examined by plotting both sides of the original integro-differential governing equation of deflection and studying the error between both sides. Besides, an increase in the internal characteristic length would cause an increase in the deflection and axial force of the beam. 展开更多
关键词 nonlocal elasticity internal characteristic length size effect nanobeam axial force unique solution
下载PDF
Semi-analytical solution for internal forces of tunnel lining with multiple longitudinal cracks
3
作者 Gan Wang Qian Fang +1 位作者 Jianming Du Jun Wang 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第8期2013-2024,共12页
Longitudinal cracks on the tunnel lining significantly influence the performance of tunnels in operation.In this study,we propose a semi-analytical method that provides a simple and effective way to calculate the inte... Longitudinal cracks on the tunnel lining significantly influence the performance of tunnels in operation.In this study,we propose a semi-analytical method that provides a simple and effective way to calculate the internal forces of tunnel linings with multiple cracks.The semi-analytical solution is obtained using structural analysis considering the flexural rigidity for the cracked longitudinal section of the tunnel lining.Then the proposed solution is verified numerically.Using the proposed method,the influences of the crack depth and the number of cracks on the bending moment and modified crack tip stress are investigated.With the increase in crack depth,the bending moment of lining scetion adjacent to the crack decreases,while the bending moment of lining scetion far away from the crack increases slightly.The more the number of cracks in a tunnel lining,the easier the new cracks initiated. 展开更多
关键词 semi-analytical method Multiple cracks Tunnel lining Structural analysis
下载PDF
Undrained semi-analytical solution for cylindrical cavity expansion in anisotropic soils under biaxial stress conditions
4
作者 Lele Hou Xiaolin Weng +1 位作者 Jibo Hu Rongming Zhou 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第5期1284-1297,共14页
This paper presents an undrained semi-analytical elastoplastic solution for cylindrical cavity expansion in anisotropic soil under the biaxial stress conditions.The advanced simplified SANICLAY model is used to simula... This paper presents an undrained semi-analytical elastoplastic solution for cylindrical cavity expansion in anisotropic soil under the biaxial stress conditions.The advanced simplified SANICLAY model is used to simulate the elastoplastic behavior of soil.The cavity expansion is treated as an initial value problem and solved as a system of eight first-order ordinary differential equations including four stress components and four anisotropic parameters.The results are validated by comparing the new solutions with existing ones.The distributions of stress components and anisotropic parameters around the cavity wall,the expansion process,the stress yield trajectory of a soil element and the shape and size of elastoplastic boundary are further investigated to explore the cavity expansion response of soils under biaxial in situ stresses.The results of extensive parameters analysis demonstrate that the circumferential position of the soil element and the anisotropy of the soils have noticeable impacts on the expansion response under biaxial in situ stresses.Since the present solution not only considers the anisotropy and anisotropy evolution of natural soil,but also eliminates the conventional assumption of uniform radial pressure,the solution is better than other theoretical solutions to explain the pressure test and pile installation effect of shallow saturated soil. 展开更多
关键词 Cylindrical cavity expansion Anisotropic soil Undrained solution Biaxial in situ stresses
下载PDF
GLOBAL SOLUTIONS TO 1D COMPRESSIBLE NAVIER-STOKES/ALLEN-CAHN SYSTEM WITH DENSITY-DEPENDENT VISCOSITY AND FREE-BOUNDARY 被引量:1
5
作者 丁时进 李颖花 王喻 《Acta Mathematica Scientia》 SCIE CSCD 2024年第1期195-214,共20页
