Due to a series of exceptional properties,titanium and titanium alloys have received extensive attention in recent years.Different from other alloy systems,there are two allotropes and a sequence of metastable phases ...Due to a series of exceptional properties,titanium and titanium alloys have received extensive attention in recent years.Different from other alloy systems,there are two allotropes and a sequence of metastable phases in titanium alloys.By summarizing the recent investigations,the phase transformation processes corresponding to the common phases and also some less reported phases are reviewed.For the phase transformation only involvingαandβphases,it can be divided intoβ→αtransformation and a reverse transformation.The former one has been demonstrated from the orientation relationship betweenαandβphases and the regulation ofαmorphology.For the latter transformation,the role of the stress has been discussed.In terms of the metastable phases,the mechanisms of phase formation and their effects on microstructure and mechanical properties have been discussed.Finally,some suggestions about the development of titanium alloys have been proposed.展开更多
A large-scale fine-grained Mg-Gd-Y-Zn-Zr alloy plate with high strength and ductility was successfully prepared by multi-pass friction stir processing(MFSP)technology in this work.The structure of grains and long peri...A large-scale fine-grained Mg-Gd-Y-Zn-Zr alloy plate with high strength and ductility was successfully prepared by multi-pass friction stir processing(MFSP)technology in this work.The structure of grains and long period stacking ordered(LPSO)phase were characterized,and the mechanical properties uniformity was investigated.Moreover,a quantitative relationship between the microstructure and tensile yield strength was established.The results showed that the grains in the processed zone(PZ)and interfacial zone(IZ)were refined from 50μm to 3μm and 4μm,respectively,and numerous original LPSO phases were broken.In IZ,some block-shaped 18R LPSO phases were transformed into needle-like 14H LPSO phases due to stacking faults and the short-range diffusion of solute atoms.The severe shear deformation in the form of kinetic energy caused profuse stacking fault to be generated and move rapidly,greatly increasing the transformation rate of LPSO phase.After MFSP,the ultimate tensile strength,yield strength and elongation to failure of the large-scale plate were 367 MPa,305 MPa and 18.0% respectively.Grain refinement and LPSO phase strengthening were the major strengthening mechanisms for the MFSP sample.In particularly,the strength of IZ was comparable to that of PZ because the strength contribution of the 14H LPSO phase offsets the lack of grain refinement strengthening in IZ.This result opposes the widely accepted notion that IZ is a weak region in MFSP-prepared large-scale fine-grained plate.展开更多
A time-resolved x-ray diffraction technique is employed to monitor the structural transformation of laser-shocked bismuth.Results reveal a retarded transformation from the shock-induced Bi-Ⅴphase to a metastable Bi-...A time-resolved x-ray diffraction technique is employed to monitor the structural transformation of laser-shocked bismuth.Results reveal a retarded transformation from the shock-induced Bi-Ⅴphase to a metastable Bi-Ⅳphase during the shock release,instead of the thermodynamically stable Bi-Ⅲphase.The emergence of the metastable Bi-Ⅳphase is understood by the competitive interplay between two transformation pathways towards the Bi-Ⅳand Bi-Ⅲ,respectively.The former is more rapid than the latter because the Bi-Ⅴto B-Ⅳtransformation is driven by interaction between the closest atoms while the Bi-Ⅴto B-Ⅲtransformation requires interaction between the second-closest atoms.The nucleation time for the Bi-Ⅴto Bi-Ⅳtransformation is determined to be 5.1±0.9 ns according to a classical nucleation model.This observation demonstrates the importance of the formation of the transient metastable phases,which can change the phase transformation pathway in a dynamic process.展开更多
Pyrolusite comprises the foremost manganese oxides and is a major source of manganese production.An innovative hydrogenbased mineral phase transformation technology to pyrolusite was proposed,where a 96.44%distributio...Pyrolusite comprises the foremost manganese oxides and is a major source of manganese production.An innovative hydrogenbased mineral phase transformation technology to pyrolusite was proposed,where a 96.44%distribution rate of divalent manganese(Mn^(2+))was observed at an optimal roasting temperature of 650℃,a roasting time of 25 min,and an H2 concentration of 20vol%;under these conditions.The manganese predominantly existed in the form of manganosite.This study investigated the generation mechanism of manganosite based on the reduction kinetics,phase transformation,and structural evolution of pyrolusite and revealed that high temperature improved the distribution rate,and the optimal kinetic model for the reaction was the random nucleation and growth model(reaction order,n=3/2)with an activation energy(E_(a))of 24.119 kJ·mol^(−1).Throughout the mineral phase transformation,manganese oxide from the outer layer of particles moves inward to the core.In addition,pyrolusite follows the reduction sequence of MnO_(2)→Mn_(2)O_(3)→Mn_(3)O_(4)→MnO,and the reduction of manganese oxides in each valence state simultaneously proceeds.These findings provide significant insight into the efficient and clean utilization of pyrolusite.展开更多
