Genetic algorithms(GAs)are very good metaheuristic algorithms that are suitable for solving NP-hard combinatorial optimization problems.AsimpleGAbeginswith a set of solutions represented by a population of chromosomes...Genetic algorithms(GAs)are very good metaheuristic algorithms that are suitable for solving NP-hard combinatorial optimization problems.AsimpleGAbeginswith a set of solutions represented by a population of chromosomes and then uses the idea of survival of the fittest in the selection process to select some fitter chromosomes.It uses a crossover operator to create better offspring chromosomes and thus,converges the population.Also,it uses a mutation operator to explore the unexplored areas by the crossover operator,and thus,diversifies the GA search space.A combination of crossover and mutation operators makes the GA search strong enough to reach the optimal solution.However,appropriate selection and combination of crossover operator and mutation operator can lead to a very good GA for solving an optimization problem.In this present paper,we aim to study the benchmark traveling salesman problem(TSP).We developed several genetic algorithms using seven crossover operators and six mutation operators for the TSP and then compared them to some benchmark TSPLIB instances.The experimental studies show the effectiveness of the combination of a comprehensive sequential constructive crossover operator and insertion mutation operator for the problem.The GA using the comprehensive sequential constructive crossover with insertion mutation could find average solutions whose average percentage of excesses from the best-known solutions are between 0.22 and 14.94 for our experimented problem instances.展开更多
Comprehensive Summary To better understand the impact of different anions on the structures and SCO properties of the CoII SCO complexes,six new complexes[Co(terpy-CH_(2)OH)_(2)]A_(2)·sol(terpy-CH_(2)OH=4′-(hydr...Comprehensive Summary To better understand the impact of different anions on the structures and SCO properties of the CoII SCO complexes,six new complexes[Co(terpy-CH_(2)OH)_(2)]A_(2)·sol(terpy-CH_(2)OH=4′-(hydroxymethyl)-2,2′;6′,2″-terpyridine,A=Br–(1,sol=1.5H_(2)O),I–(2),N3–(3,sol=2H_(2)O),H_(3)BCN–(4),OTf–(5),and TsO–(6,sol=4H_(2)O·CH_(3)CN),have been synthesized and characterized.All six compounds consist of mononuclear[Co(terpy-CH_(2)OH)_(2)]^(2+)cations and charge-balancing anions that differ in size,shape,and hydrogen bonding capacity.Complexes 1,2,3,and 6 displayed incomplete gradual SCO transitions,whereas 4 and 5 exhibited abrupt hysteretic spin transitions with loops of 12 and 16 K(250.0—262.0 K for 4,and 370.0—386.0 K for 5,respectively),closely resembling our previously reported complexes with SCN^(–)and SeCN^(–)anions.The occurrence of the order-disorder transition of the CH2OH groups and their transition temperatures are determined by the size and hydrogen bonding capability of the anions.Remarkably,the transition temperatures of complexes with H_(3)BCN^(–),SCN^(–),OTf^(–),and SeCN^(–)anions exhibit an upward trend as the size and mass of the anions increase,as confirmed through detailed single crystal structure analyses conducted in both high-spin and low-spin states for all four complexes.展开更多
Bipolar membranes(BPMs)exhibit the unique capability to regulate the operating environment of electrochemical system through the water dissociation-combination processes.However,the industrial utilization of BPMs is l...Bipolar membranes(BPMs)exhibit the unique capability to regulate the operating environment of electrochemical system through the water dissociation-combination processes.However,the industrial utilization of BPMs is limited by instability and serious energy consumption.The current-induced membrane discharge(CIMD)at high-current conditions has a negative influence on the performance of anion-exchange membranes,but the underlying ion transport mechanisms in the BPMs remain unclear.Here,the CIMD-coupled Poisson-Nernst-Planck(PNP)equations are used to explore the ion transport mechanisms in the BPMs for both reverse bias and forward bias at neutral and acid-base conditions.It is demonstrated that the CIMD effect in the reverse-bias mode can be suppressed by enhancing the diffusive transport of salt counter-ions(Na^(+)and Cl^(−))into the BPMs,and that in the forward-bias mode with acid-base electrolytes can be suppressed by matching the transport rate of water counter-ions(H_(3)O^(+)and OH^(−)).Suppressing the CIMD can promote the water dissociation in the reverse-bias mode,as well as overcome the plateau of limiting current density and reduce the interfacial blockage of salt co-ions(Cl^(−))in the anion-exchange layer in the forward-bias mode with acid-base electrolytes.Our work highlights the importance of regulating ion crossover transport on improving the performance of BPMs.展开更多
In iron-based superconductor Fe(Se,Te), a flat band-like feature near the Fermi level was observed around the Brillouin zone center in the superconducting state. It is under debate whether this is the evidence on the ...In iron-based superconductor Fe(Se,Te), a flat band-like feature near the Fermi level was observed around the Brillouin zone center in the superconducting state. It is under debate whether this is the evidence on the presence of the BCS–BEC[Bardeen–Cooper–Schrieffer(BCS), Bose–Einstein condensation(BEC)] crossover in the superconductor. High-resolution laser-based angle-resolved photoemission measurements are carried out on high quality single crystals of FeSe_(0.45)Te_(0.55) superconductor to address the issue. By employing different polarization geometries, we have resolved and isolated the dyz band and the topological surface band, making it possible to study their superconducting behaviors separately. The dyz band alone does not form a flat band-like feature in the superconducting state and the measured dispersion can be well described by the BCS picture. We find that the flat band-like feature is formed from the combination of the dyz band and the topological surface state band in the superconducting state. These results reveal the origin of the flat band-like feature and rule out the presence of BCS-BEC crossover in Fe(Se,Te) superconductor.展开更多
