Shock-induced chemical reaction characteristics of PTFE-Al-Bi_(2)O_(3)reactive materials

A ternary system of PTFE/Al/Bi_(2)O_(3)is constructed by incorporating PTFE-based reactive material and thermite for enhancing the energy release of the PTFE-based reactive material.The effects of Bi_(2)O_(3)in the PTFE/Al/Bi_(2)O_(3)on both mechanical properties and the energy release were investigated through various tests such as thermogravimetry-differential scanning calorimetry,adiabatic oxygen bomb test and split Hopkinson pressure bar test.The microstructure observed through scanning electron microscope and Xray diffraction results are used to analyze the ignition and reaction mechanism of PTFE/Al/Bi_(2)O_(3).The results indicate that the PTFE/Al/Bi_(2)O_(3)are capable of triggering the exothermic reaction of molten PTFE/Bi_(2)O_(3)and Al/Bi_(2)O_(3)over the PTFE/Al reactive materials,thereby promoting reactions.The excessive aluminum in the ternary system is beneficial for increasing energy release.The ignition of shock-induced chemical reactions in PTFE/Al/Bi_(2)O_(3)is closely related to the material fracture.The dominant mechanism for hot-spot generation under Split Hopkinson Pressure Bar test is the frictional temperature rise at the microcrack after failure.

Simulation of shock-induced instability using an essentially conservative adaptive CE/SE method

An essentially conservative adaptive space time conservation element and solution element （CE/SE） method is pro- posed for the effective simulation of shock-induced instability with low computational cost. Its implementation is based on redefined conservation elements （CEs） and solution elements （SEs）, optimized interpolations and a Courant number insensitive CE/SE scheme. This approach is used in two applications, the Woodward double Mach reflection and a two- component Richtmyer-Meshkov instability experiment. This scheme reveals the essential features of the investigated cases, captures small unstable structures, and yields a solution that is consistent with the results from experiments or other high order methods.

Research status of key techniques for shock-induced combustion ramjet(shcramjet) engine

As one of the most promising propulsion systems in the future,shock-induced combustion ramjet engine can remedy the disadvantages in the integrated design of scramjet engine and airframe.It can shorten the length of the combustor,lighten the structure weight of the engine and keep better performance in a broad range of flight Mach number.The elementary principle of shock-induced combustion ramjet engine is introduced.The key technologies of this kind of propulsion system are described,while their research status is presented in detail.Suggestion on the development of shcramjet engine in China is put forward.

A methodology for simulating 2D shock-induced dynamic stall at flight test-based fluctuating freestream

A comprehensive methodology for simulating 2 D dynamic stall at fluctuating freestream is proposed in this paper.2 D CFD simulation of a SC1095 airfoil exposed to a fluctuating freestream of Mach number 0.537±0.205 and Reynolds number 6.1×10~6(based on the mean Mach number)and undergoing a 10°±10°pitch oscillation with a frequency of 4.25 Hz was conducted.These conditions were selected to be representative of the flow experienced by a helicopter rotor airfoil section in a real-life fast forward flight.Both constant freestream dynamic stall as well as fluctuating freestream dynamic stall simulations were conducted and compared.The methodology was carefully validated with experimental data for both transonic flow and dynamic stall under fluctuating freestream.Overall,the results suggest that the fluctuating freestream alters the dynamic stall mechanism documented for constant freestream in a major way,emphasizing that inclusion of this effect in the prediction of dynamic stall related rotor loads is imperative for rotor performance analysis and blades design.

The reaction mechanism and interfacial crystallization of Al nanoparticle-embedded Ni under shock loading

The shock-induced reaction mechanism and characteristics of Ni/Al system,considering an Al nanoparticle-embedded Ni single crystal,are investigated through molecular dynamics simulation.For the shock melting of Al nanoparticle,interfacial crystallization and dissolution are the main characteristics.The reaction degree of Al particle first increases linearly and then logarithmically with time driven by rapid mechanical mixing and following dissolution.The reaction rate increases with the decrease of particle diameter,however,the reaction is seriously hindered by interfacial crystallization when the diameter is lower than 9 nm in our simulations.Meanwhile,we found a negative exponential growth in the fraction of crystallized Al atoms,and the crystallinity of B2-NiAl(up to 20%)is positively correlated with the specific surface area of Al particle.This can be attributed to the formation mechanism of B2-NiAl by structural evolution of finite mixing layer near the collapsed interface.For shock melting of both Al particle and Ni matrix,the liquid-liquid phase inter-diffusion is the main reaction mechanism that can be enhanced by the formation of internal jet.In addition,the enhanced diffusion is manifested in the logarithmic growth law of mean square displacement,which results in an almost constant reaction rate similar to the mechanical mixing process.

