Nonlinear dynamic characteristics and optimal control of a giant magnetostrictive film-shaped memory alloy composite plate subjected to in-plane stochastic excitation

The nonlinear dynamic characteristics and optimal control of a giant magnetostrictive film （GMF）-shaped memory alloy （SMA） composite plate subjected to in-plane stochastic excitation are studied. GMF is prepared based on an SMA plate, and combined into a GMF-SMA composite plate. The Van der Pol item is improved to explain the hysteretic phenomena of GMF and SMA, and the nonlinear dynamics model of a GMF-SMA composite cantilever plate subjected to in-plane stochastic excitation is developed. The stochastic stability of the system is analyzed, and the steady-state probability density function of the dynamic response of the system is obtained. The condition of stochastic Hopf bifurcation is discussed, the reliability function of the system is provided, and then the probability density of the first-passage time is given. Finally, the stochastic optimal control strategy is proposed by the stochastic dynamic programming method. Numerical simulation shows that the stability of the trivial solution varies with bifurcation parameters, and stochastic Hopf bifurcation appears in the process; the system＇s reliability is improved through stochastic optimal control, and the first- passage time is delayed. A GMF-SMA composite plate combines the advantages of GMF and SMA, and can reduce vibration through passive control and active control effectively. The results are helpful for the engineering applications of GMF-SMA composite plates.

STUDY ON THE RESPONSE TO LOW-VELOCITY IMPACT OF A COMPOSITE PLATE IMPROVED BY SHAPE MEMORY ALLOY

Improvement from the pseudo-elastic effect of shape memory alloy （SMA） on the low-velocity impact （LVI） resistance of a composite plate is investigated by the finite element method （FEM）. The stiffness matrix of the dynamic finite element equation is established step by step and the martensite fraction is obtained at each time step. The direct Newmark integration method is employed in solving the dynamic finite element equation, while the impact contact force is determined using the modified Hertz＇s law. It is found that SMA can effectively improve the performance of a composite structure subjected to low-velocity impact. Numerical results show that the deflection of a SMA-hybrid composite plate has been reduced approximately by thirty percent when the volume fraction of the embedded SMA reaches 0.3.

Electrochemical behavior of Cu-Zn-Al shape memory alloy after surface modification by electroless plated Ni-P

The electrochemical behavior of Cu-Zn-Al shape memory alloy (SMA) with andwithout electroless plated Ni-P was investigated by electrochemical methods, in artificial Tyrode'ssolution. The results showed that Cu-Zn-Al SMA engendered dezincification corrosion in Tyrode'ssolution. The anodic active current densities as well as electrochemical dissolution sensitivity ofthe electroless plated Ni-P Cu-Zn-Al SMA increased with NaCl concentration rising, pH of solutiondecreasing and environmental temperature uprising. X-ray diffraction analysis indicated that aftersurface modification by electroless plated Ni-P, an amorphous plated film formed on the surface ofCu-Zn-Al SMA. This film can effectively isolate matrix metal from corrosion media and significantlyimprove the electrochemical property of Cu-Zn-Al SMA in artificial Tyrode's solution.

LOW VELOCITY RESPONSE CHARACTERISTICS OF COMPOSITE PLATE WITH EMBEDDED SHAPE MEMORY ALLOY

This paper analyzes the characteristics of utilizing shape memory e?ect (SME) of shape memory alloy (SMA) in improving the low velocity impact resistance performance of com- posite plate by using ?nite element method. The constitutive relation for SMA hybrid composite plates is presented. The analytic model of ?nite element for SMA composite plate subjected to low velocity impact is established. The modi?ed Hertz’s contact law is used to determine the impact contact force. The computing procedures for solving the ?nite element equation using Newmark direct integration method are given. The numerical modelling results show that the SMA can e?ectively improve the low velocity impact resistance performance of composite plate.