Game theory is explored via a maze application where combinatorial optimization occurs with the objective of traversing through a defined maze with an aim to enhance decision support and locate the optimal travel sequ...Game theory is explored via a maze application where combinatorial optimization occurs with the objective of traversing through a defined maze with an aim to enhance decision support and locate the optimal travel sequence while minimizing computation time. This combinatorial optimization approach is initially demonstrated by utilizing a traditional genetic algorithm (GA), followed by the incorporation of artificial intelligence utilizing embedded rules based on domain-specific knowledge. The aim of this initiative is to compare the results of the traditional and rule-based optimization approaches with results acquired through an intelligent crossover methodology. The intelligent crossover approach encompasses a two-dimensional GA encoding where a second chromosome string is introduced within the GA, offering a sophisticated means for chromosome crossover amongst selected parents. Additionally, parent selection intelligence is incorporated where the best-traversed paths or population members are retained and utilized as potential parents to mate with parents selected within a traditional GA methodology. A further enhancement regarding the utilization of saved optimal population members as potential parents is mathematically explored within this literature.展开更多
An intelligent crossover methodology within the genetic algorithm (GA) is explored within both mathematical and finite element arenas improving both design and solution convergence time. This improved intelligent cros...An intelligent crossover methodology within the genetic algorithm (GA) is explored within both mathematical and finite element arenas improving both design and solution convergence time. This improved intelligent crossover outperforms the traditional genetic algorithm combined with a rule-based approach utilizing domain specific knowledge developed by Webb, et al. [1]. The encoding of the improved crossover consists of two chromosome strings within the genetic algorithm where the first string represents the design or solution string, and the second string represents chromosome crossover string intelligence. This improved crossover methodology saves the best population members or designs evaluated from each generation and applies crossover chromosome intelligence to the best saved population members paired with globally selected parents. Enhanced features of this crossover methodology employ the random selection of the best designs from the prior generation as a potential parent coupled with alternating intelligence pairing methods. In addition to this approach, two globally selected parents possess the ability to mate utilizing crossover chromosome string intelligence maintaining the integrity of a global GA search. Overall, the final population following crossover employs both global and best generation design chromosome strings to maximize creativity while enhancing the solution search. This is a modification to a conventional GA that can be translated into GA encoding. This technique is explored initially through a Base 10 mathematical application followed by the examination of plate structural optimization considering stress and displacement constraints. Results from crossover intelligence are compared with the conventional genetic algorithm and from Webb, et al. [1] which illustrates the outcome of a two phase genetic optimization algorithm.展开更多
We study the capacitated vehicle routing problem(CVRP)which is a well-known NP-hard combinatorial optimization problem(COP).The aim of the problem is to serve different customers by a convoy of vehicles starting from ...We study the capacitated vehicle routing problem(CVRP)which is a well-known NP-hard combinatorial optimization problem(COP).The aim of the problem is to serve different customers by a convoy of vehicles starting from a depot so that sum of the routing costs under their capacity constraints is minimized.Since the problem is very complicated,solving the problem using exact methods is almost impossible.So,one has to go for the heuristic/metaheuristic methods and genetic algorithm(GA)is broadly applied metaheuristic method to obtain near optimal solution to such COPs.So,this paper studies GAs to find solution to the problem.Generally,to solve a COP,GAs start with a chromosome set named initial population,and then mainly three operators-selection,crossover andmutation,are applied.Among these three operators,crossover is very crucial in designing and implementing GAs,and hence,numerous crossover operators were developed and applied to different COPs.There are two major kinds of crossover operators-blind crossovers and distance-based crossovers.We intend to compare the performance of four blind crossover and four distance-based crossover operators to test the suitability of the operators to solve the CVRP.These operators were originally proposed for the standard travelling salesman problem(TSP).First,these eight crossovers are illustrated using same parent chromosomes for building offspring(s).Then eight GAs using these eight crossover operators without any mutation operator and another eight GAs using these eight crossover operators with a mutation operator are developed.These GAs are experimented on some benchmark asymmetric and symmetric instances of numerous sizes and various number of vehicles.Our study revealed that the distance-based crossovers are much superior to the blind crossovers.Further,we observed that the sequential constructive crossover with and without mutation operator is the best one for theCVRP.This estimation is validated by Student’s t-test at 95%confidence level.We further determined a comparative rank of the eight crossovers for the CVRP.展开更多
Meiotic recombination plays an important role in genome evolution and crop improvement.Potato(Solanum tuberosum L.)is the most important tuber crop in the world,but research about meiotic recombination in potato is li...Meiotic recombination plays an important role in genome evolution and crop improvement.Potato(Solanum tuberosum L.)is the most important tuber crop in the world,but research about meiotic recombination in potato is limited.Here,we resequenced 2163 F2 clones derived from five different genetic backgrounds and identified 41945 meiotic crossovers.Some recombination suppression in euchromatin regions was associated with large structural variants.We also detected five shared crossover hotspots.The number of crossovers in each F2 individual from the accession Upotato 1 varied from 9 to 27,with an average of 15.5,78.25%of which were mapped within 5 kb of their presumed location.We show that 57.1%of the crossovers occurred in gene regions,with poly-A/T,poly-AG,AT-rich,and CCN repeats enriched in the crossover intervals.The recombination rate is positively related with gene density,SNP density,Class II transposon,and negatively related with GC density,repeat sequence density and Class I transposon.This study deepens our understanding of meiotic crossovers in potato and provides useful information for diploid potato breeding.展开更多
