Damage constitutive model of lunar soil simulant geopolymer under impact loading

Lunar base construction is a crucial component of the lunar exploration program,and considering the dynamic characteristics of lunar soil is important for moon construction.Therefore,investigating the dynamic properties of lunar soil by establishing a constitutive relationship is critical for providing a theoretical basis for its damage evolution.In this paper,a split Hopkinson pressure bar(SHPB)device was used to perform three sets of impact tests under different pressures on a lunar soil simulant geopolymer(LSSG)with sodium silicate(Na_(2)SiO_(3))contents of 1%,3%,5%and 7%.The dynamic stressestrain curves,failure modes,and energy variation rules of LSSG under different pressures were obtained.The equation was modified based on the ZWT viscoelastic constitutive model and was combined with the damage variable.The damage element obeys the Weibull distribution and the constitutive equation that can describe the mechanical properties of LSSG under dynamic loading was obtained.The results demonstrate that the dynamic compressive strength of LSSG has a marked strain-rate strengthening effect.Na_(2)SiO_(3) has both strengthening and deterioration effects on the dynamic compressive strength of LSSG.As Na_(2)SiO_(3) grows,the dynamic compressive strength of LSSG first increases and then decreases.At a fixed air pressure,5%Na_(2)SiO_(3) had the largest dynamic compressive strength,the largest incident energy,the smallest absorbed energy,and the lightest damage.The ZWT equation was modified according to the stress response properties of LSSG and the range of the SHPB strain rate to obtain the constitutive equation of the LSSG,and the model’s correctness was confirmed.

Health risk assessment of trace metal(loid)s in agricultural soils based on Monte Carlo simulation coupled with positive matrix factorization model in Chongqing, southwest China

This study aimed to investigate the pollution characteristics, source apportionment, and health risks associated with trace metal(loid)s(TMs) in the major agricultural producing areas in Chongqing, China. We analyzed the source apportionment and assessed the health risk of TMs in agricultural soils by using positive matrix factorization(PMF) model and health risk assessment(HRA) model based on Monte Carlo simulation. Meanwhile, we combined PMF and HRA models to explore the health risks of TMs in agricultural soils by different pollution sources to determine the priority control factors. Results showed that the average contents of cadmium(Cd), arsenic (As), lead(Pb), chromium(Cr), copper(Cu), nickel(Ni), and zinc(Zn) in the soil were found to be 0.26, 5.93, 27.14, 61.32, 23.81, 32.45, and 78.65 mg/kg, respectively. Spatial analysis and source apportionment analysis revealed that urban and industrial sources, agricultural sources, and natural sources accounted for 33.0%, 27.7%, and 39.3% of TM accumulation in the soil, respectively. In the HRA model based on Monte Carlo simulation, noncarcinogenic risks were deemed negligible(hazard index <1), the carcinogenic risks were at acceptable level(10^(-6)<total carcinogenic risk ≤ 10^(-4)), with higher risks observed for children compared to adults. The relationship between TMs, their sources, and health risks indicated that urban and industrial sources were primarily associated with As, contributing to 75.1% of carcinogenic risks and 55.7% of non-carcinogenic risks, making them the primary control factors. Meanwhile, agricultural sources were primarily linked to Cd and Pb, contributing to 13.1% of carcinogenic risks and 21.8% of non-carcinogenic risks, designating them as secondary control factors.

Corrosion and leaching behaviors of Sn-based alloy in simulated soil solutions

The corrosion and leaching behaviors of Sn-0.75Cu solders and joints in NaCl-Na2SO4 and NaCl-Na2SO4-Na2CO3 simulated soil solutions were investigated compared with those in NaCl solution, aiming to assess the potential risk from the electronic-waste disposed in soil. The leaching kinetics of Sn reveals that the leaching amount of Sn increases with increasing the time. The amount of Sn leached from the joint is the largest in NaCl solution.SO4^2- and CO3^2- inhibit the leaching of Sn from the joints, but accelerate that from the solders. Meanwhile, the corrosion layer of the joint in NaCl solution is more porous, and those immersed in NaCl-Na2SO4 and NaCl-Na2SO4-Na2CO3 solutions are compact. The XRD results indicate that the main corrosion products on the solders and joints surfaces are comprised of tin oxide, tin chloride and tin chloride hydroxide. The potentiodynamic polarization measurements for the solders were discussed in the simulated soil solutions.

