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A new method of calculating crown projection area and its comparative accuracy with conventional calculations for asymmetric tree crowns
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作者 Mingrui Zhang Huiquan Bi +1 位作者 Xingji Jin Michael McLean 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第4期171-188,共18页
This paper introduces a new method of calculating crown projection area(CPA),the area of level ground covered by a vertical projection of a tree crown from measured crown radii through numerical interpolation and inte... This paper introduces a new method of calculating crown projection area(CPA),the area of level ground covered by a vertical projection of a tree crown from measured crown radii through numerical interpolation and integration.This novel method and other four existing methods of calculating CPA were compared using detailed crown radius measurements from 30 tall trees of Eucalyptus pilularis variable in crown size,shape,and asymmetry.The four existing methods included the polygonal approach and three ways of calculating CPA as the area of a circle using the arithmetic,geometric and quadratic mean radius.Comparisons were made across a sequence of eight non-consecutive numbers(from 2 to 16)of measured crown radii for each tree over the range of crown asymmetry of the 30 trees through generalized linear models and multiple comparisons of means.The sequence covered the range of the number of crown radii measured for calculating the CPA of a tree in the literature.A crown asymmetry index within the unit interval was calculated for each tree to serve as a normative measure.With a slight overestimation of 2.2%on average and an overall mean error size of 7.9%across the numbers of crown radii that were compared,our new method was the least biased and most accurate.Calculating CPA as a circle using the quadratic mean crown radius was the second best,which had an average overestimation of 4.5%and overall mean error size of 8.8%.These two methods remained by and large unbiased as crown asymmetry increased,while the other three methods showed larger bias of underestimation.For the conventional method of using the arithmetic mean crown radius to calculate CPA as a circle,bias correction factors were developed as a function of crown asymmetry index to delineate the increasing magnitude of bias associated with greater degrees of crown asymmetry.This study reveals and demonstrates such relationships between the accuracy of CPA calculations and crown asymmetry and will help increase awareness among researchers and practitioners on the existence of bias in their CPA calculations and for the need to use an unbiased method in the future.Our new method is recommended for calculating CPA where at least four crown radius measurements per tree are available because that is the minimum number required for its use. 展开更多
关键词 crown radius measurements Interpolated crown contour Projected crown area Multiple comparisons of means
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Interfacial engineering through lead binding using crown ethers in perovskite solar cells
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作者 Sun-Ju Kim YeonJu Kim +8 位作者 Ramesh Kumar Chitumalla Gayoung Ham Thanh-Danh Nguyen Joonkyung Jang Hyojung Cha Jovana Milić Jun-Ho Yum Kevin Sivula Ji-Youn Seo 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期263-270,共8页