This paper is concerned with the Navier-Stokes/Allen-Cahn system,which is used to model the dynamics of immiscible two-phase flows.We consider a 1D free boundary problem and assume that the viscosity coefficient depen... This paper is concerned with the Navier-Stokes/Allen-Cahn system,which is used to model the dynamics of immiscible two-phase flows.We consider a 1D free boundary problem and assume that the viscosity coefficient depends on the density in the form ofη(ρ)=ρ^(α).The existence of unique global H^(2m)-solutions(m∈N)to the free boundary problem is proven for when 0<α<1/4.Furthermore,we obtain the global C^(∞)-solutions if the initial data is smooth. 展开更多
关键词 Navier-Stokes/Allen-Cahn system density-dependent viscosity free boundary global solutions
下载PDF
Localized wave solutions and interactions of the (2+1)-dimensional Hirota-Satsuma-Ito equation
6
作者 巩乾坤 王惠 王云虎 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期409-416,共8页
This paper studies the(2+1)-dimensional Hirota-Satsuma-Ito equation.Based on an associated Hirota bilinear form,lump-type solution,two types of interaction solutions,and breather wave solution of the(2+1)-dimensional ... This paper studies the(2+1)-dimensional Hirota-Satsuma-Ito equation.Based on an associated Hirota bilinear form,lump-type solution,two types of interaction solutions,and breather wave solution of the(2+1)-dimensional Hirota-Satsuma-Ito equation are obtained,which are all related to the seed solution of the equation.It is interesting that the rogue wave is aroused by the interaction between one-lump soliton and a pair of resonance stripe solitons,and the fusion and fission phenomena are also found in the interaction between lump solitons and one-stripe soliton.Furthermore,the breather wave solution is also obtained by reducing the two-soliton solutions.The trajectory and period of the one-order breather wave are analyzed.The corresponding dynamical characteristics are demonstrated by the graphs. 展开更多
关键词 lump solution rogue wave solution breather wave solution (2+1)-dimensional Hirota-Satsuma-Ito equation
下载PDF
THE LIMITING PROFILE OF SOLUTIONS FOR SEMILINEAR ELLIPTIC SYSTEMS WITH A SHRINKING SELF-FOCUSING CORE
7
作者 金可 石影 谢华飞 《Acta Mathematica Scientia》 SCIE CSCD 2024年第2期583-608,共26页
In this paper,we consider the semilinear elliptic equation systems{△u+u=αQ_(n)(x)|u|^(α-2)|v|^(β)u in R^(N),-△v+v=βQ(x)|u|^(α)|v|^(β-2)v in R^(N),where N≥3,α,β>1,α+β<2^(*),2^(*)=2N/N-2 and Q_(n) are... In this paper,we consider the semilinear elliptic equation systems{△u+u=αQ_(n)(x)|u|^(α-2)|v|^(β)u in R^(N),-△v+v=βQ(x)|u|^(α)|v|^(β-2)v in R^(N),where N≥3,α,β>1,α+β<2^(*),2^(*)=2N/N-2 and Q_(n) are bounded given functions whose self-focusing cores{x∈R^(N)|Q_(n)(x)>0} shrink to a set with finitely many points as n→∞.Motivated by the work of Fang and Wang[13],we use variational methods to study the limiting profile of ground state solutions which are concentrated at one point of the set with finitely many points,and we build the localized concentrated bound state solutions for the above equation systems. 展开更多
关键词 Schrödinger system ground states solutions bound state solutions
下载PDF
GLOBAL WEAK SOLUTIONS FOR AN ATTRACTION-REPULSION CHEMOTAXIS SYSTEM WITH p-LAPLACIAN DIFFUSION AND LOGISTIC SOURCE
8
作者 王晓闪 王忠谦 贾哲 《Acta Mathematica Scientia》 SCIE CSCD 2024年第3期909-924,共16页
This paper is concerned with the following attraction-repulsion chemotaxis system with p-Laplacian diffusion and logistic source:■The system here is under a homogenous Neumann boundary condition in a bounded domainΩ... This paper is concerned with the following attraction-repulsion chemotaxis system with p-Laplacian diffusion and logistic source:■The system here is under a homogenous Neumann boundary condition in a bounded domainΩ ■ R^(n)(n≥2),with χ,ξ,α,β,γ,δ,k_(1),k_(2)> 0,p> 2.In addition,the function f is smooth and satisfies that f(s)≤κ-μs~l for all s≥0,with κ ∈ R,μ> 0,l> 1.It is shown that(ⅰ)if l> max{2k_(1),(2k_(1)n)/(2+n)+1/(p-1)},then system possesses a global bounded weak solution and(ⅱ)if k_(2)> max{2k_(1)-1,(2k_(1)n)/(2+n)+(2-p)/(p-1)} with l> 2,then system possesses a global bounded weak solution. 展开更多
关键词 global weak solutions attraction-repulsion P-LAPLACIAN logistic source
下载PDF
