In order to clarify the slag system of high Cr2O3 vanadium-titanium magnetite smelting in BF (blast furnace), the melting properties of slag samples prepared by analytically pure reagents were measured. By means of ...In order to clarify the slag system of high Cr2O3 vanadium-titanium magnetite smelting in BF (blast furnace), the melting properties of slag samples prepared by analytically pure reagents were measured. By means of orthogonal test synthetic weighted score method, the optimal slag for high Cr2O3 vanadium-titanium magnetite was obtained, which contained 10% MgO, 8% TiO2 and 15% Al2O3, with the binary basicity being 1.15. In addition, the effects of basicity, MgO, TiO2 and A12 03 on slag melting properties were investigated by single factor test, and the results showed that, with increasing the basicity or TiO2 content, melting temperature (Tin) increased, whereas initial vis- cosity (r/0) and high temperature viscosity (r/h) decreased. With increasing the MgO content, Tm decreased firstly and then increased. With increasing the Al2 O3 content, Tm increased, and η0 and r/h decreased firstly and then increased.展开更多
In order to control the CaO-Al;O;-SiO;-MgO system inclusions in 50 CrVA spring steel in a lower melting temperature region,high temperature equilibrium experiments between steel and slag were performed in the laborato...In order to control the CaO-Al;O;-SiO;-MgO system inclusions in 50 CrVA spring steel in a lower melting temperature region,high temperature equilibrium experiments between steel and slag were performed in the laboratory,under the conditions of the initial slag basicity within 3-7and the content of Al;O;between 18-35mass%,to investigate the formation and evolution of this type of inclusion.The results indicate that the total oxygen content in the steel decreases with the increase of slag basicity and the decrease of Al;O;content in slags,and CaO-Al;O;-SiO2-MgO inclusions tend to deviate from the low melting point region with the increase of Al;O;content in slags.The most favorable composition for the refining slag is composed of 51-56mass% CaO,9-13mass% SiO;,20-25mass% Al;O;and 6mass% MgO.In this case,the inclusions in 50 CrVA spring steel are mostly in the low melting point regions,in which their plasticities are expected to improve during steel rolling.The MgO-based inclusions were observed in the steel matrix and the formation mechanism was theoretically and schematically revealed.It is also found that adding around 11mass% of MgO into the refining slags is beneficial to reducing the refractory corrosion.Further work should be carried out focusing on the evolution rates of MgO-based inclusions.展开更多
基金Item Sponsored by National Natural Science Foundation of China(51090384)National High Technology Research and Development Program(863 Program)of China(2012AA062302,2012AA062304)Fundamental Research Funds for the Central Universities of China(N110202001)
文摘In order to clarify the slag system of high Cr2O3 vanadium-titanium magnetite smelting in BF (blast furnace), the melting properties of slag samples prepared by analytically pure reagents were measured. By means of orthogonal test synthetic weighted score method, the optimal slag for high Cr2O3 vanadium-titanium magnetite was obtained, which contained 10% MgO, 8% TiO2 and 15% Al2O3, with the binary basicity being 1.15. In addition, the effects of basicity, MgO, TiO2 and A12 03 on slag melting properties were investigated by single factor test, and the results showed that, with increasing the basicity or TiO2 content, melting temperature (Tin) increased, whereas initial vis- cosity (r/0) and high temperature viscosity (r/h) decreased. With increasing the MgO content, Tm decreased firstly and then increased. With increasing the Al2 O3 content, Tm increased, and η0 and r/h decreased firstly and then increased.
基金support of the funds by the National Key Research and Development Program of China(No.2017YFB0304001)
文摘In order to control the CaO-Al;O;-SiO;-MgO system inclusions in 50 CrVA spring steel in a lower melting temperature region,high temperature equilibrium experiments between steel and slag were performed in the laboratory,under the conditions of the initial slag basicity within 3-7and the content of Al;O;between 18-35mass%,to investigate the formation and evolution of this type of inclusion.The results indicate that the total oxygen content in the steel decreases with the increase of slag basicity and the decrease of Al;O;content in slags,and CaO-Al;O;-SiO2-MgO inclusions tend to deviate from the low melting point region with the increase of Al;O;content in slags.The most favorable composition for the refining slag is composed of 51-56mass% CaO,9-13mass% SiO;,20-25mass% Al;O;and 6mass% MgO.In this case,the inclusions in 50 CrVA spring steel are mostly in the low melting point regions,in which their plasticities are expected to improve during steel rolling.The MgO-based inclusions were observed in the steel matrix and the formation mechanism was theoretically and schematically revealed.It is also found that adding around 11mass% of MgO into the refining slags is beneficial to reducing the refractory corrosion.Further work should be carried out focusing on the evolution rates of MgO-based inclusions.