In the domain of perovskite solar cells(PSCs),the imperative to reconcile impressive photovoltaic performance with lead-related issue and environmental stability has driven innovative solutions.This study pioneers an ... In the domain of perovskite solar cells(PSCs),the imperative to reconcile impressive photovoltaic performance with lead-related issue and environmental stability has driven innovative solutions.This study pioneers an approach that not only rectifies lead leakage but also places paramount importance on the attainment of rigorous interfacial passivation.Crown ethers,notably benzo-18-crown-6-ether(B18C6),were strategically integrated at the perovskite-hole transport material interface.Crown ethers exhibit a dual role:efficiently sequestering and immobilizing Pb^(2+)ions through host-guest complexation and simultaneously establishing a robust interfacial passivation layer.Selected crown ether candidates,guided by density functional theory(DFT)calculations,demonstrated proficiency in binding Pb2+ions and optimizing interfacial energetics.Photovoltaic devices incorporating these materials achieved exceptional power conversion efficiency(PCE),notably 21.7%for B18C6,underscoring their efficacy in lead binding and interfacial passivation.Analytical techniques,including time-of-flight secondary ion mass spectrometry(ToF-SIMS),ultraviolet photoelectron spectroscopy(UPS),time-resolved photoluminescence(TRPL),and transient absorption spectroscopy(TAS),unequivocally affirmed Pb^(2+)ion capture and suppression of non-radiative recombination.Notably,these PSCs maintained efficiency even after enduring 300 h of exposure to 85%relative humidity.This research underscores the transformative potential of crown ethers,simultaneously addressing lead binding and stringent interfacial passivation for sustainable PSCs poised to commercialize and advance renewable energy applications. 展开更多
关键词 Perovskite solar cells Interfacial passivation crown ether materials Stability
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Developing nonlinear additive tree crown width models based on decomposed competition index and tree variables 被引量:1
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作者 Siyu Qiu Peiwen Gao +4 位作者 Lei Pan Lai Zhou Ruiting Liang Yujun Sun Yifu Wang 《Journal of Forestry Research》 SCIE CAS CSCD 2023年第5期1407-1422,共16页
Crown development is closely related to the biomass and growth rate of the tree and its width(CW)is an important covariable in growth and yield models and in forest management.To date,various CW models have been propo... Crown development is closely related to the biomass and growth rate of the tree and its width(CW)is an important covariable in growth and yield models and in forest management.To date,various CW models have been proposed.However,limited studies have explicitly focused on additive and inherent correlation of crown components and total CW as well as the influence of competition on crown radius from the corresponding direction.In this study,two model systems were used,i.e.,aggregation method system(AMS)and disaggregation method system(DMS),to develop crown width additive model systems.For calculating spatially explicit competition index(CI),four neighbor tree selection methods were evaluated.CI was decomposed into four cardinal directions and added into the model systems.Results show that the power model form was more proper for our data to fit CW growth.For each crown radius and total CW,height to the diameter at breast height(HDR)and basal area of trees larger than the subject tree(BAL)significantly contributed to the increase of prediction accuracy.The 3-m fixed radius was optimal among the four neighborhoods selection ways.After adding decomposed competition Hegyi index into model systems AMS and DMS,the prediction accuracy improved.Of the model systems evaluated,AMS based on decomposed CI provided the best performance as well as the inherent correlation and additivity properties.Our study highlighted the importance of decomposed CI in tree CW modelling for additive model systems.This study focused on methodology and could be applied to other species or stands. 展开更多
