期刊文献+
共找到166篇文章
< 1 2 9 >
每页显示 20 50 100
Microstructure,mechanical property and in vitro biocorrosion behavior of single-phase biodegradable Mg-1.5Zn-0.6Zr alloy 被引量:3
1
作者 Tao Li Yong He +1 位作者 Hailong Zhang Xitao Wang 《Journal of Magnesium and Alloys》 SCIE EI CAS 2014年第2期181-189,共9页
The microstructure,mechanical property,and in vitro biocorrosion behavior of as-cast single-phase biodegradable Mg-1.5Zn-0.6Zr alloy were investigated and compared with a commercial as-cast AZ91D alloy.The results sho... The microstructure,mechanical property,and in vitro biocorrosion behavior of as-cast single-phase biodegradable Mg-1.5Zn-0.6Zr alloy were investigated and compared with a commercial as-cast AZ91D alloy.The results show that the Mg-1.5Zn-0.6Zr alloy had a single-phase solid solution structure,with an average grain size of 34.7±13.1μm.The alloy exhibited ultimate tensile strength of 168±2.0 MPa,yield strength of 83±0.6 MPa,and elongation of 9.1±0.6%.Immersion tests and electrochemical measurements reveal that the alloy displayed lower biocorrosion rate and more uniform corrosion mode than AZ91D in Hank's solution.The elimination of intensive galvanic corrosion reactions and the formation of a much more compact and uniform corrosion film mainly account for the better biocorrosion properties of the Mg-1.5Zn-0.6Zr alloy than AZ91D. 展开更多
关键词 Magnesium alloys BIOMATERIALS single-phase MICROSTRUCTURE Corrosion BIODEGRADABLE
下载PDF
Preparation of single-phase ammonium dimolybdate by combination process 被引量:3
2
作者 ZHANG Bao XIA Xiaomei LI Qian 《Rare Metals》 SCIE EI CAS CSCD 2012年第5期517-522,共6页
关键词 single-phase ammonium dimolybdate combination process crystallization rate phase composition total molybdenum recovery
下载PDF
Dynamic behavior of coalbed methane flow along the annulus of single-phase production 被引量:3
3
作者 Xinfu Liu Chunhua Liu Guoqiang Liu 《International Journal of Coal Science & Technology》 EI 2019年第4期547-555,共9页
Dynamic behavior of coalbed methane (CBM) flow will provide the theoretical basis to optimize production performance for a given well.A mathematical model is developed to simulate flowing pressures and pressure drops ... Dynamic behavior of coalbed methane (CBM) flow will provide the theoretical basis to optimize production performance for a given well.A mathematical model is developed to simulate flowing pressures and pressure drops of CBM column from well head to bottom hole.The measured parameters and independent variables of flow rates,flowing pressures and temperatures are involved in CBM producing process along the annulus.The developed relationships are validated against full-scale measured data in single-phase CBM wellbores.The proposed methodology can analyze the dynamic behavior in CBM reservoir and process of CBM flow with an overall accuracy of 2%.The calculating process of flowing pressures involves friction factor with variable Reynolds number and CBM temperature and compressibility factor with gravitational gradients.The results showed that the effect of flowing pressure on CBM column was more obvious than that on CBM and water column accompanied by an increase of dynamic water level.The ratios of flowing pressure on increment of CBM column to the whole column increased with the declined flow rates of water column.Bottom-hole pressure declined with the decreased flowing pressure of CBM column along the annulus.It will lead to the results of the increased pressure drop of CBM column and CBM flow rate in single-phase CBM wellbores. 展开更多
关键词 Dynamic CHARACTERISTIC single-phase CBM wellbore Flowing pressure of CBM COLUMN Flow rate of CBM COLUMN
下载PDF
Prediction of Outdoor Noise Propagation Induced By Single-Phase Power Transformers 被引量:2
4
作者 Xueyun Ruan Wei Huang +1 位作者 Linke Zhang Yan Gao 《Sound & Vibration》 2019年第1期2-13,共12页
Outdoor power transformers are one of the most pervasive noise sources in power transmission and distribution systems.Accurate prediction of outdoor noise propagation plays a dominant role for the evaluation and contr... Outdoor power transformers are one of the most pervasive noise sources in power transmission and distribution systems.Accurate prediction of outdoor noise propagation plays a dominant role for the evaluation and control of noise relevant to the transformer stations.In this paper surface vibration tests are carried out on a scale model of a single-phase transformer tank wall at different excitation frequencies.The phase and amplitude of test data are found to be randomly distributed when the excitation frequency exceeds the seventh mode