Effects of freeze-thaw on soil erosion processes and sediment selectivity under simulated rainfall

The freeze-thaw （FT） processes affect an area of 46.3% in China. It is essential for soil and water conservation and ecological construction to elucidate the mechanisms of the FF processes and its associated soil erosion processes. In this research, we designed the control simulation experiments to promote the understanding of FT-water combined erosion processes. The results showed that the runoff of freeze-thaw slope （FTS） decreased by 8% compared to the control slope （CS）, and the total sediment yield of the FTS was 1.10 times that of the CS. The sediment yield rate from the FTS was significantly greater than that from the CS after 9 min of runoff （P〈0.01）. Both in FTS and CS treatments, the relationships between cumulative runoff and sediment yield can be fitted well with power functions （R2〉0.98, P〈0.01）. Significant differences in the mean weight diameter （MWD） values of particles were between the CS and the FTS treatments in the erosion were smaller than those under FTS for both washed and observed for washed particles and splashed particles process （P〈0.05）. The mean MWD values under CS splashed particles. The ratio of the absolute value of a regression coefficient between the CS and the FTS was 1.15, being roughly correspondent with the ratio of K between the two treatments. Therefore, the parameter a of the power function between cumulative runoff and sediment yield could be an acceptable indicator for expressing the soil erodibility. In conclusion, the FTS exhibited an increase in soil erosion compared to the CS.

Effect of Simulated Acid Rain on Potential Carbon and Nitrogen Mineralization in Forest Soils

Acid rain is a serious environmental problem worldwide. In this study, a pot experiment using forest soils planted with the seedlings of four woody species was performed with weekly treatments of pH 4.40, 4.00, 3.52, and 3.05 simulated acid rain (SAR) for 42 months compared to a control of pH 5.00 lake water. The cumulative amounts of C and N mineralization in the five treated soils were determined after incubation at 25 ℃ for 65 d to examine the effects of SAR treatments. For all five treatments, cumulative CO2-C production ranged from 20.24 to 27.81 mg kg-1 dry soil, net production of available N from 17.37 to 48.95 mg kg-1 dry soil, and net production of NO-3 -N from 9.09 to 46.23 mg kg-1 dry soil. SAR treatments generally enhanced the emission of CO2-C from the soils; however, SAR with pH 3.05 inhibited the emission. SAR treatments decreased the net production of available N and NO3-N. The cumulative CH4 and N2O productions from the soils increased with increasing amount of simulated acid rain. The cumulative CO2-C production and the net production of available N of the soil under Acmena acuminatissima were significantly higher (P ≤ 0.05) than those under Schima superba and Cryptocarya concinna. The mineralization of soil organic C was related to the contents of soil organic C and N, but was not related to soil pH. However, the overall effect of acid rain on the storage of soil organic matter and the cycling of important nutrients depended on the amount of acid deposition and the types of forests.

Phosphorus transport with runoff of simulated rainfall from purple-soil cropland of different surface conditions

We investigated the patterns of phosphorus transport from purple-soil cropland of 5° and 10° slopes with bare and vegetated surfaces,respectively.Each type of land was tested under a simulated moderate rainfall of 0.33 mm/min,a downfall of 0.90 mm/min,and a rainstorm of 1.86 mm/min.Runoff dynamics and changes in the export amount of phosphorus are influenced by the rainfall intensity,the slope and surface conditions of cropland.The vegetation diverts rain water from the surface into soil and helps the formation of a subsurface runoff,but has little influence on runoff process at the same sloping degree.Vegetated soil has a smaller phosphorous loss,particularly much less in the particulate form.A heavier rainfall flushes away more phosphorous.Rainwater percolating soil carries more dissolved phosphorous than particulate phosphorous.Understanding the patterns of phosphorous transport under various conditions from purple soil in the middle of Sichuan basin is helpful for developing countermeasures against non-point-source pollution resulting in the eutrophication of water bodies in this region that could,if not controlled properly,deteriorate the water quality of the Three Gorges Reservoir.

