Separation of halogens and recovery of heavy metals from secondary copper smelting dust

The separation of halogens and recovery of heavy metals from secondary copper smelting(SCS)dust using a sulfating roasting−water leaching process were investigated.The thermodynamic analysis results confirm the feasibility of the phase transformation to metal sulfates and to gaseous HF and HCl.Under the sulfating roasting conditions of the roasting temperature of 250℃ and the sulfuric acid excess coefficient of 1.8,over 74 wt.%of F and 98 wt.%of Cl were volatilized into flue gas.Approximately 98.6 wt.%of Zn and 96.5 wt.%of Cu in the roasting product were dissolved into the leaching solution after the water leaching process,while the leaching efficiencies of Pb and Sn were only 0.12%and 0.22%,respectively.The mechanism studies indicate the pivotal effect of roasting temperature on the sulphation reactions from various metal species to metal sulfates and the salting out reactions from various metal halides to gaseous hydrogen halides.

THE EVOLUTION OF STARTING VORTEX AND SECONDARY SEPARATION ON AN ELLIPTIC CYLINDER

Flow visualization was used to investigate experimentally the evolution process from symmetrical shedding to staggered shedding of the starting vortex and the phenomenon of secondary separation on an elliptic cylinder at moderate Reynolds numbers.The vortex structure of the flow separation was studied.The temporal variation of separation angle and length of wake vortex were given. The photographs and experimental results provided basis for further investigation of the complicated feature of the starting process of unsteady separated flows around an elliptic cylinder.

Analysis of Secondary Separation of China's Rural Land Rights from the Perspective of Analytical Jurisprudence

China's rural land rights are incomplete in structure of land rights and functions due to status restriction. Settling dispute and problem of status in rural land right and function structure is of great significance for determining and guaranteeing subjects of rural land rights. The point connecting and solving rural land circulation issue is demonstration and settlement of status. Separating the status right from rural land property right,namely the secondary separation of right,is to realize such purpose. Currently,China's rural land right is a bundle of rights,not the right described in property pedigree in strict sense. Using theory of rights of Hohfeld,this paper discussed and analyzed legal relationship of secondary separation of China's rural land rights,in the hope of realizing real return from practice to theory and to practice again.

Synthesis of an IMF zeolite membrane for the separation of xylene isomer

The synthesis of a continuous IMF zeolite membrane was fabricated on tubular substrates by seeded growth for the first time. The straight channels of IMF zeolite with diameters of 0.53–0.59 nm are distinguishable for p-xylene from o-xylene molecules. Pure IMF-phase high-silica IM-5 zeolite seeds with uniform and fine crystal size were fabricated by a new sonication-assisted aging process. The seeds were coated on the support by dipcoating and induced the formation of continuous membrane. Separation performance in p-/o-xylene mixture was investigated at various temperature and pressure. The typical IM-5zeolite membrane had p-/o-xylene separation factor of 3.7. Our results suggest that IM-5 zeolite is a potentially good membrane material for the separation of xylene mixtures.

A depressant for marmatite flotation:Synthesis,characterisation and floatation performance

This study synthesised a zincic salt(ZS)as a depressant for marmatite-galena separation.The effect of ZS on the flotation of marmatite and galena was investigated through micro-flotation tests.88.89%of the galena was recovered and 83.39%of the marmatite was depressed with ZS dosage of 750 mg·L^(−1)at pH=4.The depression mechanism of ZS on marmatite was investigated by a variety of techniques,including adsorption measurements,Fourier transform infrared(FTIR),X-ray photoelectron spectroscopic(XPS)analysis,and time of flight secondary ion mass spectrometry(ToF-SIMS).Results of adsorption tests and FTIR reveal that ZS adsorbed on marmatite surface and impeded the subsequent adsorption of butyl xanthate(BX).The results of XPS and ToF-SIMS indicate that the ZnO_(2)^(3-)released by ZS could be chemisorbed on the marmatite surface and depress marmatite flotation.

Morphological Characteristics of Sand Waves in the Middle Taiwan Shoal Based on Multi-beam Data Analysis

A DTM map of the study area in the Taiwan Shoal was drawn based on precise and high- density data acquired in a field survey by a multi-beam sounding system （R2Sonic2024）. We identified sand waves in the study area at water depths of 13.89-49.12 m; the main sand waves had heights of 5- 25 m, lengths of 0.1-2.0 km, and crest lines 0.1-6.5 km long. The spatial distribution of the sand waves on the seabed is dense in the north and sparse in the south and the directions range between 50°-80° and 90°-135°. Between the main sand waves, secondary sand waves develop with heights of 0.1-5.0 m and lengths of 10-100 m, which are difficult to detect by satellite remote sensing. By comparing the evolution structures of the secondary and main sand waves, we identified three evolution modes of the secondary sand waves： parallel, oblique, and divergent modes according to the relative crest directions. Suitable water depth, reciprocating current speeds between 40 and 100 cm/s, and abundant sediment supply create favorable conditions for the formation of linear sand waves. Comparing the DTM maps and profiles of the June 2012 and June 2013 surveys of the same area, we found that the shape and morphology of the sand waves remained mostly unchanged under normal hydrodynamic conditions.

