Unveiling the challenges encountered by newly graduated nurses during night shifts:A descriptive qualitative study

Objectives:Newly graduated nurses commence night shifts during a phase of heightened vulnerability to reality shock,exacerbating the challenges faced by these graduates.Therefore,this study aimed to identify the challenges experienced by newly graduated nurses when undertaking night shifts in order to help identify a strategy for supporting their adaptation to these shifts.Methods:Semi-structured personal interviews were used to collect data.Fifteen newly graduated nurses were selected to participate in the study by purposive sampling method from November 2021 to March 2022 in one of four general hospitals situated in the southwestern region of Japan.Semi-structured interviews were analyzed by using thematic analysis.Results:The analysis revealedfive central themes and nine subthemes:challenges in task efficiency(task organization challenges,challenges in time-constrained task performance),challenges in responding to patients’changing conditions(challenges in responding to patients’irregular conditions,challenges in responding to nighttime changes in patients’behaviors),challenges in independent practice(challenges in engaging in independent nursing practice,challenges in dealing with unexpected events),challenges in establishing collaborative relationships(challenges in working closely with other staff,challenges in establishing collaborative relationships during night shifts with limited resources),challenges in adapting to shift work(challenges in managing physical conditions for shift work).Conclusions:Newly graduated nurses often encounter challenges in performing their tasks during the transition period.When working night shifts,they face additional hurdles unique to nocturnal duties.Thefindings underscore the necessity for these graduates to develop night shift-specific readiness to effectively navigate the demands inherent in such work schedules.

Climate-change habitat shifts for the vulnerable endemic oak species(Quercus arkansana Sarg.)

Quercus arkansana(Arkansas oak)is at risk of becoming endangered,as the total known population size is represented by a few isolated populations.The potential impact of climate change on this species in the near future is high,yet knowledge of its predicted effects is limited.Our study utilized the biomod2 R package to develop habi-tat suitability ensemble models based on bioclimatic and topographic environmental variables and the known loca-tions of current distribution of Q.arkansana.We predicted suitable habitats across three climate change scenarios(SSP1-2.6,SSP2-4.5,and SSP5-8.5)for 2050,2070,and 2090.Our findings reveal that the current suitable habitat for Q.arkansana is approximately 127,881 km^(2) across seven states(Texas,Arkansas,Alabama,Louisiana,Mississippi,Georgia,and Florida);approximately 9.5%is encompassed within state and federally managed protected areas.Our models predict that all current suitable habitats will disap-pear by 2050 due to climate change,resulting in a northward shift into new regions such as Tennessee and Kentucky.The large extent of suitable habitat outside protected areas sug-gests that a species-specific action plan incorporating pro-tected areas and other areas may be crucial for its conserva-tion.Moreover,protection of Q.arkansana habitat against climate change may require locally and regionally focused conservation policies,adaptive management strategies,and educational outreach among local people.

Calculation and Analysis of TVMS Considering Profile Shifts and Surface Wear Evolution Process of Spur Gear

Profile shift is a highly effective technique for optimizing the performance of spur gear transmission systems.However,tooth surface wear is inevitable during gear meshing due to inadequate lubrication and long-term operation.Both profile shift and tooth surface wear(TSW)can impact the meshing characteristics by altering the involute tooth profile.In this study,a tooth stiffness model of spur gears that incorporates profile shift,TSW,tooth deformation,tooth contact deformation,fillet-foundation deformation,and gear body structure coupling is established.This model efficiently and accurately determines the time-varying mesh stiffness(TVMS).Additionally,an improved wear depth prediction method for spur gears is developed,which takes into consideration the mutually prime teeth numbers and more accurately reflects actual gear meshing conditions.Results show that consideration of the mutual prime of teeth numbers will have a certain impact on the TSW process.Furthermore,the finite element method(FEM)is employed to accurately verify the values of TVMS and load sharing ratio(LSR)of profile-shifted gears and worn gears.This study quantitatively analyzes the effect of profile shift on the surface wear process,which suggests that gear profile shift can partially alleviate the negative effects of TSW.The contribution of this study provides valuable insights into the design and maintenance of spur gear systems.

