Individuals with special needs learn more slowly than their peers and they need repetitions to be permanent.However,in crowded classrooms,it is dif-ficult for a teacher to deal with each student individually.This probl...Individuals with special needs learn more slowly than their peers and they need repetitions to be permanent.However,in crowded classrooms,it is dif-ficult for a teacher to deal with each student individually.This problem can be overcome by using supportive education applications.However,the majority of such applications are not designed for special education and therefore they are not efficient as expected.Special education students differ from their peers in terms of their development,characteristics,and educational qualifications.The handwriting skills of individuals with special needs are lower than their peers.This makes the task of Handwriting Recognition(HWR)more difficult.To over-come this problem,we propose a new personalized handwriting verification sys-tem that validates digits from the handwriting of special education students.The system uses a Convolutional Neural Network(CNN)created and trained from scratch.The data set used is obtained by collecting the handwriting of the students with the help of a tablet.A special education center is visited and the handwrittenfigures of the students are collected under the supervision of special education tea-chers.The system is designed as a person-dependent system as every student has their writing style.Overall,the system achieves promising results,reaching a recognition accuracy of about 94%.Overall,the system can verify special educa-tion students’handwriting digits with high accuracy and is ready to integrate with a mobile application that is designed to teach digits to special education students.展开更多
The condensation of DNA induced by spermine is studied by atomic force microscopy (AFM) and molecular dynamics (MD) simulation in this paper. In our experiments, an equivalent amount of multivalent cations is adde...The condensation of DNA induced by spermine is studied by atomic force microscopy (AFM) and molecular dynamics (MD) simulation in this paper. In our experiments, an equivalent amount of multivalent cations is added to the DNA solutions in different numbers of steps, and we find that the process of DNA condensation strongly depends on the speed of adding cations. That is, the slower the spermine cations are added, the slower the DNA aggregates. The MD and steered molecular dynamics (SMD) simulation results agree well with the experimental results, and the simulation data also show that the more steps of adding multivalent cations there are, the more compact the condensed DNA structure will be. This investigation can help us to control DNA condensation and understand the complicated structures of DNA--cation complexes.展开更多
Using molecular dynamics simulations and atomic force microscopy (AFM), we study the decondensation process of DNA chains induced by multivalent cations at high salt concentrations in the presence of short cationic ...Using molecular dynamics simulations and atomic force microscopy (AFM), we study the decondensation process of DNA chains induced by multivalent cations at high salt concentrations in the presence of short cationic chains in solutions. The typical simulation conformations of DNA chains with varying salt concentrations for multivalent cations imply that the concentration of salt cations and the valence of multivalent cations have a strong influence on the process of DNA decondensation. The DNA chains are condensed in the absence of salt or at low salt concentrations, and the compacted conformations of DNA chains become loose when a number of cations and anions are added into the solution. It is explicitly demonstrated that cations can overcompensate the bare charge of the DNA chains and weaken the attraction interactions between the DNA chains and short cationic chains at high salt concentrations. The condensation-decondensation transi- tions of DNA are also experimentally observed in mixing spermidine with X-phage DNA at different concentrations of NaCl/MgCl2 solutions.展开更多
It is highly attractive to develop an efficient and flexible large eddy simulation(LES)technique for high-Reynolds-number atmospheric boundary layer(ABL)simulation using the low-order numerical scheme on a relatively ...It is highly attractive to develop an efficient and flexible large eddy simulation(LES)technique for high-Reynolds-number atmospheric boundary layer(ABL)simulation using the low-order numerical scheme on a relatively coarse grid,that could reproduce the logarithmic profile of the mean velocity and some key features of large-scale coherent structures in the outer layer.In this study,an improved near-wall correction scheme for the vertical gradient of the resolved streamwise velocity in the strain-rate tensor is proposed to calculate the eddy viscosity coefficient in the subgrid-scale(SGS)model.The LES code is realized with a second-order finite-difference scheme,the scale-dependent dynamic SGS stress model,the equilibrium wall stress model,and the proposed correction scheme.Very-high-Reynolds-number ABL flow simulation under the neutral stratification condition is conducted to assess the performance of the method in predicting the mean and fluctuating characteristics of the rough-wall turbulence.It is found that the logarithmic profile of the mean streamwise velocity and some key features of large-scale coherent structures can be reasonably predicted by adopting the proposed correction method and the low-order numerical scheme.展开更多
