Brownshale is a lithology unit in the middle of the Pematang Formation consisting of brown to black shale that is deposited in the lacustrine environment. Brownshale from the results of previous studies stated as the ...Brownshale is a lithology unit in the middle of the Pematang Formation consisting of brown to black shale that is deposited in the lacustrine environment. Brownshale from the results of previous studies stated as the main source rock in the Central Sumatra Basin, which is spread over several troughs, namely Balam, Aman, Rangau, Kiri, and Bengkalis Troughs, where Bengkalis Trough is the most extensive Trough. In the shale hydrocarbon prospecting analysis, Brownshale from previous researchers concluded that it had good prospects, based on several parameters including: TOC values with poor to very good quality. Brownshale formation is a type of kerogene as kerogen type of II/III, brittleness index greater than 0.48, and rock compressive strength below 10,000 Psi. One method in the development phase of shale hydrocarbon is to determine the fracable sweetspot window using drill cuttings and TOC, because there is no core data available. Based on the results of the well log analysis of well BS-03, it is obtained information that the Brownshale formation has a thickness of 1028 feet with intercalation laminated shale/sand section, so the mineral content varies greatly. From the ternary diagram of XRD (bulk analysis) results of drill cuttings of Brownshale formation of well BS-03, it can be seen that mineral distribution of Quartz-Clay-Calcite (Q-C-C) is spread between zone 1 to zone 3, namely: Dominant Quartz - Minor Clay & Carbonate (Zone 1: Brittle Quartz Rich), Dominant Carbonate - Quartz & Minor Clay (Zone 2: Brittle Carbonate Rich), and Quartz & Carbonate Balance - Clay minor (Zone 3: Ductile, hard to frac). This shows that not all Brownshale formation intervals are easy to frac (high fracability). From the XRD result, percentage of mineral content (bulk analysis) of Brownshale drill cuttings, there is an interesting phenomenon, <i>i.e. </i> the presence of sillimanite and kaliophilite minerals significantly starting at a depth of 10,780 ft and below, where both minerals have tenacity: brittle, and also from the results of the MBT analysis seen an interesting phenomenon, <i>i.e. </i> at a depth interval of about 10,780 ft the value of CEC drops below 3 meq/100 grams, and can be categorized as the brittle shale. Referring to the presence of sillimanite and kaliophilite minerals, as well as low MBT values, then at intervals of 10,780 ft below, it can be seen that at the bottom of the depth interval as a fracable sweetspot window, and at the upper depth interval of the Brownshale formation, it is believed to be a fracture barrier.展开更多
Sillimanite is a brittle mineral as a metamorphic mineral product which is generally derived from clay, along with an increase in pressure and high temperature (600°C - 900°C), and kaliophilite is also a bri...Sillimanite is a brittle mineral as a metamorphic mineral product which is generally derived from clay, along with an increase in pressure and high temperature (600°C - 900°C), and kaliophilite is also a brittle mineral as a potassium bearing in the sand-shale series, which contributes to the clay diagenesis process. In the development of shale hydrocarbon in the Brownshale formation in the Bengkalis Trough, Central Sumatra Basin, using the correlation of the XRD (bulk and clay oriented), TOC, Ro, and MBT analysis results from the drill cuttings of well BS-03, so that the fracable zone interval can be determined. From this correlation, it shows that the presence of sillimanite and kaliophilite minerals as minor minerals greatly affects the changes in shale character and hydrocarbon generation, where at depth intervals of 10,780 ft downward (sand series-shale) there is an interesting phenomenon, <i>i.e. </i> low MBT, low TOC, and high Ro, so it is believed that the depth interval of 10,780 ft downward is a fracable zone interval (brittle shale) which is a good candidate for hydraulic fracking planning, while the upper depth interval is a fracture barrier.展开更多