Micrometric-thin cells(MCs)with alkali vapor atoms have been valuable for research and applications of hyperfine Zeeman splitting and atomic magnetometers under strong magnetic fields.We theoretically and experimental...Micrometric-thin cells(MCs)with alkali vapor atoms have been valuable for research and applications of hyperfine Zeeman splitting and atomic magnetometers under strong magnetic fields.We theoretically and experimentally study the saturated absorption spectra using a 100-μm cesium MC,where the pump and probe beams are linearly polarized with mutually perpendicular polarizations,and the magnetic field is along the pump beam.Because of the distinctive thin chamber of the MC,crossover spectral lines in saturated absorption spectra are largely suppressed leading to clear splittings of hyperfine Zeeman transitions in experiments,and the effect of spatial magnetic field gradient is expected to be reduced.A calculation method is proposed to achieve good agreements between theoretical calculations and experimental results.This method successfully explains the suppression of crossover lines in MCs,as well as the effects of magnetic field direction,propagation and polarization directions of the pump/probe beam on saturated absorption spectrum.The saturated absorption spectrum with suppressed crossover lines is used for laser frequency stabilization,which may provide the potential value of MCs for high spatial resolution strong-field magnetometry with high sensitivity.展开更多
Using quantum hydrodynamic approaches, we study the quantum pressure correction to the collective excitation spectrum of the interacting trapped superfluid Fermi gases in the BEC-BCS crossover. Based on a phenomenolog...Using quantum hydrodynamic approaches, we study the quantum pressure correction to the collective excitation spectrum of the interacting trapped superfluid Fermi gases in the BEC-BCS crossover. Based on a phenomenological equation of state, we derive hydrodynamic equations of the system in the whole BEC-BCS crossover regime. Beyond the Thomas-Fermi approximation, expressions of the frequency corrections of collective modes for both spherical and axial symmetric traps excited in the BEC-BCS crossover are given explicitly. The corrections of the eigenfrequencies due to the quantum pressure and their dependence on the inverse interaction strength, anisotropic parameter and particle numbers of the condensate are discussed in detail.展开更多
An effective relativistic continuum massive Proca Lagrangian action is used to account for the Lorentzvector condensation effects on the equation of state of the strongly interacting fermions system.The interior quant...An effective relativistic continuum massive Proca Lagrangian action is used to account for the Lorentzvector condensation effects on the equation of state of the strongly interacting fermions system.The interior quantumfluctuation effects are incorporated as an external field approximation indirectly through a fictive generalized ThomsonProblem counterterm background.The general analytical formulas for the d-dimensional thermodynamics are given nearthe unitary limit region,In the non-relativistic limit for d=3,the universal dimensionless coefficientε=4/9 andenergy gap △/ε_f=5/18 are reasonably consistent with the existing theoretical and experimental results.In the unitarylimit for d=2 and T=0,the universal coefficient can even approach the extreme occasion ξ=0 corresponding to theinfinite effective fermion mass m~*=∞,which can be mapped to the strongly coupled two-dimensional electrons and isquite similar to the three-dimensional Bose-Einstein condensation of ideal boson gas.Instead,for d=1,the universalcoefficient ξ is negative,implying the non-existence of phase transition from superfluidity to normal state.The solutionsmanifest the quantum Ising universal class characteristic of the strongly coupled unitary fermions gas.展开更多
Digital nerve injuries are the mostly detected nerve injury in the upper extremity. However, since the clinical phenomenon of crossover innervation at some degree from uninjured digital nerve to the in- jured side occ...Digital nerve injuries are the mostly detected nerve injury in the upper extremity. However, since the clinical phenomenon of crossover innervation at some degree from uninjured digital nerve to the in- jured side occurs after digital nerve injuries is sustained, one could argue that this concept might even result in the overestimation of the outcome of the digital nerve repair. With this knowledge in mind, this study aimed to present novel, pure, focused and valuable clinical data by comparing the outcomes of bilateral and unilateral digital nerve repair. A retrospective review of 28 fingers with unilateral or bilateral digital nerve repair using end-to-end technique in 19 patients within 2 years was performed. Weber's two-point discrimination, sharp/dull discrimination, warm/cold sensation and Visual Analog Scale scoring were measured at final 12-month follow ups in all patients. There was no significant difference in recovery of sensibility after unilateral and bilateral digital nerve repairs. Though there is crossover innervation microscopically, it is not important in the clinical evaluation period. According to clinical findings from this study, crossover innervations appear to be negligible in the estimation of outcomes of digital neurorrhaphy.展开更多
In order to improve the tracking performance in this paper following TBD(Track before Detection) framework multi-level crossover and matching operator is presented.In data association stage the greedy principle is ado...In order to improve the tracking performance in this paper following TBD(Track before Detection) framework multi-level crossover and matching operator is presented.In data association stage the greedy principle is adopted to handle time complexity in DPA and at the same time crossover mathing operator is given to construct candidate trajectory.In addition the corresponding strategy is introduced in preprocessing and postprocessing to remove clutter and suppress false alarm rate.By the experimental comparison and analysis it can be found that the method is more perfer to strengthen the tracking performance of targets with SNR < 2.0 dB.展开更多
The spin crossover(SCO) compound [Fe(bapbpy)(NCS)2],where bapbpy contains two fused N,N-bis(2-pyridyl)amines,has been studied by DFT/TD-DFT/BS-DFT methods.Several density functionals and basis sets were used i...The spin crossover(SCO) compound [Fe(bapbpy)(NCS)2],where bapbpy contains two fused N,N-bis(2-pyridyl)amines,has been studied by DFT/TD-DFT/BS-DFT methods.Several density functionals and basis sets were used in the calculation to obtain optimized geometries of the compound in the low-(LS) and high-spin(HS) states.The vibrational modes and IR spectra,spin splitting energies,excited states and UV/Vis absorption spectra were obtained.The structural parameters of the calculated isolated complex are in good agreement with the X-ray data.We investigate three dimers of [Fe(bapbpy)(NCS)2] complex for their magnetic properties.It has been found that the complex(1,3) has ferromagnetic character while the others are antiferromagnetic in nature by using a broken symmetry approach in the DFT framework(BS-DFT) with support from the coupling constant values(J) and spin density plots.展开更多
