The AOX (adsorbable organic halogens) problem in wool shrinkproofing effluents has attracted more attention in recent years. The probable origins and structures of AOX compounds were proved by the reaction of DCCA wit...The AOX (adsorbable organic halogens) problem in wool shrinkproofing effluents has attracted more attention in recent years. The probable origins and structures of AOX compounds were proved by the reaction of DCCA with the model substances of different amino acid residues. The GC-MS results indicated that available chlorine could chlorinate the side chain of tyrosine, histidine and trypotophan and generate AOX load in the effluent.展开更多
A process for the shrink - resist treatment of wool by protease with a hydrogen peroxide pretreatment (the Perzym process) has been studied. A protease, selected from several commercial proteases, has been found havin...A process for the shrink - resist treatment of wool by protease with a hydrogen peroxide pretreatment (the Perzym process) has been studied. A protease, selected from several commercial proteases, has been found having higher activity in shrink - resist treatment, and its optimum technological conditions, which confer wool better shrinkproofing and less strength and elongation loss, have been obtained by an orthogonal factorial design approach. The study shows that it is possible for the wool to be conferred excellent machine washability by the Perzym process.展开更多
Chlorination occurred simultaneously with oxidationwhen wool was treated by chlorine-containing reagents.The adsorbable organic halogens(AOX) compounds were produced by the chlorination of amino acid residues,especial...Chlorination occurred simultaneously with oxidationwhen wool was treated by chlorine-containing reagents.The adsorbable organic halogens(AOX) compounds were produced by the chlorination of amino acid residues,especially tyrosine residue. The factors that might influence the reaction of dichloroisocyanuric acid (DCCA) with tyrosine residue were discussed. Higher temperature, appropriate pH value and lower concentration of chloride ion are favorable to decrease the percentage of chlorination. Determination of optimum process conditions would be helpful to control AOX compounds formation during wool chlorine pretreatment.展开更多
Plasma etching technique used in the modification of fibres,yarns and fabrics of wool is re-ported.The experimental results show that the method is useful for improving wettability and re-ducing shrinkage of wool,it m...Plasma etching technique used in the modification of fibres,yarns and fabrics of wool is re-ported.The experimental results show that the method is useful for improving wettability and re-ducing shrinkage of wool,it may be used to increase the strength of tops and yarns,and to enhancethe hand and colour of the final products.In addition,the characteristic features of the plasmamodified wool and discussions of possible mechanisms of the action are presented.展开更多
In this paper,the dyeing behavior of shrinkproofed woolusing Lanasol reactive dyes was studied.Good dyeinglevelness was obtained by modifying the common dyeingprocess.To minimize the strength loss,low temperaturedyein...In this paper,the dyeing behavior of shrinkproofed woolusing Lanasol reactive dyes was studied.Good dyeinglevelness was obtained by modifying the common dyeingprocess.To minimize the strength loss,low temperaturedyeing process was chosen.The strength loss of shrink-proofed wool dyed at low temperature and high tempera-ture were compared.The exhaustion and fixation werealso determined at different temperature and pH.展开更多
文摘The AOX (adsorbable organic halogens) problem in wool shrinkproofing effluents has attracted more attention in recent years. The probable origins and structures of AOX compounds were proved by the reaction of DCCA with the model substances of different amino acid residues. The GC-MS results indicated that available chlorine could chlorinate the side chain of tyrosine, histidine and trypotophan and generate AOX load in the effluent.
文摘A process for the shrink - resist treatment of wool by protease with a hydrogen peroxide pretreatment (the Perzym process) has been studied. A protease, selected from several commercial proteases, has been found having higher activity in shrink - resist treatment, and its optimum technological conditions, which confer wool better shrinkproofing and less strength and elongation loss, have been obtained by an orthogonal factorial design approach. The study shows that it is possible for the wool to be conferred excellent machine washability by the Perzym process.
文摘Chlorination occurred simultaneously with oxidationwhen wool was treated by chlorine-containing reagents.The adsorbable organic halogens(AOX) compounds were produced by the chlorination of amino acid residues,especially tyrosine residue. The factors that might influence the reaction of dichloroisocyanuric acid (DCCA) with tyrosine residue were discussed. Higher temperature, appropriate pH value and lower concentration of chloride ion are favorable to decrease the percentage of chlorination. Determination of optimum process conditions would be helpful to control AOX compounds formation during wool chlorine pretreatment.
文摘Plasma etching technique used in the modification of fibres,yarns and fabrics of wool is re-ported.The experimental results show that the method is useful for improving wettability and re-ducing shrinkage of wool,it may be used to increase the strength of tops and yarns,and to enhancethe hand and colour of the final products.In addition,the characteristic features of the plasmamodified wool and discussions of possible mechanisms of the action are presented.
文摘In this paper,the dyeing behavior of shrinkproofed woolusing Lanasol reactive dyes was studied.Good dyeinglevelness was obtained by modifying the common dyeingprocess.To minimize the strength loss,low temperaturedyeing process was chosen.The strength loss of shrink-proofed wool dyed at low temperature and high tempera-ture were compared.The exhaustion and fixation werealso determined at different temperature and pH.