The mechanism involved in the phase transformation process of pyrolusite (MnO_(2)) during roasting in a reducing atmosphere was systematically elucidated in this study,with the aim of effectively using low-grade compl...The mechanism involved in the phase transformation process of pyrolusite (MnO_(2)) during roasting in a reducing atmosphere was systematically elucidated in this study,with the aim of effectively using low-grade complex manganese ore resources.According to single-factor experiment results,the roasted product with a divalent manganese (Mn^(2+)) distribution rate of 95.30% was obtained at a roasting time of 25 min,a roasting temperature of 700℃,a CO concentration of 20at%,and a total gas volume of 500 mL·min^(-1),in which the manganese was mainly in the form of manganosite (MnO).Scanning electron microscopy and Brunauer–Emmett–Teller theory demonstrated the microstructural evolution of the roasted product and the gradual reduction in the pyrolusite ore from the surface to the core Thermodynamic calculations,X-ray photoelectron spectroscopy,and X-ray diffractometry analyses determined that the phase transformation of pyrolusite followed the order of MnO_(2)→Mn_(2)O_(3)→Mn_(3)O_(4)→MnO phase by phase,and the reduction of manganese oxides in each valence state proceeded simultaneously.展开更多
The layeredδ-MnO_(2)(dMO)is an excellent cathode material for rechargeable aqueous zinc-ion batteries owing to its large interlayer distance(~0.7 nm),high capacity,and low cost;however,such cathodes suffer from struc...The layeredδ-MnO_(2)(dMO)is an excellent cathode material for rechargeable aqueous zinc-ion batteries owing to its large interlayer distance(~0.7 nm),high capacity,and low cost;however,such cathodes suffer from structural degradation during the long-term cycling process,leading to capacity fading.In this study,a Co-doped dMO composite with reduced graphene oxide(GC-dMO)is developed using a simple cost-effective hydrothermal method.The degree of disorderness increases owing to the hetero-atom doping and graphene oxide composites.It is demonstrated that layered dMO and GC-dMO undergo a structural transition from K-birnessite to the Zn-buserite phase upon the first discharge,which enhances the intercalation of Zn^(2+)ions,H_(2)O molecules in the layered structure.The GC-dMO cathode exhibits an excellent capacity of 302 mAh g^(-1)at a current density of 100 mAg^(-1)after 100 cycles as compared with the dMO cathode(159 mAhg^(-1)).The excellent electrochemical performance of the GC-dMO cathode owing to Co-doping and graphene oxide sheets enhances the interlayer gap and disorderness,and maintains structural stability,which facilitates the easy reverse intercalation and de-intercalation of Zn^(2+)ions and H_(2)O molecules.Therefore,GC-dMO is a promising cathode material for large-scale aqueous ZIBs.展开更多
In order to solve negative phase sequence problem of V connection transformer in the high speed and heavy haul electrical railway of China, the hybrid compensative co-phase traction power supply system which based on ...In order to solve negative phase sequence problem of V connection transformer in the high speed and heavy haul electrical railway of China, the hybrid compensative co-phase traction power supply system which based on passive and active compensation is proposed. Firstly, There construction and capacity distribution are analyzed, and the compensation current of active equipment is gave;Second, the feature of the hybrid compensative schemes are discussed. In the end, the related simulation results have confirmed the effectiveness of the compensation schemes in this paper.展开更多
We propose a method for the compensation and phase correction of the amplitude spectrum based on the generalized S transform. The compensation of the amplitude spectrum within a reliable frequency range of the seismic...We propose a method for the compensation and phase correction of the amplitude spectrum based on the generalized S transform. The compensation of the amplitude spectrum within a reliable frequency range of the seismic record is performed in the S domain to restore the amplitude spectrum of reflection. We use spectral simulation methods to fit the time-dependent amplitude spectrum and compensate for the amplitude attenuation owing to absorption. We use phase scanning to select the time-, space-, and frequencydependent phases correction based on the parsimony criterion and eliminate the residual phase effect of the wavelet in the S domain. The method does not directly calculate the Q value; thus, it can be applied to the case of variable Q. The comparison of the theory model and field data verify that the proposed method can recover the amplitude spectrum of the strata reflectivity, while eliminating the effect of the residual phase of the wavelet. Thus, the wavelet approaches the zero-phase wavelet and, the seismic resolution is improved.展开更多
Heat treatment of Ti-50.9%Ni (mole fraction) alloy was studied by differential scanning calorimetry, X-ray diffraction, scanning electron microscopey and energy dispersive X-ray analysis to investigate the influence...Heat treatment of Ti-50.9%Ni (mole fraction) alloy was studied by differential scanning calorimetry, X-ray diffraction, scanning electron microscopey and energy dispersive X-ray analysis to investigate the influence of cooling rate on transformation behavior and microstructures of NiTi shape memory alloy. The experimental results show that three-stage phase transformation can be induced at a very low cooling rate such as cooling in furnace. The cooling rate also has a great influence on the phase transformation temperatures. Both martensitic start transformation temperature (Ms) and martensitic finish transformation temperature (Mf) decrease with the decrease of the cooling rate, and decreasing the cooling rate contributes to enhancing the M→A austenite transformation temperature. The phase transformation hysteresis (Af-Mf) increases with the decrease of the cooling rate. Heat treatment is unable to eliminate the textures formed in hot working of NiTi sample, but can weaken the intensity of them. The cooling rate has little influence on the grain size.展开更多
In order to remove or reduce the negative effect of MgO in calcium aluminate slags, the method of adding Na2O into calcium aluminate slags was studied and its effect on leaching mechanism was also analyzed. The result...In order to remove or reduce the negative effect of MgO in calcium aluminate slags, the method of adding Na2O into calcium aluminate slags was studied and its effect on leaching mechanism was also analyzed. The results show that the alumina leaching efficiency of the calcium aluminate slag increases from 68.73% to 80.86% with Na2O content increasing from 0 to 4% when MgO content is 3%. The XRD results show that the quaternary compound C20A13M3S3 disappears when Na2O content increases to 4%. The addition of Na2O cannot remove the negative effect of MgO on leachability completely. XRD and EDS results indicate that Na2O can come into the lattice of 12CaO·7Al2O3 and promote the formation of 12CaO·7Al2O3展开更多