关键词 Competition decomposition ADDITIVITY crown width Spatially explicit Competitor selection
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Prediction of tree crown width in natural mixed forests using deep learning algorithm
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作者 Yangping Qin Biyun Wu +1 位作者 Xiangdong Lei Linyan Feng 《Forest Ecosystems》 SCIE CSCD 2023年第3期287-297,共11页
Crown width(CW)is one of the most important tree metrics,but obtaining CW data is laborious and timeconsuming,particularly in natural forests.The Deep Learning(DL)algorithm has been proposed as an alternative to tradi... Crown width(CW)is one of the most important tree metrics,but obtaining CW data is laborious and timeconsuming,particularly in natural forests.The Deep Learning(DL)algorithm has been proposed as an alternative to traditional regression,but its performance in predicting CW in natural mixed forests is unclear.The aims of this study were to develop DL models for predicting tree CW of natural spruce-fir-broadleaf mixed forests in northeastern China,to analyse the contribution of tree size,tree species,site quality,stand structure,and competition to tree CW prediction,and to compare DL models with nonlinear mixed effects(NLME)models for their reliability.An amount of total 10,086 individual trees in 192 subplots were employed in this study.The results indicated that all deep neural network(DNN)models were free of overfitting and statistically stable within 10-fold cross-validation,and the best DNN model could explain 69%of the CW variation with no significant heteroskedasticity.In addition to diameter at breast height,stand structure,tree species,and competition showed significant effects on CW.The NLME model(R^(2)=0.63)outperformed the DNN model(R^(2)=0.54)in predicting CW when the six input variables were consistent,but the results were the opposite when the DNN model(R^(2)=0.69)included all 22 input variables.These results demonstrated the great potential of DL in tree CW prediction. 展开更多
关键词 Mixed forests Deep neural networks crown width Stand structure COMPETITION
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Replacement of Unesthetic Posterior Metal Crowns with Monolithic Zirconia Crowns: A Case Report
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作者 Mitsunori Uno Hajime Ishigami 《Open Journal of Stomatology》 2023年第10期334-341,共8页
Advances in metal-free materials and the popularization of Computer-Aided Design and Manufacturing (CAD/CAM) have led to the wide clinical use of all-ceramic crowns for esthetic restorations. A 72-year-old woman prese... Advances in metal-free materials and the popularization of Computer-Aided Design and Manufacturing (CAD/CAM) have led to the wide clinical use of all-ceramic crowns for esthetic restorations. A 72-year-old woman presented to our hospital with unesthetic restorations on the right upper and lower posterior teeth. Intraoral examination revealed poorly fitting metal crown margins. Defective prostheses were removed, and provisional restorations were provided to stabilize the mandibular position. Optical impressions and the maxillomandibular relationship were recorded using an intraoral scanner, and monolithic zirconia crowns were fabricated using CAD/CAM technology for complete veneer crown restorative treatment. Occlusal examination revealed an improvement in occlusal force distribution at initial examination (right side: 33.5%, left side: 66.5%) after placement of the zirconia crowns (right side: 54.9%, left side: 45.1%). Occlusal force and occlusal force distribution area also showed an increasing trend. The Oral Health Impact Profile short form (OHIP-14) score decreased from 7 points at initial examination to 0 points after prosthodontic treatment. Appropriate diagnosis and treatment planning contributed to the increased occlusal force and balanced occlusal force distribution. Therefore, the present case indicates the potential of monolithic zirconia crowns to achieve both esthetic and stable functional outcomes. 展开更多