Assessment of the Performance of WEPP in Purple Soil Area with Simulated Rainfall Experiments

The water erosion prediction project （WEPP） model is a popular water erosion prediction tool developed on the basis of the physical processes of water erosion. Although WEPP has been widely used around the world, its application in China is still insufficient. In this study, the performance of WEPP used to estimate the runoff and soil loss on purple soil （Calcaric Regosols in FAO taxonomy） sloping cropland was assessed with the data from runoff plots under simulated rainfall conditions. Based on measured soil properties, runoff and erosion parameters, namely effective hydraulic conductivity, inter-rill erodibility, rill erodibility, and critical shear stress were determined to be 2.68 mm h-1, 5.54 x l0^6 kg s-1 m-4, 0.027 s m-1 and 3-5 Pa, respectively, by using the recommended equations in the WEPP user manual. The simulated results were not good due to the low Nash efficiency of 0.41 for runoff and negative Nash efficiency for soil loss. After the four parameters were calibrated, WEPP performed better for soil loss prediction with a Nash efficiency of 0.76. The different results indicated that the equations recommended by WEPP to calculate parameters such as erodiblity and critical shear stress are not suitable for the purple soil areas, Sichuan Province, China. Although the predicted results can be accepted by optimizing the runoff and erosion parameters, more research related to the determination of erodibility and critical sheer stress must be conducted to improve the application of WEPP in the purple soil areas.

Development and characterization of the PolyU-1 lunar regolith simulant based on Chang’e-5 returned samples

Leading national space exploration agencies and private enterprises are actively engaged in lunar exploration initiatives to accomplish manned lunar landings and establish permanent lunar bases in the forthcoming years.With limited access to lunar surface materials on Earth,lunar regolith simulants are crucial for lunar exploration research.The Chang’e-5(CE-5)samples have been characterized by state-of-the-art laboratory equipment,providing a unique opportunity to develop a high-quality lunar regolith simulant.We have prepared a high-fidelity PolyU-1 simulant by pulverizing,desiccating,sieving,and blending natural mineral materials on Earth based on key physical,mineral,and chemical characteristics of CE-5 samples.The results showed that the simulant has a high degree of consistency with the CE-5 samples in terms of the particle morphology,mineral and chemical composition.Direct shear tests were conducted on the simulant,and the measured internal friction angle and cohesion values can serve as references for determining the mechanical properties of CE-5 lunar regolith.The PolyU-1 simulant can contribute to experimental studies involving lunar regolith,including the assessment of interaction between rovers and lunar regolith,as well as the development of in-situ resource utilization(ISRU)technologies.

Formation of Tianwen-1 landing crater and mechanical properties of Martian soil near the landing site

After landing in the Utopia Planitia,Tianwen-1 formed the deepest landing crater on Mars,approximately 40 cm deep,exposing precious information about the mechanical properties of Martian soil.We established numerical models for the plume-surface interaction(PSI)and the crater formation based on Computational Fluid Dynamics(CFD)methods and the erosion model modified from Roberts’Theory.Comparative studies of cases were conducted with different nozzle heights and soil mechanical properties.The increase in cohesion and internal friction angle leads to a decrease in erosion rate and maximum crater depth,with the cohesion having a greater impact.The influence of the nozzle height is not clear,as it interacts with the position of the Shock Diamond to jointly control the erosion process.Furthermore,we categorized the evolution of landing craters into the dispersive and the concentrated erosion modes based on the morphological characteristics.Finally,we estimated the upper limits of the Martian soil’s mechanical properties near Tianwen-1 landing site,with the cohesion ranging from 2612 to 2042 Pa and internal friction angle from 25°to 41°.