Combining with the low temperature material properties and the boiling heat transfer coefficient of specimen immersed in the liquid nitrogen, a numerical model based on metallo-thermo-mechanical couple theory was esta...Combining with the low temperature material properties and the boiling heat transfer coefficient of specimen immersed in the liquid nitrogen, a numerical model based on metallo-thermo-mechanical couple theory was established to reproduce the deep cryogenic treatment (DCT) process of a newly developed cold work die steel Cr8Mo2SiV (SDC99). Moreover, an experimental setup for rapid temperature measurement was designed to validate the simulation results. The investigation suggests that the differences in temperature and cooling rate between the surface and core of specimen are very significant. However, it should be emphasized that the acute temperature and cooling rate changes during DCT are mainly concentrated on the specimen surface region about 1/3 of the sample thickness. Subjected to DCT, the retained austenite of quenched specimen continues to transform to martensite and finally its phase volume fraction reduces to 2.3%. The predicted results are coincident well with the experimental data, which demonstrates that the numerical model employed in this study can accurately capture the variation characteristics of temperature and microstructure fields during DCT and provide a theoretical guidance for making the reasonable DCT procedure.展开更多
TA2 pure titanium was chosen to research the interaction among deformation, recrystallization and phase transformation during hot compression. The samples were hot compressed by thermal simulation method with differen...TA2 pure titanium was chosen to research the interaction among deformation, recrystallization and phase transformation during hot compression. The samples were hot compressed by thermal simulation method with different processing parameters. Variant selection induced by stress during cooling after compression was found. The prismatical texture component which featured that the [0001] direction perpendicular to the compressing direction produced preferentially under the compressing stress. As a result, the transformedα phase possesses strong prismatical texture which is different with the basal texture of compressed αphase. The minimum elastic strain energy is demonstrated to be the main reason that causes the variant selection. Dynamic recrystallization behavior and microstructure evolution during hot compression were also studied.展开更多
The hydrogen-induced microstructure evolution and phase transformations in Ti-6Al-4V alloy during heating and cooling were studied.The specimens were heated to 1273 K and subsequently cooled to room temperature.The hy...The hydrogen-induced microstructure evolution and phase transformations in Ti-6Al-4V alloy during heating and cooling were studied.The specimens were heated to 1273 K and subsequently cooled to room temperature.The hydrogen content is up to 0.8%(mass fraction).The hydrogen-induced dynamic phase transformations and the corresponding mechanisms were analyzed.When the hydrogen content increases,the β transus temperature significantly decreases and the magnitude decreases,and the volume fraction of β phase increases.During heating,the phase transformations in hydrogenated Ti-6Al-4V alloys can be divided into three stages,and the phase transformation order is δ→α+H2↑?δ+α′→βH?α′→αH+βH?αH→α+H2↑?α→β?βH→β+H2↑.In addition,the relationship among hydrogenation and Ms and Mf of α′ martensite were determined.展开更多
The microstructural evolution and phase transformations during partial remelting of in-situ Mg2Sip/AM60B composite modified by SiC and Sr were investigated. The results indicate that SiC and Sr are effective for refi...The microstructural evolution and phase transformations during partial remelting of in-situ Mg2Sip/AM60B composite modified by SiC and Sr were investigated. The results indicate that SiC and Sr are effective for refining primary α-Mg grains and Mg2Si particles. After being partially remelted, a semisolid microstructure with small and spheroidal primary α-Mg particles can be obtained. The microstructural evolution during partial remelting can be divided into four stages: the initial rapid coarsening, structural separation, spheroidization and final coarsening, which are essentially caused by the phase transformations of β→α, α+β→L and α→L, α→L, and α→L and L→α, respectively. The Mg2Si particles have not obvious effect on the general microstructural evolution steps, but can slower the evolution progress and change the coarsening mechanism. During partial remelting, Mg2Si particles first become blunt and then become spheroidal because of melting of their edges and corners, and finally are coarsened owing to Ostwald ripening.展开更多
Correlation between site occupation evolution of alloying elements in L12 phase and growth of DO22 phase in Ni75Al7.5V17.5 was studied using microscopic phase field model. The results demonstrate that the growing proc...Correlation between site occupation evolution of alloying elements in L12 phase and growth of DO22 phase in Ni75Al7.5V17.5 was studied using microscopic phase field model. The results demonstrate that the growing process of DO22 phase can be divided into two stages. At the early stage, composition in the centre part of L12 phase almost remains unchanged, and the nucleation and growth of DO22 phase is controlled by the decrease of interface between L12 phases. At the late stage, part of V for growth of DO22 phase is supplied from the centre part of L12 phase and mainly comes from Al sublattice, the excess Ni spared from the decreasing L12 phase migrates into the centre part of L12 phase and occupies the Ni sublattices exclusively, while the excess Al mainly occupies the Al sublattice. At the late stage, the growth of DO22 phase is controlled by the evolution of antisite atoms and ternary additions in the centre part of L12 phase.展开更多
