Essential oil, with more than thirty kinds of compounds separated and identified by gas chromatography-mass spectrometry, was extracted from Shatian shaddock peel and Sweet shaddock peel by squeeze-steam distillation ...Essential oil, with more than thirty kinds of compounds separated and identified by gas chromatography-mass spectrometry, was extracted from Shatian shaddock peel and Sweet shaddock peel by squeeze-steam distillation and direct steam distillation method. Among their composition, the main components are terpene compounds, which account for 93.926% (mass fraction, the same below) and 85.843% of essential oils extracted from Shatian shaddock peel and Sweet shaddock peel, respectively. Although nootkatone is the major contributor of shaddock characteristic scent, and its contents are 1.069% and 1.749% of essential oils from Sweet shaddock peel and Shatian shaddock peel, respectively. The results show that squeeze-steam distillation gives higher yield and good quality of essential oil and the compositions of essential oils from two kinds of shaddock peels are different, but the main contributors of the shaddock scent are the same.展开更多
Pectins had been extracted from shaddock raw material with 0.01 mol·L^-1 HCI and with three enzymic preparations including cellulase from aspergillus oryzaei.β -glucosidase from almonds and protopectinases-T, a ...Pectins had been extracted from shaddock raw material with 0.01 mol·L^-1 HCI and with three enzymic preparations including cellulase from aspergillus oryzaei.β -glucosidase from almonds and protopectinases-T, a protopectin-solubilizing enzyme, which did not degrade polygalacturonic acid, The effects of enzymic and acid soluhilization of pectin from shaddock materials were compared, The yield of pectin preparations, degree of acetylation, gelling strength, molecular weight and viscosity were determined. Enzymic methods of extraction gave much bigger yields of pectic substances. Compared with the pectin extracted with hydrochloric acid, all the samples derived from shaddock raw material with enzymic preparations had a significant lower D-galacturonic acid content.展开更多
High applied thermal-stability and superior structural property for activated carbon adsorbent are extremely promising,which also is the determining short slab in volatile organic compounds(VOCs)adsorption application...High applied thermal-stability and superior structural property for activated carbon adsorbent are extremely promising,which also is the determining short slab in volatile organic compounds(VOCs)adsorption applications.Herein,we develop the outstanding engineering carbon adsorbents from waste shaddock peel which affords greatly-enhanced thermal-stability and super structural property(S_(Lang)=4962.6 m2·g^(-1),Vmicro=1.67 cm^(3)·g^(-1)).Such character endows the obtained adsorbent with ultrahigh adsorption capture performance of VOCs specific to benzene(16.58 mmol·g^(-1))and toluene(15.50 mmol·g^(-1),far beyond traditional zeolite and activated carbon even MOFs materials.The structural expression characters were accurately correlated with excellent adsorption efficiency of VOCs by studying synthetic factor-controlling comparative samples.Ulteriorly,adsorption selectivity prediction at different relative humidity was demonstrated through DIH(difference of the isosteric heats),exceedingly highlighting great superiority(nearly sixfold)in selective adsorption of toluene compared to volatile benzene.Our findings provide the possibility for practical industrial application and fabrication of waste biomass-derived outstanding biochar adsorbent in the environmental treatment of threatening VOCs pollutants.展开更多
[Objective] The precipitation conditions of salting out method for extracting shaddock peel pectin were studied.[Method] Taking shaddock peel as the raw material, the optimal technological conditions for pectin precip...[Objective] The precipitation conditions of salting out method for extracting shaddock peel pectin were studied.[Method] Taking shaddock peel as the raw material, the optimal technological conditions for pectin precipitation were obtained by precipitating shaddock peel under dif-ferent salting-out conditions.[Result] The optimal conditions of salting out method for precipitating shaddock peel pectin were as follows: aluminum sulfate saturated solution: pectin extract 1∶1, salting out time 60 min, salting out temperature 60℃, salting out pH 4, and the extraction rate reached 6.8%.[Conclusion] Precipitation of pectin through salting out method reduced the consumption of ethanol, energy consumption and production cost.展开更多
After water imbibition, the outer layer seed coat of shaddock (Citrus grandis Osbeck) produces transparent gel-like mucilage (MSS), but its characteristics have never been studied before. This study aimed to assess th...After water imbibition, the outer layer seed coat of shaddock (Citrus grandis Osbeck) produces transparent gel-like mucilage (MSS), but its characteristics have never been studied before. This study aimed to assess the physico-chemical and functional properties of MSS. Extractions of MSS with deionized water at room temperature yielded about 3.5% based on the dry weight of seed. The major components were neutral sugars and uronic acids in the amounts of 33.5% and 49.6%, respectively. The acidic nature of MSS was confirmed by ruthenium red staining. Its water holding capacity and viscosity were 44.53 g•g<sup>-1</sup> DW and 1660 cP at 10 g/L, respectively. MSS showed a weak quenching activity against DPPH radical, and moderate ferrous ion-chelating and superoxide anion radical scavenging activities, with IC<sub>50</sub> value of 1.5 g/L and 1.1 g/L, respectively. A methyl thiazolyl tetrazolium (MTT) assay demonstrated that MSS significantly stimulated the viability of mouse skin fibroblasts (NIH/3T3) at 5 - 300 mg/L. These results impart the potential usefulness of the MSS to food, cosmetics and other applications.展开更多
文摘Essential oil, with more than thirty kinds of compounds separated and identified by gas chromatography-mass spectrometry, was extracted from Shatian shaddock peel and Sweet shaddock peel by squeeze-steam distillation and direct steam distillation method. Among their composition, the main components are terpene compounds, which account for 93.926% (mass fraction, the same below) and 85.843% of essential oils extracted from Shatian shaddock peel and Sweet shaddock peel, respectively. Although nootkatone is the major contributor of shaddock characteristic scent, and its contents are 1.069% and 1.749% of essential oils from Sweet shaddock peel and Shatian shaddock peel, respectively. The results show that squeeze-steam distillation gives higher yield and good quality of essential oil and the compositions of essential oils from two kinds of shaddock peels are different, but the main contributors of the shaddock scent are the same.
