Rapid Fabrication of Electrodes for Symmetrical Solid Oxide Cells by Extreme Heat Treatment

Symmetrical solid oxide cells(SSOCs)are very useful for energy generation and conversion.To fabricate the electrode of SSOC,it is very time-consuming to use the conventional approach.In this work,we design and develop a novel method,extreme heat treatment(EHT),to rapidly fabricate electrodes for SSOC.We show that by using the EHT method,the electrode can be fabricated in seconds(the fastest method to date),benefiting from enhanced reaction kinetics.The EHT-fabricated electrode presents a porous structure and good adhesion with the electrolyte.In contrast,tens of hours are needed to prepare the electrode by the conventional approach,and the prepared electrode exhibits a dense structure with a larger particle size due to the lengthy treatment.The EHT-fabricated electrode shows desirable electrochemical performance.Moreover,we show that the electrocatalytic activity of the perovskite electrode can be tuned by the vigorous approach of fast exsolution,deriving from the increased active sites for enhancing the electrochemical reactions.At 900℃,a promising peak power density of 966 mW cm^(-2)is reached.Our work exploits a new territory to fabricate and develop advanced electrodes for SSOCs in a rapid and high-throughput manner.

Implications of the extremely hot summer of 2022 on urban ozone control in China

Frequent occurrences of extreme heat are causing severe ozone pollution over China.This study examined the driving factors of urban ozone pollution in China during the extremely hot summer of 2022 and the impact of emission control strategies using surface measurements and the GEOS-Chem model.The results show that ozone pollution was extremely severe in summer 2022,with a significant rebound by 12-15 ppbv in the North China Plain(NCP),Yangtze River Delta(YRD),and Sichuan basin(SCB),compared to 2021.Especially over the NCP,the MDA8(maximum daily 8-hourly average)ozone exceeded 160 ppbv,and the number of ozone exceedances was over 42 days.Based on an IPR(integrated process rate)analysis,the authors found that the net chemical production was the dominant factor contributing to the strong ozone increase in summer 2022.For example,in June over the NCP,the net chemical production resulted in an increase by 3.08 Gg d^(−1)(∼270%)in ozone mass change.Sensitivity simulations showed that both NO_(x)(nitrogen oxides)and VOC(volatile organic compound)reductions were important over the NCP,and NO_(x)reductions were more important than VOCs over southern China.To keep the ozone of 2022 at the same level as 2021,a joint reduction of NO_(x)and VOCs by at least 50%-60%would have been required.This study highlights the urgency to develop effective ozone management since extreme heat will become more frequent.

A review of recent studies on extreme heat in China

This paper reviews recent studies on extreme high temperatures in China during summer. The focus is on the variation in extreme heat and tropical nights（i.e. high temperature at night）, and the factors of influence. Potential research topics in the future are also discussed.

Monitoring Spatio-temporal Variance of an Extreme Heat Event Using Multiple-source Remote Sensing Data

Extreme heat events have serious effects on human daily life. Accurately capturing the dynamic variance of extreme high-temperature distributions in a timely manner is the basis for analyzing the potential impacts of extreme heat, thereby informing risk prevention strategies. This paper demonstrates the potential application of multiple source remote sensing data in mapping and monitoring the extreme heat events that occurred on Aug. 8, 2013 in Jiangsu Province, China. In combination with MODIS products, the thermal sharpening(Ts HARP) method and a binary linear model are compared to downscale the original daytime FengY un 2 F(FY-2 F) land surface temperature(LST) imagery, with a temporal resolution of 60 min, from 5 km to 1 km. Using the meteorological measurement data from Nanjing station as the reference, the research then estimates the instantaneous air temperature by using an iterative computation based on the Surface Energy Balance Algorithm for Land(SEBAL), which is used to analyze the spatio-temporal air temperature variance. The results show that the root mean square error(RMSE) of the LST downscaled from the binary linear model is 1.30℃ compared to the synchronous MODIS LST, and on this basis the estimated air temperature has the RMSE of 1.78℃. The spatial and temporal distribution of air temperature variance at each geographical location from 06:30 to 18:30 can be accurately determined, and indicates that the high temperature gradually increases and expands from the city center. For the spatial distribution, the air temperature and the defined scorching temperature proportion index increase from northern to middle, to southern part of Jiangsu, and are slightly lower in the eastern area near the Yellow Sea. In terms of temporal characteristics, the percentage of area with air temperature above 37℃ in each city increase with time after 10:30 and reach the peak value at 14:30 or 15:30. Then, they decrease gradually, and the rising and falling trends become smaller from the southern cities to the northern regions. Moreover, there is a distinct positive relationship between the percentage of area above 37℃ and the population density. The above results show that the spatio-temporal distributions of heat waves and their influencing factors can be determined by combining multiple sources of remotely sensed image data.