Based on the microscopic phase-field model, the correlation between site occupation evolution of alloying elements in Ni3V-DO22 phase and growth of Ni3Al-L12 phase was studied during the phase transformation of Ni75Al...Based on the microscopic phase-field model, the correlation between site occupation evolution of alloying elements in Ni3V-DO22 phase and growth of Ni3Al-L12 phase was studied during the phase transformation of Ni75Al4.2V20.8. The results demonstrate that the growth of L12 phase can be divided into two stages: at the early stage, the composition of alloying elements in DO22 phase almost remains unchanged; at the late stage, the compositions of Ni and Al decrease while V increases in DO22 phase. Part of alloying elements for L12 phase growth are supplied from the site occupation evolution of alloying elements on three kinds of sublattices in DO22 phase. Ni is mainly supplied from V sublattice, and part of Al is supplied from NiⅠ and V sites at the centre of DO22 phase. The excessive V from the decreasing DO22 phase migrates into the centre of DO22 phase and mainly occupies V and NiII sites. It is the site occupation evolution of antisite atoms and ternary additions in DO22 phase that controls the growth rate of L12 phase at the late stage.展开更多
α-titanium and its alloys with a dual-phase structure (α+β) were deformed dynamically under strain rate of about 10^4 s^-1. The formation and microstructural evolution of the localized shear bands were character...α-titanium and its alloys with a dual-phase structure (α+β) were deformed dynamically under strain rate of about 10^4 s^-1. The formation and microstructural evolution of the localized shear bands were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results reveal that both the strain and strain rate should be considered simultaneously as the mechanical conditions for shear band formation, and twinning is an important mode of deformation. Both experimental and calculation show that the materials within the bands underwent a superhigh strain rate (9×10^5 S^-1) deformation, which is two magnitudes of that of average strain rate required for shear band formation; the dislocations in the bands can be constricted and developed into cell structures; the phase transformation from α to α2 within the bands was observed, and the transformation products (α2) had a certain crystallographic orientation relationship with their parent; the equiaxed grains with an average size of 10 μm in diameter observed within the bands are proposed to be the results of recrystallization.展开更多
Microstructural evolution and phase transformation induced by different heat treatments of the hypereutectic aluminium-silicon alloy, Al-25Si-5Fe-3Cu (wt%, signed as 3C), fabricated by traditional cast (TC) and sp...Microstructural evolution and phase transformation induced by different heat treatments of the hypereutectic aluminium-silicon alloy, Al-25Si-5Fe-3Cu (wt%, signed as 3C), fabricated by traditional cast (TC) and spray forming (SF) processes, were investigated by differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) combined with energy dispersive X-ray spectroscopy and X-ray diffraction techniques. The results show that A17Cu2Fe phase can be formed and transformed in TC- and SF-3C alloys between 802-813 K and 800-815 K, respectively. The transformation from β-Al5FeSi to δ-Al4FeSi2 phase via peritectic reaction can occur at around 858-870 K and 876-890 K in TC- and SF-3C alloys, respectively. The starting precipitation temperature of δ-Al4FeSi2 phase as the dominant Fe-bearing phase in the TC-3C alloy is 997 K and the exothermic peak about the peritectic transformation of δ-Al4FeSi2→β-Al5FeSi is not detected in the present DSC experiments. Also, the mechanisms of the microstructural evolution and phase transformation are discussed.展开更多
In this paper, we present wavelet transformation method to measure interstation phase velocity. We use Morlet wavelet function as mother wavelet to filter two seismograms at various period of interest, and correlate t...In this paper, we present wavelet transformation method to measure interstation phase velocity. We use Morlet wavelet function as mother wavelet to filter two seismograms at various period of interest, and correlate the wavelet filtered seismograms to form cross-correlogram. If both wavelet filtered signals are in phase at that period, the phase of the cross-correlogram is a minimum. Using 3-spline interpolation to transform cross-correlation matrix to a phase velocity verse period image, it is convenient for us to measure interstation phase velocity.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.U23A20540,52371127)the Science and Technology Innovation Program of Hunan Province,China(No.2022RC3035)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2024ZZTS0077)。
文摘Due to a series of exceptional properties,titanium and titanium alloys have received extensive attention in recent years.Different from other alloy systems,there are two allotropes and a sequence of metastable phases in titanium alloys.By summarizing the recent investigations,the phase transformation processes corresponding to the common phases and also some less reported phases are reviewed.For the phase transformation only involvingαandβphases,it can be divided intoβ→αtransformation and a reverse transformation.The former one has been demonstrated from the orientation relationship betweenαandβphases and the regulation ofαmorphology.For the latter transformation,the role of the stress has been discussed.In terms of the metastable phases,the mechanisms of phase formation and their effects on microstructure and mechanical properties have been discussed.Finally,some suggestions about the development of titanium alloys have been proposed.