In China, hot researches on shale oil were raised by the important breakthrough of shale oil in America. Obviously, the first important issue is the actual shale oil resource potential of China, and the selection of t...In China, hot researches on shale oil were raised by the important breakthrough of shale oil in America. Obviously, the first important issue is the actual shale oil resource potential of China, and the selection of the key appraisement parameter is vital to the shale oil resource amount. Among the appraisement parameters, the oil content parameter（S1） is the key one, but the evaluation result is generally lower because of light hydrocarbon losing and heavy hydrocarbon handling. And the more important thing is that the light hydrocarbon with small molecular weight is more recoverable, and therefore its amount is important to the total shale oil yields. Based on pyrolysis experiments and the kinetic model of hydrocarbon generation, correction factors and a model of light hydrocarbon losing and heavy hydrocarbon handling were established. The results show that the correction factor of heavy hydrocarbon handling is 3.2, and that of light hydrocarbon losing is controlled by kerogen type, maturity and hydrocarbon generation environment（closed or open）.展开更多
The kinetic parameters of hydrocarbon generation are determined through experimental simulation and mathematical calculation using four typical samples selected from the Cretaceous Nenjiang Formation in the northwest ...The kinetic parameters of hydrocarbon generation are determined through experimental simulation and mathematical calculation using four typical samples selected from the Cretaceous Nenjiang Formation in the northwest of Songliao Basin,Chang 7 Member of Triassic Yanchang Formation in the southwest of Ordos Basin,Paleogene in the southwest of Qaidam Basin,and Lucaogou Formation of Jimusar Sag in the east of Junggar Basin.The results show that activation energy of hydrocarbon generation of organic matter is closely related to maturity and mainly ranges between 197 kJ/mol and 227 kJ/mol.On this basis,the temperature required for organic matter in shale to convert into oil was calculated.The ideal heating temperature is between 270℃and 300℃,and the conversation rate can reach 90%after 50-300 days of heating at constant temperature.When the temperature rises at a constant rate,the temperature corresponding to the major hydrocarbon generation period ranges from 225 to 350℃at the temperature rise rate of 1-150℃/month.In order to obtain higher economic benefits,it is suggested to adopt higher temperature rise rate(60-150℃/month).The more reliable kinetic parameters obtained can provide a basis for designing more reasonable scheme of in-situ heating conversion.展开更多
文摘Brownshale is a lithology unit in the middle of the Pematang Formation consisting of brown to black shale that is deposited in the lacustrine environment. Brownshale from the results of previous studies stated as the main source rock in the Central Sumatra Basin, which is spread over several troughs, namely Balam, Aman, Rangau, Kiri, and Bengkalis Troughs, where Bengkalis Trough is the most extensive Trough. In the shale hydrocarbon prospecting analysis, Brownshale from previous researchers concluded that it had good prospects, based on several parameters including: TOC values with poor to very good quality. Brownshale formation is a type of kerogene as kerogen type of II/III, brittleness index greater than 0.48, and rock compressive strength below 10,000 Psi. One method in the development phase of shale hydrocarbon is to determine the fracable sweetspot window using drill cuttings and TOC, because there is no core data available. Based on the results of the well log analysis of well BS-03, it is obtained information that the Brownshale formation has a thickness of 1028 feet with intercalation laminated shale/sand section, so the mineral content varies greatly. From the ternary diagram of XRD (bulk analysis) results of drill cuttings of Brownshale formation of well BS-03, it can be seen that mineral distribution of Quartz-Clay-Calcite (Q-C-C) is spread between zone 1 to zone 3, namely: Dominant Quartz - Minor Clay & Carbonate (Zone 1: Brittle Quartz Rich), Dominant Carbonate - Quartz & Minor Clay (Zone 2: Brittle Carbonate Rich), and Quartz & Carbonate Balance - Clay minor (Zone 3: Ductile, hard to frac). This shows that not all Brownshale formation intervals are easy to frac (high fracability). From the XRD result, percentage of mineral content (bulk analysis) of Brownshale drill cuttings, there is an interesting phenomenon, <i>i.e. </i> the presence of sillimanite and kaliophilite minerals significantly starting at a depth of 10,780 ft and below, where both minerals have tenacity: brittle, and also from the results of the MBT analysis seen an interesting phenomenon, <i>i.e. </i> at a depth interval of about 10,780 ft the value of CEC drops below 3 meq/100 grams, and can be categorized as the brittle shale. Referring to the presence of sillimanite and kaliophilite minerals, as well as low MBT values, then at intervals of 10,780 ft below, it can be seen that at the bottom of the depth interval as a fracable sweetspot window, and at the upper depth interval of the Brownshale formation, it is believed to be a fracture barrier.