URBANIZATION EFFECTS ON OBSERVED CHANGES IN SUMMER EXTREME HEAT EVENTS OVER ZHEJIANG PROVINCE, EAST CHINA

Although the urban heat island(UHI) is a well-documented phenomenon, relatively little information in the literature is available about its impact on summer extreme heat event(EHE). As UHI is characterized by increased temperature, it can potentially increase the magnitude and duration of EHEs within cities. Based on daily maximum temperature records from 62 observation stations in Zhejiang province from the period 1971-2011 and satellite-measured nighttime light imagery from the Defense Meteorological Satellite Program(DMSP) Operational Linescan System(OLS) during 1992-2010, we analyzed the long-term change of summer EHEs and its association with the rapid urbanization process. The results could be concluded as follows:(1) Zhejiang has experienced rapid urbanization and dramatic growth in urban areas in the past two decades, especially after 2000.(2) The summer mean maximum temperature and the 95 th percentile of summer daily maximum temperature in most of its stations have increased, with the most significant increase occurring in the highly urbanized areas including the city belt around Hangzhou Bay, Taizhou-Wenzhou and Jinghua-Yiwu city belts.(3) The hot days and hot-day degrees, defined by both daily 95 th percentile and the threshold of 35℃, show that the UHI effect causes additional hot days and heat stress in urban stations compared to rural stations.The results in this study suggest that the UHI effect should be determined and incorporated in preparing high temperature forecasts in cities.

HadISDH.extremes Part Ⅱ:Exploring Humid Heat Extremes Using Wet Bulb Temperature Indices

Heat events may be humid or dry.While several indices incorporate humidity,such combined indices obscure identification and exploration of heat events by their different humidity characteristics.The new HadISDH.extremes global gridded monitoring product uniquely provides a range of wet and dry bulb temperature extremes indices.Analysis of this new data product demonstrates its value as a tool for quantifying exposure to humid verses dry heat events.It also enables exploration into“stealth heat events”,where humidity is high,perhaps enough to affect productivity and health,while temperature remains moderate.Such events may not typically be identified as“heat events”by temperature-focused heat indices.Over 1973-2022,the peak magnitude of humid extremes(maximum daily wet bulb temperature over a month;T_(w)X)for the global annual mean increased significantly at 0.13±0.04℃(10 yr)^(−1),which is slightly slower than the global annual mean T_(w) increase of 0.22±0.04℃(10 yr)^(−1).The frequency of moderate humid extreme events per year(90th per-centile daily maxima wet bulb temperature exceedance;T_(w)X90p)also increased significantly at 4.61±1.07 d yr^(−1)(10 yr)^(−1).These rates were slower than for temperature extremes,TX and TX90p,which respectively increased significantly at 0.27±0.04℃(10 yr)^(−1) and 5.53±0.72 d yr^(−1)(10 yr)^(−1).Similarly,for the UK/Europe focus region,JJA-mean T_(w)X increased significantly,again at a slower rate than for TX and mean T_(w).HadISDH.extremes shows some evidence of“stealth heat events”occurring where humidity is high but temperature remains more moderate.