基金supported by the National Key Research and Development Program of China(2021YFB3501002)State Key Program of National Natural Science Foundation of China(5203405)+3 种基金National Natural Science Foundation of China(51974220,52104383)National Key Research and Development Program of China(2021YFB3700902)Key Research and Development Program of Shaanxi Province(2020ZDLGY13-06,2017ZDXM-GY-037)Shaanxi Province National Science Fund for Distinguished Young Scholars(2022JC-24)。
文摘A large-scale fine-grained Mg-Gd-Y-Zn-Zr alloy plate with high strength and ductility was successfully prepared by multi-pass friction stir processing(MFSP)technology in this work.The structure of grains and long period stacking ordered(LPSO)phase were characterized,and the mechanical properties uniformity was investigated.Moreover,a quantitative relationship between the microstructure and tensile yield strength was established.The results showed that the grains in the processed zone(PZ)and interfacial zone(IZ)were refined from 50μm to 3μm and 4μm,respectively,and numerous original LPSO phases were broken.In IZ,some block-shaped 18R LPSO phases were transformed into needle-like 14H LPSO phases due to stacking faults and the short-range diffusion of solute atoms.The severe shear deformation in the form of kinetic energy caused profuse stacking fault to be generated and move rapidly,greatly increasing the transformation rate of LPSO phase.After MFSP,the ultimate tensile strength,yield strength and elongation to failure of the large-scale plate were 367 MPa,305 MPa and 18.0% respectively.Grain refinement and LPSO phase strengthening were the major strengthening mechanisms for the MFSP sample.In particularly,the strength of IZ was comparable to that of PZ because the strength contribution of the 14H LPSO phase offsets the lack of grain refinement strengthening in IZ.This result opposes the widely accepted notion that IZ is a weak region in MFSP-prepared large-scale fine-grained plate.
基金supported by the National Natural Science Foundation of China (Grant No.12072331)the Science Challenge Project (Grant No.TZ2018001)+2 种基金the Japan Society for the Promotion of Science (Grant Nos.17H04820 and 21H01677)the Foundation of the United Laboratory of High-Pressure Physics and Earthquake Scienceperformed under the approval of the Photon Factory Program Advisory Committee (Proposal Nos.2016S2-006 and 2020G680)。
文摘A time-resolved x-ray diffraction technique is employed to monitor the structural transformation of laser-shocked bismuth.Results reveal a retarded transformation from the shock-induced Bi-Ⅴphase to a metastable Bi-Ⅳphase during the shock release,instead of the thermodynamically stable Bi-Ⅲphase.The emergence of the metastable Bi-Ⅳphase is understood by the competitive interplay between two transformation pathways towards the Bi-Ⅳand Bi-Ⅲ,respectively.The former is more rapid than the latter because the Bi-Ⅴto B-Ⅳtransformation is driven by interaction between the closest atoms while the Bi-Ⅴto B-Ⅲtransformation requires interaction between the second-closest atoms.The nucleation time for the Bi-Ⅴto Bi-Ⅳtransformation is determined to be 5.1±0.9 ns according to a classical nucleation model.This observation demonstrates the importance of the formation of the transient metastable phases,which can change the phase transformation pathway in a dynamic process.
基金supported by the National Key Research and Development Program of China(No.2023YFC 2909000)the National Natural Science Foundation of China(No.52174240)+4 种基金the Major Science and Technology Projects of Xinjiang Uygur Autonomous Region(No.2023A03003-2)the XingLiao Talent Program of Liaoning Province(No.XLYC2203167)the Excellent Youth Fund Project of Liaoning Natural Science Foundation(No.2023JH3/10200010)the Fundamental Research Funds for the Central Universities(No.N23011026)the Open Foundation of State Key Laboratory of Mineral Processing(No.BGRIMM-KJSKL-2023-15).
文摘Pyrolusite comprises the foremost manganese oxides and is a major source of manganese production.An innovative hydrogenbased mineral phase transformation technology to pyrolusite was proposed,where a 96.44%distribution rate of divalent manganese(Mn^(2+))was observed at an optimal roasting temperature of 650℃,a roasting time of 25 min,and an H2 concentration of 20vol%;under these conditions.The manganese predominantly existed in the form of manganosite.This study investigated the generation mechanism of manganosite based on the reduction kinetics,phase transformation,and structural evolution of pyrolusite and revealed that high temperature improved the distribution rate,and the optimal kinetic model for the reaction was the random nucleation and growth model(reaction order,n=3/2)with an activation energy(E_(a))of 24.119 kJ·mol^(−1).Throughout the mineral phase transformation,manganese oxide from the outer layer of particles moves inward to the core.In addition,pyrolusite follows the reduction sequence of MnO_(2)→Mn_(2)O_(3)→Mn_(3)O_(4)→MnO,and the reduction of manganese oxides in each valence state simultaneously proceeds.These findings provide significant insight into the efficient and clean utilization of pyrolusite.