Numerical Study of Flow and Thermal Field on a Parallel Flow Vortex Tube

Flow and thermal field of a parallel flow vortex tube has been simulated and analyzed numerically. A secondary zone model is found at the core region near the inlet to the middle of the vortex tube. Blockage effect due to a narrow area of the hot exit has deflected air flow towards the cold exit, caused expansion and compression at the cold and hot outlet, respectively. The cooling and heating effect due to energy separation is contributed by expansion and compression of air near the outlet. Coeficient of performance (COP) for a refrigerator is higher as cold mass fraction increases due to a higher temperature difference and cold mass flow rate.

Removal of the airwave effect by main-part decomposition of the anomalous field of MCSEM data

The airwave effect greatly influences the observational data from controlledsource electromagnetic exploration in shallow seas, which obscures the abnormal effects generated by exploration targets and, hence, affects the accuracy of the late exploration data interpretation. In this study, we propose a method to separate the main part from the anomalous field of marine controlled-source electromagnetic method （MCSEM） data based on Stratton-Chu integral transforms to eliminate the airwave effect, which dominates observed electromagnetic （EM） response in shallow seawater. This method of separating the main part from the anomalous field is a type of finite impulse response filter based on a discrete data set. Theoretical analysis proved that the method is stable and able to effectively depress noise. A numerical test indicated that the method could successfully eliminate the airwave effect from the observed EM signals generated by an air water interface and a seawater layer. This technique is applicable for seawater models with either flat or rough seabeds.

Quality Improvement of Granular Wastes-The Effective Way to Recycle Secondary Raw Building Materials

Granular wastes have negative effects on the environment due to contamination. On the other hand, stony components in granular wastes have a potential good perspectives for utilization in civil engineering works as secondary raw building materials. To reuse such materials without environmental risks, all contaminants must be removed or reduced to an acceptable level. Therefore liberation of materials is an important step in waste treatment. For this purpose, separation and cleansing techniques are suitable. Based on the analysis of contaminants in wastes, it is discussed how to select suitable techniques. The rules for technique selection and processes for quality improvement are set up. To evaluate the environmental quality and technical quality of output products, it is necessary to check leaching behaviours and physical properties.

Research on Experimental and Application for the High Efficient Enrichment of the Low-grade Precious Metal Materials

On the basis of reviewing the progress in the high efficient enrichment from secondary resources of low grade precious metals at home and abroad, a process route of the high efficient enrichment precious metals from secondary resources of low-grade metals by adding iron oxide as the trapping agent, reducing agent, additive, mixing uniformly and grinding, pelletizing, reduction, grinding and separation, and selectively acid leaching iron has been put forward in this paper. The experiments of reduction, grinding and separation, and selectively acid leaching iron were carried out mainly. Under the decided experiment parameters and conditions, iron generated during the reduction can trap precious metals during reduction, high active alloy powders were obtained from the reduced products by grinding and separation, the concentration of precious metals was obtained by acid leaching high active alloy powders. The better enrichment effect was obtained by adopting the technical route of processing. Other low grade noble metal materials and enrichment ratio of precious metals from the materials to acid products was high through acid leaching. This process has the advantages of simple process, environmental-friendly, strong adaptability of raw materials, high concentration ratio, which was regarded as a kind of the general efficient enrichment technology of low grade precious metal materials.

Classification and exploration potential of sedimentary basins based on the superposition and evolution process of prototype basins

Classification,superimposed evolution and sedimentary filling of prototype basins are analyzed based on the Wilson cycle principle of plate theory,by dissecting the evolution history of 483 sedimentary basins around the world since the Pre-cambrian,combined with the three stress environments of tension,compression and shear.It is found that plate tectonic evo-lution controls the superimposed development process and petroleum-bearing conditions of the prototype basins in three as-pects:first,more than 85%of the sedimentary basins in the world are developed from the superimposed development of two or more prototype basins;second,the superposition evolution process of the prototype basin takes Wilson cycle as the cycle and cycles in a fixed trajectory repeatedly.In each stage of a cycle,a specific type of prototype basin can be formed;third,each prototype basin can form a unique tectonic-sedimentary system,which determines its unique source,reservoir,cap conditions etc.For hydrocarbon accumulation,the later superimposed prototype basin can change the oil and gas accumulation conditions of the earlier prototype basin,and may form new petroleum systems.Based on this,by defining the type of a current basin as its prototype basin formed by the latest plate tectonic movement,14 types of prototype basins can be classified in the world,namely,intracontinental growth rift,intr acontinental aborted rift,intercontinental rift,passive continental margin,interior craton,trench,fore-arc rift,ba ck-arc rift,back-arc de pression,back-arc small ocean,peri pheral foreland,back-arc foreland,strike-slip pull-apart,and strike-slip flexural basins.The classification scheme can ensure the uniqueness of the types of in di-vidual sedimentary basin,and make it possible to predict their oil and gas potential scientifically through analogy.

