The simultaneous removal of SO_(2),NO_(x)and Hg^(0)from industrial exhaust flue gas has drawn worldwide attention in recent years.A particularly attractive technique is selective catalytic reduction,which effectively ...The simultaneous removal of SO_(2),NO_(x)and Hg^(0)from industrial exhaust flue gas has drawn worldwide attention in recent years.A particularly attractive technique is selective catalytic reduction,which effectively removes SO_(2),NO_(x)and Hg^(0)at low temperatures.This paper first reviews the simultaneous removal of SO_(2),NO_(x)and Hg^(0)by unsupported and supported catalysts.It then describes and compares the research progress of various carriers,eg.,carbon-based materials,metal oxides,silica,molecular sieves,metal-organic frameworks,and pillared interlayered clays,in the simultaneous removal of SO_(2),NO_(x)and Hg^(0).The effects of flue-gas components(such as O_(2),NH3,HCl,H2 O,SO_(2),NO and Hg^(0))on the removal of SO_(2),NOx,and Hg^(0)are discussed comprehensively and systematically.After summarizing the pollutantremoval mechanism,the review discusses future developments in the simultaneous removal of SO_(2),NOx and Hg^(0)by catalysts.展开更多
Coal slime can be disposed in quantity and fully utilized in a well-designed circulating fluidized bed(CFB)boiler,but the nitrogen oxides(NO_(x))and sulphur dioxide(SO_(2))emissions generated in the combustion of coal...Coal slime can be disposed in quantity and fully utilized in a well-designed circulating fluidized bed(CFB)boiler,but the nitrogen oxides(NO_(x))and sulphur dioxide(SO_(2))emissions generated in the combustion of coal slime have contributed to serious atmospheric pollution.High Temperature&Post-combustion Technology,a novel and high-efficient way to reduce the NO_(x)emission in the process of combustion,is applied to a 75 t/h CFB boiler burning exclusively coal slime,which will succeed to meet the ultra-low NO_(x)emission standard.To further explore an appropriate method to reduce the SO_(2)emission under the condition of new technology,the experiments were conducted on a 75 t/h CFB boiler with post-combustion chamber to study the influence of limestone addition on the combustion and emission characteristics of coal slime.The experimental results showed that High Temperature&Post-combustion Technology combined with the sorbent injection in the furnace is a very promising technology to control the NO_(x)and SO_(2)emissions simultaneously.Limestone addition can cause the slight decrease in combustion temperature.Limestone addition will lead to the increase in NO_(x)emission in the combustion of coal slime.In 75 t/h coal slime CFB boiler,the desulfurization efficiency of limestone injection in furnace is close to 98%,achieving the ultra-low SO_(2)emission.To meet the standard of ultra-low NO_(x)and SO_(2)emission,the two technologies for simultaneous removal of NO_(x)and SO_(2)emissions are economical and feasible currently:Removal of SO_(2)under ultra-low NO_(x)emission and Removal of NO_(x)under ultra-low SO_(2)emission.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52000093,51968034,41807373 and21667015)National Key R&D Program of China(No.2018YFC0213400)+1 种基金China Postdoctoral Science Foundation(Nos.2020T130271,2019M663911XB)Open Fund of National Engineering Laboratory for Mobile Source Emission Control Technology(No.NELMS2019B03)。
文摘The simultaneous removal of SO_(2),NO_(x)and Hg^(0)from industrial exhaust flue gas has drawn worldwide attention in recent years.A particularly attractive technique is selective catalytic reduction,which effectively removes SO_(2),NO_(x)and Hg^(0)at low temperatures.This paper first reviews the simultaneous removal of SO_(2),NO_(x)and Hg^(0)by unsupported and supported catalysts.It then describes and compares the research progress of various carriers,eg.,carbon-based materials,metal oxides,silica,molecular sieves,metal-organic frameworks,and pillared interlayered clays,in the simultaneous removal of SO_(2),NO_(x)and Hg^(0).The effects of flue-gas components(such as O_(2),NH3,HCl,H2 O,SO_(2),NO and Hg^(0))on the removal of SO_(2),NOx,and Hg^(0)are discussed comprehensively and systematically.After summarizing the pollutantremoval mechanism,the review discusses future developments in the simultaneous removal of SO_(2),NOx and Hg^(0)by catalysts.
基金financially supported by the"Transformational Technologies for Clean Energy and Demonstration",Strategic Priority Research Program of the Chinese Academy of Sciences,Grant No.XDA21040100。
文摘Coal slime can be disposed in quantity and fully utilized in a well-designed circulating fluidized bed(CFB)boiler,but the nitrogen oxides(NO_(x))and sulphur dioxide(SO_(2))emissions generated in the combustion of coal slime have contributed to serious atmospheric pollution.High Temperature&Post-combustion Technology,a novel and high-efficient way to reduce the NO_(x)emission in the process of combustion,is applied to a 75 t/h CFB boiler burning exclusively coal slime,which will succeed to meet the ultra-low NO_(x)emission standard.To further explore an appropriate method to reduce the SO_(2)emission under the condition of new technology,the experiments were conducted on a 75 t/h CFB boiler with post-combustion chamber to study the influence of limestone addition on the combustion and emission characteristics of coal slime.The experimental results showed that High Temperature&Post-combustion Technology combined with the sorbent injection in the furnace is a very promising technology to control the NO_(x)and SO_(2)emissions simultaneously.Limestone addition can cause the slight decrease in combustion temperature.Limestone addition will lead to the increase in NO_(x)emission in the combustion of coal slime.In 75 t/h coal slime CFB boiler,the desulfurization efficiency of limestone injection in furnace is close to 98%,achieving the ultra-low SO_(2)emission.To meet the standard of ultra-low NO_(x)and SO_(2)emission,the two technologies for simultaneous removal of NO_(x)and SO_(2)emissions are economical and feasible currently:Removal of SO_(2)under ultra-low NO_(x)emission and Removal of NO_(x)under ultra-low SO_(2)emission.