A novel approach is introduced to generate simulated ground motion records by considering spectral acceleration correlations at multiple periods. Most of the current reliable Ground Motion Record(GMR) simulation proce...A novel approach is introduced to generate simulated ground motion records by considering spectral acceleration correlations at multiple periods. Most of the current reliable Ground Motion Record(GMR) simulation procedures use a seismological model including source, path and site characteristics. However, the response spectrum of simulated GMR is somewhat different when compared with the response spectrum based on recorded GMRs. More specifi cally, the correlation between the spectral values at multiple periods is a characteristic of a record which is usually different between simulated and recorded GMRs. As this correlation has a signifi cant infl uence on the structural response, it is needed to investigate the consistency of the simulated ground motions with actual records. This issue has been investigated in this study by incorporating an optimization algorithm within the Boore simulation technique. Eight seismological key parameters were optimized in order to achieve approximately the same correlation coeffi cients and spectral acceleration between two sets of real and simulated records. The results show that the acceleration response spectra of the synthetic ground motions also have good agreement with the real recorded response spectra by implementation of the proposed optimized values.展开更多
Remote sensing techniques have the potential to provide information on agricultural crops quantitstively,instantaneously and above all nondestrctively over large areas.Crop simulation models describe the relationship ...Remote sensing techniques have the potential to provide information on agricultural crops quantitstively,instantaneously and above all nondestrctively over large areas.Crop simulation models describe the relationship between physiological process in plants and environmental growing conditions.The integration between remote sensing data and crop growth simulation model is an important trent for yield estirmation and prediction,since remote sensing can provide information on the actual status of the agricultural crop.In this study,a new model(Rice-SRS) was developed based mainly on ORYZA1 model and modified to accept remote sensing data as input from different sources.The modelc an accept three kinds of NDVI,data.NOAA AVHRR(LAC)-NDVI,NOAA AVHRR(GAC)-NDVI and radiometric measurements-HDVI,The integration between NOAA AVHRR(LAC) data and simulation model as applied to Rice-SPS resulted in accurate estimates for rice yield in the Shaoxing area.reduced the estimating error to 1.027%,0.794% and (-0.787%) for early,single,and late season repectively.Utilizing NDVI data derived from NOAA AVHRR(GAC) as input in Rice-SRS can yield good estimation for rice yield with the average error (-7.43%) .Testing the new model for radiometric meassurements showed that the average estimation error for 10 varieties under early rice conditions was less than 1%.展开更多
GIS中的隔离开关在操作过程中由于断口重复击穿会产生特快速瞬态过电压(very fast transient overvoltage,VFTO)。VFTO幅值高、波前陡,严重威胁电气一次绝缘,并会产生电磁干扰问题。目前,实际工程中除采用带投切电阻的隔离开关抑制VFTO...GIS中的隔离开关在操作过程中由于断口重复击穿会产生特快速瞬态过电压(very fast transient overvoltage,VFTO)。VFTO幅值高、波前陡,严重威胁电气一次绝缘,并会产生电磁干扰问题。目前,实际工程中除采用带投切电阻的隔离开关抑制VFTO外,还可以采用磁环型阻尼母线对VFTO进行抑制。为了保证GIS的可靠性,磁环型阻尼母线抑制性能的优劣至关重要。为此,亟需研究提出一种在试验室进行磁环抑制效果的评定方法。文中针对磁环型阻尼母线的抑制性能,设计了专门的抑制性能试验回路,该试验回路中主要包含套管、阻尼电阻、放电间隙、磁环型阻尼母线、GIS短母线、VFTO传感器以及VFTO测量系统。该试验回路的额定电压为1100 kV,回路中的套管和母线可承受的额定工频电压为1100 kV,阻尼电阻的阻值为560Ω或1500Ω,放电间隙可以通过电极间距的调整产生不同等级的放电电压值和放电陡波,陡波上升时间可以达到30 ns。应用该试验回路在试验室进行模拟试验的方法检验磁环型阻尼母线的抑制效果,试验结果表明,该试验回路可以完成磁环型阻尼母线抑制效果的检验,可以定量地给出抑制效果的优劣。该方法可以推广到其他电压等级的GIS产品中,有助于推动实现磁环型阻尼母线的工业化设计、制造及检验。展开更多
There exists large space to save energy of high-sulfur natural gas purification process.The multi-objective optimization problem has been investigated to effectively reduce the total comprehensive energy consumption a...There exists large space to save energy of high-sulfur natural gas purification process.The multi-objective optimization problem has been investigated to effectively reduce the total comprehensive energy consumption and further improve the production rate of purified gas.A steady-state simulation model of high-sulfur natural gas purification process has been set up by using ProMax.Seven key operating parameters of the purification process have been determined based on the analysis of comprehensive energy consumption distribution.To solve the problem that the process model does not converge in some conditions,back-propagation(BP)neural network has been applied to substitute the simulation model to predict the relative parameters in the optimization model.The uniform design method and the table U21(107)have been applied to design the experiment points for training and testing BP model.High prediction accuracy can be achieved by using the BP model.Nondominated sorting genetic algorithm-II has been developed to optimize the two objectives,and 100 Pareto optimal solutions have been obtained.Three optimal points have been selected and evaluated further.The results demonstrate that the total comprehensive energy consumption is reduced by 13.4%and the production rate of purified gas is improved by 0.2%under the optimized operating conditions.展开更多