Transport of phosphorus in runoff and sediment with surface runoff from bare purple soil during indoor simulated rainfall

Phosphorus(P)in surface runoff from purple soil is a critical element of agricultural nonpoint source pollution,leading to eutrophication of surface waters in the Three Gorges Reservoir Area(TGRA)of China.This work aimed to understand the processes and mechanisms of P losses from bare purple soil.Based on an indoor rainfall simulation experiment,we focused on the processes of surface runoff and P losses via different hydrological pathways.Experimental treatments included three simulated rainfall intensities,four slope gradients,and three fertilizer treatments.P loss from sediment was the main pathway in the purple soil,and bioavailable P was mainly transferred in dissolved P(DP)of runoff water.The P loss loads tend to grow with the increase of the slope until 25°for the maximum load of runoff water and 20°for the maximum load of sediment.Concentrations of DP in the surface runoff after fertilizer application can exceed the estimates of those required for accelerated eutrophication.Sediment P control might be an essential way for reducing P loss in purple soil for the local government and farmers of TGRA.

Application of Ground Phosphate Rock to Dimmish the Effects of Simulated Acid Rain on Soil Properties

The effects of simulated acid rain retained in soil on the properties of acid soil and its diminishing by application of ground phosphate rock were investigated by using the sorption method. Results show as follows: (1) For yellow brown soil, the effect of simulated acid rain on the properties of soil with a pH value of 5.9 was relatively small, except a great quantity of acid rain deposited on it. (2) For red soil, the effect of simulated acid rain on the properties of soil was significant. With the increase of the amount of acid deposition, the pH value of soil was declined, but the contents of exchangeable H+, Al3+ and Mn2+ and the amount of SO42- retention were increased. (3) Many properties of acid soils could be improved by applying ground phosphate rock. For example, pH value of soils and the amounts of available P and exchangeable Ca2+ and Mg2+ were increased, and the amounts of exchangeable H+ and Al3+ and SO42- retained was reduced. The application of ground posphate rock could effctively dimmish the pollution of acid rain to soil.

Performance evaluation of laterite soil embankment stabilized with bottom ash,coir fiber,and lime

In tropical regions,heavy rainfall induces erosion and shallow landslides on road embankments.Cement-based stabilization methods,common in these regions,contribute to climate change due to their high carbon footprint.This study explored the potential application of coir fiber-reinforced laterite soil-bottom ash mixtures as embankment materials in the tropics.The objective is to enhance engineered embankment slopes'erosion resistance and stability while offering reuse options for industrial byproducts.This study examined various mix designs for unconfined compressive strength(UCS)and permeability,utilizing 30%bottom ash(BA)and 1%coir fiber(CF)with varying sizes ranging from 10 to 40 mm,6%lime,and laterite soil(LS),followed by microstructural analyses.The results demonstrate that the compressive strength increases as the CF length increases to 25 mm.In contrast,permeability increases continuously with increasing CF length.Lime-treated mixtures exhibit superior short-and long-term strength and reduce permeability owing to the formation of cementitious materials,as confirmed by microstructural analyses.A lab-scale slope box was constructed to evaluate the surface erosion of the stabilized laterite soil embankment.Based on the rainfall simulation results,the LS-BA-CF mixtures show better resistance to erosion and deformation compared to untreated LS,especially when lime is added to the top layer.This study provides insights into a sustainable and cost-effective approach for slope stabilization using BA and CF,offering a promising solution for tropical regions susceptible to surface erosion and landslides.