基金financially supported by the National Key Research and Development Program of China (No.2023YFC2909000)the National Natural Science Foundation of China(No.52174240)the Open Foundation of State Key Laboratory of Mineral Processing (No.BGRIMM-KJSKL-2023-15)。
文摘The mechanism involved in the phase transformation process of pyrolusite (MnO_(2)) during roasting in a reducing atmosphere was systematically elucidated in this study,with the aim of effectively using low-grade complex manganese ore resources.According to single-factor experiment results,the roasted product with a divalent manganese (Mn^(2+)) distribution rate of 95.30% was obtained at a roasting time of 25 min,a roasting temperature of 700℃,a CO concentration of 20at%,and a total gas volume of 500 mL·min^(-1),in which the manganese was mainly in the form of manganosite (MnO).Scanning electron microscopy and Brunauer–Emmett–Teller theory demonstrated the microstructural evolution of the roasted product and the gradual reduction in the pyrolusite ore from the surface to the core Thermodynamic calculations,X-ray photoelectron spectroscopy,and X-ray diffractometry analyses determined that the phase transformation of pyrolusite followed the order of MnO_(2)→Mn_(2)O_(3)→Mn_(3)O_(4)→MnO phase by phase,and the reduction of manganese oxides in each valence state proceeded simultaneously.
基金supported by the National Research Foundation of Korea(NRF)grants funded by the Korean Government(NRF-2021R1A4A1030318,NRF-2022R1C1C1011386,NRF-2020M3H4A1A03084258)supported by the"Regional Innovation Strategy(RIS)"through the National Research Foundation of Korea(NRF)funded by the Ministry of Education(MOE)(2021RIS-003)
文摘The layeredδ-MnO_(2)(dMO)is an excellent cathode material for rechargeable aqueous zinc-ion batteries owing to its large interlayer distance(~0.7 nm),high capacity,and low cost;however,such cathodes suffer from structural degradation during the long-term cycling process,leading to capacity fading.In this study,a Co-doped dMO composite with reduced graphene oxide(GC-dMO)is developed using a simple cost-effective hydrothermal method.The degree of disorderness increases owing to the hetero-atom doping and graphene oxide composites.It is demonstrated that layered dMO and GC-dMO undergo a structural transition from K-birnessite to the Zn-buserite phase upon the first discharge,which enhances the intercalation of Zn^(2+)ions,H_(2)O molecules in the layered structure.The GC-dMO cathode exhibits an excellent capacity of 302 mAh g^(-1)at a current density of 100 mAg^(-1)after 100 cycles as compared with the dMO cathode(159 mAhg^(-1)).The excellent electrochemical performance of the GC-dMO cathode owing to Co-doping and graphene oxide sheets enhances the interlayer gap and disorderness,and maintains structural stability,which facilitates the easy reverse intercalation and de-intercalation of Zn^(2+)ions and H_(2)O molecules.Therefore,GC-dMO is a promising cathode material for large-scale aqueous ZIBs.
文摘In order to solve negative phase sequence problem of V connection transformer in the high speed and heavy haul electrical railway of China, the hybrid compensative co-phase traction power supply system which based on passive and active compensation is proposed. Firstly, There construction and capacity distribution are analyzed, and the compensation current of active equipment is gave;Second, the feature of the hybrid compensative schemes are discussed. In the end, the related simulation results have confirmed the effectiveness of the compensation schemes in this paper.
基金supported by the National Natural Science Foundation of China(No.41204091)New Teachers’ Fund for Doctor Stations,the Ministry of Education(No.20105122120001)Science and Technology Support Program from Science and Technology Department of Sichuan Province(No.2011GZ0244)
文摘We propose a method for the compensation and phase correction of the amplitude spectrum based on the generalized S transform. The compensation of the amplitude spectrum within a reliable frequency range of the seismic record is performed in the S domain to restore the amplitude spectrum of reflection. We use spectral simulation methods to fit the time-dependent amplitude spectrum and compensate for the amplitude attenuation owing to absorption. We use phase scanning to select the time-, space-, and frequencydependent phases correction based on the parsimony criterion and eliminate the residual phase effect of the wavelet in the S domain. The method does not directly calculate the Q value; thus, it can be applied to the case of variable Q. The comparison of the theory model and field data verify that the proposed method can recover the amplitude spectrum of the strata reflectivity, while eliminating the effect of the residual phase of the wavelet. Thus, the wavelet approaches the zero-phase wavelet and, the seismic resolution is improved.