Hamiltonian system for the inhomogeneous plane elasticity of dodecagonal quasicrystal plates and its analytical solutions
9
作者 孙志强 侯国林 +1 位作者 乔艳芬 刘金存 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第1期581-590,共10页
A Hamiltonian system is derived for the plane elasticity problem of two-dimensional dodecagonal quasicrystals by introducing the simple state function. By using symplectic elasticity approach, the analytic solutions o... A Hamiltonian system is derived for the plane elasticity problem of two-dimensional dodecagonal quasicrystals by introducing the simple state function. By using symplectic elasticity approach, the analytic solutions of the phonon and phason displacements are obtained further for the quasicrystal plates. In addition, the effectiveness of the approach is verified by comparison with the data of the finite integral transformation method. 展开更多
关键词 Hamiltonian system symplectic elasticity QUASICRYSTALS analytic solution state function
下载PDF
On entire solutions of some Fermat type differential-difference equations
10
作者 LONG Jian-ren QIN Da-zhuan 《Applied Mathematics(A Journal of Chinese Universities)》 SCIE CSCD 2024年第1期69-88,共20页
On one hand,we study the existence of transcendental entire solutions with finite order of the Fermat type difference equations.On the other hand,we also investigate the existence and growth of solutions of nonlinear ... On one hand,we study the existence of transcendental entire solutions with finite order of the Fermat type difference equations.On the other hand,we also investigate the existence and growth of solutions of nonlinear differential-difference equations.These results extend and improve some previous in[5,14]. 展开更多
关键词 entire solutions differential-difference equations EXISTENCE finite order
下载PDF
Multi-soliton solutions, breather-like and bound-state solitons for complex modified Korteweg–de Vries equation in optical fibers
11
作者 兰中周 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期119-123,共5页
Under investigation in this paper is a complex modified Korteweg–de Vries(KdV) equation, which describes the propagation of short pulses in optical fibers. Bilinear forms and multi-soliton solutions are obtained thro... Under investigation in this paper is a complex modified Korteweg–de Vries(KdV) equation, which describes the propagation of short pulses in optical fibers. Bilinear forms and multi-soliton solutions are obtained through the Hirota method and symbolic computation. Breather-like and bound-state solitons are constructed in which the signs of the imaginary parts of the complex wave numbers and the initial separations of the two parallel solitons are important factors for the interaction patterns. The periodic structures and position-induced phase shift of some solutions are introduced. 展开更多
关键词 complex modified KdV equation multi-soliton solutions breather-like BOUND-STATE
下载PDF
Bifurcation Analysis Reveals Solution Structures of Phase Field Models
12
作者 Xinyue Evelyn Zhao Long-Qing Chen +1 位作者 Wenrui Hao Yanxiang Zhao 《Communications on Applied Mathematics and Computation》 EI 2024年第1期64-89,共26页
The phase field method is playing an increasingly important role in understanding and predicting morphological evolution in materials and biological systems.Here,we develop a new analytical approach based on the bifur... The phase field method is playing an increasingly important role in understanding and predicting morphological evolution in materials and biological systems.Here,we develop a new analytical approach based on the bifurcation analysis to explore the mathematical solution structure of phase field models.Revealing such solution structures not only is of great mathematical interest but also may provide guidance to experimentally or computationally uncover new morphological evolution phenomena in materials undergoing electronic and structural phase transitions.To elucidate the idea,we apply this analytical approach to three representative phase field equations:the Allen-Cahn equation,the Cahn-Hilliard equation,and the Allen-Cahn-Ohta-Kawasaki system.The solution structures of these three phase field equations are also verified numerically by the homotopy continuation method. 展开更多