关键词 Monolithic Zirconia crown Intraoral Scanner Computer-Aided Design and Manufacturing
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Changes in concentrations and transcripts of plant hormones in wheat seedling roots in response to Fusarium crown rot
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作者 Yutian Gao Xuejun Tian +10 位作者 Weidong Wang Xiangru Xu Yuqing Su Jiatian Yang Shuonan Duan Jinlong Li Mingming Xin Huiru Peng Qixin Sun Chaojie Xie Jun Ma 《The Crop Journal》 SCIE CSCD 2023年第5期1441-1450,共10页
Fusarium crown rot(FCR) is a soilborne disease causing severe yield losses in many wheat-growing areas of the world. Diseased plants show browning and necrosis of roots and stems causing white heads at maturity. Littl... Fusarium crown rot(FCR) is a soilborne disease causing severe yield losses in many wheat-growing areas of the world. Diseased plants show browning and necrosis of roots and stems causing white heads at maturity. Little is known about the molecular processes employed by wheat roots to respond to the disease. We characterized morphological, transcriptional and hormonal changes in wheat seedling roots following challenge with Fusarium pseudograminearum(Fp), the main pathogen of FCR. The pathogen inhibited root development to various extents depending on plants' resistance level. Many genes responsive to FCR infection in wheat roots were enriched in plant hormone pathways. The contents of compounds involved in biosynthesis and metabolism of jasmonic acid, salicylic acid, cytokinin and auxin were drastically changed in roots at five days post-inoculation. Presoaking seeds in methyl jasmonate for 24 h promoted FCR resistance, whereas presoaking with cytokinin 6-benzylaminopurine made plants more susceptible. Overexpression of TaOPR3, a gene involved in jasmonic acid biosynthesis, enhanced plant resistance as well as root and shoot growth during infection. 展开更多
关键词 Fusarium crown rot(FCR) Wheat HORMONE ROOT TaOPR3
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Assessment of Cork Oak Decline Using Digital Multispectral Imagery in Relation with in Situ Crown Condition
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作者 Soumia El Ahmadi Hassan Ramzi +2 位作者 Abderrahman Aafi Nejm Eddine Jmii Taoufik Aadel 《Open Journal of Forestry》 2023年第1期145-160,共16页
Cork oak in Maamora forest is experiencing the dieback phenomenon. The evaluation of the latter in this forest has gained the importance over time and with the solicitation of managers to objectify its phytosanitary s... Cork oak in Maamora forest is experiencing the dieback phenomenon. The evaluation of the latter in this forest has gained the importance over time and with the solicitation of managers to objectify its phytosanitary situation. Aiming at prioritizing management actions, remote sensing seems to be an effective tool to inquire about stands’ health conditions and their evolution. To this end, this study aims at mapping and validating health status of cork oak stands in Maamora. Sentinel 2 images in 2015 and 2020 were processed to calculate the differential normalized difference water index (NDWI), revealing vegetation moisture variation caused by drought. A statistical method based on thresholds was used to map cork oak dieback stands, those with no changes and those recovered. Results have shown that 54.63% of cork oak in Maamora forest have not changed in terms of phytosanitary situation between 2015 and 2020, 31.10% of oak stands are afflicted by a slight decline and 12.97% by a severe decline. Areas with slight or strong recovery remain minimal and represent 1.04% and 0.25% respectively. Ground data indicated that the map generated displayed a good distinction between stands severely and slightly declined with a global accuracy of 66.66%. Therefore, further research elaborating an advanced vegetation index reflecting the various factors of dieback would be of much importance. 展开更多
