Optimal synthesis of heat-integrated distillation configurations using the two-column superstructure

In the realm of the synthesis of heat-integrated distillation configurations,the conventional approach for exploring more heat integration possibilities typically entails the splitting of a single column into a twocolumn configuration.However,this approach frequently necessitates tedious enumeration procedures,resulting in a considerable computational burden.To surmount this formidable challenge,the present study introduces an innovative remedy:The proposition of a superstructure that encompasses both single-column and multiple two-column configurations.Additionally,a simultaneous optimization algorithm is applied to optimize both the process parameters and heat integration structures of the twocolumn configurations.The effectiveness of this approach is demonstrated through a case study focusing on industrial organosilicon separation.The results underscore that the superstructure methodology not only substantially mitigates computational time compared to exhaustive enumeration but also furnishes solutions that exhibit comparable performance.

Process design and intensification of multicomponent azeotropes special distillation separation via molecular simulation and system optimization

This work provides an overview of distillation processes,including process design for different distillation processes,selection of entrainers for special distillation processes,system integration and intensification of distillation processes,optimization of process parameters for distillation processes and recent research progress in dynamic control strategies.Firstly,the feasibility of using thermodynamic topological theories such as residual curve,phase equilibrium line and distillation boundary line to analyze different separation regions is discussed,and the rationality of distillation process design is discussed by using its feasibility.Secondly,the application of molecular simulation methods such as molecular dynamics simulation and quantum chemical calculation in the screening of entrainer is discussed for the extractive distillation process.The thermal coupling mechanism of different distillation processes is used to explore the process of different process intensifications.Next,a mixed integer nonlinear optimization strategy for the distillation process based on different algorithms is introduced.Finally,the improvement of dynamic control strategies for different distillation processes in recent years is summarized.This work focuses on the application of process intensification and system optimization in the design of distillation process,and analyzes the challenges,prospects,and development trends of distillation technology in the separation of multicomponent azeotropes.

Experimental Investigation on Heat Exchange and Separation Performance of an Annular Structured Internal Heat-integrated Distillation Column

In this paper heat exchange coefficient and separation efficiency of an annular structured internal heat-integrated distillation column(HIDi C) were experimentally measured. About 50% heat of the inner column could be transferred to the outer column. The overall heat exchange coefficient decreased with an increase in pressure ratio of the inner column and the outer column, but was little affected by the F-factor. The increase of the pressure ratio decreased obviously the separation efficiency of the outer column but had little effect on that of the inner column.

EXISTENCE AND UNIQUENESS OF SOLUTIONS FOR NONLINEAR FRACTIONAL DIFFERENTIAL EQUATIONS WITH NON-SEPARATED TYPE INTEGRAL BOUNDARY CONDITIONS

In this paper, we study a boundary value problem of nonlinear fractional dif- ferential equations of order q （1 〈 q 〈 2） with non-separated integral boundary conditions. Some new existence and uniqueness results are obtained by using some standard fixed point theorems and Leray-Schauder degree theory. Some illustrative examples are also presented. We extend previous results even in the integer case q = 2.

Independent integration and innovation of the first domestically-integrated 60000 m^3/h air separation unit

Baosteel＇s 60000 m……3/h air separation unit （ASU）, the first domestically-integrated unit of its class, is a milestone in the Chinese air separation industry. In this paper,the process characteristics of the unit and the application of the original techniques are expatiated. Some difficulties in the process design, the risk control, the quality control, the control system integration and the system commissioning are analyzed and appraised. The mode of the project integration and innovation, the cooperation among industries and the user-orientated project management mode are introduced. Finally,the successful experiences in innovation are summarized with the focus on the integration of the project.

Hydrate-based carbon dioxide capture from simulated integrated gasification combined cycle gas

The equilibrium hydrate formation conditions for CO2/H2 gas mixtures with different CO2 concentrations in 0.29 mol% TBAB aqueous solution are firstly measured.The results illustrate that the equilibrium hydrate formation pressure increases remarkably with the decrease of CO2 concentration in the gas mixture.Based on the phase equilibrium data,a three stages hydrate CO2 separation from integrated gasification combined cycle （IGCC） synthesis gas is investigated.Because the separation efficiency is quite low for the third hydrate separation,a hybrid CO2 separation process of two hydrate stages in conjunction with one chemical absorption process （absorption with MEA） is proposed and studied.The experimental results show H2 concentration in the final residual gas released from the three stages hydrate CO2 separation process was approximately 95.0 mol% while that released from the hybrid CO2 separation process was approximately 99.4 mol%.Thus,the hybrid process is possible to be a promising technology for the industrial application in the future.