关键词 Phase field modeling BIFURCATIONS Multiple solutions
下载PDF
THE GLOBAL EXISTENCE OF STRONG SOLUTIONS TO THERMOMECHANICAL CUCKER-SMALE-STOKES EQUATIONS IN THE WHOLE DOMAIN
13
作者 邹委员 《Acta Mathematica Scientia》 SCIE CSCD 2024年第3期887-908,共22页
We study the global existence and uniqueness of a strong solution to the kinetic thermomechanical Cucker-Smale(for short,TCS) model coupled with Stokes equations in the whole space.The coupled system consists of the k... We study the global existence and uniqueness of a strong solution to the kinetic thermomechanical Cucker-Smale(for short,TCS) model coupled with Stokes equations in the whole space.The coupled system consists of the kinetic TCS equation for a particle ensemble and the Stokes equations for a fluid via a drag force.In this paper,we present a complete analysis of the existence of global-in-time strong solutions to the coupled model without any smallness restrictions on the initial data. 展开更多
关键词 thermomechanical Cucker-Smale model Stokes equations strong solutions global existence
下载PDF
Dialectical Thermodynamics’Solution to the Conceptual Imbroglio That Is the Reversible Path
14
作者 José C. Íñiguez 《Journal of High Energy Physics, Gravitation and Cosmology》 CAS 2024年第2期775-799,共25页
According to the second law of thermodynamics, as currently understood, any given transit of a system along the reversible path proceeds with a total entropy change equal to zero. The fact that this condition is also ... According to the second law of thermodynamics, as currently understood, any given transit of a system along the reversible path proceeds with a total entropy change equal to zero. The fact that this condition is also the identifier of thermodynamic equilibrium, makes each and every point along the reversible path a state of equilibrium, and the reversible path, as expressed by a noted thermodynamic author, “a dense succession of equilibrium states”. The difficulties with these notions are plural. The fact, for example, that systems need to be forced out of equilibrium via the expenditure of work, would make any spontaneous reversible process a consumer of work, this in opposition to common thermodynamic wisdom that makes spontaneous reversible processes the most efficient transformers of work-producing-potential into actual work. The solution to this and other related impasses is provided by Dialectical Thermodynamics via its previously proved notion assigning a negative entropy change to the energy upgrading process represented by the transformation of heat into work. The said solution is here exemplified with the ideal-gas phase isomerization of butane into isobutane. 展开更多
关键词 Thermodynamic Reversibility solution to Inconsistencies Dialectical Thermodynamics
下载PDF
Efficacy of ginseng-based Renshenguben oral solution for cancer-related fatigue among patients with advanced-stage hepatocellular carcinoma:A prospective multicenter cohort study
15
作者 Ming-Da Wang Chen Yuan +5 位作者 Ke-Chun Wang Nan-Ya Wang Ying-Jian Liang Hong Zhu Xiang-Min Tong Tian Yang 《Hepatobiliary & Pancreatic Diseases International》 SCIE CAS CSCD 2024年第3期249-256,共8页
Background:Cancer-related fatigue(CRF)is a common and debilitating symptom experienced by patients with advanced-stage cancer,especially those undergoing antitumor therapy.This study aimed to evaluate the efficacy and... Background:Cancer-related fatigue(CRF)is a common and debilitating symptom experienced by patients with advanced-stage cancer,especially those undergoing antitumor therapy.This study aimed to evaluate the efficacy and safety of Renshenguben(RSGB)oral solution,a ginseng-based traditional Chinese medicine,in alleviating CRF in patients with advanced hepatocellular carcinoma(HCC)receiving antitumor treatment.Methods:In this prospective,open-label,controlled,multicenter study,patients with advanced HCC at BCLC stage C and a brief fatigue inventory(BFI)score of≥4 were enrolled.Participants were assigned to the RSGB group(RSGB,10 mL twice daily)or the control group(with supportive care).Primary and secondary endpoints