Piecewise Linear Analysis for Pseudo-elasticity of Shape Memory Alloy (SMA)

Based on the Brinson constitutive model of SMA, a piecewise linear model for the hysteresis loop of pseudo-elasticity is proposed and applied in the analysis of responses of an SMA-spring-mass system under initial velocity activation. The histories of displacement and velocity of the mass, and the response of stress of SMA are calculated with Brinson’s model and the piecewise linear model. The difference of results of the two models is not significant. The calculation with piecewise-linear model needs no iteration and is highly efficient.

STRUCTURAL HEALTH MONITORING IN COMPOSITE MATERIALS USING EMBEDDED SHAPE MEMORY ALLOY(SMA) WIRE SENSORS

Shape memory alloy （SMA） materials possess completely superelasticity or pseudoelasticity above the austenite finish temperature and many unique mechanical, thermal, thermal-mechanical and electrical properties compared with other conventional materials. Many studies have reported that the superelastic and hysteresis properties of the SMA materials can absorb energies coming from external excitations or sudden impacts. In addition, due to the special electrical properties of NiTi superelastic wires, they can also be used as strain-sensing element to monitor structural health conditions. Composite laminated specimens embedded with SMA wire sensors are fabricated and detailed testing system is designed such as multi-parameters measuring for impact and weak signal processing for SMA sensor. Low velocity impact test shows that SMA wire sensors embedded in fiber-reinforced plastic （FRP） laminate can be well used to monitor impact responses, such as the location of impact damage, impact degree, and strain distribution. Experimental results and theoretical predictions reveal almost the same. Comparing with other method, a simple, economic and reliable technique method monitoring important engineering structures on line is provided.

A Computational Fluid Dynamics (CFD) Analysis of an Undulatory Mechanical Fin Driven by Shape Memory Alloy

Many fishes use undulatory fin to propel themselves in the underwater environment. These locomotor mechanisms have a popular interest to many researchers. In the present study, we perform a three-dimensional unsteady computation of an undulatory mechanical fin that is driven by Shape Memory Alloy （SMA）. The objective of the computation is to investigate the fluid dynamics of force production associated with the undulatory mechanical fin. An unstructured, grid-based, unsteady Navier-Stokes solver with automatic adaptive remeshing is used to compute the unsteady flow around the fin through five complete cycles. The pressure distribution on fin surface is computed and integrated to provide fin forces which are decomposed into lift and thrust. The velocity field is also computed throughout the swimming cycle. Finally, a comparison is conducted to reveal the dynamics of force generation according to the kinematic parameters of the undulatory fin （amplitude, frequency and wavelength）.

Role of Ag addition on microstructure,mechanical properties,corrosion behavior and biocompatibility of porous Ti-30 at%Ta shape memory alloys

In the present study,the thermal,mechanical,and biological properties of xAg/Ti-30Ta(x=0,0.41,0.82 and 2.48 at%)shape memory alloys(SMAs)were investigated.The study was conducted using optical and scanning electron microscopy(SEM),X-ray diffractometry(XRD),compression test,and shape memory testing.The xAg/Ti-Ta was made using a powder metallurgy technique and microwave-sintering process.The results revealed that the addition of Ag has a significant effect on the pore size and shape,whereas the smallest pore size of 11μm was found with the addition of 0.41 at%along with a relative density of 72%.The fracture stress and strain increased with the addition of Ag,reaching the minimum values around 0.41 at%Ag.Therefore,this composition showed the maximum stress and strain at fracture region.Moreover,0.82 Ag/Ti-Ta shows more excellent corrosion resistance and biocompatibility than other percentages,obtaining almost the same behaviour of the pure Ti and Ti-6Al-4V alloys,which can be recommended for their promising and potential response for biomaterial applications.