In large loop transient electromagnetic method(TEM),the late time apparent resistivity formula cannot truly reflect the geoelectric model,thus it needs to define the all-time apparent resistivity with the position inf...In large loop transient electromagnetic method(TEM),the late time apparent resistivity formula cannot truly reflect the geoelectric model,thus it needs to define the all-time apparent resistivity with the position information of measuring point.Utilizing very fast simulated annealing(VFSA) to fit the theoretical electromagnetic force(EMF) and measured EMF could obtain the all-time apparent resistivity of the measuring points in rectangular transmitting loop.The selective cope of initial model of VFSA could be confirmed by taking the late time apparent resistivity of transient electromagnetic method as the prior information.For verifying the correctness,the all-time apparent resistivities of the geoelectric models were calculated by VFSA and dichotomy,respectively.The results indicate that the relative differences of apparent resistivities calculated by these two methods are within 3%.The change of measuring point position has little influence on the tracing pattern of all-time apparent resistivity.The first branch of the curve of all-time apparent resistivity is close to the resistivity of the first layer medium and the last branch is close to the resistivity of the last layer medium,which proves the correctness of the arithmetics proposed.展开更多
For the purpose of functional validation,the mung bean(Vigna radiata)VrPR gene was cloned and overexpressed in Arabidopsis thaliana.Thefindings revealed that the ORF of VrPR contained 1200 bp,in which 399 amino acids w...For the purpose of functional validation,the mung bean(Vigna radiata)VrPR gene was cloned and overexpressed in Arabidopsis thaliana.Thefindings revealed that the ORF of VrPR contained 1200 bp,in which 399 amino acids were encoded.Bioinformatics analysis showed that the VrPR protein belonged to the NADB Rossmann superfamily,which was one of the non-transmembrane hydrophilic proteins.VrPR was assumed to have 44 amino acid phosphorylation sites and be contained in chloroplasts.The VrPR secondary structure comprised of random coil,αhelix,βangle,and extended chain,all of which were quite compatible with the anticipated tertiary structure.Moreover,analysis of the phylogenetic tree indicated that the soybean PR(Glyma.12G222200)and VrPR were closely related.Furthermore,chlorophyll content in leaves is markedly increased in Arabidopsis when VrPR is overexpressed.Ourfindings will serve as a reference for more functional studies on the PR genes in mung bean.展开更多
Medical data mining has become an essential task in healthcare sector to secure the personal and medical data of patients using privacy policy.In this background,several authentication and accessibility issues emerge ...Medical data mining has become an essential task in healthcare sector to secure the personal and medical data of patients using privacy policy.In this background,several authentication and accessibility issues emerge with an inten-tion to protect the sensitive details of the patients over getting published in open domain.To solve this problem,Multi Attribute Case based Privacy Preservation(MACPP)technique is proposed in this study to enhance the security of privacy-preserving data.Private information can be any attribute information which is categorized as sensitive logs in a patient’s records.The semantic relation between transactional patient records and access rights is estimated based on the mean average value to distinguish sensitive and non-sensitive information.In addition to this,crypto hidden policy is also applied here to encrypt the sensitive data through symmetric standard key log verification that protects the personalized sensitive information.Further,linear integrity verification provides authentication rights to verify the data,improves the performance of privacy preserving techni-que against intruders and assures high security in healthcare setting.展开更多