A Variable Separation Approach to Solve the Integrable and Nonintegrable Models:Coherent Structures of the (2 + 1)-Dimensional KdV Eqnation

We study the localized coherent structures ofa generally nonintegrable (2+ 1 )-dimensional KdV equation via a variable separation approach. In a special integrable case, the entrance of some arbitrary functions leads to abundant coherent structures. However, in the general nonintegrable case, an additional condition has to be introduced for these arbitrary functions. Although the additional condition has been introduced into the solutions of the nonintegrable KdV equation, there still exist many interesting solitary wave structures. Especially, the nonintegrable KdV equation possesses the breather-like localized excitations, and the similar static ring soliton solutions as in the integrable case. Furthermor,in the integrable case, the interaction between two travelling ring solitons is elastic, while in the nonintegrable case we cannot find even the single travelling ring soliton solution.

CoB and BN composites enabling integrated adsorption/catalysis to polysulfides for inhibiting shuttle-effect in Li-S batteries

Lithium-sulfur(Li-S)batteries are hampered by the infamous shuttle effect and slow redox kinetics,resulting in rapid capacity decay.Herein,a bifunctional catalysis CoB/BN@rGO with integrated structure and synergy effect between adsorption and catalysis is proposed to solve the above problems.The integrated CoB and BN are simultaneously and uniformly introduced on the rGO substrate through a one-step calcination strategy,applied to modify the cathode side of PP separator.The transition metal borides can catalyze the conversion of lithium polysulfides(Li_(2)Sn,n≥4),whereas the bond of B-S is too weak to absorb LPS.Thus BN introduced can effectively restrict the diffusion of polysulfides via strong chemisorption with LiSnLi+…N,while the rGO substrate ensures smooth electron transfer for redox reaction.Therefore,through the integrated adsorption/catalysis,the shuttle effect is suppressed,the kinetics of redox reaction is enhanced,and the capacity decay is reduced.Using CoB/BN@rGO modified PP separator,the Li-S batteries with high initial capacity(1450 mAh g^(-1)at 0.35 mA cm^(-2))and long-cycle stability(700 cycles at 1.74 mA cm^(-2)with a decay rate of 0.032%per cycle)are achieved.This work provides a novel insight for the preparation of bifunctional catalysis with integrated structure for long-life Li-S batteries.

Heat Transfer Investigation and Modeling of Heat Integrated Distillation Column

The high degree of reversibility of heat integrated distillation column(HIDiC) has been thermodynamically interpreted by the entropy method. In this paper, a heat transfer model and a more universal method were proposed, through which the overall heat transfer coefficient at different height of column under different operating conditions could be obtained before the experiment. Then the separation of a binary ethanol-water system was carried out experimentally as a case study to verify the heat transfer model and the aforementioned calculation method. The close results between the calculation, the simulation, and the experiments suggested that the proposed model and the calculation method in this paper were accurate and applicable. Meanwhile, it was demonstrated that the HIDiC shows obvious effect of reducing entropy increase and improving thermodynamic efficiency as compared to conventional distillation column.

Assessment of the Regime of Functioning Agroecosystems Depending on the Climate and Technogenic Pollution of the Soils

Some results of monitoring (for the period from 1992 to 2005) related to transformations of carbon in agroecosystems of Baikal Siberia (Russia) characterized by unpolluted grey forest soils as well as the soils technogenically polluted with heavy metals are discussed with use the unique approach to integrated assessment of the agroecosystem’s functioning regime. The peculiarities of accumulation of carbon in soil microbial biomass and CO2 emission during the years differing in climate conditions are demonstrated. Analysis of formation of net-mineralized and (re)immobilized carbon is conducted, their ratio being used for the purpose of assessment of the level of influence upon the agroecosystem. The agroecosystems having technogenically polluted soils are characterized by processes of the soil microbial biomass reduction and by an obvious increase of CO2 emission into the atmosphere. Negative changes, which are bound up with carbon transformation, are intensified under unfavorable climate conditions. Intensification of processes of carbon net mineralization and, vice versa, lowering the intensity of processes related to carbon (re)immobilization (especially under the effect of soil pollution and climate changes) provoke instability of the agroecosystem and cause formation of a new regime of its functioning.

