The oxygen-ion-permeable membrane galvanic short-circuit method has been developed, in which pure metal was directly extracted from the molten oxide slag, and no external voltage is applied. The galvanic cell employed...The oxygen-ion-permeable membrane galvanic short-circuit method has been developed, in which pure metal was directly extracted from the molten oxide slag, and no external voltage is applied. The galvanic cell employed in the experiment was as follows: graphite rod|[O]Fe+C saturation|ZrO2(MgO)|(FeO)(slag)|Fe rod. The reduction current in the galvanic cell consisted of an external short-circuit current and an interior short-circuit current in the oxygen-ion-permeable membrane. The real-time variation of external circuit reduction ratio of the molten slag could be obtained from the curve of the external circuit current to the time.展开更多
The oxygen-ion-permeable membrane galvanic short-circuit method has been developed, in which pure metal was directly extracted from the molten oxide slag, and no external voltage is applied. The galvanic cell employed...The oxygen-ion-permeable membrane galvanic short-circuit method has been developed, in which pure metal was directly extracted from the molten oxide slag, and no external voltage is applied. The galvanic cell employed in the experiment was as follows: graphite rod|[O][ZrO(MgO)|(FeO))|Fe rod. The reduction current in the galvanic cell consisted of an external short-circuit current and an interior short-circuit current in the oxygen-ion-permeable membrane. The real-time variation of external circuit reduction ratio of the molten slag could be obtained from the curve of the external circuit current to the time.展开更多
提供了一种新的钢液无污染脱氧的方法。对比研究了在钢液与CaO(35%)-Al2O3(55%)-MgO(10%)(质量分数)熔渣间不加电压(断路),外加电压U=0.5 V和U=1.0 V 3种条件下的脱氧情况,试验结果表明脱氧速率随着外加电压的增加而增加。此外,推导并...提供了一种新的钢液无污染脱氧的方法。对比研究了在钢液与CaO(35%)-Al2O3(55%)-MgO(10%)(质量分数)熔渣间不加电压(断路),外加电压U=0.5 V和U=1.0 V 3种条件下的脱氧情况,试验结果表明脱氧速率随着外加电压的增加而增加。此外,推导并分析了电化学脱氧的机制方程,发现可以通过增强钢液搅拌强度,加大外加电压,选择高电导率、高碱度、低黏度的渣系,降低外电路电阻等措施来加快电化学脱氧的速度。展开更多
基金This work was financially supported by the National Natural Science Foundation of China (No.59934090) and the National Key Basic Research and Development Program of China (No.G1998061506)
文摘The oxygen-ion-permeable membrane galvanic short-circuit method has been developed, in which pure metal was directly extracted from the molten oxide slag, and no external voltage is applied. The galvanic cell employed in the experiment was as follows: graphite rod|[O]Fe+C saturation|ZrO2(MgO)|(FeO)(slag)|Fe rod. The reduction current in the galvanic cell consisted of an external short-circuit current and an interior short-circuit current in the oxygen-ion-permeable membrane. The real-time variation of external circuit reduction ratio of the molten slag could be obtained from the curve of the external circuit current to the time.
文摘The oxygen-ion-permeable membrane galvanic short-circuit method has been developed, in which pure metal was directly extracted from the molten oxide slag, and no external voltage is applied. The galvanic cell employed in the experiment was as follows: graphite rod|[O][ZrO(MgO)|(FeO))|Fe rod. The reduction current in the galvanic cell consisted of an external short-circuit current and an interior short-circuit current in the oxygen-ion-permeable membrane. The real-time variation of external circuit reduction ratio of the molten slag could be obtained from the curve of the external circuit current to the time.
文摘提供了一种新的钢液无污染脱氧的方法。对比研究了在钢液与CaO(35%)-Al2O3(55%)-MgO(10%)(质量分数)熔渣间不加电压(断路),外加电压U=0.5 V和U=1.0 V 3种条件下的脱氧情况,试验结果表明脱氧速率随着外加电压的增加而增加。此外,推导并分析了电化学脱氧的机制方程,发现可以通过增强钢液搅拌强度,加大外加电压,选择高电导率、高碱度、低黏度的渣系,降低外电路电阻等措施来加快电化学脱氧的速度。