关键词 DIEBACK Cork Oak Forest Mâamora Satellite Images crown Condition
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Li^(+)-ion bound crown ether functionalization enables dual promotion of dynamics and thermodynamics for ambient ammonia synthesis
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作者 Qiyang Cheng Sisi Liu +8 位作者 Mengfan Wang Lifang Zhang Yanzheng He Jiajie Ni Jingru Zhang Chengwei Deng Yi Sun Tao Qian Chenglin Yan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第10期191-197,I0007,共8页
Electrosynthesis of ammonia from the reduction of nitrogen is still confronted with the limited supply of gas reactant in dynamics as well as high activation barrier in thermodynamics.Unfortunately,despite tremendous ... Electrosynthesis of ammonia from the reduction of nitrogen is still confronted with the limited supply of gas reactant in dynamics as well as high activation barrier in thermodynamics.Unfortunately,despite tremendous efforts devoted to electrocatalysts themselves,they still fail to tackle the above two challenges simultaneously.Herein,we employ a heterogeneous catalyst adlayer-composed of crown ethers associated with Li^(+)ions-to achieve the dual promotion of dynamics and thermodynamics for ambient ammonia synthesis.Dynamically,the bound Li^(+)ions interact with the strong quadrupole moment of nitrogen,and trigger considerable reactant flux toward the catalyst.Thermodynamically,Li^(+)associated with the oxygen of crown ether achieves a higher density of states at the Fermi level for the catalyst,enabling effortless electron transfer from the catalysts to nitrogen and thus greatly reducing the activation barrier.As expected,the proof-of-concept system achieves an ammonia yield rate of 168.5μg h^(-1)mg^(-1)and a Faradaic efficiency of 75.3%at-0.3 V vs.RHE.This system-level approach opens up pathways for tackling the two key challenges that have limited the field of ammonia synthesis. 展开更多
关键词 Li^(+)-ion bound crown ether DYNAMICS Thermodynamics Nitrogen reduction Ammonia synthesis
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Wave Force on the Crown Wall of Rubble Mound Breakwaters at Intermediate Depths
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作者 HAN Xinyu DONG Sheng 《Journal of Ocean University of China》 SCIE CAS CSCD 2023年第1期53-64,共12页
Rubble mound breakwaters with a crown wall are a common coastal engineering structure.The wave force on crown walls is an important parameter for the practice engineering design.Particularly,the wave force on crown wa... Rubble mound breakwaters with a crown wall are a common coastal engineering structure.The wave force on crown walls is an important parameter for the practice engineering design.Particularly,the wave force on crown walls under intermediate depths has been studied through physical model tests and numerical simulations.In this study,a three-dimensional numerical wave flume was developed to investigate monochromatic wave interactions in a rubble mound breakwater with a crown wall.Armor blocks were modeled in detail.The Navier-Stokes equations for two-phase incompressible flows,combined with shear stress transport k-ωturbulence model and volume of fluid method