Heat Integration for Different Separation Processes

The distribution of heat duties among individual separation subsystems and other aspects of heat integration in such systems are reviewed. Heat integration for different separation processes is investigated, using the pinch point method. Such a study will provide theoretical guide lines for the proper choice of a desirable separation process.

Variable Separation Approach to Solve a （2＋1）-Dimensional Integrable System

In this letter, starting from a B?cklund transformation, a general solution of a (2+1)-dimensional integrable system is obtained by using the new variable separation approach.

Multi-linear Variable Separation Approach to Solve a （1＋1）-Dimensional Coupled Integrable Dispersionless System

The multi-linear variable separation approach (MLVSA ) is very useful to solve (2+ 1)-dimensional integrable systems. In this letter, we extend this method to solve a (1+1)-dimensional coupled integrable dispersion-less system.Namely, by using a Backlund transformation and the MLVSA, we find a new general solution and define a new "universal formula". Then, some new (1+1)-dimensional coherent structures of this universal formula can be found by selecting corresponding functions appropriately. Specially, in some conditions, bell soliton and kink soliton can transform each other, which are illustrated graphically.

宅基地使用权依托农房转让的制度沿革、司法裁判与实践创新

宅基地使用权依托农房转让的制度沿革经历了从允许到限制的转变,体现了政府政策的强制驱动和利益诱导的结合。宅基地使用权依托农房转让的司法裁判具有明显的被动性,农户在集体经济组织外部转让农房时,法院一般会认定该转让合同无效,但司法政策又为宅基地改革预留了政策空间,体现了原则性与灵活性的统一。在宅基地使用权依托农房转让的实践创新中,国家并没有直接废除宅基地使用权依托农房限制转让的既有路径,径行允许转让,而是秉持审慎原则,独辟蹊径。试点地区宅基地使用权依托农房转让下受让人范围拓展,与集体经营性建设用地入市衔接,与宅基地资格权退出耦合及与宅基地入股、合作打通,均体现了对宅基地使用权权能受限的克服。

气流分选技术研究进展

双碳背景下,气流分选技术因污染低、成本低、不用水、投资省、工艺简单等优势备受关注。为提升气流分选技术在多领域、多地区、多工况的适应性,解决气流分选物料适用范围窄、细粒分选效率低、设备大型化难等问题迫在眉睫。围绕气流分选理论、技术应用和技术改进3方面系统评述气流分选技术研究进展。首先,介绍了气流分选技术原理,分析气流分选过程颗粒受力及分选理论进展;其次,综述了气流分选在固废、矿业、农业等领域的应用进展,并评析了技术优势和技术短板;再次,系统分析了气流分选供风方式优化和设备结构优化等技术改进进展;最后,给出了通过单体并联和相似放大准则提高设备处理量,通过预干燥、分选干燥一体化、改进入料方式提高潮湿物料适应性与分散性,通过窄粒级分选和保持物料形状一致性的预处理过程提高细粒和薄片物料分选效率等路径。展望了未来气流分选技术在线检测与控制智能化、分选装备大型化、分选效率精细化、分选工艺联合化等方面的发展方向,为气流分选技术进一步研究和推广应用提供重要依据。

直升机整体式惯性粒子分离器研究现状

整体式惯性粒子分离器是一种直升机进气防护装置,其性能优异、应用广泛,对于保护直升机发动机、延长其使用寿命具有重要意义。本文从4个方面对整体式惯性粒子分离器的研究现状进行归纳总结,包括:总结了现有直升机进气防护装置的类型及相关气动参数,梳理了整体式惯性粒子分离器现有的研究方法及取得的相关成果,分析了影响整体式惯性粒子分离器工作性能的因素,并展望了整体式惯性粒子分离器未来的发展方向。研究成果可为今后开展整体式惯性粒子分离器研究及优化设计提供一定参考。