Discrete Phase Shifts Control and Beam Selection in RIS-Aided MISO System via Deep Reinforcement Learning

Reconfigurable intelligent surface(RIS)for wireless networks have drawn lots of attention in both academic and industry communities.RIS can dynamically control the phases of the reflection elements to send the signal in the desired direction,thus it provides supplementary links for wireless networks.Most of prior works on RIS-aided wireless communication systems consider continuous phase shifts,but phase shifts of RIS are discrete in practical hardware.Thus we focus on the actual discrete phase shifts on RIS in this paper.Using the advanced deep reinforcement learning(DRL),we jointly optimize the transmit beamforming matrix from the discrete Fourier transform(DFT)codebook at the base station(BS)and the discrete phase shifts at the RIS to maximize the received signal-to-interference plus noise ratio(SINR).Unlike the traditional schemes usually using alternate optimization methods to solve the transmit beamforming and phase shifts,the DRL algorithm proposed in the paper can jointly design the transmit beamforming and phase shifts as the output of the DRL neural network.Numerical results indicate that the DRL proposed can dispose the complicated optimization problem with low computational complexity.

Dynamic modeling of total ionizing dose-induced threshold voltage shifts in MOS devices

The total ionizing dose(TID) effect is a key cause for the degradation/failure of semiconductor device performance under energetic-particle irradiation. We developed a dynamic model of mobile particles and defects by solving the rate equations and Poisson's equation simultaneously, to understand threshold voltage shifts induced by TID in silicon-based metal–oxide–semiconductor(MOS) devices. The calculated charged defect distribution and corresponding electric field under different TIDs are consistent with experiments. TID changes the electric field at the Si/SiO_(2) interface by inducing the accumulation of oxide charged defects nearby, thus shifting the threshold voltage accordingly. With increasing TID, the oxide charged defects increase to saturation, and the electric field increases following the universal 2/3 power law. Through analyzing the influence of TID on the interfacial electric field by different factors, we recommend that the radiation-hardened performance of devices can be improved by choosing a thin oxide layer with high permittivity and under high gate voltages.

Identifying the Cultural Shifts and Societal Changes That Facilitated the Rise in Box Office Performance of Chinese Women’s Cinema in the 21st Century

With the gradual improvement of Chinese women’s status in the 21st century,gender studies and gender relations have become one of the hottest topics in Chinese society,which consequently prompted Chinese Women’s Cinema to attract the attention of larger audiences.With regard to the box office performance of Chinese Women’s Cinema,there seems to be a gap in research in finding an association between women’s status and the relevant films’box office performance.The purpose of this research is to outline the underlying reasons for the changes in gender roles and gender representation in the Chinese film industry over the past few decades in order to better understand this expansive social change in the 21st century.This study provides a comprehensive analysis through the use of questionnaires to better understand society’s attitude towards gender representation within the film industry.The questionnaire findings indicate that there is a direct correlation between people’s awareness of women’s changing status and gender equality and their acceptance of materials produced by Chinese Women’s Cinema.At the some time,it highlights that the Chinese government’s support and initiatives for gender equality have had a significant impact on the general popularity of Chinese Women’s Cinema.The significance of this research is to effectively popularize Chinese Women’s Cinema culture and the box office growth by understanding the social attitude towards gender representation in the Chinese film industry and to provide relevant information about the development direction and trend of Chinese Women’s Cinema.Furthermore,this research aims to provide foundational support for gender equality and help to understand the underlying factors that society needs to promote gender equality.