基金Project (51071056) supported by the National Natural Science Foundation of ChinaProjects (HEUCFR1132, HEUCF121712) supported by the Fundamental Research Funds for the Central Universities of China
文摘Heat treatment of Ti-50.9%Ni (mole fraction) alloy was studied by differential scanning calorimetry, X-ray diffraction, scanning electron microscopey and energy dispersive X-ray analysis to investigate the influence of cooling rate on transformation behavior and microstructures of NiTi shape memory alloy. The experimental results show that three-stage phase transformation can be induced at a very low cooling rate such as cooling in furnace. The cooling rate also has a great influence on the phase transformation temperatures. Both martensitic start transformation temperature (Ms) and martensitic finish transformation temperature (Mf) decrease with the decrease of the cooling rate, and decreasing the cooling rate contributes to enhancing the M→A austenite transformation temperature. The phase transformation hysteresis (Af-Mf) increases with the decrease of the cooling rate. Heat treatment is unable to eliminate the textures formed in hot working of NiTi sample, but can weaken the intensity of them. The cooling rate has little influence on the grain size.
基金Project (51104053) supported by the National Natural Science Foundation of ChinaProject (XL200921) supported by the Foundation Research funds for Hebei University of Science and Technology, China
文摘In order to remove or reduce the negative effect of MgO in calcium aluminate slags, the method of adding Na2O into calcium aluminate slags was studied and its effect on leaching mechanism was also analyzed. The results show that the alumina leaching efficiency of the calcium aluminate slag increases from 68.73% to 80.86% with Na2O content increasing from 0 to 4% when MgO content is 3%. The XRD results show that the quaternary compound C20A13M3S3 disappears when Na2O content increases to 4%. The addition of Na2O cannot remove the negative effect of MgO on leachability completely. XRD and EDS results indicate that Na2O can come into the lattice of 12CaO·7Al2O3 and promote the formation of 12CaO·7Al2O3
基金Project (51171104) supported by the National Natural Science Foundation of China
文摘Combining with the low temperature material properties and the boiling heat transfer coefficient of specimen immersed in the liquid nitrogen, a numerical model based on metallo-thermo-mechanical couple theory was established to reproduce the deep cryogenic treatment (DCT) process of a newly developed cold work die steel Cr8Mo2SiV (SDC99). Moreover, an experimental setup for rapid temperature measurement was designed to validate the simulation results. The investigation suggests that the differences in temperature and cooling rate between the surface and core of specimen are very significant. However, it should be emphasized that the acute temperature and cooling rate changes during DCT are mainly concentrated on the specimen surface region about 1/3 of the sample thickness. Subjected to DCT, the retained austenite of quenched specimen continues to transform to martensite and finally its phase volume fraction reduces to 2.3%. The predicted results are coincident well with the experimental data, which demonstrates that the numerical model employed in this study can accurately capture the variation characteristics of temperature and microstructure fields during DCT and provide a theoretical guidance for making the reasonable DCT procedure.
文摘TA2 pure titanium was chosen to research the interaction among deformation, recrystallization and phase transformation during hot compression. The samples were hot compressed by thermal simulation method with different processing parameters. Variant selection induced by stress during cooling after compression was found. The prismatical texture component which featured that the [0001] direction perpendicular to the compressing direction produced preferentially under the compressing stress. As a result, the transformedα phase possesses strong prismatical texture which is different with the basal texture of compressed αphase. The minimum elastic strain energy is demonstrated to be the main reason that causes the variant selection. Dynamic recrystallization behavior and microstructure evolution during hot compression were also studied.
基金Project(51275132)supported by the National Natural Science Foundation of China
文摘The hydrogen-induced microstructure evolution and phase transformations in Ti-6Al-4V alloy during heating and cooling were studied.The specimens were heated to 1273 K and subsequently cooled to room temperature.The hydrogen content is up to 0.8%(mass fraction).The hydrogen-induced dynamic phase transformations and the corresponding mechanisms were analyzed.When the hydrogen content increases,the β transus temperature significantly decreases and the magnitude decreases,and the volume fraction of β phase increases.During heating,the phase transformations in hydrogenated Ti-6Al-4V alloys can be divided into three stages,and the phase transformation order is δ→α+H2↑?δ+α′→βH?α′→αH+βH?αH→α+H2↑?α→β?βH→β+H2↑.In addition,the relationship among hydrogenation and Ms and Mf of α′ martensite were determined.
基金Project(G2010CB635106)supported by the National Basic Research Program of ChinaProject(NCET-10-0023)supported by the Program for New Century Excellent Talents in University of ChinaProject supported by the Program for Hongliu Outstanding Talents of Lanzhou University of Technology,China
文摘The microstructural evolution and phase transformations during partial remelting of in-situ Mg2Sip/AM60B composite modified by SiC and Sr were investigated. The results indicate that SiC and Sr are effective for refining primary α-Mg grains and Mg2Si particles. After being partially remelted, a semisolid microstructure with small and spheroidal primary α-Mg particles can be obtained. The microstructural evolution during partial remelting can be divided into four stages: the initial rapid coarsening, structural separation, spheroidization and final coarsening, which are essentially caused by the phase transformations of β→α, α+β→L and α→L, α→L, and α→L and L→α, respectively. The Mg2Si particles have not obvious effect on the general microstructural evolution steps, but can slower the evolution progress and change the coarsening mechanism. During partial remelting, Mg2Si particles first become blunt and then become spheroidal because of melting of their edges and corners, and finally are coarsened owing to Ostwald ripening.