frequency,which allows the single-phase power transformer to be simplified as incoherent point sources.An outdoor-coherent model is subsequently developed and incorporated with the image source method to investigate noise propagation from single-phase power transformers,due to the occurrence of multiple reflections and diffractions in the propagation path of each point source.The proposed model is used to calculate the sound field of the power transformer group by exploiting the additional phase information.In comparison with the ISO9613 model and the boundary element method,it is found that the proposed coherent image source method leads to more accurate prediction results,and hence better performance for the prediction of the outdoor noise induced by single-phase power transformers. 展开更多
关键词 single-phase transformer surface vibration scale model noise prediction coherent image source method
下载PDF
Symmetrical dynamical characteristic of peak and valley current-mode controlled single-phase H-bridge inverter 被引量:1
5
作者 刘洪臣 李飞 +1 位作者 苏振霞 孙立山 《Chinese Physics B》 SCIE EI CAS CSCD 2013年第11期226-231,共6页
Complex dynamical phenomenon was studied in the single phase H-bridge inverter which was controlled by either a peak current or a valley current. The state functions and the discrete iterative map equations were estab... Complex dynamical phenomenon was studied in the single phase H-bridge inverter which was controlled by either a peak current or a valley current. The state functions and the discrete iterative map equations were established to analyze the dynamical phenomenon in the single phase H-bridge inverter. The dynamical characteristics of the single phase H- bridge inverter, such as time domain waveform diagram, bifurcation diagram, and folding map, were obtained by using the numerical calculation when the circuit parameters varied in specific range. Moreover, the simulation results were obtained by using the OrCAD-PSpice software to validate the numerical calculation. Both the numerical calculation and the circuit simulation show that the symmetrical dynamical phenomenon occurs in the single phase H-bridge inverter controlled by the peak current or the valley current. 展开更多
关键词 single-phase H-bridge inverter symmetrical dynamical phenomenon folding map bifurcation di-agram
下载PDF
The Use of Single-Phase Immersion Cooling by Using Two Types of Dielectric Fluid for Data Center Energy Savings 被引量:2
6
作者 Nugroho Agung Pambudi Awibi Muhamad Yusuf Alfan Sarifudin 《Energy Engineering》 EI 2022年第1期275-286,共12页
Data centers are recognized as one of the most important aspects of the fourth industrial revolution since conventional data centers are inefficient and have dependency on high energy consumption,in which the cooling ... Data centers are recognized as one of the most important aspects of the fourth industrial revolution since conventional data centers are inefficient and have dependency on high energy consumption,in which the cooling is responsible for 40%of the usage.Therefore,this research proposes the immersion cooling method to solving the high energy consumption of data centers by cooling its component using two types of dielectric fluids.Four stages of experimentalmethods are used,such as fluid types,cooling effectiveness,optimization,and durability.Furthermore,benchmark software is used to measure the CPU maximum work with the temperature data performed for 24 h.The results of this study show that the immersion cooling reduces 13℃ lower temperature than the conventional cooling method which means it saves more energy consumption in the data center.The most optimum variable used to decrease the temperature is 1.5 lpm of flow rate and 800 rpm of fan rotation.Furthermore,the cooling performance of the dielectric fluids shows that the mineral oil(MO)is better than the virgin coconut oil(VCO).In durability experiment,there are no components damage after five months immersed in the fluid. 展开更多
关键词 single-phase immersion cooling data center dielectric fluid mineral oil virgin coconut oil
下载PDF
Real-Time Method for Detecting Harmonic and Reactive Currents of Single-Phase Circuits 被引量:1
7
作者 张秀峰 丁菊霞 《Journal of Southwest Jiaotong University(English Edition)》 2006年第2期135-141,共7页