DAO to HANOI via DeSci: AI Paradigm Shifts from AlphaGo to ChatGPT

From AlphaGo to ChatGPT,the field of AI has launched a series of remarkable achievements in recent years.Analyzing,comparing,and summarizing these achievements at the paradigm level is important for future AI innovation,but has not received sufficient attention.In this paper,we give an overview and perspective on machine learning paradigms.First,we propose a paradigm taxonomy with three levels and seven dimensions from a knowledge perspective.Accordingly,we give an overview on three basic and twelve extended learning paradigms,such as Ensemble Learning,Transfer Learning,etc.,with figures in unified style.We further analyze three advanced paradigms,i.e.,AlphaGo,AlphaFold and ChatGPT.Second,to enable more efficient and effective scientific discovery,we propose to build a new ecosystem that drives AI paradigm shifts through the decentralized science(DeSci)movement based on decentralized autonomous organization(DAO).To this end,we design the Hanoi framework,which integrates human factors,parallel intelligence based on a combination of artificial systems and the natural world,and the DAO to inspire AI innovations.

Substituent Effects on 13C NMR and 1H NMR Chemical Shifts of CH=N in Multi-substituted Benzylideneanilines

Fifty-three samples of multi-substituted benzylideneanilines XArCH=NArYs （abbreviated XBAYs） were synthesized and their NMR spectra were determined. An extensional study of substituent effects on the 1H NMR chemical shifts （δH（CH=N）） and 13C NMR chemical shifts （δc（CH=N）） of the CH=N bridging group from di-substituted to multi-substituted XBAYs was made based on a total of 182 samples of XBAYs, together with the NMR data of other 129 samples of di-substituted XBAYs quoted from literatures. The results show thatthe substituent specific cross-interaction effect parameter （△（∑σ）2） plays an important role in quantifying the δc（CH=N） values of XBAYs, but it is negligible for quantifying the δH （CH=N） values; the other substituent parameters also present different influences on the δc （CH=N） and （δH （CH=N）. On the whole, the contributions of X and Y to the δc （CH=N） of XBAYs are balanced, but the δH（CH=N） values of XBAYs mainly rely on the contributions of X.

Large spatial shifts of reflected light beam off biaxial hyperbolic materials

Many optical systems that deal with polarization rely on the adaptability of controlling light reflection in the lithography-free nanostructure. In this study, we explore the Goos–H?nchen(GH) shift and Imbert–Fedorov(IF) shift in a biaxial hyperbolic film on a uniaxial hyperbolic substrate. This research statistically calculates and analyzes the GH shift and IF shift for the natural biaxial hyperbolic material(NBHM). We select the surface with the strongest anisotropy within the NBHM and obtain the complex beam-shift spectrum. By incorporating the NBHM film, the GH shift caused by a transversely magnetic incident-beam on the surface increases significantly compared with that on the uniaxial hyperbolic material. The maximum of GH shift can reach 86 λ0at about 841 cm-1when the thickness of NBHM is 90 nm, and the IF shift can approach 2.7 λ0for a circularly-polarized beam incident on a 1700-nm-thick NBHM. It is found that the spatialshift increases when a highly anisotropic hyperbolic polariton is excited in hyperbolic material, where the shift spectrum exhibits an oscillating behaviour accompanied with sharp shift peak(steep slope). This large spatial shift may provide an alternative strategy to develop novel sub-micrometric optical devices and biosensors.

Isotope Shifts of Nitrogen around 800 nm

The Doppler-limited absorption spectra of ^14N and ^15N atoms were measured around 800 nm using concentration modulation spectroscopy to study their isotope shifts. The nitrogen atoms were generated by discharging molecular nitrogen buffered with helium in a homemade discharge tube. The isotope shifts of four multiplets （3s^4PJ→3p^4D^oJ, 3s^4PJ→3p^4P^oJ, 3s^2DJ→5s^2P^oJ, and 3p^2P^oJ→5s^2D^oJ） were measured and their J-dependent specific mass shifts were observed and discussed.

Spectral Characterization of Hyponormal Weighted Shifts

The complete characterizations of the spectra and their various parts of hyponormal unilateral and bilateral weighted shifts are presented respectively in this paper. The results obtained here generalize the corresponding work of the references.