基金The Key Program of Science and Technology Office of Hunan Province (00KNY1010)
文摘Pectins had been extracted from shaddock raw material with 0.01 mol·L^-1 HCI and with three enzymic preparations including cellulase from aspergillus oryzaei.β -glucosidase from almonds and protopectinases-T, a protopectin-solubilizing enzyme, which did not degrade polygalacturonic acid, The effects of enzymic and acid soluhilization of pectin from shaddock materials were compared, The yield of pectin preparations, degree of acetylation, gelling strength, molecular weight and viscosity were determined. Enzymic methods of extraction gave much bigger yields of pectic substances. Compared with the pectin extracted with hydrochloric acid, all the samples derived from shaddock raw material with enzymic preparations had a significant lower D-galacturonic acid content.
基金financially supported by National Natural Science Foundation of China (21908085)Natural Science Foundation of Jiangsu Province, China (BK20190961)+2 种基金Postdoctoral Research Foundation of Jiangsu Province (2020Z291)Foundation from Marine Equipment and Technology Institute for Jiangsu University of Science and Technology, China (HZ20190004)High-tech Ship Research Project of the Ministry of Industry and Information Technology, China (No. [2017] 614)
文摘High applied thermal-stability and superior structural property for activated carbon adsorbent are extremely promising,which also is the determining short slab in volatile organic compounds(VOCs)adsorption applications.Herein,we develop the outstanding engineering carbon adsorbents from waste shaddock peel which affords greatly-enhanced thermal-stability and super structural property(S_(Lang)=4962.6 m2·g^(-1),Vmicro=1.67 cm^(3)·g^(-1)).Such character endows the obtained adsorbent with ultrahigh adsorption capture performance of VOCs specific to benzene(16.58 mmol·g^(-1))and toluene(15.50 mmol·g^(-1),far beyond traditional zeolite and activated carbon even MOFs materials.The structural expression characters were accurately correlated with excellent adsorption efficiency of VOCs by studying synthetic factor-controlling comparative samples.Ulteriorly,adsorption selectivity prediction at different relative humidity was demonstrated through DIH(difference of the isosteric heats),exceedingly highlighting great superiority(nearly sixfold)in selective adsorption of toluene compared to volatile benzene.Our findings provide the possibility for practical industrial application and fabrication of waste biomass-derived outstanding biochar adsorbent in the environmental treatment of threatening VOCs pollutants.
基金Supported by Guangxi Scientific Research and Technology Development Plan "Construction of Science and Technology Service Platform of Hezhou Agricultural Science and Technology Park"(GKN14258003)Research Project of Hezhou University(HZUJS201617)
文摘[Objective] The precipitation conditions of salting out method for extracting shaddock peel pectin were studied.[Method] Taking shaddock peel as the raw material, the optimal technological conditions for pectin precipitation were obtained by precipitating shaddock peel under dif-ferent salting-out conditions.[Result] The optimal conditions of salting out method for precipitating shaddock peel pectin were as follows: aluminum sulfate saturated solution: pectin extract 1∶1, salting out time 60 min, salting out temperature 60℃, salting out pH 4, and the extraction rate reached 6.8%.[Conclusion] Precipitation of pectin through salting out method reduced the consumption of ethanol, energy consumption and production cost.
文摘After water imbibition, the outer layer seed coat of shaddock (Citrus grandis Osbeck) produces transparent gel-like mucilage (MSS), but its characteristics have never been studied before. This study aimed to assess the physico-chemical and functional properties of MSS. Extractions of MSS with deionized water at room temperature yielded about 3.5% based on the dry weight of seed. The major components were neutral sugars and uronic acids in the amounts of 33.5% and 49.6%, respectively. The acidic nature of MSS was confirmed by ruthenium red staining. Its water holding capacity and viscosity were 44.53 g•g<sup>-1</sup> DW and 1660 cP at 10 g/L, respectively. MSS showed a weak quenching activity against DPPH radical, and moderate ferrous ion-chelating and superoxide anion radical scavenging activities, with IC<sub>50</sub> value of 1.5 g/L and 1.1 g/L, respectively. A methyl thiazolyl tetrazolium (MTT) assay demonstrated that MSS significantly stimulated the viability of mouse skin fibroblasts (NIH/3T3) at 5 - 300 mg/L. These results impart the potential usefulness of the MSS to food, cosmetics and other applications.