In paired Fermi systems,strong many-body effects exhibit in the crossover regime between the Bardeen–Cooper–Schrieffer(BCS)and the Bose–Einstein condensation(BEC)limits.The concept of the BCS–BEC crossover,which i...In paired Fermi systems,strong many-body effects exhibit in the crossover regime between the Bardeen–Cooper–Schrieffer(BCS)and the Bose–Einstein condensation(BEC)limits.The concept of the BCS–BEC crossover,which is studied intensively in the research field of cold atoms,has been extended to condensed matters.Here by analyzing the typical superconductors within the BCS–BEC phase diagram,we find that FeSe-based superconductors are prone to shift their positions in the BCS–BEC crossover regime by charge doping or substrate substitution,since their Fermi energies and the superconducting gap sizes are comparable.Especially at the interface of single-layer FeSe on SrTiO3 substrate,the superconductivity is relocated closer to the crossover unitary than other doped FeSe-based materials,indicating that the pairing interaction is effectively modulated.We further show that hole-doping can drive the interfacial system into the phase with possible pre-paired electrons,demonstrating its flexible tunability within the BCS–BEC crossover regime.展开更多
In this paper,a new approach to design terahertz(THz)E-plane crossover coupler is reported.By cascading two symmetrical septum polarizers,a simple structure with wide operating bandwidth and high isolation performance...In this paper,a new approach to design terahertz(THz)E-plane crossover coupler is reported.By cascading two symmetrical septum polarizers,a simple structure with wide operating bandwidth and high isolation performance is achieved.The working principle is explained by operating waveguide modes.To simplify the optimization process,the scattering matrix(S-matrix)of the crossover is calculated.Two prototypes loaded and unloaded electromagnetic band gap(EBG)are fabricated and measured.The electrical contact problem at assembly plane is eliminated by the prototype loaded EBG.A measured bandwidth of 17.3%from 92.5 to 110 GHz for reflection and isolation coefficients<-15 dB and transmission coefficient>-2 dB is achieved.展开更多
The convergence of genetic algorithm is mainly determined by its core operation crossover operation. When the objective function is a multiple hump function, traditional genetic algorithms are easily trapped into loca...The convergence of genetic algorithm is mainly determined by its core operation crossover operation. When the objective function is a multiple hump function, traditional genetic algorithms are easily trapped into local optimum, which is called premature conver- gence. In this paper, we propose a new genetic algorithm with improved arithmetic crossover operation based on gradient method. This crossover operation can generate offspring along quasi-gradient direction which is the Steepest descent direction of the value of objective function. The selection operator is also simplified, every individual in the population is given an opportunity to get evolution to avoid complicated selection algorithm. The adaptive mutation operator and the elitist strategy are also applied in this algorithm. The case 4 indicates this algorithm can faster converge to the global optimum and is more stable than the conventional genetic algorithms.展开更多
Resource management in Underground Wireless Sensor Networks(UWSNs)is one of the pillars to extend the network lifetime.An intriguing design goal for such networks is to achieve balanced energy and spectral resource ut...Resource management in Underground Wireless Sensor Networks(UWSNs)is one of the pillars to extend the network lifetime.An intriguing design goal for such networks is to achieve balanced energy and spectral resource utilization.This paper focuses on optimizing the resource efficiency in UWSNs where underground relay nodes amplify and forward sensed data,received from the buried source nodes through a lossy soil medium,to the aboveground base station.A new algorithm called the Hybrid Chaotic Salp Swarm and Crossover(HCSSC)algorithm is proposed to obtain the optimal source and relay transmission powers to maximize the network resource efficiency.The proposed algorithm improves the standard Salp Swarm Algorithm(SSA)by considering a chaotic map to initialize the population along with performing the crossover technique in the position updates of salps.Through experimental results,the HCSSC algorithm proves its outstanding superiority to the standard SSA for resource efficiency optimization.Hence,the network’s lifetime is prolonged.Indeed,the proposed algorithm achieves an improvement performance of 23.6%and 20.4%for the resource efficiency and average remaining relay battery per transmission,respectively.Furthermore,simulation results demonstrate that the HCSSC algorithm proves its efficacy in the case of both equal and different node battery capacities.展开更多
We report near-zero crossover for vanadium cross-permeation through single-layer graphene immobilized at the interface of two Nafion?polymer electrolyte membranes.Vanadium ion diffusion and migration,including proton ...We report near-zero crossover for vanadium cross-permeation through single-layer graphene immobilized at the interface of two Nafion?polymer electrolyte membranes.Vanadium ion diffusion and migration,including proton mobility through membrane composites,were studied with and without graphene under diffusion and migration conditions.Single-layer graphene was found to effectively inhibit vanadium ion diffusion and migration under specific conditions.The single-layer graphene composites also enabled remarkable ion transmission selectivity improvements over pure Nafion membranes,with proton transport being four orders of magnitude faster than vanadium ion transport.Resistivity values of 0.02±0.005Ωcm^(2) for proton and 223±4Ωcm^(2) for vanadium ion through single atomic layer graphene are reported.This high selectivity may have significant impact on flow battery applications or for other electrochemical devices where proton conductivity is required,and transport of other species is detrimental.Our results emphasize that crossover may be essentially completely eliminated in some cases,enabling for greatly improved operational viability.展开更多
基金the Deanship of Scientific Research at Imam Mohammad Ibn Saud Islamic University(IMSIU)(Grant Number IMSIU-RP23030).