Nickel-rich LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811) cathode material has been widely concerned due to its high voltage,high specific capacity and excellent rate performance,which is considered as one of the most promi...Nickel-rich LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811) cathode material has been widely concerned due to its high voltage,high specific capacity and excellent rate performance,which is considered as one of the most promising cathode materials for the next generation of high-energy-density solid-state lithium batteries.However,serious electro-chemo-mechanical degradation of Nickel-rich cathode during cycling,especially at a high voltage(over 4.5 V),constrains their large-scale application.Here,using the multiphysical simulation,highly-conductive polymer matrix with spontaneous stress-buffering effect was uncovered theoretically for reinforcing the electrochemical performance of composited NCM81 1 cathode through the visualization of uniform concentration distribution of Li-ion coupled with improved stress field inside NCM811 cathode.Thereupon,polyacrylonitrile(PAN) and soft polyvinylidene fluoride(PVDF) were selected as the polymer matrix to fabricate the composited NCM811 cathode(PVDFPAN@NCM811) for improving the electrochemical performance of the solid-state NMC811|Li full cells,which can maintain high capacity over 146.2 mA h g^(-1)after 200 cycles at a high voltage of 4.5 V.Suggestively,designing a multifunctional polymer matrix with high ionic conductivity and mechanical property can buffer the stress and maintain the integrity of the structure,which can be regarded as the door-opening avenue to realize the high electrochemical performance of Ni-rich cathode for solidstate batteries.展开更多
文摘Individuals with special needs learn more slowly than their peers and they need repetitions to be permanent.However,in crowded classrooms,it is dif-ficult for a teacher to deal with each student individually.This problem can be overcome by using supportive education applications.However,the majority of such applications are not designed for special education and therefore they are not efficient as expected.Special education students differ from their peers in terms of their development,characteristics,and educational qualifications.The handwriting skills of individuals with special needs are lower than their peers.This makes the task of Handwriting Recognition(HWR)more difficult.To over-come this problem,we propose a new personalized handwriting verification sys-tem that validates digits from the handwriting of special education students.The system uses a Convolutional Neural Network(CNN)created and trained from scratch.The data set used is obtained by collecting the handwriting of the students with the help of a tablet.A special education center is visited and the handwrittenfigures of the students are collected under the supervision of special education tea-chers.The system is designed as a person-dependent system as every student has their writing style.Overall,the system achieves promising results,reaching a recognition accuracy of about 94%.Overall,the system can verify special educa-tion students’handwriting digits with high accuracy and is ready to integrate with a mobile application that is designed to teach digits to special education students.
基金supported by the National Natural Science Foundation of China (Grant Nos. 20974081, 20934004, 21174131, and 21104060)the Zhejiang Provincial Natural Science Foundation of China (Grant No. Y4110357)
文摘The condensation of DNA induced by spermine is studied by atomic force microscopy (AFM) and molecular dynamics (MD) simulation in this paper. In our experiments, an equivalent amount of multivalent cations is added to the DNA solutions in different numbers of steps, and we find that the process of DNA condensation strongly depends on the speed of adding cations. That is, the slower the spermine cations are added, the slower the DNA aggregates. The MD and steered molecular dynamics (SMD) simulation results agree well with the experimental results, and the simulation data also show that the more steps of adding multivalent cations there are, the more compact the condensed DNA structure will be. This investigation can help us to control DNA condensation and understand the complicated structures of DNA--cation complexes.
基金supported by the National Natural Science Foundation of China(Grant No.31340026)the Natural Science Foundation of Zhejiang Province,China(Grant Nos.Z13F20019 and LQ12E01003)the Science and Technology Project of Zhejiang Science and Technology Department,China(Grant No.2014C31147)
文摘Using molecular dynamics simulations and atomic force microscopy (AFM), we study the decondensation process of DNA chains induced by multivalent cations at high salt concentrations in the presence of short cationic chains in solutions. The typical simulation conformations of DNA chains with varying salt concentrations for multivalent cations imply that the concentration of salt cations and the valence of multivalent cations have a strong influence on the process of DNA decondensation. The DNA chains are condensed in the absence of salt or at low salt concentrations, and the compacted conformations of DNA chains become loose when a number of cations and anions are added into the solution. It is explicitly demonstrated that cations can overcompensate the bare charge of the DNA chains and weaken the attraction interactions between the DNA chains and short cationic chains at high salt concentrations. The condensation-decondensation transi- tions of DNA are also experimentally observed in mixing spermidine with X-phage DNA at different concentrations of NaCl/MgCl2 solutions.