Tungsten combustion in impact initiated W-Al composite based on W(Al) super-saturated solid solution

Element W can effectively improve the density of energetic structural materials. However, W is an inert element and does not combust in air. To change the reaction characteristics of W, 60 at.% Al was introduced into W through mechanical alloying. XRD analysis shows that after 50 h of ball milling, the diffraction peak of Al completely disappears and W(Al60) super-saturated solid solution powder is obtained. Further observation by HAADF and HRTEM reveals that the W(Al60) super-saturated solid solution powder is a mixture of solid solution and amorphous phase. Based on the good thermal stability of W(Al60) alloy powder below 1000℃, W(Al60)-Al composite was synthesized by hot pressing process.Impact initiation experiments suggest that the W(Al60)-Al composite has excellent reaction characteristics, and multiple types of tungsten oxides are detected in the reaction products, showing that the modified W is combustible in air. Due to the combustion of tungsten, the energy release rate of the W(Al60)-Al composite at speed of 1362 m/s reaches 2.71 kJ/g.

Study on energy release characteristics of reactive material casings under explosive loading

Reactive Materials(RMs),a new material with structural and energy release characteristics under shockinduced chemical reactions,are promising in extensive applications in national defense and military fields.They can increase the lethality of warheads due to their dual functionality.This paper focuses on the energy release characteristics of RM casings prepared by alloy melting and casting process under explosive loading.Explosion experiments of RM and conventional 2A12 aluminum alloy casings were conducted in free field to capture the explosive fireballs,temperature distribution,peak overpressure of the air shock wave and the fracture morphology of fragments of reactive material(RM)warhead casings by using high-speed camera,infrared thermal imager temperature and peak overpressure testing and scanning electron microscope.Results showed that an increase of both the fireball temperature and air shock wave were observed in all RM casings compared to conventional 2A12 aluminum ally casings.The RM casings can improve the peak overpressure of the air shock wave under explosion loading,though the results are different with different charge ratios.According to the energy release characteristics of the RM,increasing the thickness of RM casings will increase the peak overpressure of the near-field air shock wave,while reducing the thickness will increase the peak overpressure of the far-field air shock wave.

THE FLOW STRUCTURE OF DILUTE GAS-PARTICLE SUSPENSIONS BEHIND A SHOCK WAVE MOVING ALONG A FLAT SURFACE

The asymptotic and numerical investigations of shock-induced boundary layers in gas-particle mixtures are presented. The Saffman lift force acting on a particle in a shear flow is taken into account. It is shown that particle migration across the boundary layer leads to intersections of particle trajectories. The corresponding modification of dusty gas model is proposed in this paper.The equations of two-phase sidewall boundary layer behind a shock wave moving at a constant speed are obtained by using the method of matched asymptotic expansions. The method of the calculation of particle phase parameters in Lagrangian coordinates is described in detail. Some numerical results for the case of small particle concentration are given.

Shock metamorphism in meteorites

Shock metamorphism resulting from hyperveloeity collisions between planetary bodies, is a fundamental processes in the solar system. The term ＂shock metamorphism＂ is used to describe all changes in rocks and minerals resulting from the passage of shock waves. Most meteorites have experienced coUisions and have a record of shock metamorphism, which includes brecciation, deformation, phase transformation, local melting and crystallization. The key to reading this record is to use the shock features to estimate the pressure and duration of shock event. In this paper, the history of the study of shock metamorphism is reviewed; basic knowledge of shock physics is discussed; recent 10 years＇ studies of shock-induced melt veins are summarized; and finally a short note to the shock metamorphism in general is given.

Light emission properties of sapphire under shock loading in the stress range of 40-120 GPa

The measurement of emissions from the window material of sapphire was performed through multi-wavelength pyrometer and spontaneous spectroscopic techniques in the pressure range of 40 -120 GPa. The results showed that the spectral distribution with wavelength clearly fit well with the grey-body spectrum. We have analyzed the emissions and discovered they mostly came from the shear banding, which is a typical thermal radiation. The radiance intensity changing linearly with time revealed it was a volume effect. All of the data from pyrometer can be explained by the model of Boslough＇s study, especially for pres- sures over megabar. The color temperature of shocked sapphire changing with increased stress disagrees with the computed melt curve which is likely explained by the differcnt phase structures of sapphire.