Influences of tropical circulation and sea surface temperature anomalies on extreme heat over Northeast Asia in the midsummer of 2018

A destructive extreme heat attacked Northeast Asia(NEA)in the midsummer of 2018,characterized by the average midsummer Tmax(daily maximum air temperature at 2 m)ranking first during the study period.The current study indicates that the cyclonic anomaly over the western North Pacific(WNP)was an important cause,which presents an anomaly of two standard deviations.The cyclonic anomaly over the WNP was accompanied by anomalous convection,which favored descending and anticyclonic anomalies over NEA through a local meridional cell.The anticyclonic anomaly over NEA corresponds to the northwestward extension of the WNP subtropical high and facilitated the occurrence of extreme heat.The tropical sea surface temperature anomaly(SSTA)presents a La Ni?a decaying episode,but the SSTA over the tropical Pacific and North Indian Ocean was weak in the summer.In contrast,the southeastern tropical Indian Ocean(SETIO)was obviously cool,which was the coolest after detrending.The SETIO cooling triggered a low-level southeasterly anomaly,which turned into a southwesterly after crossing the equator,due to the Coriolis force.The southwesterly anomaly extended eastwards and favored the cyclonic anomaly over the WNP.Meanwhile,the circulation anomalies over the SETIO and WNP were connected via a local meridional cell,with the ascending branch over the WNP.Moreover,the above mechanism also operates for the climate statistics,verifying the robust in?uence of the SETIO SSTA.Considering the consistency of the SETIO SSTA,it could be a potential predictor for the climate over the WNP and NEA.

Increases in Anthropogenic Heat Release from Energy Consumption Lead to More Frequent Extreme Heat Events in Urban Cities

With economic development and rapid urbanization,increases in Gross Domestic Product and population in fastgrowing cities since the turn of the 21st Century have led to increases in energy consumption.Anthropogenic heat flux released to the near-surface atmosphere has led to changes in urban thermal environments and severe extreme temperature events.To investigate the effects of energy consumption on urban extreme temperature events,including extreme heat and cold events,a dynamic representation scheme of anthropogenic heat release(AHR)was implemented in the Advanced Research version of the Weather Research and Forecasting(WRF)model,and AHR data were developed based on energy consumption and population density in a case study of Beijing,China.Two simulations during 1999−2017 were then conducted using the developed WRF model with 3-km resolution with and without the AHR scheme.It was shown that the mean temperature increased with the increase in AHR,and more frequent extreme heat events were produced,with an annual increase of 0.02−0.19 days,as well as less frequent extreme cold events,with an annual decrease of 0.26−0.56 days,based on seven extreme temperature indices in the city center.AHR increased the sensible heat flux and led to surface energy budget changes,strengthening the dynamic processes in the atmospheric boundary layer that reduce AHR heating efficiency more in summer than in winter.In addition,it was concluded that suitable energy management might help to mitigate the impact of extreme temperature events in different seasons.

Ultrafast synthetic strategies under extreme heating conditions toward single-atom catalysts

Dispersing atomic metals on substrates provides an ideal method to maximize metal utilization efficiency, which is important for the production of cost-effective catalysts and the atomic-level control of the electronic structure. However, due to the high surface energy, individual single atoms tend to migrate and aggregate into nanoparticles during preparation and catalytic operation. In the past few years, various synthetic strategies based on ultrafast thermal activation toward the effective preparation of single-atom catalysts(SACs) have emerged, which could effectively solve the aggregation issue. Here, we highlight and summarize the latest developments in various ultrafast synthetic strategy with rapid energy input by heating shockwave and instant quenching for the synthesis of SACs, including Joule heating, microwave heating, solid-phase laser irradiation, flame-assisted method, arc-discharge method and so on,with special emphasis on how to achieve the uniform dispersion of single metal atoms at high metal loadings as well as the suitability for scalable production. Finally, we point out the advantages and disadvantages of the ultrafast heating strategies as well as the trends and challenges of future developments.

More extreme-heat occurrences related to humidity in China

极端日夜复合高温往往会造成更为严重的社会经济影响及健康风险,受到了广泛关注。本文基于ERA5逐小时资料,针对中国区域极端日夜复合湿热和高温事件的变化及其影响进行了比较分析.结果指出,中国区域夏季极端湿热和高温在空间分布上较为一致,强度高值区主要分布在南方地区,但高频中心主要出现在北方地区.两类事件发生频次在全国范围内均呈明显增加趋势,尤其在西部和北部地区.进一步研究表明,在中国大部分地区,湿度异常在极端湿热事件变化中有着十分重要的作用,部分区域甚至超过温度异常的影响。随着极端湿热事件的增加其影响也在加剧,自1961年以来中国暴露于极端湿热事件的人口数量和城市面积增速明显大于高温事件.

