A method is proposed for the extraction and separation of trivalent gallium,indium and thallium from their corresponding aqueous solutions at 65 deg C with 2,6-bis-(1'-phenyl-3'-methyl-5'-oxopyrazole-4'...A method is proposed for the extraction and separation of trivalent gallium,indium and thallium from their corresponding aqueous solutions at 65 deg C with 2,6-bis-(1'-phenyl-3'-methyl-5'-oxopyrazole-4') pyridineacyl (H_2PMBPP or H_2A) using molten paraffinwax as a diluent. The values of pH_(1/2) for extraction of gallium, indium and thallium are2.62,4.32 and 4.93, respectively. Gallium can he extracted by H_2PMBPP at a lower acid medium. Theeffect of solvent and the composition of the extracted species are reported. And the thermodynamicdata of the extraction are also obtained.展开更多
基金This project is financially supported in part by the Gansu Province Natural Science Foundation (ZR96016) the KJCXGC-01 of NWNU, 2000, China
文摘A method is proposed for the extraction and separation of trivalent gallium,indium and thallium from their corresponding aqueous solutions at 65 deg C with 2,6-bis-(1'-phenyl-3'-methyl-5'-oxopyrazole-4') pyridineacyl (H_2PMBPP or H_2A) using molten paraffinwax as a diluent. The values of pH_(1/2) for extraction of gallium, indium and thallium are2.62,4.32 and 4.93, respectively. Gallium can he extracted by H_2PMBPP at a lower acid medium. Theeffect of solvent and the composition of the extracted species are reported. And the thermodynamicdata of the extraction are also obtained.
