A systematic experiment relating to the electrochemistry of oxygen ion transport in slag has been studied in lab. An equivalent circuit has been used to describe ion transfer between metal and slag in this paper and a...A systematic experiment relating to the electrochemistry of oxygen ion transport in slag has been studied in lab. An equivalent circuit has been used to describe ion transfer between metal and slag in this paper and a kinetic model with electrochemical characteristic representing oxygen ion immigration has been worked out. The different experimental phenomena can be explained generally by this model. It can be seen that the theoretical results are in good agreement with experiments. The comparison of experimental data with model calculation proved that the electrochemical model is right.展开更多
A study of flow characteristics of blast furnace slag helps determine its softening and flow (liquid-mobility) temperatures. The slag with a narrow difference between the two temperatures is termed a “Short Slag”. I...A study of flow characteristics of blast furnace slag helps determine its softening and flow (liquid-mobility) temperatures. The slag with a narrow difference between the two temperatures is termed a “Short Slag”. Its formation ensures higher rates of slag-metal reactions with the trickle of the slag soon after its formation exposing fresh mass for faster reactions, the trickling slag, creating fresh interfaces facilitating slag-metal exchanges. In the present work, a novel technique is adopted to determine the flow characteristics of blast furnace slag obtained from different industrial blast furnaces. It is seen that the results so obtained agree very closely with the values obtained from adopting conventional methods of determining the liquidus temperature using “slag atlas”. It is observed that under the range of compositions studied a high C/S ratio combined with a high MgO content in the slag is beneficial to the B.F. process as it renders a “short slag”.展开更多
研究了210 t BOF-LF-RH-CC工艺流程生产X80管线钢(%:0.041～0.044C、0.15Si、1.78～1.80Mn、0.007～0.010P、0.000 8～0.001 2S、0.039～0.047[Al]s)时精炼过程中夹杂物的变化。在BOF出钢阶段采用加Al强脱氧(0.01%～0.02%[Al]s),LF精炼...研究了210 t BOF-LF-RH-CC工艺流程生产X80管线钢(%:0.041～0.044C、0.15Si、1.78～1.80Mn、0.007～0.010P、0.000 8～0.001 2S、0.039～0.047[Al]s)时精炼过程中夹杂物的变化。在BOF出钢阶段采用加Al强脱氧(0.01%～0.02%[Al]s),LF精炼过程采用高碱度、强还原性精炼渣(精炼渣成分%:50～58CaO、7～10MgO、20～25Al_2O_3、4～7SiO_2、0.5～1.4TFe),炉渣和钢液反应活跃,使得钢中Al_2O_3夹杂物很快向液态钙铝酸盐和部分液态CaO-MgO-Al_2O_3复合夹杂物转变。液态夹杂物通过碰撞、聚合、长大及上浮去除,提高了钢液的洁净度。浇铸前T[O]降到(7～10)×10^(-6),钢中夹杂物尺寸在3～5μm,试验炉次的热轧板内未发现大尺寸的低熔点钙铝酸盐类长条夹杂物。展开更多
The oxidation of alloying elements during the ESR of stainless steel has been studied. The model previously developed by WEI and Mitchell for the chemical reactions and mass transfer processes during ESR was applied t...The oxidation of alloying elements during the ESR of stainless steel has been studied. The model previously developed by WEI and Mitchell for the chemical reactions and mass transfer processes during ESR was applied to the remelting of the high Cr steel 1Cr18Ni9(Ti).The laboratory data for the unsteady state A.C.ESR were analyzed and dealt with by the model.When the remelting process reached a steady state,an oxidant(Fe_2O_3 powder)or a deoxidant(Ca-Si powder or metallic Ca)was added to the slag bath.The results showed that this model is applicable to the remelting of stainless steel rather precisely, and it is expected that the model may offer a reliable basis for the control of composition during practical ESR of high alloy steel. Also,the oxidation of Cr in the steel must be noticed when its content is high;but it is entirely possible to adjust the Cr content of ingot within a considerable range,using a special technique by means of the slag-metal reactions during the remelting.展开更多
文摘A systematic experiment relating to the electrochemistry of oxygen ion transport in slag has been studied in lab. An equivalent circuit has been used to describe ion transfer between metal and slag in this paper and a kinetic model with electrochemical characteristic representing oxygen ion immigration has been worked out. The different experimental phenomena can be explained generally by this model. It can be seen that the theoretical results are in good agreement with experiments. The comparison of experimental data with model calculation proved that the electrochemical model is right.
文摘A study of flow characteristics of blast furnace slag helps determine its softening and flow (liquid-mobility) temperatures. The slag with a narrow difference between the two temperatures is termed a “Short Slag”. Its formation ensures higher rates of slag-metal reactions with the trickle of the slag soon after its formation exposing fresh mass for faster reactions, the trickling slag, creating fresh interfaces facilitating slag-metal exchanges. In the present work, a novel technique is adopted to determine the flow characteristics of blast furnace slag obtained from different industrial blast furnaces. It is seen that the results so obtained agree very closely with the values obtained from adopting conventional methods of determining the liquidus temperature using “slag atlas”. It is observed that under the range of compositions studied a high C/S ratio combined with a high MgO content in the slag is beneficial to the B.F. process as it renders a “short slag”.
文摘研究了210 t BOF-LF-RH-CC工艺流程生产X80管线钢(%:0.041～0.044C、0.15Si、1.78～1.80Mn、0.007～0.010P、0.000 8～0.001 2S、0.039～0.047[Al]s)时精炼过程中夹杂物的变化。在BOF出钢阶段采用加Al强脱氧(0.01%～0.02%[Al]s),LF精炼过程采用高碱度、强还原性精炼渣(精炼渣成分%:50～58CaO、7～10MgO、20～25Al_2O_3、4～7SiO_2、0.5～1.4TFe),炉渣和钢液反应活跃,使得钢中Al_2O_3夹杂物很快向液态钙铝酸盐和部分液态CaO-MgO-Al_2O_3复合夹杂物转变。液态夹杂物通过碰撞、聚合、长大及上浮去除,提高了钢液的洁净度。浇铸前T[O]降到(7～10)×10^(-6),钢中夹杂物尺寸在3～5μm,试验炉次的热轧板内未发现大尺寸的低熔点钙铝酸盐类长条夹杂物。
文摘The oxidation of alloying elements during the ESR of stainless steel has been studied. The model previously developed by WEI and Mitchell for the chemical reactions and mass transfer processes during ESR was applied to the remelting of the high Cr steel 1Cr18Ni9(Ti).The laboratory data for the unsteady state A.C.ESR were analyzed and dealt with by the model.When the remelting process reached a steady state,an oxidant(Fe_2O_3 powder)or a deoxidant(Ca-Si powder or metallic Ca)was added to the slag bath.The results showed that this model is applicable to the remelting of stainless steel rather precisely, and it is expected that the model may offer a reliable basis for the control of composition during practical ESR of high alloy steel. Also,the oxidation of Cr in the steel must be noticed when its content is high;but it is entirely possible to adjust the Cr content of ingot within a considerable range,using a special technique by means of the slag-metal reactions during the remelting.