文摘Sillimanite is a brittle mineral as a metamorphic mineral product which is generally derived from clay, along with an increase in pressure and high temperature (600°C - 900°C), and kaliophilite is also a brittle mineral as a potassium bearing in the sand-shale series, which contributes to the clay diagenesis process. In the development of shale hydrocarbon in the Brownshale formation in the Bengkalis Trough, Central Sumatra Basin, using the correlation of the XRD (bulk and clay oriented), TOC, Ro, and MBT analysis results from the drill cuttings of well BS-03, so that the fracable zone interval can be determined. From this correlation, it shows that the presence of sillimanite and kaliophilite minerals as minor minerals greatly affects the changes in shale character and hydrocarbon generation, where at depth intervals of 10,780 ft downward (sand series-shale) there is an interesting phenomenon, <i>i.e. </i> low MBT, low TOC, and high Ro, so it is believed that the depth interval of 10,780 ft downward is a fracable zone interval (brittle shale) which is a good candidate for hydraulic fracking planning, while the upper depth interval is a fracture barrier.
基金supported by "the Fundamental Research Funds for the Central Universities" (14CX05017A)the Natural Science Foundation of China (41330313)+1 种基金Program for New Century Excellent Talents in Heilongjiang Provincial University (1252-NCET-012)CNPC Innovation Foundation (2011D-5006-0101)
文摘In China, hot researches on shale oil were raised by the important breakthrough of shale oil in America. Obviously, the first important issue is the actual shale oil resource potential of China, and the selection of the key appraisement parameter is vital to the shale oil resource amount. Among the appraisement parameters, the oil content parameter（S1） is the key one, but the evaluation result is generally lower because of light hydrocarbon losing and heavy hydrocarbon handling. And the more important thing is that the light hydrocarbon with small molecular weight is more recoverable, and therefore its amount is important to the total shale oil yields. Based on pyrolysis experiments and the kinetic model of hydrocarbon generation, correction factors and a model of light hydrocarbon losing and heavy hydrocarbon handling were established. The results show that the correction factor of heavy hydrocarbon handling is 3.2, and that of light hydrocarbon losing is controlled by kerogen type, maturity and hydrocarbon generation environment（closed or open）.
基金Supported by the PetroChina Science and Technology Major Project(2016E-0101).
文摘The kinetic parameters of hydrocarbon generation are determined through experimental simulation and mathematical calculation using four typical samples selected from the Cretaceous Nenjiang Formation in the northwest of Songliao Basin,Chang 7 Member of Triassic Yanchang Formation in the southwest of Ordos Basin,Paleogene in the southwest of Qaidam Basin,and Lucaogou Formation of Jimusar Sag in the east of Junggar Basin.The results show that activation energy of hydrocarbon generation of organic matter is closely related to maturity and mainly ranges between 197 kJ/mol and 227 kJ/mol.On this basis,the temperature required for organic matter in shale to convert into oil was calculated.The ideal heating temperature is between 270℃and 300℃,and the conversation rate can reach 90%after 50-300 days of heating at constant temperature.When the temperature rises at a constant rate,the temperature corresponding to the major hydrocarbon generation period ranges from 225 to 350℃at the temperature rise rate of 1-150℃/month.In order to obtain higher economic benefits,it is suggested to adopt higher temperature rise rate(60-150℃/month).The more reliable kinetic parameters obtained can provide a basis for designing more reasonable scheme of in-situ heating conversion.