were the change in multidimensional fatigue inventory(MFI)score,and BFI and functional assessment of cancer therapy-hepatobiliary(FACT-Hep)scores at weeks 4 and 8 after enrollment.Adverse events(AEs)and toxicities were assessed.Results:A total of 409 participants were enrolled,with 206 assigned to the RSGB group.At week 4,there was a trend towards improvement,but the differences were not statistically significant.At week 8,the RSGB group exhibited a significantly lower MFI score(P<0.05)compared to the control group,indicating improved fatigue levels.Additionally,the RSGB group showed significantly greater decrease in BFI and FACT-Hep scores at week 8(P<0.05).Subgroup analyses among patients receiving various antitumor treatments showed similar results.Multivariate linear regression analyses revealed that the RSGB group experienced a significantly substantial decrease in MFI,BFI,and FACT-Hep scores at week 8.No serious drug-related AEs or toxicities were observed.Conclusions:RSGB oral solution effectively reduced CRF in patients with advanced HCC undergoing antitumor therapy over an eight-week period,with no discernible toxicities.These findings support the potential of RSGB oral solution as an adjunctive treatment for managing CRF in this patient population. 展开更多
关键词 Cancer-related fatigue Hepatocellular carcinoma Renshenguben oral solution EFFICACY Safety GINSENG
下载PDF
Design of low-alloying and high-performance solid solution-strengthened copper alloys with element substitution for sustainable development
16
作者 Jiaqiang Li Hongtao Zhang +2 位作者 Jingtai Sun Huadong Fu Jianxin Xie 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第5期826-832,共7页
Solid solution-strengthened copper alloys have the advantages of a simple composition and manufacturing process,high mechanical and electrical comprehensive performances,and low cost;thus,they are widely used in high-... Solid solution-strengthened copper alloys have the advantages of a simple composition and manufacturing process,high mechanical and electrical comprehensive performances,and low cost;thus,they are widely used in high-speed rail contact wires,electronic component connectors,and other devices.Overcoming the contradiction between low alloying and high performance is an important challenge in the development of solid solution-strengthened copper alloys.Taking the typical solid solution-strengthened alloy Cu-4Zn-1Sn as the research object,we proposed using the element In to replace Zn and Sn to achieve low alloying in this work.Two new alloys,Cu-1.5Zn-1Sn-0.4In and Cu-1.5Zn-0.9Sn-0.6In,were designed and prepared.The total weight percentage content of alloying elements decreased by 43%and 41%,respectively,while the product of ultimate tensile strength(UTS)and electrical conductivity(EC)of the annealed state increased by 14%and 15%.After cold rolling with a 90%reduction,the UTS of the two new alloys reached 576 and 627MPa,respectively,the EC was 44.9%IACS and 42.0%IACS,and the product of UTS and EC(UTS×EC)was 97%and 99%higher than that of the annealed state alloy.The dislocations proliferated greatly in cold-rolled alloys,and the strengthening effects of dislocations reached 332 and 356 MPa,respectively,which is the main reason for the considerable improvement in mechanical properties. 展开更多
关键词 element substitution copper alloy solid solution strengthening microstructure and performance
下载PDF
ENERGY CONSERVATION FOR THE WEAK SOLUTIONS TO THE 3D COMPRESSIBLE NEMATIC LIQUID CRYSTAL FLOW
17
作者 谭忠 李心亮 杨惠 《Acta Mathematica Scientia》 SCIE CSCD 2024年第3期851-864,共14页
In this paper,we establish some regularity conditions on the density and velocity fields to guarantee the energy conservation of the weak solutions for the three-dimensional compressible nematic liquid crystal flow in... In this paper,we establish some regularity conditions on the density and velocity fields to guarantee the energy conservation of the weak solutions for the three-dimensional compressible nematic liquid crystal flow in the periodic domain. 展开更多
关键词 compressible nematic liquid crystal flow weak solutions energy conservation
下载PDF