for tracking the free surface,were solved.A set of laboratory experiments were performed to validate the adopted model.Subsequently,a series of numerical simulations were implemented to examine the impacts of different hydrodynamic parameters(including wave height,incident wave period,and water depth)and the berm width on the wave force of the crown wall.Finally,a comparison of the experimental results and Martin method shows that the latter method is not suitable for this experimental scope.New empirical formulas are proposed to predict the wave force on crown walls under intermediate depth.The results can provide a basis for the design of crown wall of rubble mound breakwaters at intermediate depths. 展开更多
关键词 wave force crown wall rubble mound breakwater intermediate depth experimental test numerical simulation
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Third-Order Nonlinear Optical Responses of Bis(15-crown-5)-stilbenes Binding to One-or Two-Alkali Metal Cation(Li^(+),Na^(+)and K^(+))
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作者 Hai-Ling Yu Tong Zhang +2 位作者 Tian-Liang Ma Bo Hong Zhi-Qiang Cheng 《Chinese Journal of Chemical Physics》 SCIE EI CAS CSCD 2023年第5期601-612,I0002,共13页
Bis(15-crown-5)-stilbenes containing crown ether parts have been widely used in a variety of chemical applications,such as cation detectors,because of their ability to selectively bind to alkali metal cations,Bis(15-c... Bis(15-crown-5)-stilbenes containing crown ether parts have been widely used in a variety of chemical applications,such as cation detectors,because of their ability to selectively bind to alkali metal cations,Bis(15-crown-5)-stilbenes and its derivatives with complexation of one-or two-alkali metal cation(Li^(+),Na^(+)and K^(+))have been theoretically investigat-ed by quantum chemistry methods.The coordination of alkali cations results in partial shrinkage of crown ethers,which directly affected natural distribution analysis charges and molecular orbital energy levels.The number of alkali metal ions has significant effects on absorption spectra and mean second hyperpolarizability.When one alkali metal ion was added to the anticonformer of bis(15-crown-5)-stilbene,the absorption spectra were obvious-ly redshifted and the mean second hyperpolarizability values were slightly increased;while two alkali metal ions were added to bis(15-crown-5)-stilbene,the absorption spectra were ob-viously blue shifted and the mean second hyperpolarizability values decreased.On the other hand,as the radius of the alkali ions increased,the mean second hyperpolarizability values of the compounds increased gradually.It is indicated that the mean second hyperpolarizability value is sensitive to the number and radius of the alkali metal cations,thus the third order nonlinear optical response can be used as a signal to detect the number and type of alkali met-al ions. 展开更多
关键词 Bis(crown)-stilbene Cation detector Metal cation Quantum chemistry Sec-ond hyperpolarizability
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生物活性陶瓷iRoot BP Plus^(■)在儿童年轻恒前牙复杂冠折牙髓切断术中的应用 被引量:1
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作者 郑佳佳 杨雪 +3 位作者 温泉 付元 邵校 丁美丽 《北京大学学报(医学版)》 CAS CSCD 北大核心 2024年第1期179-184,共6页
目的:观察生物活性陶瓷材料iRoot BP Plus^(■)(Innovative BioCeramix Inc,Vancouver,BC,Canada)在儿童年轻恒前牙复杂冠折牙髓切断术中的应用,并对其预后进行分析,为该术式的更广泛应用提供临床参考。方法:收集2017年3月至2022年9月... 目的:观察生物活性陶瓷材料iRoot BP Plus^(■)(Innovative BioCeramix Inc,Vancouver,BC,Canada)在儿童年轻恒前牙复杂冠折牙髓切断术中的应用,并对其预后进行分析,为该术式的更广泛应用提供临床参考。方法:收集2017年3月至2022年9月因恒前牙复杂冠折就诊于北京大学口腔医院急诊科,行以生物活性陶瓷iRoot BP Plus^(■)为盖髓剂的牙髓切断术患者。根据患者术前根尖片和初诊病历显示为年轻恒牙者,纳入97颗年轻恒牙进行研究。收集患者初诊及复查时的临床及影像学检查资料,临床检查包括根尖孔形成情况、松动度、牙冠颜色、牙髓活力测试(冷测)、有无脓肿和瘘管,影像学检查包括根周膜连续性、根尖周低密度影像、复诊时盖髓剂下方牙本质桥形成情况、髓腔及根管钙化情况,并对上述结果进行分析。结果:最终纳入有复诊记录的64例患者共75颗患牙,其中男性37例(57.8%),女性27例(42.2%),就诊时平均年龄为9.1岁,平均随访时长19.3个月。采用iRoot BP Plus^(■)盖髓的牙髓切断术后6个月成功率为96.0%,术后1年成功率为94.7%。术后复查2年以上者共23例,累计失败6例。成功率在患牙就诊时距外伤的时间是否超过24 h组中(P=0.61)以及是否松动组中(P=0.28)的差异无统计学意义。结论:对无移位性损伤的年轻恒牙复杂冠折患牙,采用iRoot BP Plus^(■)盖髓的牙髓切断术1年成功率很高,该术式具备广泛推广价值。 展开更多