Theoretical Calculation on Isotope Shifts of N(I)

The special mass shift coefficient and field parameter factor of four multiples,3s^4P→3p4P°,3s^4P→3p^4D°,3s^2D→5p^2D°,and 3s^2P→3p^2P°,of ^14N and ^15N were studied using the multi-configuration Dirac-Hartree-Fock method and the relativistic configuration interaction approach.The normal mass shifts,special mass shifts,field shifts,and isotope shifts of N(I)were derived from the theoretical calculated normal mass shift parameter,special mass shift parameter and field parameter factor,and compared with the reported experimental measurements and theoretical results.

Holocene Abrupt Climate Shifts and Mid-Holocene Drought Intervals Recorded in Barkol Lake of Northern Xinjiang of China

Study results in this paper have indicated that the Holocene climate in Xinjiang, Northwestem China has been alternating between wet and dry conditions, and was punctuated with a series of abrupt climate shifts. A sediment core taken from Barkol Lake in the northern Xinjiang of Northwest China was analyzed at 1 cm interval for grain-size distribution. Abrupt climate shifts revealed by the grain-size proxy occurred at ca 1.4, 3.0, 4.3, 5.6, 8.0 cal kyr B.E, which were well correlated to both the abrupt shifts recorded in the North Atlantic Ocean （NAO） and the Holocene sea surface temperature （SST） cooling events in the Arabian Ocean. The correlation indicated that the climatic changes in the extreme arid Northwest China were associated with the NAO, probably via the North Atlantic Oscillation-affected westerly winds. The strength and position of westerly winds probably modulated the Siberian-Mongolian high- pressure system （winter monsoon）, and played an important role in climate change of Northwest China. Moreover, an evident drought interval during the middle Holocene was also revealed by grain-size proxy.

ENTIRE FUNCTIONS SHARING ONE SMALL FUNCTION CM WITH THEIR SHIFTS AND DIFFERENCE OPERATORS

In this article, we mainly devote to proving uniqueness results for entire functionssharing one small function CM with their shift and difference operator simultaneously. Letf（z） be a nonconstant entire function of finite order, c be a nonzero finite complex constant, and n be a positive integer. If f（z）, f（z＋c）, and △n cf（z） share 0 CM, then f（z＋c）≡Af（z）, where A（≠0） is a complex constant. Moreover, let a（z）, b（z）（ O） ∈ S（f） be periodic entire functions with period c and if f（z） - a（z）, f（z ＋ c） - a（z）, △cn f（z） - b（z） share 0 CM, then f（z ＋ c） ≡ f（z）.

Prediction of the ^(13)C NMR Chemical Shifts of Fluorenone Analogues by the GIAO Method

After the geometry optimization at B3LYP/6-31＋G（d,p） level,the NMR calcula-tions of a series of fluorenone analogues have been carried out by GIAO method at HF/6-31＋G（d） level and B3LYP/6-311G＋（2d,p） level,respectively.The 13C NMR chemical shifts calculated at HF/6-31＋G（d） level show better agreement with the observed values.By a series of linear correction equations （δpred=a ＋ bδcalc）,accurate prediction of 13C chemical shifts was achieved for the new fluorenone compound.The linear correlation of δpred with δexptl is excellent,and the square of correlation coefficient,r2,is up to 0.994.The maximum absolute difference between δpred and δexptl,Δδ,is 4.6 ppm,and the root-mean-square error between δpred and δexptl is only 2.6 ppm.

Paradigm Shifts or Methodology Changes ? Think Twice Before You Put Paradigms into Practice

ThepresentpaperaddressestheapplicabilityofKuhn'stheoryofparadigmshiftsandscientificrevolutionstothefieldoflanguageteaching.First,itillustratestheconceptionofparadigmshiftsandscientificrevolutions.Andthen,itsetsuptwotestsforexaminingtheissueofwhetherK...