Analytical solutions to the precession relaxation of magnetization with uniaxial anisotropy
18
作者 张泽南 贾镇林 薛德胜 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第4期656-660,共5页
Based on the Landau-Lifshitz-Gilbert(LLG)equation,the precession relaxation of magnetization is studied when the external field H is parallel to the uniaxial anisotropic field H_(k).The evolution of three-component ma... Based on the Landau-Lifshitz-Gilbert(LLG)equation,the precession relaxation of magnetization is studied when the external field H is parallel to the uniaxial anisotropic field H_(k).The evolution of three-component magnetization is solved analytically under the condition of H=nH_(k)(n=3,1 and 0).It is found that with an increase of H or a decrease of the initial polar angle of magnetization,the relaxation time decreases and the angular frequency of magnetization increases.For comparison,the analytical solution for H_(k)=0 is also given.When the magnetization becomes stable,the angular frequency is proportional to the total effective field acting on the magnetization.The analytical solutions are not only conducive to the understanding of the precession relaxation of magnetization,but also can be used as a standard model to test the numerical calculation of LLG equation. 展开更多
关键词 precession relaxation Landau-Lifshitz-Gilbert(LLG)equation uniaxial anisotropy analytical solutions
下载PDF
GLOBAL CLASSICAL SOLUTIONS OF SEMILINEAR WAVE EQUATIONS ON R^(3)×T WITH CUBIC NONLINEARITIES
19
作者 陶飞 《Acta Mathematica Scientia》 SCIE CSCD 2024年第1期115-128,共14页
In this paper,we establish global classical solutions of semilinear wave equations with small compact supported initial data posed on the product space R^(3)×T.The semilinear nonlinearity is assumed to be of the ... In this paper,we establish global classical solutions of semilinear wave equations with small compact supported initial data posed on the product space R^(3)×T.The semilinear nonlinearity is assumed to be of the cubic form.The main ingredient here is the establishment of the L^(2)-L^(∞)decay estimates and the energy estimates for the linear problem,which are adapted to the wave equation on the product space.The proof is based on the Fourier mode decomposition of the solution with respect to the periodic direction,the scaling technique,and the combination of the decay estimates and the energy estimates. 展开更多
关键词 semilinear wave equation product space decay estimate energy estimate global solution
下载PDF
Improvement effect of reversible solid solutions Mg_(2)Ni(Cu)/Mg_(2)Ni(Cu)H_(4)on hydrogen storage performance of MgH_(2)
20
作者 Yingyan Zhao Zhibing Liu +5 位作者 Jiangchuan Liu Yunfeng Zhu Jiguang Zhang Yana Liu Xiaohui Hu Liquan Li 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第1期197-208,共12页
The hydrogen absorption/desorption kinetic properties of MgH_(2)can be effectively enhanced by doping specific catalysts.In this work,MOFs-derived NiCu@C nanoparticles(~15 nm)with regular core-shell structure were suc... The hydrogen absorption/desorption kinetic properties of MgH_(2)can be effectively enhanced by doping specific catalysts.In this work,MOFs-derived NiCu@C nanoparticles(~15 nm)with regular core-shell structure were successfully prepared and introduced into MgH_(2)(denoted as MgH_(2)-NiCu@C).The onset and peak temperatures of hydrogen desorption of MgH_(2)-11 wt.%NiCu@C are 175.0℃and282.2℃,respectively.The apparent activation energy of dehydrogenated reaction is 77.2±4.5 kJ/mol for MgH_(2)-11 wt.%NiCu@C,which is lower than half of that of the as-milled MgH_(2).Moreover,MgH_(2)-11 wt.%NiCu@C displays great cyclic stability.The strengthening"hydrogen pumping"effect of reversible solid solutions Mg_(2)Ni(Cu)/Mg_(2)Ni(Cu)H_(4)is proposed to explain the remarkable improvement in hydrogen absorption/desorption kinetic properties of MgH_(2).This work offers a novel perspective for the design of bimetallic nanoparticles and beyond for application in hydrogen storage and other energy related fields. 展开更多
关键词 Magnesium hydride Reversible solid solution Core-shell nanoparticles Hydrogen storage performance
下载PDF
上一页 1 2 250 下一页 到第
使用帮助 返回顶部