Regulation of the Warsaw Stock Exchange： History and Operating Rules

The aim of this article is to present the principles of the operation of the Warsaw Stock Exchange （WSE）, which is the most important institution of the capital market in Poland. The article is an attempt to explore the history and structure of the exchange and its investment possibilities in order to understand the number of existing security features which make cooperation with this institution-with appropriate assumptions and diversification-an activity providing profits to potential investors who are aware of its operating rules. This topic deserves a historical outline because of the socialist past and the current status of the WSE, now called the most dynamically growing capital market in Central and Eastern Europe.

THEORETICAL ANALYSIS AND EXPERIMENTAL VERIFICATION ON TERNARY-WAVES METHOD TO COMPILE ACCELERATED SPECTRA

The equivalent damage calculation formulae of fatigue crack formation andgrowth are established. In order to compile the fatigue crack formation and growth accelerated loadspectra, the main wave shapes and load sequence of the actual load spectrum are kept constant, andthe carrier waves are cut off. And secondary waves are put together into new secondary waves toshorten the test time according to the equivalent damage calculation formulae respectively. Then bythe fatigue cumulative damage calculation of the fatigue crack formation and growth accelerated loadspectra, the one corresponding to the bigger damage is determined as the fatigue accelerated testload spectrum. Therefore in the test process, the fatigue accelerated test spectrum may be appliedtill fatigue failure, the engineering fatigue crack length of full-scale structure need not beinspected, and the fatigue crack formation accelerated load spectrum need not be transferred intothe fatigue crack growth accelerated load spectrum. Finally, it is verified by tests of two kinds ofspecimens that the damages of the specimens caused by the accelerated load spectra are near tothose by the actual load spectra; namely, the tested life of actual load spectra is similar to thatof accelerated load spectra. But the test time of accelerated load spectra is shortened by aboutthree-quarters that of actual load spectra. From these tests, it is also found that the fatigueaccelerated test spectrum has an advantage over FALSTAFF spectra.

Improving advantages and reducing risks in increasing cyclone height via an apex cone to grasp vortex end

For a cyclone, it is possible to improve separation efficiency and reduce pressure drop by increasing the cyclone height. However, an exceeded height increase could result in a dramatical drop in separation efficiency. In this study, experimental and computational fluid dynamics simulation results exhibit that the introduction of an apex cone at the dust outlet could avoid the risk of separation efficiency drop but lead to a continuous reducing of the pressure drop. Generally, the optimal cyclone height should be closely related to the natural vortex length. While, when the vortex end contracts into the separation space in the cyclone with an exceeded height, severe back-mixing of particles always occurs, which will result in the decrease of separation efficiency. Herein, it is found that when an apex cone is installed at the dust outlet, the vortex end can be grasped by the cone so as to weaken the back-mixing of particles.Meanwhile, the introduction of this apex cone can enhance the secondary separation to capture the back-mixed particles again so as to protect the efficiency. In addition, it is found that the enhanced secondary separation could come from either the stagnant current of axial velocity in the center or the improved tangential velocity of inner vortex whereas the forcibly extending the length of vortex to exceed its natural length will not significantly increase efficiency.

New finding on out-of-step separation configuration of large-scale power systems

In this paper,two new concepts—“main out-of-step mode” and “minor out-of-step mode”—are proposed for power system reliability analysis. Large-scale power system studies found that out-of-step generator groups may have characteristics of the main out-of-step mode and the minor out-of-step mode. The generator groups with main out-of-step modes can determine the out-of-step interface of the large-scale power system,while generators with the minor out-of-step modes cannot play such a role. Therefore,the method of capturing the out-of-step interface by seeking the lowest voltage point(the out-of-step center) can only group the generators with the main out-of-step modes,and may fail to combine the generators with the minor out-of-step modes into proper coherent generator groups. Thus,it is necessary in engineering applications to equip the generators that are likely to have the characteristics of the minor out-of-step modes with separation devices based on off-line simulation studies in order to reduce the risk of further accidents caused by these generators after system separation.