文摘Genetic algorithms(GAs)are very good metaheuristic algorithms that are suitable for solving NP-hard combinatorial optimization problems.AsimpleGAbeginswith a set of solutions represented by a population of chromosomes and then uses the idea of survival of the fittest in the selection process to select some fitter chromosomes.It uses a crossover operator to create better offspring chromosomes and thus,converges the population.Also,it uses a mutation operator to explore the unexplored areas by the crossover operator,and thus,diversifies the GA search space.A combination of crossover and mutation operators makes the GA search strong enough to reach the optimal solution.However,appropriate selection and combination of crossover operator and mutation operator can lead to a very good GA for solving an optimization problem.In this present paper,we aim to study the benchmark traveling salesman problem(TSP).We developed several genetic algorithms using seven crossover operators and six mutation operators for the TSP and then compared them to some benchmark TSPLIB instances.The experimental studies show the effectiveness of the combination of a comprehensive sequential constructive crossover operator and insertion mutation operator for the problem.The GA using the comprehensive sequential constructive crossover with insertion mutation could find average solutions whose average percentage of excesses from the best-known solutions are between 0.22 and 14.94 for our experimented problem instances.
基金supported by the National Natural Science Foundation of China(22273036,21973039)Y.-C S.acknowledges the support from the Postgraduate Research&Practice Innovation Program of Jiangsu Province(KYCX23_0108).
文摘Comprehensive Summary To better understand the impact of different anions on the structures and SCO properties of the CoII SCO complexes,six new complexes[Co(terpy-CH_(2)OH)_(2)]A_(2)·sol(terpy-CH_(2)OH=4′-(hydroxymethyl)-2,2′;6′,2″-terpyridine,A=Br–(1,sol=1.5H_(2)O),I–(2),N3–(3,sol=2H_(2)O),H_(3)BCN–(4),OTf–(5),and TsO–(6,sol=4H_(2)O·CH_(3)CN),have been synthesized and characterized.All six compounds consist of mononuclear[Co(terpy-CH_(2)OH)_(2)]^(2+)cations and charge-balancing anions that differ in size,shape,and hydrogen bonding capacity.Complexes 1,2,3,and 6 displayed incomplete gradual SCO transitions,whereas 4 and 5 exhibited abrupt hysteretic spin transitions with loops of 12 and 16 K(250.0—262.0 K for 4,and 370.0—386.0 K for 5,respectively),closely resembling our previously reported complexes with SCN^(–)and SeCN^(–)anions.The occurrence of the order-disorder transition of the CH2OH groups and their transition temperatures are determined by the size and hydrogen bonding capability of the anions.Remarkably,the transition temperatures of complexes with H_(3)BCN^(–),SCN^(–),OTf^(–),and SeCN^(–)anions exhibit an upward trend as the size and mass of the anions increase,as confirmed through detailed single crystal structure analyses conducted in both high-spin and low-spin states for all four complexes.
基金sponsored by the National Key R&D Program of China(2022YFB4602101)the Fundamental Research Funds for the Central Universities(2022ZFJH004 and 2024SMECP05)+2 种基金the National Natural Science Foundation of China(22278127 and 22378112)the Shanghai Pilot Program for Basic Research(22T01400100-18)the Postdoctoral Fellowship Program of CPSF(GZC20230801)。
文摘Bipolar membranes(BPMs)exhibit the unique capability to regulate the operating environment of electrochemical system through the water dissociation-combination processes.However,the industrial utilization of BPMs is limited by instability and serious energy consumption.The current-induced membrane discharge(CIMD)at high-current conditions has a negative influence on the performance of anion-exchange membranes,but the underlying ion transport mechanisms in the BPMs remain unclear.Here,the CIMD-coupled Poisson-Nernst-Planck(PNP)equations are used to explore the ion transport mechanisms in the BPMs for both reverse bias and forward bias at neutral and acid-base conditions.It is demonstrated that the CIMD effect in the reverse-bias mode can be suppressed by enhancing the diffusive transport of salt counter-ions(Na^(+)and Cl^(−))into the BPMs,and that in the forward-bias mode with acid-base electrolytes can be suppressed by matching the transport rate of water counter-ions(H_(3)O^(+)and OH^(−)).Suppressing the CIMD can promote the water dissociation in the reverse-bias mode,as well as overcome the plateau of limiting current density and reduce the interfacial blockage of salt co-ions(Cl^(−))in the anion-exchange layer in the forward-bias mode with acid-base electrolytes.Our work highlights the importance of regulating ion crossover transport on improving the performance of BPMs.