基金Project supported by the National Natural Science Foundation of China(No.11490551)the Fundamental Research Funds for the Central Universities(Nos.lzujbky-2016-k13 and lzujbky-2018-k07)
文摘It is highly attractive to develop an efficient and flexible large eddy simulation(LES)technique for high-Reynolds-number atmospheric boundary layer(ABL)simulation using the low-order numerical scheme on a relatively coarse grid,that could reproduce the logarithmic profile of the mean velocity and some key features of large-scale coherent structures in the outer layer.In this study,an improved near-wall correction scheme for the vertical gradient of the resolved streamwise velocity in the strain-rate tensor is proposed to calculate the eddy viscosity coefficient in the subgrid-scale(SGS)model.The LES code is realized with a second-order finite-difference scheme,the scale-dependent dynamic SGS stress model,the equilibrium wall stress model,and the proposed correction scheme.Very-high-Reynolds-number ABL flow simulation under the neutral stratification condition is conducted to assess the performance of the method in predicting the mean and fluctuating characteristics of the rough-wall turbulence.It is found that the logarithmic profile of the mean streamwise velocity and some key features of large-scale coherent structures can be reasonably predicted by adopting the proposed correction method and the low-order numerical scheme.
文摘A novel approach is introduced to generate simulated ground motion records by considering spectral acceleration correlations at multiple periods. Most of the current reliable Ground Motion Record(GMR) simulation procedures use a seismological model including source, path and site characteristics. However, the response spectrum of simulated GMR is somewhat different when compared with the response spectrum based on recorded GMRs. More specifi cally, the correlation between the spectral values at multiple periods is a characteristic of a record which is usually different between simulated and recorded GMRs. As this correlation has a signifi cant infl uence on the structural response, it is needed to investigate the consistency of the simulated ground motions with actual records. This issue has been investigated in this study by incorporating an optimization algorithm within the Boore simulation technique. Eight seismological key parameters were optimized in order to achieve approximately the same correlation coeffi cients and spectral acceleration between two sets of real and simulated records. The results show that the acceleration response spectra of the synthetic ground motions also have good agreement with the real recorded response spectra by implementation of the proposed optimized values.
文摘Remote sensing techniques have the potential to provide information on agricultural crops quantitstively,instantaneously and above all nondestrctively over large areas.Crop simulation models describe the relationship between physiological process in plants and environmental growing conditions.The integration between remote sensing data and crop growth simulation model is an important trent for yield estirmation and prediction,since remote sensing can provide information on the actual status of the agricultural crop.In this study,a new model(Rice-SRS) was developed based mainly on ORYZA1 model and modified to accept remote sensing data as input from different sources.The modelc an accept three kinds of NDVI,data.NOAA AVHRR(LAC)-NDVI,NOAA AVHRR(GAC)-NDVI and radiometric measurements-HDVI,The integration between NOAA AVHRR(LAC) data and simulation model as applied to Rice-SPS resulted in accurate estimates for rice yield in the Shaoxing area.reduced the estimating error to 1.027%,0.794% and (-0.787%) for early,single,and late season repectively.Utilizing NDVI data derived from NOAA AVHRR(GAC) as input in Rice-SRS can yield good estimation for rice yield with the average error (-7.43%) .Testing the new model for radiometric meassurements showed that the average estimation error for 10 varieties under early rice conditions was less than 1%.
基金Financial support from National Science and Technology Major Project of the Ministry of Science and Technology of China(Grant No.2016ZX05017-004)
文摘There exists large space to save energy of high-sulfur natural gas purification process.The multi-objective optimization problem has been investigated to effectively reduce the total comprehensive energy consumption and further improve the production rate of purified gas.A steady-state simulation model of high-sulfur natural gas purification process has been set up by using ProMax.Seven key operating parameters of the purification process have been determined based on the analysis of comprehensive energy consumption distribution.To solve the problem that the process model does not converge in some conditions,back-propagation(BP)neural network has been applied to substitute the simulation model to predict the relative parameters in the optimization model.The uniform design method and the table U21(107)have been applied to design the experiment points for training and testing BP model.High prediction accuracy can be achieved by using the BP model.Nondominated sorting genetic algorithm-II has been developed to optimize the two objectives,and 100 Pareto optimal solutions have been obtained.Three optimal points have been selected and evaluated further.The results demonstrate that the total comprehensive energy consumption is reduced by 13.4%and the production rate of purified gas is improved by 0.2%under the optimized operating conditions.