The runoff characteristics under simulated rainfall on purple soil sloping cropland

Rainfall runoff is a critical hydrological process related to soil erosion and agricultural non-point pollu-tion. In this study, 25 simulation experiments on rainfall were carried out in five runoff plots. Rape (Brassica campestris) was planted on the downslope of the plots. Experiments were conducted when the vegetation coverage reached 80%. Each plot was subjected to five rainfall events differing in intensity. The results showed: (1) the runoff coefficients of overland flow and subsurface flow were less than 0.6 and 0.005, respectively; (2) the discharge of overland flow was the quadratic function of time; (3) runoff coefficient was the function of slope gradient and rain-fall intensity. When the slope gradient increased from 8.7% to 46.6%, the runoff coefficient of overland flow first increased and then decreased. The runoff coefficient reached the maximum when the slope gradient was within the range of 17.6%-36.4%; and (4) the process of subsurface flow generation included the increasing phase and reces-sion phase. Discharge was a logarithm function of time in the increasing phase, and an exponential function in the recession phase. Runoff coefficient of subsurface flow decreased first and then increased when the slope gradient varied from 8.7% to 46.6% and was not correlated with rainfall intensity.

Effects of simulated acid rain on root growth of Cunninghamia lanceolata and Schima superba saplings planted in acidified soil

Results from pot culture (with one-year old Cunninghamia lanceolata and Schima superba) are described. It was found that the biomass production and elongation of C. lanceolata was seriously inhibited at pH 2.0 rain, but for S. superba, was not affected markedly. When pH values of experimental rain were higher than 2.0, the root growth of both species was not adversely affected. Aluminium had already accumulated to some degrees in the roots of both trees, and started to affect the root growth of C. lanceolata at pH 2.0 rain. The soil chemistry was also examined. Increased acidity of experimental rain increased the leaching of Ca and Mg. The Al/Ca mol ratio increased from 0.3 to 0.9 in top soil, and in rhizosphere to 1.5 when the pH values of simulated acid rain were 4.5 to 2.0. In this experiment, NO3- fertilization effect was discovered.

Comparison between Sequential Gaussian Simulation and Kriging Interpolation on Soil Heavy Metal Pollution

[Objective] This study was to explore the difference of kriging interpolation and sequential Gaussian simulation on analyzing soil heavy metal pollution with a view to provide references for analyzing the heavy metal pollution of soil. [Method] The sampling data of soil copper from a county of Liaocheng, Shandong Province was set as the study objective. Kriging interpolation and sequential Gaussian simu- lation were used to simulate the spatial distribution of soil copper. And 30 sampling points were selected as the cross-validation data set to compare the two interpola- tion methods. [Result] Kriging method and Gaussian sequential simulation have their own advantages on simulating mean segment and extreme segment, therefore, re- searchers should choose the proper method based on the characteristics of test data and application purposes. [Conclusion] Analysis of soil heavy metal pollution is the prerequisite for soil management and ecological restoration. The result of this study is of important significance for choosing different interpolating and simulating methods to analyze soil heavy metal pollution based on different purposes.

Simulated rainfall in Brazil:An alternative for assesment of soil surface processes and an opportunity for technological development

Rainfall simulators(RS)have been used,above all,to evaluate hydrological processes related to soil water infiltration,surface runoff and soil erosion.They allow repeatability of rain application with different precipitation intensities in field and/or laboratory conditions and should produce events with physical characteristics similar to natural rain.In this manuscript,we carried out a bibliometric and scientometric analysis of studies with simulated rainfall in Brazil to assess the temporal evolution of publications,the main topics addressed and the degree of technological development of the equipment.We searched for the terms“rainfall simulator”OR“simulated rainfall”AND“Brazil”in the Scopus,Web of Science,SciELO and Google Scholar databases.We found 143 articles published in the last 37 years(1985-2022).Our findings indicate that the main research areas covered in papers are soil erosion(57.34%),soil water infiltration(24.47%),nutrient losses(9.8%)and RS development and calibration/assessment(8.39%).In recent years,the number of published papers in international high-impact factor journals has increased.Most of the papers(49.65%)refer to studies carried out by institutions located in the south and southeast regions of Brazil.Moreover,there is a large gap of studies on simulated rainfall in other regions of Brazil,where important biomes such as the Cerrado,Amazon,Caatinga,and their transitions are located.This study informs research priorities on soil erosion under simulated rainfall and provides a bibliographic database that can assist in more detailed future analyses.