Impact of the Horizontal Heat Flux in the Mixed Layer on an Extreme Heat Event in North China:A Case Study

Extreme heat over the North China Plain is typically induced by anomalous descending flows associated with anticyclonic circulation anomalies. However, an extreme heat event that happened in the North China Plain region on 12–13 July 2015,with maximum temperature higher than 40℃ at some stations, was characterized by only a weak simultaneous appearance of an anomalous anticyclone and descending flow, suggesting that some other factor(s) may have induced this heat event. In this study, we used the forecast data produced by the Beijing Rapid Updated Cycling operational forecast system, which predicted the heat event well, to investigate the formation mechanism of this extreme heat event. We calculated the cumulative heat in the mixed-layer air column of North China to represent the change in surface air temperature. The cumulative heat was composed of sensible heat flux from the ground surface and the horizontal heat flux convergence. The results indicated that the horizontal heat flux in the mixed layer played a crucial role in the temporal and spatial distribution of high temperatures.The horizontal heat flux was found to be induced by distinct distributions of air temperatures and horizontal winds at low levels during the two days, implying a complexity of the low-level atmosphere in causing the extreme heat.

An interdecadal decrease in extreme heat days in August over Northeast China around the early 1990s

Northeast China(NEC)witnessed an interdecadal increase in summer extreme heat days(EHDs)around the mid-1990s.The current study reveals that this interdecadal increase only occurs in June and July,while August features a unique interdecadal decrease in EHDs around the early 1990s.Plausible reasons for the interdecadal decrease in EHDs in August are further investigated.Results show that the interdecadal decrease in EHDs in August is due to the deceased variability of daily maximum temperature(Tmax).Overall,the variation of the Tmax over NEC in August is modulated by the Eurasian teleconnection pattern,Silk Road pattern,and East AsiaPacific pattern.However,the influence of the Silk Road pattern dramatically weakens after the early 1990s because the meridional wind variability along the westerly jet significantly decreases.The weakened influence of the Silk Road pattern contributes to the decreased Tmax variability over NEC.Meanwhile,the convection over the western North Pacific,which accompanies the East Asia-Pacific pattern,presents a significant decrease in variance after the early 1990s,further decreasing the Tmax variability over NEC.

Linkage of the Decadal Variability of Extreme Summer Heat in North China with the IPOD since 1981

Extreme summer heat can have serious socioeconomic impacts in North China.Here,we explore the decadal variability of the number of extreme heat days in early-to-mid summer(June and July)and a related potential mechanism consistent with the major seasonal occurrence period of extreme heat events in North China(NCSH).Observational analyses show significant decadal variability in NCSH for 1981–2021,potentially linked to the Indo-Pacific warm pool and Northwest Pacific Ocean dipole(IPOD)in early-to-mid summer.Dynamic diagnostic analysis and the linear baroclinic model(LBM)show that the positive IPOD in early-to-mid summer can excite upward vertical wind anomalies in the South China-East China Sea region,shifting the position of the western Pacific subtropical high(WPSH)to the east or weakening the degree of its control of the South China-East China Sea region,thus generating a positive geopotential height quadrupole(EAWPQ)pattern in the East Asia-Northwest Pacific region.Subsequently,the EAWPQ can cause air compression(expansion)over North China by regulating the tropospheric thickness anomalies in North China,thus increasing(decreasing)NCSH.Finally,an empirical model that incorporates the linear trend can better simulate the decadal NCSH compared to an empirical model based solely on the IPOD index,suggesting that the decadal variability of NCSH may be a combined contribution of the decadal IPOD and external linear forcing.