基金Projects(40804027,41074085) supported by the National Natural Science Foundation of ChinaProject(09JJ3048) supported by the Natural Science Foundation of Hunan Province,ChinaProject(200805331082) supported by the Research Fund for the Doctoral Program of Higher Education,China
文摘In large loop transient electromagnetic method(TEM),the late time apparent resistivity formula cannot truly reflect the geoelectric model,thus it needs to define the all-time apparent resistivity with the position information of measuring point.Utilizing very fast simulated annealing(VFSA) to fit the theoretical electromagnetic force(EMF) and measured EMF could obtain the all-time apparent resistivity of the measuring points in rectangular transmitting loop.The selective cope of initial model of VFSA could be confirmed by taking the late time apparent resistivity of transient electromagnetic method as the prior information.For verifying the correctness,the all-time apparent resistivities of the geoelectric models were calculated by VFSA and dichotomy,respectively.The results indicate that the relative differences of apparent resistivities calculated by these two methods are within 3%.The change of measuring point position has little influence on the tracing pattern of all-time apparent resistivity.The first branch of the curve of all-time apparent resistivity is close to the resistivity of the first layer medium and the last branch is close to the resistivity of the last layer medium,which proves the correctness of the arithmetics proposed.
基金This research was funded by National Natural Science Foundation of China,Grant Number(31871576)National Keypoint Research and Invention Program of the Thirteenth,Grant Number(2019YFD1002205)The APC was funded by National Keypoint Research and Invention Program of the Thirteenth.
文摘For the purpose of functional validation,the mung bean(Vigna radiata)VrPR gene was cloned and overexpressed in Arabidopsis thaliana.Thefindings revealed that the ORF of VrPR contained 1200 bp,in which 399 amino acids were encoded.Bioinformatics analysis showed that the VrPR protein belonged to the NADB Rossmann superfamily,which was one of the non-transmembrane hydrophilic proteins.VrPR was assumed to have 44 amino acid phosphorylation sites and be contained in chloroplasts.The VrPR secondary structure comprised of random coil,αhelix,βangle,and extended chain,all of which were quite compatible with the anticipated tertiary structure.Moreover,analysis of the phylogenetic tree indicated that the soybean PR(Glyma.12G222200)and VrPR were closely related.Furthermore,chlorophyll content in leaves is markedly increased in Arabidopsis when VrPR is overexpressed.Ourfindings will serve as a reference for more functional studies on the PR genes in mung bean.
文摘Medical data mining has become an essential task in healthcare sector to secure the personal and medical data of patients using privacy policy.In this background,several authentication and accessibility issues emerge with an inten-tion to protect the sensitive details of the patients over getting published in open domain.To solve this problem,Multi Attribute Case based Privacy Preservation(MACPP)technique is proposed in this study to enhance the security of privacy-preserving data.Private information can be any attribute information which is categorized as sensitive logs in a patient’s records.The semantic relation between transactional patient records and access rights is estimated based on the mean average value to distinguish sensitive and non-sensitive information.In addition to this,crypto hidden policy is also applied here to encrypt the sensitive data through symmetric standard key log verification that protects the personalized sensitive information.Further,linear integrity verification provides authentication rights to verify the data,improves the performance of privacy preserving techni-que against intruders and assures high security in healthcare setting.
基金financially supported by the Natural Science Foundation of Hunan Province(2020JJ5653)the National Natural Science Foundation of China(21875282,22102212)+1 种基金the Ministry of Science and Higher Education of the Russian Federation(07515-2022-1150)the National University of Defense Technology Scientific Research Project(ZK20-44)。
文摘Nickel-rich LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM811) cathode material has been widely concerned due to its high voltage,high specific capacity and excellent rate performance,which is considered as one of the most promising cathode materials for the next generation of high-energy-density solid-state lithium batteries.However,serious electro-chemo-mechanical degradation of Nickel-rich cathode during cycling,especially at a high voltage(over 4.5 V),constrains their large-scale application.Here,using the multiphysical simulation,highly-conductive polymer matrix with spontaneous stress-buffering effect was uncovered theoretically for reinforcing the electrochemical performance of composited NCM81 1 cathode through the visualization of uniform concentration distribution of Li-ion coupled with improved stress field inside NCM811 cathode.Thereupon,polyacrylonitrile(PAN) and soft polyvinylidene fluoride(PVDF) were selected as the polymer matrix to fabricate the composited NCM811 cathode(PVDFPAN@NCM811) for improving the electrochemical performance of the solid-state NMC811|Li full cells,which can maintain high capacity over 146.2 mA h g^(-1)after 200 cycles at a high voltage of 4.5 V.Suggestively,designing a multifunctional polymer matrix with high ionic conductivity and mechanical property can buffer the stress and maintain the integrity of the structure,which can be regarded as the door-opening avenue to realize the high electrochemical performance of Ni-rich cathode for solidstate batteries.