新型沙漏形隔磁结构的主副齿式永磁游标电机的设计与分析

基于传统交替极双定子分裂齿式永磁游标电机的拓扑结构提出一种新型沙漏形隔磁结构的主副齿式永磁游标电机,旨在进一步提高电机转矩密度和解决永磁体极间漏磁的问题。依据磁场调制原理,首先对定子主齿和副齿的结构参数进行优化设计,主齿的调节作用使低速旋转永磁体磁场和高速旋转电枢磁场进行耦合,副齿对气隙磁场进一步调节产生其他次有效谐波增加电机的同步转矩分量。在永磁体两侧引入沙漏形隔磁结构,该结构不仅抑制极间泄漏,而且大大降低永磁体径向应力和径向形变;并探究永磁体极弧系数对转矩及功率因数的影响,确定优化设计后的模型参数。最后用有限元仿真结果验证了沙漏形隔磁结构的主副齿式永磁游标电机的优越性,相较于传统的分裂齿式永磁游标电机,该电机具有更大的转矩和更小的转矩脉动。

小保当一号煤矿特大型智能主运输系统设计

针对小保当煤矿主运输系统大运量、高带速、高带强的特点,进行了技术方案的分析研究并对各部带式输送机均采用了最佳配置设计。文章介绍了采用多项国内外先进技术对主运输系统的各个具体环节进行的优化设计,包括:采用智能化设计技术,实现主运输系统的远程集中控制、协同运行和无人值守;采用特大型装备设计技术,对系统关键位置及重要部件进行分析研究,确保安全;采用井下煤水分离技术,对原煤进行脱水处理,避免“水煤”隐患;采用动力学分析技术,对多种不利工况下的输送带张力特性进行模拟,优化设备布置。最终实现了国内井下总运输距离最长、装机总容量最大的煤炭主运输系统的智能化、无人化长期连续平稳运行,为国内特大型矿井的煤炭主运输系统设计起到了引领示范作用。

基于多PRI脉压回波的单通道雷达干扰分离方法

研究了一种基于盲源分离的单通道雷达有源相干干扰抑制方法。针对伴随式干扰场景,在间歇采样转发干扰、部分脉冲密集转发干扰等有源相干干扰并存的条件下,建立了基于脉冲压缩的多脉冲重复间隔采样抗主瓣有源相干干扰模型并对其可行性进行了证明。针对现有单通道盲源分离方法在时域进行分离效果有限的问题,提出对脉压后的距离维数据进行盲源分离的思想,可在一定程度上抑制噪声对盲源分离的影响。同时,由于目标信号和干扰信号在脉冲压缩后重合度较低,可获得更好的分离效果。仿真和实测结果表明,在多个干扰源存在的条件下,本方法可有效分离真实目标回波和干扰回波。当信噪比大于5 dB时,目标脉压回波相似系数接近100%;选取虚拟通道数越多,分离效果越好。

集沙仪内二次流对沙尘收集范围的影响分析

二次流动是工程实际中普遍存在的物理现象,是一种相对于主流的次要流动。为研究集沙仪内二次流对气流速度、不同粒径的沙尘粒子的影响规律,利用数值模拟和试验验证相结合的方法,以分流对冲与多级扩容式集沙仪的风沙分离器为研究对象,对二次流被削弱前后的流场特性进行分析。研究结果表明:在二次流被削弱前,粒径大于0.083 mm的沙尘被完全收集,粒径小于0.083 mm的沙尘被大部分收集;在二次流被削弱后,高速气流分布范围更大,流场似乎变得不稳定,排气管内气流速度明显增高,粒径大于0.12 mm的沙尘才被完全收集,沙尘被完全收集的范围明显缩小。

Numerical Study of the Feed Flow and Its Influence on the Separation Efficiency of a Gas Centrifuge

In a Zippe-type 3-pole gas centrifuge, feed gas is introduced through a sonic nozzle into the rarefied region in the rotor. Introduction of the nonrotating feed gas will slow the whirl flow and introduce a secondary recirculating flow in the meridian plane. The effects of feed gas on the output of a gas centrifuge are investigated. The non-linear. axisymmetric N-S equations are used to calculate the secondary flow induced by the feed gas. Three types of numerical schemes. an implicit scheme similar to the Beam-Warming scheme. an implicit unfactorized scheme and an improved Newton-Raphson scheme are used. The Cohen separation theory with axial variation is used forcalculating the isotope concentration. Optimization of the output is achieved by automatic variation of the weighting factors for a number of linear flow solutions which can be superimposed. A Rome type centrifuge is analyzed as an example. Results show the recirculating flow caused by the feed gas. especially the acceleration loss. has an important effect on the output of a gas centrifuge.