Interdecadal Change in Extreme Precipitation over South China and Its Mechanism

Based on the daily precipitation data taken from 17 stations over South China during the period of 1961 2003, a sudden change in summer extreme precipitation events over South China in the early 1990s along with the possible mechanism connected with the anomalies of the latent heat flux over the South China Sea and the sensible heat flux over the Indochina peninsula are examined. The results show that both the annual and summer extreme precipitation events have obvious interdecadal variations and have increased significantly since the early 1990s. Moreover, the latent heat flux over the South China Sea and the sensible heat flux over the Indochina peninsula also have obvious interdecadal variations consistent with that of the extreme precipitation, and influence different months＇ extreme precipitation, respectively. Their effects are achieved by the interdecadal increases of the strengthening convection over South China through the South China Sea Summer Monsoon.

Urbanization Impact on Regional Climate and Extreme Weather:Current Understanding,Uncertainties,and Future Research Directions

Urban environments lie at the confluence of social,cultural,and economic activities and have unique biophysical characteristics due to continued infrastructure development that generally replaces natural landscapes with built-up structures.The vast majority of studies on urban perturbation of local weather and climate have been centered on the urban heat island(UHI)effect,referring to the higher temperature in cities compared to their natural surroundings.Besides the UHI effect and heat waves,urbanization also impacts atmospheric moisture,wind,boundary layer structure,cloud formation,dispersion of air pollutants,precipitation,and storms.In this review article,we first introduce the datasets and methods used in studying urban areas and their impacts through both observation and modeling and then summarize the scientific insights on the impact of urbanization on various aspects of regional climate and extreme weather based on more than 500 studies.We also highlight the major research gaps and challenges in our understanding of the impacts of urbanization and provide our perspective and recommendations for future research priorities and directions.

Effects of short-term heat stress on PSII and subsequent recovery for senescent leaves of Vitis vinifera L. cv. Red Globe

Heat stress occurs frequently in energy-saving sunlight greenhouses(ESSG) at the late growth stage. Three-year delayed cultivation(DC) of the Red Globe cultivar of Vitis vinifera L. was used to clarify the physiological mechanisms of short-term heat stress on PSII and subsequent recovery from heat stress. By November, the photosynthetic function had declined and the fall in transpiration rate(E) with heating time increased the possibility of heat damage. In July, the most obvious increase was in the relative variable fluorescence at J point at 40°C, and in November it changed to K point. The 5 min of heat treatment resulted in a significant increase of the relative variable fluorescence at 0.3 ms(W), and after 10 min of heat treatment, the number of reactive centres per excited cross section(RC/CS), probability that a trapped exciton moves an electron into the electron transport chain beyond Q–(at t=0)(Ψ) and quantum yield of electron transport at t=0(φ) decreased significantly(P<0.05), suggesting that the reaction centre, donor and acceptor side of photosystem II(PSII) were all significantly inhibited(P<0.05) and that the thermal stability of the photosynthetic mechanism was reduced. The inhibition of energy fluxes for senescent leaves in November was earlier and more pronounced than that for healthy leaves, which did not recover from heat stress of more than 15 min after 2 h recovery at room temperature.

HadISDH.extremes Part Ⅰ:A Gridded Wet Bulb Temperature Extremes Index Product for Climate Monitoring

HadISDH.extremes is an annually updated global gridded monthly monitoring product of wet and dry bulb temperature–based extremes indices,from January 1973 to December 2022.Data quality,including spatial and temporal stability,is a key focus.The hourly data are quality controlled.Homogeneity is assessed on monthly means and used to score each gridbox according to its homogeneity rather than to apply adjustments.This enables user-specific screening for temporal stability and avoids errors from inferring adjustments from monthly means for the daily maximum values.For general use,a score(HQ Flag)of 0 to 6 is recommended.A range of indices are presented,aligning with existing standardised indices.Uniquely,provision of both wet and dry bulb indices allows exploration of heat event character—whether it is a“humid and hot”,“dry and hot”or“humid and warm”event.It is designed for analysis of long-term trends in regional features.HadISDH.extremes can be used to study local events,but given the greater vulnerability to errors of maximum compared to mean values,cross-validation with independent information is advised.