Ingredient Losses during Melting Binary Ni-Ti Shape Memory Alloys

Losses of the alloying elements during vacuum induction melting of the binary NiTi alloys were evaluated by visual observation and chemical analysis of the NiTi melted specimens and the scalp formed on the internal surface of the crucible. The results indicated that the major sources of the losses were （a） evaporation of the metals, （b） formation of the NiTi scalp and （c） the sprinkling drops splashed out of the melt due to the exothermic reactions occurring between Ni and Ti to form the NiTi parent phase. Quantitative evaluations were made for the metallic losses by holding the molten alloy for 0.5, 3, 5, 10 and 15 min at around 100℃ above the melting point inside the crucible.Chemical analysis showed that there existed an optimum holding time of 3 min during which the alloying elements were only dropped to a predictable limit. Microstructure, chemical composition, shape memory and mechanical properties of the cast metal ingots were determined to indicate the appropriate achievements with the specified 3 min optimum holding time.

Review:Recent advances in nonlinear control technologies for shape memory alloy actuators

This paper reviews recent developments in nonlinear control technologies for shape memory alloy (SMA) actuators in robotics and their related applications. SMA possesses large hysteresis, low bandwidth, slow response, and non-linear behavior, which make them difficult to control. The fast response of the SMA actuator mostly depends upon, (1) type of controller, (2) rate of addition and removal of heat, and (3) shape or form of the actuator. Though linear controllers are more desirable than nonlinear ones, the review of literature shows that the results obtained using nonlinear controllers were far better than the former one. Therefore, more emphasis is made on the nonlinear control technologies taking into account the intelligent controllers. Various forms of SMA actuator along with different heating and cooling methods are presented in this review, followed by the nonlinear control methods and the control problems encountered by the researchers.

Kinetic grain growth, shape memory and corrosion behavior of two Cu-based shape memory alloys after thermomechanical treatment

Metallurgical and mechanical properties along with shape memory and corrosion behavior of Cu-11.8% AI-3.7% Ni-1 %Mn and Cu-11% A1 5.6% Mn shape memory alloys （SMAs） were comparatively studied. The influence of grain refinement on the properties was studied by optical microscopy （OM）, scanning electron microscopy （SEM）, differential scanning calorimetry （DSC）, potentiodynamic polarizations and bend and tensile tests. Static recrystallization and kinetic grain growth show a rapid recrystallization in the first 15 s of annealing at 800℃ followed by grain growths. The minimum grain sizes obtained after 15 s are 90 and 260 μm for Cu-A1-Ni-Mn and Cu-A1-Mn, respectively. Tensile tests show typical three-stage curves for both alloys, and it is seen that alloys exhibit high fracture stress and strain after grain refinement. Microstructural observations show zig-zag morphology of β 1martensite in the Cu-A1-Ni-Mn and coexistence of β1 and y1 in the Cu-A1-Mn, which were confirmed by differential scanning calorimetry results. The shape memory ratios （17） of the alloys before thermomechanieal treatment, and after thermomechanical annealing at 800 ℃ for different time up to 15 min followed by water quenching, were evaluated. In addition, corrosion behavior of alloys after grain refinement was analyzed by means of potentiodynamic polarization measurements. The results showed that the anodic reactions were dominated by dissolution of copper, and Cu-AI-Ni-Mn alloy exhibits a better corrosion resistance than Cu-A1-Mn alloy.

In situ synthesis of nanostructured titania film on NiTi shape memory alloy by Fenton’s oxidation method

Fenton’s oxidation method was successfully used to synthesize an ideal titania film in situ on NiTi shape memory alloy(SMA) for medical applications. Characterized with scanning electron microscopy, X-ray photoelectron spectroscopy, X-ray diffractometry, inductively coupled plasma mass spectrometry and electrochemical tests, it is found that the titania film produced by Fenton’s oxidation method on NiTi SMA is nanostructured and has a Ni-free zone near its top surface, which results in a notable improvement in corrosion resistance and a remarkable decrease in leaching of harmful Ni ions from NiTi SMA in simulated body fluids. The improvement of effectiveness to corrosion resistance and the reduction in Ni release of NiTi SMA by Fenton’s oxidation method are comparable to those by oxygen plasma immersion ion implantation reported earlier.