According to the characteristics of single-phase circuits and demand of using active filter for real-time detecting harmonic and reactive currents, a detecting method based on Fryze's power definition is proposed. Th... According to the characteristics of single-phase circuits and demand of using active filter for real-time detecting harmonic and reactive currents, a detecting method based on Fryze's power definition is proposed. The results of theoretical analysis and simula- tion show that the proposed method is effective in realtime detecting of instantaneous harmonic and reactive currents in single-phase circuits. When only detecting the total reactive currents, this method does not need a phase-locked loop circuit, and it also can be used in some special applications to provide different compensations on the ground of different requirements of electric network. Compared with the other methods based on the theory of instantaneous reactive power, this method is simple and easy to realize. 展开更多
关键词 Active filter HARMONIC Reactive current Real-time detection single-phase circuit Electric-network
下载PDF
Modified surface tension model for free surface flow with single-phase lattice Boltzmann method 被引量:1
8
作者 严永华 杨帆 +1 位作者 钱忠东 钱跃竑 《Journal of Shanghai University(English Edition)》 CAS 2010年第2期145-149,共5页
A single-phase lattice Boltzmann model with modified surface tension is developed in this paper to solve the problem of high-density-ratio free surface flow.The computational efficiency and accuracy are both enhanced.... A single-phase lattice Boltzmann model with modified surface tension is developed in this paper to solve the problem of high-density-ratio free surface flow.The computational efficiency and accuracy are both enhanced.The restriction to the relaxation factor (which needs to be smaller than 1) is circumvented by the new surface tension algebra,due to its rational physical nature compared with the treatment of Xing,Buther and Yang in their paper (Comp.Mater.Sci.,2007,39(2):282-290).The proposed stable surface tension scheme is applied to simulate the free deformation of a square droplet with surface tension effect and the process of a droplet impinging on a liquid film.The numerical solution for free deformation of a droplet agrees well with thermodynamic principles,and also achieves high accuracy in comparison with Xing,et al.'s model.Three typical impinging modes are successfully obtained with the new scheme,and another particular mode found by Wang and Chen is also successfully simulated.The evolutions of liquid crown agree well with the power law related to time. 展开更多
关键词 surface tension lattice Boltzmann model (LBM) single-phase model high density ratio free surface DROPLET
下载PDF
Industrial frequency single-phase AC traction power supply system for urban rail transit and its key technologies 被引量:1
9
作者 Qunzhan Li 《Journal of Modern Transportation》 2016年第2期103-113,共11页
To avoid stray current and maintain the benefit of no phase-split in the DC traction power supply system, an AC traction power supply system was proposed for the urban public transport such as metro and light rail tra... To avoid stray current and maintain the benefit of no phase-split in the DC traction power supply system, an AC traction power supply system was proposed for the urban public transport such as metro and light rail transit. The proposed system consists of a main substation (MSS) and cable traction network (CTN). The MSS includes a single-phase main traction transformer and a negative-se- quence compensation device, while the CTN includes double-core cables, traction transformers, overhead catenary system, rails, etc. Several key techniques for the proposed system were put forward and discussed, which can be summarized as (1) the power supply principle, equivalent circuit and transmission ability of the CTN, the cable-catenary matching technique, and the selection of catenary voltage level; (2) the segmentation technology and status identification method for traction power supply network, distributed and centralized protection schemes, etc.; (3) a power supply scheme for single-line MSS and a power supply scheme of MSS shared by two or more lines. The proposed industrial frequency single-phase AC traction power supply system shows an excellent technical performance, good economy, and high reliability, hence provides a new alternative for metro and urban rail transit power supply systems. 展开更多
关键词 Urban rail transit 50 Hz industrial frequency single-phase AC traction power supply Cable traction
下载PDF
A Single-phase of Supercritical CO_2/Polystyrene Solution in Foam Extrusion
10
作者 吴晓丹 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2008年第6期804-808,共5页