基金Projects supported by the National Key Research and Development Program of China(GrantNos.2021YFA1401800,2022YFA1604200,2022YFA1403900,and2023YFA1406000)the National Natural Science Foundation of China(Grant Nos.12488201,12374066,12074411,and 12374154)+3 种基金the Strategic Priority Research Program(B)of the Chinese Academy of Sciences(Grant Nos.XDB25000000 and XDB33000000)the Innovation Program for Quantum Science and Technology(Grant No.2021ZD0301800)the Youth Innovation Promotion Association of the Chinese Academy of Sciences(Grant No.Y2021006)the Synergetic Extreme Condition User Facility(SECUF)。
文摘In iron-based superconductor Fe(Se,Te), a flat band-like feature near the Fermi level was observed around the Brillouin zone center in the superconducting state. It is under debate whether this is the evidence on the presence of the BCS–BEC[Bardeen–Cooper–Schrieffer(BCS), Bose–Einstein condensation(BEC)] crossover in the superconductor. High-resolution laser-based angle-resolved photoemission measurements are carried out on high quality single crystals of FeSe_(0.45)Te_(0.55) superconductor to address the issue. By employing different polarization geometries, we have resolved and isolated the dyz band and the topological surface band, making it possible to study their superconducting behaviors separately. The dyz band alone does not form a flat band-like feature in the superconducting state and the measured dispersion can be well described by the BCS picture. We find that the flat band-like feature is formed from the combination of the dyz band and the topological surface state band in the superconducting state. These results reveal the origin of the flat band-like feature and rule out the presence of BCS-BEC crossover in Fe(Se,Te) superconductor.
文摘Game theory is explored via a maze application where combinatorial optimization occurs with the objective of traversing through a defined maze with an aim to enhance decision support and locate the optimal travel sequence while minimizing computation time. This combinatorial optimization approach is initially demonstrated by utilizing a traditional genetic algorithm (GA), followed by the incorporation of artificial intelligence utilizing embedded rules based on domain-specific knowledge. The aim of this initiative is to compare the results of the traditional and rule-based optimization approaches with results acquired through an intelligent crossover methodology. The intelligent crossover approach encompasses a two-dimensional GA encoding where a second chromosome string is introduced within the GA, offering a sophisticated means for chromosome crossover amongst selected parents. Additionally, parent selection intelligence is incorporated where the best-traversed paths or population members are retained and utilized as potential parents to mate with parents selected within a traditional GA methodology. A further enhancement regarding the utilization of saved optimal population members as potential parents is mathematically explored within this literature.
文摘An intelligent crossover methodology within the genetic algorithm (GA) is explored within both mathematical and finite element arenas improving both design and solution convergence time. This improved intelligent crossover outperforms the traditional genetic algorithm combined with a rule-based approach utilizing domain specific knowledge developed by Webb, et al. [1]. The encoding of the improved crossover consists of two chromosome strings within the genetic algorithm where the first string represents the design or solution string, and the second string represents chromosome crossover string intelligence. This improved crossover methodology saves the best population members or designs evaluated from each generation and applies crossover chromosome intelligence to the best saved population members paired with globally selected parents. Enhanced features of this crossover methodology employ the random selection of the best designs from the prior generation as a potential parent coupled with alternating intelligence pairing methods. In addition to this approach, two globally selected parents possess the ability to mate utilizing crossover chromosome string intelligence maintaining the integrity of a global GA search. Overall, the final population following crossover employs both global and best generation design chromosome strings to maximize creativity while enhancing the solution search. This is a modification to a conventional GA that can be translated into GA encoding. This technique is explored initially through a Base 10 mathematical application followed by the examination of plate structural optimization considering stress and displacement constraints. Results from crossover intelligence are compared with the conventional genetic algorithm and from Webb, et al. [1] which illustrates the outcome of a two phase genetic optimization algorithm.
基金the Deanship of Scientific Research at Imam Mohammad Ibn Saud Islamic University for funding thiswork through Research Group No.RG-21-09-17.
文摘We study the capacitated vehicle routing problem(CVRP)which is a well-known NP-hard combinatorial optimization problem(COP).The aim of the problem is to serve different customers by a convoy of vehicles starting from a depot so that sum of the routing costs under their capacity constraints is minimized.Since the problem is very complicated,solving the problem using exact methods is almost impossible.So,one has to go for the heuristic/metaheuristic methods and genetic algorithm(GA)is broadly applied metaheuristic method to obtain near optimal solution to such COPs.So,this paper studies GAs to find solution to the problem.Generally,to solve a COP,GAs start with a chromosome set named initial population,and then mainly three operators-selection,crossover andmutation,are applied.Among these three operators,crossover is very crucial in designing and implementing GAs,and hence,numerous crossover operators were developed and applied to different COPs.There are two major kinds of crossover operators-blind crossovers and distance-based crossovers.We intend to compare the performance of four blind crossover and four distance-based crossover operators to test the suitability of the operators to solve the CVRP.These operators were originally proposed for the standard travelling salesman problem(TSP).First,these eight crossovers are illustrated using same parent chromosomes for building offspring(s).Then eight GAs using these eight crossover operators without any mutation operator and another eight GAs using these eight crossover operators with a mutation operator are developed.These GAs are experimented on some benchmark asymmetric and symmetric instances of numerous sizes and various number of vehicles.Our study revealed that the distance-based crossovers are much superior to the blind crossovers.Further,we observed that the sequential constructive crossover with and without mutation operator is the best one for theCVRP.This estimation is validated by Student’s t-test at 95%confidence level.We further determined a comparative rank of the eight crossovers for the CVRP.
基金This work was supported by the China National Key Research and Development Program(Grant Number 2019YFE0120500)the National Natural Science Foundation of China(32022075)+3 种基金the Natural Science Foundation of Shenzhen(JCYJ20190813142201666)the National Science Fund of Yunnan for Distinguished Young Scholars(Grant No.202001AV070003)the Agricultural Science and Technology Innovation Program(CAAS-ZDRW202101)Science Technology and Innovation Commission of Shenzhen Municipality of China(ZDSYS20200811142605017).