中低速磁浮梁轨一体轨道梁钢混接头试验研究

针对中低速磁浮分离式轨道梁建筑高度较大、无法考虑F轨刚度贡献等问题,提出了一种开孔钢板式梁轨一体轨道梁结构,并针对其钢-混结合部的静力性能开展足尺模型试验和有限元仿真计算分析.首先,介绍了梁轨一体轨道梁工程背景以及钢-混结合部的结构特征;其次,设计了钢-混结合部静载模型试验,测试F轨、钢连接件和混凝土等构件在各级荷载下的应力和位移;最后,建立了钢-混结合部实体有限元模型,并结合试验数据分析了钢-混结合部的受力性能、传力机理以及设计参数影响.研究结果表明:1)在1.50倍设计荷载内,钢-混结合部基本处于弹性状态,连接件承载力满足设计要求;荷载继续增大时,F轨的荷载-应力曲线表现出一定的非线性;5.47倍设计荷载下,混凝土梁体发生开裂破坏.2)F轨内外磁极位移均较小,钢-混结合部刚度较大;F轨内外磁极位移差在设计荷载下满足设计限值;1.58倍设计荷载下内外磁极位移差达到0.54 mm,开始超过位移差限值;表明钢混结合部刚度的富裕量小于强度,钢连接件应以刚度控制设计.3)在正常运营状态,磁浮列车荷载主要由钢连件的钢板承压传递,焊钉与开孔钢板传力比例较小;钢连接件中开孔直径、贯穿钢筋直径对传力影响较小,钢连接件腹板厚度增加使得钢混结合部处传力更加平顺.

随迁祖辈夫妻分居现象的实证研究——基于厦门地区调查数据的分析

利用厦门地区随迁祖辈群体的抽样调查数据,选取拥有配偶的随迁祖辈样本,并划分为有伴侣共同随迁和与伴侣因随迁而分居的两种状态,通过对有配偶的随迁分居者的群体样貌、分居原因和分居影响进行描述性分析,掌握随迁祖辈被动分居现象的基本情况。通过假设检验和回归分析,论证因随迁照料孙辈而导致中老年夫妻分居状态会抑制随迁祖辈对随迁生活的积极体验感,还会通过影响随迁祖辈的家庭融入和社会融入而降低祖辈对于随迁生活的积极感受,但并不会增加祖辈对随迁生活的消极感受。对随迁分居者样本的单独分析显示,减轻随迁祖辈的家务劳动负担、增强子代的代际关怀能够帮助其减少独自随迁生活的消极体验感,而增进其在迁入地的社会参与度、促进随迁祖辈与子代家庭的沟通满意度则能够分别提升他们的积极体验感和降低他们的消极体验感。

横向贯通式中低速磁浮一体轨道梁钢-混结合部试验研究

为解决中低速磁浮分离式轨道梁存在的养护难、构件多,以及无法考虑F轨刚度贡献等问题,提出一种横向贯通式梁轨一体轨道梁结构,针对其钢-混结合部的静力性能开展有限元分析和足尺模型试验研究,并对关键设计参数进行参数分析。结果表明,在5倍设计荷载内,钢-混结合部基本处于弹性状态,承载力满足设计要求,且具备较高富裕量;竖向荷载主要通过钢板承压作用传递至混凝土梁体,焊钉对竖向荷载的传递作用较小;设计参数分析表明,适量提高钢连接件钢板厚度有利于竖向荷载的平顺传递。研究结果可以为梁轨一体轨道梁设计提供参考。

无人艇载多波束测深系统一体化结构优化设计

为了提升无人艇载多波束测深系统(以下简称多波束系统)在复杂环境下的作业安全和精度,通过对多波束系统与无人艇艇型一体化安装结构的分析,采用基于有限元协同仿真技术开展动力及平台结构性能优化设计研究,设计出了在一定航行速度下能保证较优效率和航行安全的无人艇载多波束系统安装结构,并在珠江口海域进行了试验。结果表明:与传统的无人艇平台与多波束系统分离式设计的方法相比,设计的无人艇载多波束系统横摇角度小,抖动现象减弱,作业性能得到提升。运用该系统不仅可以获取水下高精度的三维地形数据,也可以为水下障碍物排查、目标物搜寻和水下构筑物巡检巡查等提供技术支撑。