The high quality single-phase solution of CO2/ Polystyrene was achieved,by analyzing the influential factors for polymer microcellular foaming extrusion.The curve of pressure distribution along the barrel was determin... The high quality single-phase solution of CO2/ Polystyrene was achieved,by analyzing the influential factors for polymer microcellular foaming extrusion.The curve of pressure distribution along the barrel was determined.The axial position of gas-injecting port on the barrel was chosen form the results of stable foaming,and the number of gas-injecting ports in the circumference of the barrel was determined from the CO2 solubility in polymer.The effect of the screw rotation speed on CO2 solubility was studied,and the effects of pressure difference between the gas and the polymer melt on gas-injecting process and on the foaming stability were investigated.The influence of the gas temperature before injection on the single-phase of CO2/Polystyrene solution also was studied. 展开更多
关键词 POLYMER extrusion foaming SOLUBILITY single-phase solution
下载PDF
A quasi single-phase model for debris flows and its comparison with a two-phase model
11
作者 XIA Chun-chen LI Ji +2 位作者 CAO Zhi-xian LIU Qing-quan HU Kai-heng 《Journal of Mountain Science》 SCIE CSCD 2018年第5期1071-1089,共19页
A depth-averaged quasi single-phase mixture model is proposed for debris flows over inclined bed slopes based on the shallow water hydrosediment-morphodynamic theory with multi grain sizes. The stresses due to fluctua... A depth-averaged quasi single-phase mixture model is proposed for debris flows over inclined bed slopes based on the shallow water hydrosediment-morphodynamic theory with multi grain sizes. The stresses due to fluctuations are incorporated based on analogy to turbulent flows, as estimated using the depth-averaged k-? turbulence model and a modification component. A fully conservative numerical algorithm, using wellbalanced slope limited centred scheme, is deployed to solve the governing equations. The present quasi single-phase model using four closure relationships for the bed shear stresses is evaluated against USGS experimental debris flow and compared with traditional quasi single-phase models and a recent physically enhanced two-phase model. It is found that the present quasi single-phase model performs much better than the traditional models, and is attractive in terms of computational cost while the two-phase model performs even better appreciably. 展开更多
关键词 DEBRIS flows QUASI single-phase mixturemodel Stresses DUE to fluctuations Well-balanced
下载PDF
Mixture Regression-Cum-Ratio Estimator Using Multi-Auxiliary Variables and Attributes in Single-Phase Sampling
12
作者 Teresio Mutembei John Kung’u Christopher Ouma 《Open Journal of Statistics》 2014年第5期367-376,共10页
In this paper, we have proposed a class of mixture regression-cum-ratio estimator for estimating population mean by using information on multiple auxiliary variables and attributes simultaneously in single-phase sampl... In this paper, we have proposed a class of mixture regression-cum-ratio estimator for estimating population mean by using information on multiple auxiliary variables and attributes simultaneously in single-phase sampling and analyzed the properties of the estimator. An empirical was carried out to compare the performance of the proposed estimator with the existing estimators of finite population mean using simulated population. It was found that the mixture regression-cum-ratio estimator was more efficient than ratio and regression estimators using one auxiliary variable and attribute, ratio and regression estimators using multiple auxiliary variables and attributes and regression-cum-ratio estimators using multiple auxiliary variables and attributes in single-phase sampling for finite population. 展开更多
关键词 Regression-Cum-Ratio ESTIMATOR Multiple AUXILIARY VARIABLES and Attributes single-phase Sampling
下载PDF
Positron Annihilation Behaviors and Magnetic Properties of Single-phase Nd_2Fe_(14)B and NanocompositeNd_2Fe_(14)B/α-Fe Magnets
13
作者 Dingkang XIONG, Xiaokai SUN,Liangyue XIONG, Wei LIU,Tong ZHAO and Zhidong ZHANG Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110015, China 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2001年第4期453-456,共4页