Spatial-temporal Analysis and Prediction of Precipitation Extremes: A Case Study in the Weihe River Basin, China

Extreme precipitation events bring considerable risks to the natural ecosystem and human life.Investigating the spatial-temporal characteristics of extreme precipitation and predicting it quantitatively are critical for the flood prevention and water resources planning and management.In this study,daily precipitation data(1957–2019)were collected from 24 meteorological stations in the Weihe River Basin(WRB),Northwest China and its surrounding areas.We first analyzed the spatial-temporal change of precipitation extremes in the WRB based on space-time cube(STC),and then predicted precipitation extremes using long short-term memory(LSTM)network,auto-regressive integrated moving average(ARIMA),and hybrid ensemble empirical mode decomposition(EEMD)-LSTM-ARIMA models.The precipitation extremes increased as the spatial variation from northwest to southeast of the WRB.There were two clusters for each extreme precipitation index,which were distributed in the northwestern and southeastern or northern and southern of the WRB.The precipitation extremes in the WRB present a strong clustering pattern.Spatially,the pattern of only high-high cluster and only low-low cluster were primarily located in lower reaches and upper reaches of the WRB,respectively.Hot spots(25.00%–50.00%)were more than cold spots(4.17%–25.00%)in the WRB.Cold spots were mainly concentrated in the northwestern part,while hot spots were mostly located in the eastern and southern parts.For different extreme precipitation indices,the performances of the different models were different.The accuracy ranking was EEMD-LSTM-ARIMA>LSTM>ARIMA in predicting simple daily intensity index(SDII)and consecutive wet days(CWD),while the accuracy ranking was LSTM>EEMD-LSTM-ARIMA>ARIMA in predicting very wet days(R95 P).The hybrid EEMD-LSTM-ARIMA model proposed was generally superior to single models in the prediction of precipitation extremes.

Sap-flow measurement and scale transferring from sample trees to entire forest stand of Populus euphratica in desert riparian forest in extreme arid region

Understanding how the transpiration of this vegetation type responds to environmental stress is important for determining the wa-ter-balance dynamics of the riparian ecosystem threatened by groundwater depletion. Transpiration and sap flow were measured using the heat-pulse technique. The results were then projected up to the stand level to investigate the stand’s water-use in relation to climate forcing in the desert riparian forest in an extreme arid region. This study took place from April through October 2003 and from May through October 2004. The experimental site was selected in the Populus euphratica Forest Reserve (101o10' E, 41o59' N) in Ejina county, in the lower Heihe River basin, China. The sapwood area was used as a scalar to extrapolate the stand-water consumption from the whole trees’ water consumption measured by the heat-pulse velocity recorder (HPVR). Scale transferring from a series of individual trees to a stand was done according to the existing natural variations between trees under given environmental conditions. The application of the biometric parameters available from individual tree and stand levels was proved suitable for this purpose. A significant correlation between the sapwood area and tree diameter at breast height (DBH) was found. The prediction model is well fitted by the power model. On the basis of the prediction model, the sapwood area can be cal-culated by DBH. The sap-flow density can then be used to extrapolate the stand-water use by means of a series of mathematical models.

The impacts of the East Asian subtropical westerly jet on weather extremes over China in early and late summer

Summer weather extremes(e.g.,heavy rainfall,heat waves)in China have been linked to anomalies of summer monsoon circulations.The East Asian subtropical westerly jet(EASWJ),an important component of the summer monsoon circulations,was investigated to elucidate the dynamical linkages between its intraseasonal variations and local weather extremes.Based on EOF analysis,the dominant mode of the EASWJ in early summer is characterized by anomalous westerlies centered over North China and anomalous easterlies centered over the south of Japan.This mode is conducive to the occurrence of precipitation extremes over Central and North China and humid heat extremes over most areas of China except Northwest and Northeast China.The centers of the dominant mode of the EASWJ in late summer extend more to the west and north than in early summer,and induce anomalous weather extremes in the corresponding areas.The dominant mode of the EASWJ in late summer is characterized by anomalous westerlies centered over the south of Lake Baikal and anomalous easterlies centered over Central China,which is favorable for the occurrence of precipitation extremes over northern and southern China and humid heat extremes over most areas of China except parts of southern China and northern Xinjiang Province.The variability of the EASWJ can influence precipitation and humid heat extremes by driving anomalous vertical motion and water vapor transport over the corresponding areas in early and late summer.