Triangular silver nanoprisms were prepared and applied to make colorimetric detection of cysteine based on our findings that cysteine could lead to the blue shift of the dipole plasmon resonance absorption, but other ...Triangular silver nanoprisms were prepared and applied to make colorimetric detection of cysteine based on our findings that cysteine could lead to the blue shift of the dipole plasmon resonance absorption, but other 19 kinds of natural amino acids could not. Cysteine with a concentration 160 nmol/L can result in a color change that can be discerned with naked eyes.展开更多
In this work we explore the influence of the factors that affect the formation of silver nanoprisms (AgNPs) with distinct size and size distribution as well as the most intense absorption peak shift. Box-Behnken desig...In this work we explore the influence of the factors that affect the formation of silver nanoprisms (AgNPs) with distinct size and size distribution as well as the most intense absorption peak shift. Box-Behnken design analysis was applied to optimize the production of silver nanoprism via colloidal synthesis. The analysis of the responses was based on the nanoprisms plasmon peak wavelength related to in-plane dipole (tunable band) at λmax. ≥ 420 nm. The obtained results indicate that Silver ion is the main variable for the tuning of the size and the Localized Surface Plasmon Resonance (LSPR) frequency. By using the Box-Behnken design it was possible to synthesize nanoparticles with a predictable size and to establish a rigorous control of the plasmon frequency at the range of 600 up to 800 nm.展开更多
In this study,we established a simple colorimetric method for visual detection of chromium(Ⅲ)ions using aggregated silver nanoprisms induced by monohydrogen phosphate.The detection strategy had two steps,selective ag...In this study,we established a simple colorimetric method for visual detection of chromium(Ⅲ)ions using aggregated silver nanoprisms induced by monohydrogen phosphate.The detection strategy had two steps,selective aggregation of silver nanoprisms with monohydrogen phosphate at high temperature,and anti aggregation of silver nanoprisms in the presence of chromium(Ⅲ)ions.In this strategy,significant spectral shift of the localized surface plasmon resonance(LSPR)absorption peak of silver nanoprisms could be visualized with the color changed from yellow to blue.The spectral peak shift of silver nanoprisms in the anti-aggregation process was linear with the concentrations of the added chromium(Ⅲ)ions in the range of 20.0-800.0 nM.Thus,a colorimetric method for chromium(Ⅲ)ions detection was established with the detection limit of 3.6 nM.The experimental results of real water samples indicated that the colorimetric sensor was potential in environmental monitoring.展开更多
基金the financial support of the Ministry of Science and Technology of the People's Republic of China(No.2006CB 933100).
文摘Triangular silver nanoprisms were prepared and applied to make colorimetric detection of cysteine based on our findings that cysteine could lead to the blue shift of the dipole plasmon resonance absorption, but other 19 kinds of natural amino acids could not. Cysteine with a concentration 160 nmol/L can result in a color change that can be discerned with naked eyes.
基金supported by Brazilian agencies CNPq and CAPES,as well as INFo(Instituto de Fotonica).
文摘In this work we explore the influence of the factors that affect the formation of silver nanoprisms (AgNPs) with distinct size and size distribution as well as the most intense absorption peak shift. Box-Behnken design analysis was applied to optimize the production of silver nanoprism via colloidal synthesis. The analysis of the responses was based on the nanoprisms plasmon peak wavelength related to in-plane dipole (tunable band) at λmax. ≥ 420 nm. The obtained results indicate that Silver ion is the main variable for the tuning of the size and the Localized Surface Plasmon Resonance (LSPR) frequency. By using the Box-Behnken design it was possible to synthesize nanoparticles with a predictable size and to establish a rigorous control of the plasmon frequency at the range of 600 up to 800 nm.
基金financially supported by the National Natural Science Foundation of China(21565030 and 21465025)Program for Excellent Young Talents of Yunnan UniversityFoundation of National Demonstration Center for Experimental Chemistry and Chemical Engineering Education(Yunnan University)
文摘In this study,we established a simple colorimetric method for visual detection of chromium(Ⅲ)ions using aggregated silver nanoprisms induced by monohydrogen phosphate.The detection strategy had two steps,selective aggregation of silver nanoprisms with monohydrogen phosphate at high temperature,and anti aggregation of silver nanoprisms in the presence of chromium(Ⅲ)ions.In this strategy,significant spectral shift of the localized surface plasmon resonance(LSPR)absorption peak of silver nanoprisms could be visualized with the color changed from yellow to blue.The spectral peak shift of silver nanoprisms in the anti-aggregation process was linear with the concentrations of the added chromium(Ⅲ)ions in the range of 20.0-800.0 nM.Thus,a colorimetric method for chromium(Ⅲ)ions detection was established with the detection limit of 3.6 nM.The experimental results of real water samples indicated that the colorimetric sensor was potential in environmental monitoring.