Positron annihilation behaviors have been studied in the single phase Nd2Fe14B magnet and the nanocomposite Nd2Fe14B/α-Fe magnet, prepared by melt spinning. The results showed that the number of vacancy-cluster at gr... Positron annihilation behaviors have been studied in the single phase Nd2Fe14B magnet and the nanocomposite Nd2Fe14B/α-Fe magnet, prepared by melt spinning. The results showed that the number of vacancy-cluster at grain boundaries increases with increasing annealing temperature for the both types of magnets. The increase of this kind of defect can improve the coercivity of the single-phase magnet. Conversely,the increase of vacancy-cluster amount leads to decreasing of the coercivity for the nanocomposite magnet. It implies that the mechanism of dominant magnetic hardening for the two types of magnets is different, and the domain walls pinning mechanism in the single-phase magnet and the reversal magnetization nucleation mechanism in the nanocomposite magnet operate, respectively. 展开更多
关键词 ND Positron Annihilation Behaviors and Magnetic Properties of single-phase Nd2Fe
下载PDF
HC-55 Single-Phase AC Series-Excitation Commutator Motor
14
《China's Foreign Trade》 1997年第2期20-20,共1页
The HC-55 single-phase AC series-excitation commutator motor exported to Japan by the Linquan Motor Factory is an open-type motor characterized by simple structure, small volume, high rotary speed, large starting torq... The HC-55 single-phase AC series-excitation commutator motor exported to Japan by the Linquan Motor Factory is an open-type motor characterized by simple structure, small volume, high rotary speed, large starting torque, reliable operation and easy installation. It can be used as a driving component for various kinds of household electrical appliances, such as electric mills, pulverlizers, small stirrers, vacuum cleaners and electric hair dryers, an ideal product for electrical equipment. 展开更多
关键词 HC-55 single-phase AC Series-Excitation Commutator Motor AC
下载PDF
Single-Phase Velocity Determination Based in Video and Sub-Images Processing:An Optical Flow Method Implemented with Support of a Programmed MatLab Structured Script
15
作者 Andreas Nascimento Edson Da Costa Bortoni +2 位作者 José Luiz Goncalves Pedro Antunes Duarte Mauro Hugo Mathias 《Journal of Software Engineering and Applications》 2015年第6期290-294,共5页
Important in many different sectors of the industry, the determination of stream velocity has become more and more important due to measurements precision necessity, in order to determine the right production rates, d... Important in many different sectors of the industry, the determination of stream velocity has become more and more important due to measurements precision necessity, in order to determine the right production rates, determine the volumetric production of undesired fluid, establish automated controls based on these measurements avoiding over-flooding or over-production, guaranteeing accurate predictive maintenance, etc. Difficulties being faced have been the determination of the velocity of specific fluids embedded in some others, for example, determining the gas bubbles stream velocity flowing throughout liquid fluid phase. Although different and already applicable methods have been researched and already implemented within the industry, a non-intrusive automated way of providing those stream velocities has its importance, and may have a huge impact in projects budget. Knowing the importance of its determination, this developed script uses a methodology of breaking-down real-time videos media into frame images, analyzing by pixel correlations possible superposition matches for further gas bubbles stream velocity estimation. In raw sense, the script bases itself in functions and procedures already available in MatLab, which can be used for image processing and treatments, allowing the methodology to be implemented. Its accuracy after the running test was of around 97% (ninety-seven percent);the raw source code with comments had almost 3000 (three thousand) characters;and the hardware placed for running the code was an Intel Core Duo 2.13 [Ghz] and 2 [Gb] RAM memory capable workstation. Even showing good results, it could be stated that just the end point correlations were actually getting to the final solution. So that, making use of self-learning functions or neural network, one could surely enhance the capability of the application to be run in real-time without getting exhaust by iterative loops. 展开更多
关键词 Optical Flow single-phase Velocity Video and Image Processing Sensing MatLab Script
下载PDF
Vector Control of the Single-Phase Inverter Based on the Extended and Virtual Circuits
16
作者 Tao Xu Ming Yang +5 位作者 Naizhe Diao Xianrui Sun Suliang Wu Zhuangzhuang Shen Hongzhi Chen Chonghui Song 《CES Transactions on Electrical Machines and Systems》 2018年第3期320-327,共8页