关键词 牙髓切断术 复杂冠折 年轻恒牙 生物活性陶瓷
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回鹘戴三叉冠人物身份再考 被引量:1
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作者 吕钊 马艳辉 《西北大学学报(哲学社会科学版)》 北大核心 2024年第1期23-34,共12页
回鹘三叉冠造型独特,是研究回鹘文化的重要历史遗存,关于其佩戴者身份众说纷纭,主要包括回鹘王、回鹘王子、元帅及乐师等。然而,这些解读往往缺乏系统性的论证与深入分析。本研究在现有观点的基础上,首先对回鹘三叉冠佩戴者的身份进行... 回鹘三叉冠造型独特,是研究回鹘文化的重要历史遗存,关于其佩戴者身份众说纷纭,主要包括回鹘王、回鹘王子、元帅及乐师等。然而,这些解读往往缺乏系统性的论证与深入分析。本研究在现有观点的基础上,首先对回鹘三叉冠佩戴者的身份进行了细致的梳理与分类,通过比对图像资料与文献资料,将三叉冠的形制及其象征的身份进行了归类,指出其身份象征随时间的演变而发生变化。并采用物质文化史的研究方法,探究了三叉冠在回鹘文化中身份象征演变的深层原因。研究发现:回鹘在西迁前,受到萨满教及阿尔泰系部落生活方式的影响,三叉冠主要象征回鹘王或部落首领。西迁后,随着生活方式的转变和佛教的兴盛,三叉冠的身份象征逐渐世俗化,扩展到王子、贵族以及高级军官。 展开更多
关键词 回鹘 三叉冠 形制 身份探究 宗教文化
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三种梨简化棚架栽培树形树冠与产量形成差异比较分析
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作者 曾少敏 陈小明 +2 位作者 胡宁三 黄新忠 姜翠翠 《中国南方果树》 北大核心 2024年第3期217-221,共5页
以梨双臂顺行式树形为对照,对单干单主枝、双干双主枝2种改进型简化棚架栽培树形早期树冠与产量形成进行多年跟踪调查分析.结果表明,与梨双臂顺行式树形相比,单干单主枝、双干双主枝2种树形主干增粗较慢、主枝增长较快,差异达显著或极... 以梨双臂顺行式树形为对照,对单干单主枝、双干双主枝2种改进型简化棚架栽培树形早期树冠与产量形成进行多年跟踪调查分析.结果表明,与梨双臂顺行式树形相比,单干单主枝、双干双主枝2种树形主干增粗较慢、主枝增长较快,差异达显著或极显著水平;大、中、小型3类结果枝组数量峰值分别出现于定植后第5年、第3年、第3年,均提早1年以上;定植当年至定植后第5年形成花芽数量更多,差异达显著或极显著水平;定植后第2至第6年单位面积累计产量分别增加3009.93、2830.18kg/667m^(2),累计纯收益分别增加23429.44元/667m^(2)与21991.44元/667 m^(2),加快树冠形成与缩短进入盛产期和回收建园成本时间的作用显著. 展开更多
关键词 棚架栽培 简化树形 树冠 产量
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一种新型的用于萃取铷的冠醚功能化磁性固相纳米材料
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作者 付华 陈慧媛 +1 位作者 宋维君 赵云 《材料导报》 EI CAS CSCD 北大核心 2024年第17期278-283,共6页
本研究成功制备了一种新型的用于萃取铷的冠醚功能化磁性固相纳米材料(CFE)。通过溶剂热法合成了Fe_(3)O_(4)纳米颗粒磁核,利用3-氨丙基三乙氧基硅烷在碱性环境下的酯水解反应,在磁核表面包覆SiO_(2)并修饰氨基,制备了Fe_(3)O_(4)@SiO_(... 本研究成功制备了一种新型的用于萃取铷的冠醚功能化磁性固相纳米材料(CFE)。通过溶剂热法合成了Fe_(3)O_(4)纳米颗粒磁核,利用3-氨丙基三乙氧基硅烷在碱性环境下的酯水解反应,在磁核表面包覆SiO_(2)并修饰氨基,制备了Fe_(3)O_(4)@SiO_(2)-NH_(2)中间产物,再利用4′-羧基苯并-18-冠6-醚上的羧基与修饰在Fe_(3)O_(4)@SiO_(2)-NH_(2)表面的氨基在1-乙基-(3-二甲基氨基丙基)碳二亚胺盐酸盐的催化下发生酰胺化反应,将该冠醚修饰在中间产物的表面,制备了CFE新型材料。分析了Fe_(3)O_(4)、Fe_(3)O_(4)@SiO_(2)-NH_(2)、CFE的微观形貌、磁化性质、X射线衍射性质、红外吸收性质、元素组成,佐证了材料被成功制备,验证了CFE对Rb^(+)的萃取能力,研究了溶液pH对Rb^(+)萃取效果的影响。结果表明,室温下萃取30 min,在pH为13时CFE对Rb^(+)具有最佳的萃取效果,萃取率为90.0%。 展开更多
关键词 磁性固相萃取 冠醚 功能材料 纳米材料
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年轻恒牙外伤性冠折露髓时间与初诊叩痛对预后的影响
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作者 张海龙 陈雪 +3 位作者 王敬 陈喜波 霍峰 李乐 《中国医刊》 CAS 2024年第7期768-772,共5页
目的探讨外伤引起的年轻恒牙冠折露髓患者经活髓切断术或直接盖髓术后预后不良的独立危险因素,并评价露髓时间、初诊叩痛对牙髓预后的影响。方法回顾性分析2018年3月至2020年9月河北省承德医学院附属医院收治的219例外伤引起的年轻恒牙... 目的探讨外伤引起的年轻恒牙冠折露髓患者经活髓切断术或直接盖髓术后预后不良的独立危险因素,并评价露髓时间、初诊叩痛对牙髓预后的影响。方法回顾性分析2018年3月至2020年9月河北省承德医学院附属医院收治的219例外伤引起的年轻恒牙冠折露髓患者的临床资料。患者初诊治疗为活髓切断术或直接盖髓术且于术后1年进行随访。采用单因素和多因素logistic回归分析影响牙髓预后不良的独立危险因素,并通过受试者操作特征(ROC)曲线分析上述独立危险因素对牙髓预后不良的预测价值。结果经术后1年随访,治疗失败20例,成功199例,活髓切断术总成功率为90.87%。单因素分析结果显示,根尖发育情况、露髓时间、初诊叩痛与牙髓预后不良有关(P<0.05),而年龄、性别、受伤原因、受伤牙位、温度试验结果、牙髓电活力差值、露髓孔直径、患牙松动度、治疗方案与牙髓不良预后无关(P>0.05)。多因素logistic回归分析结果显示,初诊叩痛(+++)是影响牙髓预后不良的独立危险因素(P<0.05)。ROC曲线分析结果显示,初诊叩痛(+++)预测牙髓预后不良的曲线下面积为0.860,敏感度为0.832,特异度为0.865。结论初诊叩痛(+++)是外伤引起的年轻恒牙冠折露髓患者预后不良的独立危险因素,且对预后不良的预测价值较高,而露髓时间与牙髓预后无明显相关性。 展开更多
关键词 外伤 冠折 活髓切断术 露髓时间 初诊叩痛 预后
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金冠豆角籽粒淀粉组成及性质研究
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作者 宋永 贾璐泽 +3 位作者 张一婷 刘佳莉 刘大军 孙庆申 《食品工业科技》 CAS 北大核心 2024年第7期59-67,共9页