Thermo-mechanical Behaviors of Functionally Graded Shape Memory Alloy Timoshenko Composite Beams

This paper focuses on the thermo-mechanical behaviors of functionally graded(FG)shape memory alloy(SMA)composite beams based on Timoshenko beam theory.The volume fraction of SMA fiber is graded in the thickness of beam according to a power-law function and the equivalent parameters are formulated.The governing differential equations,which can be solved by direct integration,are established by employing the composite laminated plate theory.The influences of FG parameter,ambient temperature and SMA fiber laying angle on the thermo-mechanical behaviors are numerically simulated and discussed under different boundary conditions.Results indicate that the neutral plane does not coincide with the middle plane of the composite beam and the distribution of martensite is asymmetric along the thickness.Both the increments of the functionally graded parameter and ambient temperature make the composite beam become stiffer.However,the influence of the SMA fiber laying angle can be negligent.This work can provide the theoretical basis for the design and application of FG SMA structures.

New finite strain elastoplastic equations for accurately and explicitly simulating pseudoelastic-to-plastic transition effects of shape memory alloys

A new finite strain elatoplastic J2-flow model with coupling effects of both isotropic and anisotropic hardening is proposed with the co-rotational logarithmic rate.In terms of certain single-variable shape functions representing uniaxial loading and unloading curves,explicit multi-axial expressions for the three hardening quantities incorporated in the new model proposed are derived in unified forms for the purpose of automatically and accurately simulating complex pseudoelastic-to-plastic transition effects of shape memory alloys(SMAs)under multiple loading-unloading cycles.Numerical examples show that with only a single parameter of direct physical meaning for each cycle,accurate and explicit simulations may be achieved for extensive data from multiple cycle tests.

SMA绞线预制梁-柱自复位耗能节点数值研究与参数优化

为了提高预制混凝土框架的抗震能力并控制震后残余变形,提出了一种新型的混合自复位预制混凝土梁柱节点(self-centring precast concrete beam-column connection,SC-PCBCC),其中采用了旋转摩擦阻尼器(rotational friction hinge damper,RFHD)和形状记忆合金(shape memory alloy,SMA)并联的结构。重点探讨了使用SMA绞线控制的自复位装置对SC-PCBCC进行改进。首先,介绍了SC-PCBCC的结构和工作原理;其次验证对比了1.0%、1.5%、2%和2.0%预应变下的超弹性1×7 SMA绞线、RFHD和SC-PCBCC的有限元模型,并进行了初步验证。研究结果表明,该节点具有较高的刚度、承载力、耗能能力以及较好的复位性能;最后对SC-PCBCC中SMA绞线的关键参数:SMA绞线预应变、直径和长度进行了参数分析,以优化其抗震性能。建议SC-PCBCC使用的SMA绞线初始预应变、直径和长度范围分别为1.5%~2.0%、15~18 mm和175~205 mm,以实现SC-PCBCC的优异承载性能、能量耗散和自复位性能。此外,节点中的SMA绞线和RFHD可在震后快速更换,实现高效灾后修复。总体而言,所提出的SC-PCBCC表现出了卓越的减震能力、自复位能力和可修复性。

Effects of H_2O_2 pretreatment on surface characteristics and bioactivity of NaOH-treated NiTi shape memory alloy

The effects of H2O2 pretreatment on the surface characteristics and bioactivity of NaOH-treated NiTi shape memory alloy(SMA)were investigated by scanning electron microscopy,X-ray diffraction,X-ray photoelectron spectroscopy,Raman spectra,Fourier transform infrared spectroscopy as well as a simulated body fluid(SBF)soaking test.It is found that the H2O2 pretreatment can lead to the direct creation of more Ti—OH groups and the decrease in the amount of Ni2O3,Na2TiO3 and remnant NiTi phases on the surfaces of bioactive NiTi SMA prepared by NaOH treatment.As a result,the induction period of apatite formation is shortened by dispensing with the slow kinetic formation process of Ti—OH groups via an exchange of Na+ ions from Na2TiO3 phase with H3O+ ions in SBF,which indicates that the bioactivity of NaOH-treated NiTi SMA can be further improved by the H2O2 pretreatment.