A vector control based on the extended equivalent circuit and virtual circuits is proposed for the single-phase inverter.By the extended circuit,the other two phase voltages can be extended by the output voltage of th... A vector control based on the extended equivalent circuit and virtual circuits is proposed for the single-phase inverter.By the extended circuit,the other two phase voltages can be extended by the output voltage of the single-phase inverter so as to construct the voltage vector.The voltage outer-loop is to control the voltage vector in dq coordinate system,and the output voltage can track the target value without deviation in steady state.By designing the virtual circuit,the voltage inner-loop can achieve approximate decoupling and improve the dynamic response under the changeable load.Compared with the traditional dual closed-loop control,the proposed dual closed-loop control scheme only needs to detect and control the voltage without the current.It not only can achieve good control effect,but also reduce the complexity of the hardware.Finally,the simulation and experimental results show that the single-phase inverter has good static and dynamic characteristics regardless of stable load or changeable load. 展开更多
关键词 Coordinate transformation dual closed-loop control extended circuit single-phase inverter vector control virtual circuit
下载PDF
一种新型带曲率补偿的带隙基准
17
作者 李新 高梦真 杨森林 《电子元件与材料》 CAS 北大核心 2024年第7期878-883,共6页
针对传统带隙基准存在温度漂移大以及电源抑制比低的问题,提出了一种新型的带曲率补偿的带隙基准电压源。采用基极电流补偿以及曲率补偿技术对传统带隙基准结构进行改进。设计了低失配改进电路、低温漂改进以及启动电路等。利用共源共... 针对传统带隙基准存在温度漂移大以及电源抑制比低的问题,提出了一种新型的带曲率补偿的带隙基准电压源。采用基极电流补偿以及曲率补偿技术对传统带隙基准结构进行改进。设计了低失配改进电路、低温漂改进以及启动电路等。利用共源共栅电流镜技术和负反馈网络保证带隙基准输出电压,极大程度降低了运放失调电压对带隙基准电压的干扰,实现了低温漂特性。基于东部高科0.18μm BCD工艺,在Cadence Spectre下进行仿真。仿真结果表明:该带隙基准电路在-40~150℃温度范围内,输入电压为5 V,输出电压稳定在1.192 V;温度系数为4.84×10^(-6)/℃;在低频时电源抑制比为-78 dB。 展开更多
关键词 带隙基准 基极电流补偿 曲率补偿 低温度系数 电源抑制比
下载PDF
人防工程电气专业平战功能转换设计要点探讨
18
作者 笪良飞 《建筑电气》 2024年第5期36-41,共6页
结合安徽省地方标准DB34/T4628-2023《人民防空工程平战转换技术规范》,对其中与电气专业相关的内容进行梳理归纳,并结合现行人防工程相关规范及设计通常做法,对DB34/T4628-2023的新要求新规定进行分析,给出相应的解决办法。
关键词 人防工程 设计要点 平战结合 平战功能转换 土建条件 战时电源 照明系统 弱电系统
下载PDF
某超高层建筑供配电系统设计探讨
19
作者 丑凤麟 《建筑电气》 2024年第1期8-12,共5页
通过大连某工程实例,介绍超高层公共建筑的供配电系统设计,包括负荷分级、供电电源、备用电源配置、变配电所及变压器选择,重点对高区变配电所不同位置及数量的设置方案进行比较分析,最后结合新版变压器能效标准介绍变压器的节能设计。
关键词 超高层建筑 负荷分级 供电半径 高区变配电所 自备电源 柴油发电机 变压器能效等级 绿色建筑
下载PDF
Electro-triggered Joule heating method to synthesize single-phase CuNi nano-alloy catalyst for efficient electrocatalytic nitrate reduction toward ammonia 被引量:5
20
作者 Zunjie Zhang Yang Liu +6 位作者 Xiaozhi Su Ziwei Zhao Zhenkun Mo Chenyi Wang Yaling Zhao Ye Chen Shuyan Gao 《Nano Research》 SCIE EI CSCD 2023年第5期6632-6641,共10页
Electrochemical nitrate reduction reaction(NO_(3)RR)has great potential for ammonia(NH_(3))synthesis benefiting from its environmental friendliness and sustainability.Cu-based alloys with elemental diversity and adsor... Electrochemical nitrate reduction reaction(NO_(3)RR)has great potential for ammonia(NH_(3))synthesis benefiting from its environmental friendliness and sustainability.Cu-based alloys with elemental diversity and adsorption tunability are widely used as electrocatalyst to lower the reaction overpotential for NO_(3)RR catalysis.However,phase separation commonly found in alloys leads to uneven distribution of elements,which limits the possibility of further optimizing the catalytic activity.Herein,an electrotriggered Joule heating method,possessing unique superiority of flash heating and cooling that lead to well-dispersed nanoparticles and uniform mixing of various elements,was adopted to synthesize a single-phase CuNi nano-alloy catalyst evenly dispersed on carbon fiber paper,CFP-Cu_(1)Ni_(1),which exhibited a more positive NO_(3)RR initial potential of 0.1 V versus reversible hydrogen electrode(vs.RHE)than that of pure copper nanoparticles at 10 mA·cm^(−2)in 0.5 mol·L^(−1)Na_(2)SO_(4)+0.1 mol·L^(−1)KNO_(3)solution.Importantly,CFP-Cu_(1)Ni_(1) presented high electrocatalytic activity with a Faradaic efficiency of 95.7%and NH_(3)yield rate of 180.58μmol·h^(−1)·cm^(−2)(2550μmol·h^(−1)·mg_(cat)^(−1))at−0.22 V vs.RHE.Theoretical calculations showed that alloying Cu with Ni into single-phase caused an upshift of its d-band center,which promoted the adsorption of NO_(3)−and weakened the adsorption of NH_(3).Moreover,the competitive adsorption of hydrogen ions was restrained until−0.24 V.This work offers a rational design concept with clear guidance for rapid synthesis of uniformly dispersed single-phase nano-alloy catalyst for efficient electrochemical NO_(3)RR toward ammonia. 展开更多
关键词 AMMONIA nitrate reduction reaction CuNi nano-alloy single-phase adsorption energy
原文传递
上一页 1 2 9 下一页 到第
使用帮助 返回顶部