为了明确金冠豆角淀粉的基本性质,本文以提取盐溶蛋白后剩余的金冠豆角籽粒豆渣为原料,采用水提法提取淀粉,观察淀粉颗粒形态,测定其组成、粒径、理化性质及体外抗消化特性。结果表明,金冠豆角籽粒淀粉中直链淀粉和支链淀粉的含量分别为... 为了明确金冠豆角淀粉的基本性质,本文以提取盐溶蛋白后剩余的金冠豆角籽粒豆渣为原料,采用水提法提取淀粉,观察淀粉颗粒形态,测定其组成、粒径、理化性质及体外抗消化特性。结果表明,金冠豆角籽粒淀粉中直链淀粉和支链淀粉的含量分别为47.39%和52.07%,淀粉的颗粒形态与豌豆淀粉类似,呈卵圆形或球型,颗粒表面光滑完整,粒径为75.10μm。金冠豆角籽粒淀粉的峰值粘度(212.20 RVU)、衰减值(68.50 RVU)较低,但回生值(96.80 RVU)高于玉米淀粉;金冠豆角籽粒淀粉糊化的起始温度(T_(0))、峰值温度(T_(p))显著高于豌豆淀粉(P<0.05)。金冠豆角籽粒淀粉的凝沉值在90 min时接近80%,凝沉速度显著高于玉米淀粉,透光率介于豌豆淀粉和玉米淀粉之间,持水性(WHC)和持油性(OHC)值分别为1.08和1.00 g/g,凝胶硬度小,属于易凝沉淀粉,其抗性淀粉(RS)含量为68.43%,高于玉米淀粉和豌豆淀粉(P<0.05),具有良好的抗消化特性。 展开更多
关键词 金冠豆角籽粒 淀粉 理化性质 抗消化特性
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小麦茎基腐病抗性位点研究进展
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作者 李巧云 郝晓鹏 +3 位作者 姜玉梅 郭振峰 牛吉山 殷贵鸿 《河南农业大学学报》 CAS CSCD 北大核心 2024年第4期539-551,共13页
对小麦茎基腐病(FCR)抗性位点研究进行综述。目前,在小麦所有的21条染色体上定位了140个抗性QTL,含10个抗性基因,虽然报道的抗性位点很多,但主效位点不明确,严重影响小麦FCR抗性改良进程。分析了小麦FCR抗性位点研究中的主要问题,提出... 对小麦茎基腐病(FCR)抗性位点研究进行综述。目前,在小麦所有的21条染色体上定位了140个抗性QTL,含10个抗性基因,虽然报道的抗性位点很多,但主效位点不明确,严重影响小麦FCR抗性改良进程。分析了小麦FCR抗性位点研究中的主要问题,提出了统一抗性鉴定标准、增强成株期抗性研究等建议,以明确抗FCR主效位点/基因并开发分子标记,通过分子标记辅助选择促进FCR抗性改良进程。 展开更多
关键词 小麦 茎基腐病 抗性基因 分子标记 种质创制
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聚醚醚酮、氧化锆及钴铬合金制作的套筒冠内冠耐磨损性及固位力比较
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作者 陈卓 韩琳 +1 位作者 艾昕 邱晓霞 《郑州大学学报(医学版)》 CAS 北大核心 2024年第5期722-726,共5页
目的:比较使用聚醚醚酮(PEEK)、氧化锆及钴铬合金制作的套筒冠内冠的耐磨损性及固位力。方法:制作24个圆锥状金属基牙代型,分别使用钴铬合金、氧化锆和PEEK制作其上内冠各9个,使用钴铬合金制作外冠24个,对所有外冠外及内冠内表面进行喷... 目的:比较使用聚醚醚酮(PEEK)、氧化锆及钴铬合金制作的套筒冠内冠的耐磨损性及固位力。方法:制作24个圆锥状金属基牙代型,分别使用钴铬合金、氧化锆和PEEK制作其上内冠各9个,使用钴铬合金制作外冠24个,对所有外冠外及内冠内表面进行喷砂处理后待用。根据内冠制作材料的不同,将所有试件分为A、B、C三组,每组9个内冠及8个外冠。A组:内冠为钴铬合金材料;B组:内冠为氧化锆材料;C组:内冠为PEEK材料。每组随机选取一个内冠使用扫描电镜观察外表面,并称重其余所有内外冠。将内冠粘接于基牙代型上,对基牙金属代型和外冠进行包埋。在万能拉力试验机上模拟摘戴循环10000次,观察并记录未循环、循环1000次、循环5000次与循环10000次时的固位力。去除包埋及粘接材料后再次进行称重,记录重量变化。电镜下观察内冠表面磨损情况。结果:3组固位力差异有统计学意义(P<0.001),并随着摘戴次数的增加,A组固位力逐渐下降,B、C组先升高后降低;未循环时,A组固位力>B组>C组,循环10000次后,A组和C组固位力>B组。C组内冠相对质量损耗大于A、B组,外冠相对质量损耗小于A、B组(P<0.017)。循环10000次后,A、B、C组表面粗糙度较实验前均有所增加,C组表面磨损更严重。结论:PEEK作为内冠材料可提供不低于钴铬合金和氧化锆内冠的固位力,耐磨损性能较钴铬合金和氧化锆内冠差,但对外冠的磨损较小。 展开更多
关键词 套筒冠 内冠材料 聚醚醚酮 固位力 耐磨损性
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种衣剂防治小麦茎基腐病效果的评价
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作者 张建周 李春盈 +4 位作者 王风涛 刘明 张天兴 崔明珠 齐建双 《沈阳农业大学学报》 CAS CSCD 北大核心 2024年第2期187-194,共8页
茎基腐病已成为黄淮小麦主产区最具破坏性的土传病害之一,对我国粮食安全供给构成严重威胁。目前抗茎基腐病主栽品种稀少,生产上主要依赖于化学农药措施。药剂拌种可以有效防治茎基腐病。综合评价现有的种衣剂对小麦茎基腐病的防治及增... 茎基腐病已成为黄淮小麦主产区最具破坏性的土传病害之一,对我国粮食安全供给构成严重威胁。目前抗茎基腐病主栽品种稀少,生产上主要依赖于化学农药措施。药剂拌种可以有效防治茎基腐病。综合评价现有的种衣剂对小麦茎基腐病的防治及增产效果,以期为合理用药提供依据。采取高感茎基腐病小麦品种郑麦1354为研究对象,播种前种子包衣晾干,利用高致病力茎基腐病菌株PY20-20培养小米菌谷,连续2个小麦生长季利用进行人工接种病圃,包衣种子和接种菌谷等重量混合播种,分别于小麦拔节期和乳熟期记载处理小区植株发病情况,调查9种种衣剂处理后不同生育期的病情指数(disease index,DI),成熟收获后测定小区实际产量,结合小麦产量相关性状,比较种衣剂防病增产作用。结果表明:种衣剂处理后拔节期茎基腐病DI值均小于1.0,显著小于空白对照(5.07),防治效果为85.09%~100%,其中33 g·L^(-1)咯菌·噻虫胺、9%苯甲·吡虫啉和35 g·L^(-1)精甲霜灵·咯菌腈的防效达到为97%~100%。在乳熟期,种衣剂处理后茎基腐病DI平均值低于15,显著小于空白对照(81.55),其中35 g·L^(-1)精甲霜灵·咯菌腈和9%苯甲·吡虫啉防效较好,平均防效分别达到92%和95%,而且分别增产39.62%和36.31%。综合而言,采用种衣剂35 g·L^(-1)精甲霜灵·咯菌腈和9%苯甲·吡虫啉防治小麦茎基腐病效果好且增产效果显著,具有较好的应用前景。 展开更多
关键词 小麦 茎基腐病 种衣剂 病情指数 产量相关性状
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前牙高透氧化锆全瓷冠修复单颗前牙缺损的美学效果分析
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作者 徐菁 李敏 《中国美容医学》 CAS 2024年第6期162-165,共4页
目的:探究高透氧化锆全瓷冠修复单颗前牙缺损的美学效果。方法:选取2018年1月-2020年10月笔者医院收治的单颗前牙缺损患者80例(共80颗患牙),按随机数表法分为观察组(高透氧化锆全瓷冠修复)和对照组(钴铬烤瓷冠修复),每组40例(40颗患牙)... 目的:探究高透氧化锆全瓷冠修复单颗前牙缺损的美学效果。方法:选取2018年1月-2020年10月笔者医院收治的单颗前牙缺损患者80例(共80颗患牙),按随机数表法分为观察组(高透氧化锆全瓷冠修复)和对照组(钴铬烤瓷冠修复),每组40例(40颗患牙),比较两组的修复效果,修复前、修复后1个月的牙周指标及龈沟液指标[碱性磷酸酶(Alkaline phosphatase,ALP)、白介素6(Interleukin-6,IL-6)、白介素8(Interleukin-8,IL-8)]水平,对比两组修复后1年的满意度及并发症发生情况。结果:修复后1年,两组颜色对比、边缘着色、解剖外形、边缘密合度、龋齿等修复效果评估观察组均高于对照组(P<0.05)。修复后1个月,两组牙周探诊深度、菌斑指数、出血指数均升高,但观察组低于对照组(均P<0.05);两组龈沟液ALP、IL-6、IL-8水平均降低,且观察组均低于对照组(均P<0.05)。修复后1年,观察组修复总满意度高于对照组(P<0.05);修复后1年期间,两组均未发生牙体腐蚀,疼痛、牙龈炎、根折发生率差异无统计学意义,观察组并发症总发生率低于对照组(P<0.05)。结论:采用高透氧化锆全瓷冠修复单颗前牙缺损的美学效果较好,可减轻牙周组织炎症,值得临床推广应用。 展开更多
关键词 前牙缺损 高透氧化锆全瓷冠 钴铬烤瓷冠 牙齿修复 美学效果 牙周指数
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