The basic formulation of Al2O3- C slide plates was65%（ in mass,the same hereinafter） white fused corundum particles,25% white fused corundum fines,6% active α-Al2O3 micropowder,4% carbon black and flake graphite, a...The basic formulation of Al2O3- C slide plates was65%（ in mass,the same hereinafter） white fused corundum particles,25% white fused corundum fines,6% active α-Al2O3 micropowder,4% carbon black and flake graphite, and additional 4% phenolic resin.Based on this formulation,3% Al powder,3% Si powder,and 3% Al ＋ 3% Si powder were used to substitute equivalent white corundum fines to improve the hot mechanical properties of Al2O3- C slide plates. The specimens with dimensions of 140 mm × 25 mm × 25 mm were pressed at 150 MPa,dried at 200 ℃ for 24 h,and hot treated at 1 400 ℃ for 3 h in carbon embedded condition. Then hot modulus of rupture and thermal shock resistance of the specimens were tested and the phase compositions and microstructure were analyzed. The results show that specimen with 3% Al powder has the higher hot modulus of rupture but lower residual modulus of rupture after thermal shock than the specimen with3% Si powder; the specimen with 3% Al ＋ 3% Si powders exhibits the highest hot modulus of rupture and the best thermal shock resistance; the change of mechanical property is closely related with the in-situ formed nonoxides： AlN in the form of bars is formed in specimens with Al powder; fibrous SiC whiskers are formed in specimens with Si powder; in the specimens with both Al and Sipowders,besides AlN and SiC whiskers,hexagonal tabular SiAlON is in-situ synthesized,which interlocks with each other.展开更多
The zirconia ceramic ring was prepared using fused monoclinic zirconia as main starting material, adopting composite stabilizer of magnesia, yttria and calcium nitrate, and applying recombination technology of traditi...The zirconia ceramic ring was prepared using fused monoclinic zirconia as main starting material, adopting composite stabilizer of magnesia, yttria and calcium nitrate, and applying recombination technology of traditional refractories and ceramics. Effect of the preparation process on material properties was comparatively studied, and the microstructure and phase composition were analyzed. The results show that adopting the high-speed mixing granulation process and the appropriate heat treatment can realize the control on the phase composition and microstructure, the zirconia ceramic ring with good thermal shock resitance and mechanical properties can be prepared.展开更多
Magnesium aluminate spinel -corundum composite was prepared with waste slide plate and magnesia carbon brick. Microstructure and sintering ability of as-prepared magnesium aluminate spinel -corundum composite were inv...Magnesium aluminate spinel -corundum composite was prepared with waste slide plate and magnesia carbon brick. Microstructure and sintering ability of as-prepared magnesium aluminate spinel -corundum composite were investigated with XRD, SEM, and DSC/TG. With the addition of waste slide plate increasing or synthesis tem- perature rising, the bulk density of the specimen increases and the apparent porosity decreases, but the crystallinity of the specimen decreases and the magnesium alaminate spinel phase increases. The obtained composite contains 72% spinel and 26% corundum. Primary phase and secondary phase are bonded by glass phase. The results show that it is feasible to synthesis magnesium aluminate spinel - corundum material with waste slide plate and magnesia carbon brick.展开更多
Several kinds of slide nozzle plate such as A12O3-C-ZrO2, MgO, Al2O3, Spinel-C and A12O3-C SN plate for high oxygen steel used in BaoSteel have been analysed, the appearance and size of the SN plate after using have b...Several kinds of slide nozzle plate such as A12O3-C-ZrO2, MgO, Al2O3, Spinel-C and A12O3-C SN plate for high oxygen steel used in BaoSteel have been analysed, the appearance and size of the SN plate after using have been measured. The Al2O3-C SN plate has longer service life in casting high oxygen steel, and the wear mechanism of different SN plates is discussed.展开更多
文摘The basic formulation of Al2O3- C slide plates was65%（ in mass,the same hereinafter） white fused corundum particles,25% white fused corundum fines,6% active α-Al2O3 micropowder,4% carbon black and flake graphite, and additional 4% phenolic resin.Based on this formulation,3% Al powder,3% Si powder,and 3% Al ＋ 3% Si powder were used to substitute equivalent white corundum fines to improve the hot mechanical properties of Al2O3- C slide plates. The specimens with dimensions of 140 mm × 25 mm × 25 mm were pressed at 150 MPa,dried at 200 ℃ for 24 h,and hot treated at 1 400 ℃ for 3 h in carbon embedded condition. Then hot modulus of rupture and thermal shock resistance of the specimens were tested and the phase compositions and microstructure were analyzed. The results show that specimen with 3% Al powder has the higher hot modulus of rupture but lower residual modulus of rupture after thermal shock than the specimen with3% Si powder; the specimen with 3% Al ＋ 3% Si powders exhibits the highest hot modulus of rupture and the best thermal shock resistance; the change of mechanical property is closely related with the in-situ formed nonoxides： AlN in the form of bars is formed in specimens with Al powder; fibrous SiC whiskers are formed in specimens with Si powder; in the specimens with both Al and Sipowders,besides AlN and SiC whiskers,hexagonal tabular SiAlON is in-situ synthesized,which interlocks with each other.
文摘The zirconia ceramic ring was prepared using fused monoclinic zirconia as main starting material, adopting composite stabilizer of magnesia, yttria and calcium nitrate, and applying recombination technology of traditional refractories and ceramics. Effect of the preparation process on material properties was comparatively studied, and the microstructure and phase composition were analyzed. The results show that adopting the high-speed mixing granulation process and the appropriate heat treatment can realize the control on the phase composition and microstructure, the zirconia ceramic ring with good thermal shock resitance and mechanical properties can be prepared.
文摘Magnesium aluminate spinel -corundum composite was prepared with waste slide plate and magnesia carbon brick. Microstructure and sintering ability of as-prepared magnesium aluminate spinel -corundum composite were investigated with XRD, SEM, and DSC/TG. With the addition of waste slide plate increasing or synthesis tem- perature rising, the bulk density of the specimen increases and the apparent porosity decreases, but the crystallinity of the specimen decreases and the magnesium alaminate spinel phase increases. The obtained composite contains 72% spinel and 26% corundum. Primary phase and secondary phase are bonded by glass phase. The results show that it is feasible to synthesis magnesium aluminate spinel - corundum material with waste slide plate and magnesia carbon brick.
文摘Several kinds of slide nozzle plate such as A12O3-C-ZrO2, MgO, Al2O3, Spinel-C and A12O3-C SN plate for high oxygen steel used in BaoSteel have been analysed, the appearance and size of the SN plate after using have been measured. The Al2O3-C SN plate has longer service life in casting high oxygen steel, and the wear mechanism of different SN plates is discussed.