文摘Meiotic recombination plays an important role in genome evolution and crop improvement.Potato(Solanum tuberosum L.)is the most important tuber crop in the world,but research about meiotic recombination in potato is limited.Here,we resequenced 2163 F2 clones derived from five different genetic backgrounds and identified 41945 meiotic crossovers.Some recombination suppression in euchromatin regions was associated with large structural variants.We also detected five shared crossover hotspots.The number of crossovers in each F2 individual from the accession Upotato 1 varied from 9 to 27,with an average of 15.5,78.25%of which were mapped within 5 kb of their presumed location.We show that 57.1%of the crossovers occurred in gene regions,with poly-A/T,poly-AG,AT-rich,and CCN repeats enriched in the crossover intervals.The recombination rate is positively related with gene density,SNP density,Class II transposon,and negatively related with GC density,repeat sequence density and Class I transposon.This study deepens our understanding of meiotic crossovers in potato and provides useful information for diploid potato breeding.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61571018 and 61531003).
文摘Micrometric-thin cells(MCs)with alkali vapor atoms have been valuable for research and applications of hyperfine Zeeman splitting and atomic magnetometers under strong magnetic fields.We theoretically and experimentally study the saturated absorption spectra using a 100-μm cesium MC,where the pump and probe beams are linearly polarized with mutually perpendicular polarizations,and the magnetic field is along the pump beam.Because of the distinctive thin chamber of the MC,crossover spectral lines in saturated absorption spectra are largely suppressed leading to clear splittings of hyperfine Zeeman transitions in experiments,and the effect of spatial magnetic field gradient is expected to be reduced.A calculation method is proposed to achieve good agreements between theoretical calculations and experimental results.This method successfully explains the suppression of crossover lines in MCs,as well as the effects of magnetic field direction,propagation and polarization directions of the pump/probe beam on saturated absorption spectrum.The saturated absorption spectrum with suppressed crossover lines is used for laser frequency stabilization,which may provide the potential value of MCs for high spatial resolution strong-field magnetometry with high sensitivity.
基金supported by the National Natural Science Foundation of China (Grant Nos 10574028, 10775032 and J0730310)
文摘Using quantum hydrodynamic approaches, we study the quantum pressure correction to the collective excitation spectrum of the interacting trapped superfluid Fermi gases in the BEC-BCS crossover. Based on a phenomenological equation of state, we derive hydrodynamic equations of the system in the whole BEC-BCS crossover regime. Beyond the Thomas-Fermi approximation, expressions of the frequency corrections of collective modes for both spherical and axial symmetric traps excited in the BEC-BCS crossover are given explicitly. The corrections of the eigenfrequencies due to the quantum pressure and their dependence on the inverse interaction strength, anisotropic parameter and particle numbers of the condensate are discussed in detail.
基金the Scientific Starting Research Fund of Central China Normal UniversityNational Natural Science Foundation of China under Grant No.10675052
文摘An effective relativistic continuum massive Proca Lagrangian action is used to account for the Lorentzvector condensation effects on the equation of state of the strongly interacting fermions system.The interior quantumfluctuation effects are incorporated as an external field approximation indirectly through a fictive generalized ThomsonProblem counterterm background.The general analytical formulas for the d-dimensional thermodynamics are given nearthe unitary limit region,In the non-relativistic limit for d=3,the universal dimensionless coefficientε=4/9 andenergy gap △/ε_f=5/18 are reasonably consistent with the existing theoretical and experimental results.In the unitarylimit for d=2 and T=0,the universal coefficient can even approach the extreme occasion ξ=0 corresponding to theinfinite effective fermion mass m~*=∞,which can be mapped to the strongly coupled two-dimensional electrons and isquite similar to the three-dimensional Bose-Einstein condensation of ideal boson gas.Instead,for d=1,the universalcoefficient ξ is negative,implying the non-existence of phase transition from superfluidity to normal state.The solutionsmanifest the quantum Ising universal class characteristic of the strongly coupled unitary fermions gas.
文摘Digital nerve injuries are the mostly detected nerve injury in the upper extremity. However, since the clinical phenomenon of crossover innervation at some degree from uninjured digital nerve to the in- jured side occurs after digital nerve injuries is sustained, one could argue that this concept might even result in the overestimation of the outcome of the digital nerve repair. With this knowledge in mind, this study aimed to present novel, pure, focused and valuable clinical data by comparing the outcomes of bilateral and unilateral digital nerve repair. A retrospective review of 28 fingers with unilateral or bilateral digital nerve repair using end-to-end technique in 19 patients within 2 years was performed. Weber's two-point discrimination, sharp/dull discrimination, warm/cold sensation and Visual Analog Scale scoring were measured at final 12-month follow ups in all patients. There was no significant difference in recovery of sensibility after unilateral and bilateral digital nerve repairs. Though there is crossover innervation microscopically, it is not important in the clinical evaluation period. According to clinical findings from this study, crossover innervations appear to be negligible in the estimation of outcomes of digital neurorrhaphy.
基金Sponsored by the Young Talent Program of Fujian Province (Grant No.2007F3097)
文摘In order to improve the tracking performance in this paper following TBD(Track before Detection) framework multi-level crossover and matching operator is presented.In data association stage the greedy principle is adopted to handle time complexity in DPA and at the same time crossover mathing operator is given to construct candidate trajectory.In addition the corresponding strategy is introduced in preprocessing and postprocessing to remove clutter and suppress false alarm rate.By the experimental comparison and analysis it can be found that the method is more perfer to strengthen the tracking performance of targets with SNR < 2.0 dB.