Model Establishment for Simulating Soil Organic Carbon Dynamics

Assuming that decomposition of organic matter in soils follows the first-order kinetics reaction, a computer model was developed to simulate soil organic matter dynamics. Organic matter in soils is divided up into two parts that include incorporated organic carbon from crop residues or other organic fertilizer and soil intrinsic carbon. The incorporated organic carbon was assumed to consist of two components, labile-C and resistant-C. The model was represented by a differential equation of dCt/dt = Kt × fr × fw × fs × ct (i = 1, r,S) and an integral equation of Cit = Cio × EXP(Ki × fT × fw × fs × t). Effect of soil parameters of temperature, moisture and texture on the decomposition was functioned by the fT, fw and fs, respectively. Data from laboratory incubation experiments were used to determine the first-order decay rate K, and the fraction of labile-C of crop residues by employing a nonlinear method. The values of K for the components of labile-C and resistant-C and the soil intrinsic carbon were evaluated to be 0.025,0.080 X 10-2 and 0.065 X 10-3d-1, respectively. The labile-C fraction of wheat straw, wheat roots, rice straw and rice roots were 0.50, 0.25, 0.40 and 0.20, respectively. These values are related to the initial residue carbon-to-nitrogen ratio (C/N) and lignin content.

Grassland Evolution Under Soil Degradation: Numerical Simulation and Test

Both theoretical and field observations were examined to study the close relationship between soil degeneration and the evolution of grassland vegetation. A general n-species model of equal competition under different degrees of soil degradation was applied to field data in order to probe the dynamic processes and mechanisms of vegetation evolution due to the effects of the soil's ecological deterioration on grassland vegetation. Comparisons were made between the theoretical results and the practical surveys with satisfactory results.

Numerical Simulation on Explosion in Double-Layer Medium of Concrete and Soil

The numerical simulation on explosion in concrete and soil is performed by using the three-dimension finite element code LS-DYNA, into which a continuum damage model which can well describe the fracture of concrete is implemented. As a consequence, wave propagation and attenuation in concrete and on soil-concrete interface are obtained respectively. Moreover, the damage regions of concrete at different thicknesses of soil （TOS） and depths of charge （DOC） are procured. The existent soil reduces damage region of concrete. Numerical results provide reference for design of warhead and protective structure and blasting.

Preparation and Characterization of High-Strength Geopolymer Based on BH-1 Lunar Soil Simulant with Low Alkali Content

The construction of a lunar base and habitation on the Moon has always been on researchers’minds.Building materials used in in situ lunar resources are of great significance for saving expensive space freight.In this study,a new type of lunar soil simulant named Beihang(BH)-1 was developed.The chemical mineral composition and microstructure of BH-1 closely resemble those of real lunar soil,as verified by X-ray fluorescence spectroscopy(XRF),X-ray diffraction(XRD),scanning electron microscopy(SEM),and reflectance spectra.This research also synthesized a geopolymer based on BH-1 cured at simulated lunar atmospheric conditions.We also investigated the effect of supplementing aluminum(Al)sources on the enhancement of geopolymer strength based on BH-1.The rheological behavior of alkali-activated BH-1 pastes was determined for workability.XRF,XRD,Fourier transform infrared spectroscopy,SEM coupled with energy dispersive spectroscopy,and 27Al magic angle spinningnuclear magnetic resonance were used to characterize resulting geopolymers.Rheological test findings showed that the rheology of BH-1 pastes fits the Herschel–Bulkley model,and they behaved like a shear-thinning fluid.The results showed that the 28-day compressive strength of the BH-1 geopolymer was improved by up to 100.8%.Meanwhile,the weight of additives required to produce per unit strength decreased,significantly reducing the mass of materials transported from the Earth for the construction of lunar infrastructure and saving space transportation costs.Microscopic analyses showed that the mechanism to improve the mechanical properties of the BH-1 geopolymer by adding an additional Al source enhances the replacement of silicon atoms by Al atoms in the silicon–oxygen group and generates a more complete and dense amorphous gel structure.