QPA (Quantitative Phase Analysis) of carbonate rocks bearing calcite and dolomite using X-ray diffractometry (XRD) can be performed using the combined Rietveld Structure Refinement (RSR) and semiquantitative Reference...QPA (Quantitative Phase Analysis) of carbonate rocks bearing calcite and dolomite using X-ray diffractometry (XRD) can be performed using the combined Rietveld Structure Refinement (RSR) and semiquantitative Reference Intensity Ratio (RIR) methods, providing an estimation of crystalline phase in a mixture. Different ratios of five samples were prepared by mixing these crystal minerals with high sensitively. The scan speeds, adequate to determine mineral phases in rock samples, were used as 6 degrees per minute with 0.08 steps. The XRD analysis with commercial TOPAS 3.0 program, defined by a new generation of profile and structure analysis software, based on RSR provides Bragg reflection profiles and the dimension of the unit cell of a phase. The weight fractions of each phase were found by Le Bail and Pawley methods in RSR using a pseudo-Voigt peak shape model. The samples were also characterized by using X-ray fluorescence (XRF) and atomic absorption spectrometer (AAS). These analyses were conducted to compare these results with those obtained from the RSR. In addition to these, RSR of phases is very important to improve the goodness of fit (GOF). Therefore, the discussions of refinement of the carbonate mixing were made and a refinement procedure was given for these mixing in detail. Taking advantage of the RSR with the addition of an internal standard, the phase fraction of all the crystalline phases as well as the amorphous component, has been accurately determined. RSR technique offers a valid support for the characterization of marble in the light of industrial products.展开更多
Both Cu60Ni38Co2 and Cu60Ni40 alloy were naturally cooled after rapid solidification from the liquid phase.The transformation law of the microstructure characteristics of the rapidly solidified alloy with the change o...Both Cu60Ni38Co2 and Cu60Ni40 alloy were naturally cooled after rapid solidification from the liquid phase.The transformation law of the microstructure characteristics of the rapidly solidified alloy with the change of undercooling(ΔT)was systematically studied.It is found that the two alloys experience the same transformation process.The refinement structures under different undercoolings were characterized by electron backscatter diffraction(EBSD).The results show that the characteristics of the refinement structure of the two alloys with low undercooling are the same,but the characteristics of the refinement structure with high undercooling are opposite.The transmission electron microscopy(TEM)results of Cu60Ni38Co2 alloy show that the dislocation network density of low undercooled microstructure is lower than that of high undercooled microstructure.By combining EBSD and TEM,it could be confirmed that the dendrite remelting fracture is the reason for the refinement of the low undercooled structure,while the high undercooled structure is refined due to recrystallization.On this basis,in the processing of copper base alloys,there will be serious work hardening phenomenon and machining hard problem of consciousness problems caused by excessive cutting force.A twodimensional orthogonal turning finite element model was established using ABAQUS software to analyze the changes in cutting speed and tool trajectory in copper based alloy ultrasonic elliptical vibration turning.The results show that in copper based alloy ultrasonic elliptical vibration turning,cutting process parameters have a significant impact on cutting force.Choosing reasonable process parameters can effectively reduce cutting force and improve machining quality.展开更多
The crystal structure of compound ErNiSb has been refined by the Rietveld wholepatternfitting method from X-ray powder diffraction data.The compound ErNiSb is cubic, space group F43m and the structure parameters and r...The crystal structure of compound ErNiSb has been refined by the Rietveld wholepatternfitting method from X-ray powder diffraction data.The compound ErNiSb is cubic, space group F43m and the structure parameters and reliability factors were refined to be a=6.268 3(1), V=246.29^(3), Z=4, D_(x)=9.377 g/cm^3, R_(B)=3.57%, R_(F)=3.64%, R_(p)=6.63%, R_(WP)=8.80%.展开更多
文摘QPA (Quantitative Phase Analysis) of carbonate rocks bearing calcite and dolomite using X-ray diffractometry (XRD) can be performed using the combined Rietveld Structure Refinement (RSR) and semiquantitative Reference Intensity Ratio (RIR) methods, providing an estimation of crystalline phase in a mixture. Different ratios of five samples were prepared by mixing these crystal minerals with high sensitively. The scan speeds, adequate to determine mineral phases in rock samples, were used as 6 degrees per minute with 0.08 steps. The XRD analysis with commercial TOPAS 3.0 program, defined by a new generation of profile and structure analysis software, based on RSR provides Bragg reflection profiles and the dimension of the unit cell of a phase. The weight fractions of each phase were found by Le Bail and Pawley methods in RSR using a pseudo-Voigt peak shape model. The samples were also characterized by using X-ray fluorescence (XRF) and atomic absorption spectrometer (AAS). These analyses were conducted to compare these results with those obtained from the RSR. In addition to these, RSR of phases is very important to improve the goodness of fit (GOF). Therefore, the discussions of refinement of the carbonate mixing were made and a refinement procedure was given for these mixing in detail. Taking advantage of the RSR with the addition of an internal standard, the phase fraction of all the crystalline phases as well as the amorphous component, has been accurately determined. RSR technique offers a valid support for the characterization of marble in the light of industrial products.
基金Funded by the Basic Research Projects in Shanxi Province(202103021224183)。
文摘Both Cu60Ni38Co2 and Cu60Ni40 alloy were naturally cooled after rapid solidification from the liquid phase.The transformation law of the microstructure characteristics of the rapidly solidified alloy with the change of undercooling(ΔT)was systematically studied.It is found that the two alloys experience the same transformation process.The refinement structures under different undercoolings were characterized by electron backscatter diffraction(EBSD).The results show that the characteristics of the refinement structure of the two alloys with low undercooling are the same,but the characteristics of the refinement structure with high undercooling are opposite.The transmission electron microscopy(TEM)results of Cu60Ni38Co2 alloy show that the dislocation network density of low undercooled microstructure is lower than that of high undercooled microstructure.By combining EBSD and TEM,it could be confirmed that the dendrite remelting fracture is the reason for the refinement of the low undercooled structure,while the high undercooled structure is refined due to recrystallization.On this basis,in the processing of copper base alloys,there will be serious work hardening phenomenon and machining hard problem of consciousness problems caused by excessive cutting force.A twodimensional orthogonal turning finite element model was established using ABAQUS software to analyze the changes in cutting speed and tool trajectory in copper based alloy ultrasonic elliptical vibration turning.The results show that in copper based alloy ultrasonic elliptical vibration turning,cutting process parameters have a significant impact on cutting force.Choosing reasonable process parameters can effectively reduce cutting force and improve machining quality.
文摘The crystal structure of compound ErNiSb has been refined by the Rietveld wholepatternfitting method from X-ray powder diffraction data.The compound ErNiSb is cubic, space group F43m and the structure parameters and reliability factors were refined to be a=6.268 3(1), V=246.29^(3), Z=4, D_(x)=9.377 g/cm^3, R_(B)=3.57%, R_(F)=3.64%, R_(p)=6.63%, R_(WP)=8.80%.