The Two-step Reverse Martensitic Transformations of TiNi Shape Memory Alloy Based on Solution-treatment and Aging

A TiNi-alloy is solution-treated in a vacuum furnace of 6.7×10^-3 Pa at 1 223 K for 3.6 ks, and then aged at 773 K for 1.8 ks. The differential scanning calorimetry （DSC） measurements show that after the heat-treatment, takes place a two-step reverse Martensitic transformation, from which results the two-stage recovery strain in a prestrained Martensitic TiNi-alloy wire during heating. The Vickers microhardness indentation test in cross-sectional areas of the TiNi-alloy wire indicates the compositional heterogeneity between its surface layers and its inside. The fact that the sizes of the indentation in surface layers smaller than those in the inside bears witness to the existence of slightly harder surface layers. It is believed that these phenomena are related to the compositional fluctuation caused by the evaporation and oxidization of Ti-element during the solution-treatment and heterogeneity formed during the subsequent aging treatment.

Fracture Behavior of TiNi Based Shape Memory Alloy Cold-rolled Tube

The microstructures and interracial characteristics of matrices at the inwalls and the out-walls of the cold-rolled tube with different amounts of deformation were investigated by the scanning electronic microscope （SEM）, the optical microscope （OM）, and the transmission electronic microscope （TEM） techniques. It was observed that as the amount of deformation increases, the flaws nucleate at the out-walls of the cold rolled tube, the stress-induced martensites change from （111 ） type Ⅰ twins to （011） type Ⅱ twins and then to （100） compound twins, nanocrystals and bulk amorphisation happen, the high density dislocation causes stress concentration at the out-walls of the Ti50Ni50 cold-rolled tube, and then precipitates its fracture, and the Ti2Ni particles strengthen the grain boundaries and curb the dislocation movements during plastic deformation. The inhomogeneity level of the grains in the Ti50Ni50 alloy plays an important role on the fracture of the Ti50Ni50 cold rolled tube.

PHASE TRANSFORMATION BEHAVIOR AND MICROSTRUCTURE OBSERVATION OF Nb-Ru HIGH TEMPERATURE SHAPE MEMORY ALLOY

The phase transformation behavior and micro structure of Nb-Ru alloys have been studied by DSC, X-ray diffraction, optical microscopy, transmission electron microscopy (TEM) and high-resolution electron microscopy (HREM). Two-step phase transformation of CsCl (β) →face-centered tetragonal (β)→ monoclinic (β') occurs during cooling from high temperature to room temperature. The lattice parameters of marten-sites of Nb-Ru alloys were found to increase with the increase of Nb content. The martensite variants exhibit triangular self-accommodating morphology, with alternating regular bands inside. The twinning relationship between the sub structural bands was found to be (101) type I mode, and this kind of twinning interface was straight, well-defined and coherent.

Modeling of Pneumatic Muscle with Shape Memory Alloy and Braided Sleeve

Pneumatic muscle （PM） of flexible actuators used in bionic robot is an active area of recent research. A novel PM with shape memory alloy （SMA） braided sleeve is proposed in this paper, and SMA is used to improve PM working characteristics. Based on the principle of virtual work, output force model of PM and relationship with braided wire inner-stress are established, and analysis of PM deformation has shown that braided wire length is the key factor of output force characteristic. Based on the crystal structure transitions, the relationship of temperature with wire shrinkage is derived. Then, the synthetic dynamics of novel PM is established. A physical prototype of PM with SMA braided sleeve is developed, and test platform that is built for the experiment. Experiment and simulation test of static isometric-length, static isobaric-pressure, and dynamic characteristics are done. The experimental results are compared with the simulation of theoretical model. Moreover, based on experiment, model of output force was improved by adding a correction factor to deal with the elastic force of rubber tube. The results analysis demonstrates that the established models are correct, and SMA wires can reinforce PM and make PM working characteristics adjustable. PM proposed in this paper has greater output force and is beneficial to achieve more accurate control that is useful for manipulating fragile things.