We present a semiclassical （SC） approach for quantum dissipative dynamics, constructed on basis of the hierarchical-equation-of-motion （HEOM） formalism. The dynamical components considered in the developed SC-HEOM...We present a semiclassical （SC） approach for quantum dissipative dynamics, constructed on basis of the hierarchical-equation-of-motion （HEOM） formalism. The dynamical components considered in the developed SC-HEOM are wavepackets＇ phase-space moments of not only the primary reduced system density operator but also the auxiliary density operators （ADOs） of HEOM. It is a highly numerically efficient method, meanwhile taking into account the high-order effcts of system-bath couplings. The SC-HEOM methodology is exemplified in this work on the hierarchical quantum master equation [J. Chem. Phys. 131, 214111 （2009）] and numerically demonstrated on linear spectra of anharmonic oscillators.展开更多
基金supported by the National Natural Science Foundation of China(No.21373191,No.21573202,No.21633006,and No.21703225)the Fundamental Research Funds for the Central Universities(No.2030020028,No.2060030025,and No.2340000074)
文摘We present a semiclassical （SC） approach for quantum dissipative dynamics, constructed on basis of the hierarchical-equation-of-motion （HEOM） formalism. The dynamical components considered in the developed SC-HEOM are wavepackets＇ phase-space moments of not only the primary reduced system density operator but also the auxiliary density operators （ADOs） of HEOM. It is a highly numerically efficient method, meanwhile taking into account the high-order effcts of system-bath couplings. The SC-HEOM methodology is exemplified in this work on the hierarchical quantum master equation [J. Chem. Phys. 131, 214111 （2009）] and numerically demonstrated on linear spectra of anharmonic oscillators.