基金Projects (50941020, 10902086, 50875217, 20903075) supported by the National Natural Science Foundation of ChinaProjects (SJ08-ZT05, SJ08-B14) supported by the Natural Science Foundation of Shaanxi Province, China
文摘Correlation between site occupation evolution of alloying elements in L12 phase and growth of DO22 phase in Ni75Al7.5V17.5 was studied using microscopic phase field model. The results demonstrate that the growing process of DO22 phase can be divided into two stages. At the early stage, composition in the centre part of L12 phase almost remains unchanged, and the nucleation and growth of DO22 phase is controlled by the decrease of interface between L12 phases. At the late stage, part of V for growth of DO22 phase is supplied from the centre part of L12 phase and mainly comes from Al sublattice, the excess Ni spared from the decreasing L12 phase migrates into the centre part of L12 phase and occupies the Ni sublattices exclusively, while the excess Al mainly occupies the Al sublattice. At the late stage, the growth of DO22 phase is controlled by the evolution of antisite atoms and ternary additions in the centre part of L12 phase.
基金Projects(51174168,51274167)supported by the National Natural Science Foundation of ChinaProject(2013M532082)supported by Postdoctoral Science Foundation of ChinaProjects(13R21421700,13R21421800)supported by the Postdoctoral Science Foundation of Shanghai,China
文摘Based on the microscopic phase-field model, the correlation between site occupation evolution of alloying elements in Ni3V-DO22 phase and growth of Ni3Al-L12 phase was studied during the phase transformation of Ni75Al4.2V20.8. The results demonstrate that the growth of L12 phase can be divided into two stages: at the early stage, the composition of alloying elements in DO22 phase almost remains unchanged; at the late stage, the compositions of Ni and Al decrease while V increases in DO22 phase. Part of alloying elements for L12 phase growth are supplied from the site occupation evolution of alloying elements on three kinds of sublattices in DO22 phase. Ni is mainly supplied from V sublattice, and part of Al is supplied from NiⅠ and V sites at the centre of DO22 phase. The excessive V from the decreasing DO22 phase migrates into the centre of DO22 phase and mainly occupies V and NiII sites. It is the site occupation evolution of antisite atoms and ternary additions in DO22 phase that controls the growth rate of L12 phase at the late stage.
基金This research was supported by the National Nature Science Foundation of China(No.50071064).
文摘α-titanium and its alloys with a dual-phase structure (α+β) were deformed dynamically under strain rate of about 10^4 s^-1. The formation and microstructural evolution of the localized shear bands were characterized by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results reveal that both the strain and strain rate should be considered simultaneously as the mechanical conditions for shear band formation, and twinning is an important mode of deformation. Both experimental and calculation show that the materials within the bands underwent a superhigh strain rate (9×10^5 S^-1) deformation, which is two magnitudes of that of average strain rate required for shear band formation; the dislocations in the bands can be constricted and developed into cell structures; the phase transformation from α to α2 within the bands was observed, and the transformation products (α2) had a certain crystallographic orientation relationship with their parent; the equiaxed grains with an average size of 10 μm in diameter observed within the bands are proposed to be the results of recrystallization.
基金supported by the Major State Basic Research & Development Program of China (No2006CB605204)
文摘Microstructural evolution and phase transformation induced by different heat treatments of the hypereutectic aluminium-silicon alloy, Al-25Si-5Fe-3Cu (wt%, signed as 3C), fabricated by traditional cast (TC) and spray forming (SF) processes, were investigated by differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) combined with energy dispersive X-ray spectroscopy and X-ray diffraction techniques. The results show that A17Cu2Fe phase can be formed and transformed in TC- and SF-3C alloys between 802-813 K and 800-815 K, respectively. The transformation from β-Al5FeSi to δ-Al4FeSi2 phase via peritectic reaction can occur at around 858-870 K and 876-890 K in TC- and SF-3C alloys, respectively. The starting precipitation temperature of δ-Al4FeSi2 phase as the dominant Fe-bearing phase in the TC-3C alloy is 997 K and the exothermic peak about the peritectic transformation of δ-Al4FeSi2→β-Al5FeSi is not detected in the present DSC experiments. Also, the mechanisms of the microstructural evolution and phase transformation are discussed.
基金funded by Na-tional Natural Science Foundation of China (No.40774039)
文摘In this paper, we present wavelet transformation method to measure interstation phase velocity. We use Morlet wavelet function as mother wavelet to filter two seismograms at various period of interest, and correlate the wavelet filtered seismograms to form cross-correlogram. If both wavelet filtered signals are in phase at that period, the phase of the cross-correlogram is a minimum. Using 3-spline interpolation to transform cross-correlation matrix to a phase velocity verse period image, it is convenient for us to measure interstation phase velocity.