DFT Studies on Thermal Stabilities,Electronic Structures,and ^(13)C Chemical Shifts of C_(24)O_2 Based on Fullerene C_(24)(D_6)

Quantum chemical calculations on some possible equilibrium geometries of C24O2 isomers derived from C24 （D6） and C24O have been performed using density functional theory （DFT） method. The geometric and electronic structures as well as the relative energies and thermal stabilities of various C24O2 isomers at the ground state have been calculated at the B3LYP/6-31G（d） level of theory. And the 1,4,2,5-C24O2 isomer was found to be the most stable geometry where two oxygen atoms were added to the longest carbon-carbon bonds in the same pentagon from a thermodynamic point of view. Based on the optimized neutral geometries, the vertical ionization potential and vertical electron affinity have been obtained. Meanwhile, the vibrational frequencies, IR spectrum, and 13C chemical shifts of various C24O2 isomers have been calculated and analyzed.

Analysis of the influence of various effects on frequency shifts of the acetylene saturated absorption lines

Frequency shifts of the acetylene saturated absorption lines at 1.5μm with temperature, gas pressure and laser power have been investigated in detail. The second-order Doppler effect, the recoil effect, the Zeeman effect, the pressure shift and the power shift are taken into consideration. The magnitudes of those shifts caused by various effects are evaluated. In order to reproduce the stability of 5.7 × 10^-14 obtained by Edwards, all necessary conditions are given. The results show that when there is a larger external magnetic field, the Zeeman shift could not be neglected, so that the shield should be employed. And the design of a long cavity is advantageous to reduce the influence of the second-order Doppler effect. The results also show that at least 4-2.5℃ temperature control for cavity can effectively prevent several effects and improve the frequency stability.

Non-Local pH Shifts and Shared Changing Angular Velocity Magnetic Fields: Discrete Energies and the Importance of Point Durations

Macroscopic productions of “non-locality” or “excess correlations” of dynamic changes within media between two spaces could be utilized as alternative communication systems. Previous experiments have shown that injections of a weak acid within one of two volumes of spring water sharing the same patterned circular magnetic fields with changing angular accelerations separated by non-traditional (5 m) distances were associated with opposite (basic) shifts in pH within the non-injected, non-local volume. In the present experiments, employing a different technology, pairs of beakers separated by 1 m containing either 25 cc, 50 cc, or 100 cc of spring water were placed within toroids generating weak (30, 300 nT) changing acceleration magnetic fields with 1 ms, 2 ms, or 3 ms point durations or a field whose point durations changed. When a proton source (weak acid) was injected into one beaker (local) pH shifts in the other (non-local) beaker exhibit increased acidity for the 3 ms point duration but increased alkalinity for the 1 ms duration. Neither intermittent point durations nor variable point durations for the same volumes of water placed between the two magnetic field-coupled beakers exhibited significant changes from baseline. Contingent upon the point duration of the applied field, the pH shift was consistent with a fixed quantity of decreased free protons (increased pH) or increased protons (decreased pH) in the non-local beakers. The opposite directions of the pH shifts at 1 ms and 3 ms that correspond to quantitative cosmological solutions for electrons and protons suggest these results may reflect a fundamental physical process.

Multimodal Discourse Analysis of Judges’Footing Shifts in Criminal Courtroom

The paper,based on the concept of FOOTING,makes a multimodal discourse analysis of the relationship between the judge’s discourse and his footing shifts in a criminal courtroom.The results show that in the interaction,multimodal resources in judges’discourse include conversational features(prolonging keywords,interrupting,repeating,taking turns,etc.),acoustic ones(ascending F0 for pitches and d B for intensity,transition tracks between consonants and formants of vowels,duration of some keywords in important sentences,etc.),and visual ones(facing other parties,facing the materials,etc.).The multimodal resources activate different judges’footings,including ANIMATOR,ANIMATOR+AUTHOR and ANIMATOR+AUTHOR+PRINCIPAL,and identify the judge’s footing shifts in the courtroom.The results also demonstrate that the judge’s footing shifts perform the functions of trial organizing,information confirming,fact investigating,spokesperson of the collegial panel,law educating and so on in criminal trials.