基金Supported by the Natural Science Foundation of Shandong Province(No.Y2006B43)
文摘The spin crossover(SCO) compound [Fe(bapbpy)(NCS)2],where bapbpy contains two fused N,N-bis(2-pyridyl)amines,has been studied by DFT/TD-DFT/BS-DFT methods.Several density functionals and basis sets were used in the calculation to obtain optimized geometries of the compound in the low-(LS) and high-spin(HS) states.The vibrational modes and IR spectra,spin splitting energies,excited states and UV/Vis absorption spectra were obtained.The structural parameters of the calculated isolated complex are in good agreement with the X-ray data.We investigate three dimers of [Fe(bapbpy)(NCS)2] complex for their magnetic properties.It has been found that the complex(1,3) has ferromagnetic character while the others are antiferromagnetic in nature by using a broken symmetry approach in the DFT framework(BS-DFT) with support from the coupling constant values(J) and spin density plots.
基金Supported by the National Key R&D Program of China under Grant Nos 2017YFA0303600,2016YFA0300600 and2016YFA0202300the National Natural Science Foundation of China under Grant No 11634016+3 种基金the Strategic Priority Research Program(B)of Chinese Academy of Sciences under Grant No XDB07030100the Research Program of Beijing Academy of Quantum Information Sciences under Grant No Y18G09the Youth Innovation Promotion Association of Chinese Academy of Sciences under Grant No 2016008the Hundred Talents Program of Chinese Academy of Sciences
文摘In paired Fermi systems,strong many-body effects exhibit in the crossover regime between the Bardeen–Cooper–Schrieffer(BCS)and the Bose–Einstein condensation(BEC)limits.The concept of the BCS–BEC crossover,which is studied intensively in the research field of cold atoms,has been extended to condensed matters.Here by analyzing the typical superconductors within the BCS–BEC phase diagram,we find that FeSe-based superconductors are prone to shift their positions in the BCS–BEC crossover regime by charge doping or substrate substitution,since their Fermi energies and the superconducting gap sizes are comparable.Especially at the interface of single-layer FeSe on SrTiO3 substrate,the superconductivity is relocated closer to the crossover unitary than other doped FeSe-based materials,indicating that the pairing interaction is effectively modulated.We further show that hole-doping can drive the interfacial system into the phase with possible pre-paired electrons,demonstrating its flexible tunability within the BCS–BEC crossover regime.
基金the National Natural Science Foundation of China under Grant No.61474112 and Grant No.62001039.
文摘In this paper,a new approach to design terahertz(THz)E-plane crossover coupler is reported.By cascading two symmetrical septum polarizers,a simple structure with wide operating bandwidth and high isolation performance is achieved.The working principle is explained by operating waveguide modes.To simplify the optimization process,the scattering matrix(S-matrix)of the crossover is calculated.Two prototypes loaded and unloaded electromagnetic band gap(EBG)are fabricated and measured.The electrical contact problem at assembly plane is eliminated by the prototype loaded EBG.A measured bandwidth of 17.3%from 92.5 to 110 GHz for reflection and isolation coefficients<-15 dB and transmission coefficient>-2 dB is achieved.
文摘The convergence of genetic algorithm is mainly determined by its core operation crossover operation. When the objective function is a multiple hump function, traditional genetic algorithms are easily trapped into local optimum, which is called premature conver- gence. In this paper, we propose a new genetic algorithm with improved arithmetic crossover operation based on gradient method. This crossover operation can generate offspring along quasi-gradient direction which is the Steepest descent direction of the value of objective function. The selection operator is also simplified, every individual in the population is given an opportunity to get evolution to avoid complicated selection algorithm. The adaptive mutation operator and the elitist strategy are also applied in this algorithm. The case 4 indicates this algorithm can faster converge to the global optimum and is more stable than the conventional genetic algorithms.
文摘Resource management in Underground Wireless Sensor Networks(UWSNs)is one of the pillars to extend the network lifetime.An intriguing design goal for such networks is to achieve balanced energy and spectral resource utilization.This paper focuses on optimizing the resource efficiency in UWSNs where underground relay nodes amplify and forward sensed data,received from the buried source nodes through a lossy soil medium,to the aboveground base station.A new algorithm called the Hybrid Chaotic Salp Swarm and Crossover(HCSSC)algorithm is proposed to obtain the optimal source and relay transmission powers to maximize the network resource efficiency.The proposed algorithm improves the standard Salp Swarm Algorithm(SSA)by considering a chaotic map to initialize the population along with performing the crossover technique in the position updates of salps.Through experimental results,the HCSSC algorithm proves its outstanding superiority to the standard SSA for resource efficiency optimization.Hence,the network’s lifetime is prolonged.Indeed,the proposed algorithm achieves an improvement performance of 23.6%and 20.4%for the resource efficiency and average remaining relay battery per transmission,respectively.Furthermore,simulation results demonstrate that the HCSSC algorithm proves its efficacy in the case of both equal and different node battery capacities.
文摘We report near-zero crossover for vanadium cross-permeation through single-layer graphene immobilized at the interface of two Nafion?polymer electrolyte membranes.Vanadium ion diffusion and migration,including proton mobility through membrane composites,were studied with and without graphene under diffusion and migration conditions.Single-layer graphene was found to effectively inhibit vanadium ion diffusion and migration under specific conditions.The single-layer graphene composites also enabled remarkable ion transmission selectivity improvements over pure Nafion membranes,with proton transport being four orders of magnitude faster than vanadium ion transport.Resistivity values of 0.02±0.005Ωcm^(2) for proton and 223±4Ωcm^(2) for vanadium ion through single atomic layer graphene are reported.This high selectivity may have significant impact on flow battery applications or for other electrochemical devices where proton conductivity is required,and transport of other species is detrimental.Our results emphasize that crossover may be essentially completely eliminated in some cases,enabling for greatly improved operational viability.