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Role of heterogenous microstructure and deformation behavior in achieving superior strength-ductility synergy in zinc fabricated via laser powder bed fusion 被引量:1
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作者 Zhi Dong Changjun Han +7 位作者 Yanzhe Zhao Jinmiao Huang Chenrong Ling Gaoling Hu Yunhui Wang Di Wang Changhui Song Yongqiang Yang 《International Journal of Extreme Manufacturing》 SCIE EI CAS CSCD 2024年第4期225-245,共21页
Zinc(Zn)is considered a promising biodegradable metal for implant applications due to its appropriate degradability and favorable osteogenesis properties.In this work,laser powder bed fusion(LPBF)additive manufacturin... Zinc(Zn)is considered a promising biodegradable metal for implant applications due to its appropriate degradability and favorable osteogenesis properties.In this work,laser powder bed fusion(LPBF)additive manufacturing was employed to fabricate pure Zn with a heterogeneous microstructure and exceptional strength-ductility synergy.An optimized processing window of LPBF was established for printing Zn samples with relative densities greater than 99%using a laser power range of 80∼90 W and a scanning speed of 900 mm s−1.The Zn sample printed with a power of 80 W at a speed of 900 mm s−1 exhibited a hierarchical heterogeneous microstructure consisting of millimeter-scale molten pool boundaries,micrometer-scale bimodal grains,and nanometer-scale pre-existing dislocations,due to rapid cooling rates and significant thermal gradients formed in the molten pools.The printed sample exhibited the highest ductility of∼12.1%among all reported LPBF-printed pure Zn to date with appreciable ultimate tensile strength(∼128.7 MPa).Such superior strength-ductility synergy can be attributed to the presence of multiple deformation mechanisms that are primarily governed by heterogeneous deformation-induced hardening resulting from the alternative arrangement of bimodal Zn grains with pre-existing dislocations.Additionally,continuous strain hardening was facilitated through the interactions between deformation twins,grains and dislocations as strain accumulated,further contributing to the superior strength-ductility synergy.These findings provide valuable insights into the deformation behavior and mechanisms underlying exceptional mechanical properties of LPBF-printed Zn and its alloys for implant applications. 展开更多
关键词 laser powder bed fusion ZINC heterogeneous microstructure bimodal grains strength-ductility synergy
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Synergy of inside doped metals–Outside coated graphene to enhance hydrogen storage in magnesium-based alloys
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作者 Kun Zhang Yu Chang +7 位作者 Jingjing Lei Jing Chen Tingzhi Si Xiaoli Ding Ping Cui Hai-Wen Li Qingan Zhang Yongtao Li 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第6期2462-2471,共10页
Grain growth of magnesium(Mg)and its hydride is one of the main reasons for kinetic and capacity degradation during the hydrogen absorption and desorption cycles.To solve this problem,herein we propose a novel method ... Grain growth of magnesium(Mg)and its hydride is one of the main reasons for kinetic and capacity degradation during the hydrogen absorption and desorption cycles.To solve this problem,herein we propose a novel method involving synergistic effect of inside embedded metals and outside coated graphene to limit the growth of Mg and its hydride grains.The graphene coated Mg-Y-Al alloys were selected as a model system for demonstrating this positive effect where the Mg_(91)Y_(3)Al_(6)alloy was first prepared by rapidly solidified method and then high-pressure milled with 5 wt%graphene upon 5 MPa hydrogen gas for obtaining in-situ formed YAl_(2)and YH_(3)embedded in the MgH_(2)matrix with graphene shell(denoted as MgH_(2)-Y-Al@GR).In comparison to pure MgH_(2),the obtained MgH_(2)-Y-Al@GR composites deliver much better kinetics and more stable cyclic performance.For instance,the MgH_(2)-Y-Al@GR can release about 6.1 wt%H_(2)within 30 min at 300℃ but pure MgH_(2)only desorbs∼1.5 wt%H_(2).The activation energy for desorption of MgH_(2)-Y-Al@GR samples is calculated to be 75.3±9.1 kJ/mol that is much lower than approximately 160 kJ/mol for pure MgH_(2).Moreover,its capacity retention is promoted from∼57%of pure MgH_(2)to∼84%after 50th cycles without obvious particle agglomeration and grain growth.The synergistic effect of outside graphene coating with inside embedded metals which could provide a huge number of active sites for catalysis as well as inhibit the grain growth of Mg and its hydride is believed to be responsible for these. 展开更多
关键词 Energy Hydrogen storage Mg alloys synergy effect
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Tuning synergy between nickel and iron in Ruddlesden-Popper perovskites through controllable crystal dimensionalities towards enhanced oxygenevolving activity and stability
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作者 Haijuan Zhang Daqin Guan +4 位作者 Yuxing Gu Hengyue Xu Chunchang Wang Zongping Shao Youmin Guo 《Carbon Energy》 SCIE EI CAS CSCD 2024年第6期113-123,共11页
Ni-Fe-based oxides are among the most promising catalysts developed to date for the bottleneck oxygen evolution reaction(OER)in water electrolysis.However,understanding and mastering the synergy of Ni and Fe remain ch... Ni-Fe-based oxides are among the most promising catalysts developed to date for the bottleneck oxygen evolution reaction(OER)in water electrolysis.However,understanding and mastering the synergy of Ni and Fe remain challenging.Herein,we report that the synergy between Ni and Fe can be tailored by crystal dimensionality of Ni,Fe-contained Ruddlesden-Popper(RP)-type perovskites(La_(0.125)Sr_(0.875))n+1(Ni_(0.25)Fe_(0.75))nO3n+1(n=1,2,3),where the material with n=3 shows the best OER performance in alkaline media.Soft X-ray absorption spectroscopy spectra before and after OER reveal that the material with n=3 shows enhanced Ni/Fe-O covalency to boost the electron transfer as compared to those with n=1 and n=2.Further experimental investigations demonstrate that the Fe ion is the active site and the Ni ion is the stable site in this system,where such unique synergy reaches the optimum at n=3.Besides,as n increases,the proportion of unstable rock-salt layers accordingly decreases and the leaching of ions(especially Sr^(2+))into the electrolyte is suppressed,which induces a decrease in the leaching of active Fe ions,ultimately leading to enhanced stability.This work provides a new avenue for rational catalyst design through the dimensional strategy. 展开更多
关键词 crystal dimensionalities oxygen evolution reaction Ruddlesden-Popper perovskites synergy
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Tailoring the microenvironment of Ti sites in Ti-containing materials for synergizing with Au sites to boost propylene epoxidation
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作者 Shudong Shi Zhihua Zhang +3 位作者 Yundao Jing Wei Du Xuezhi Duan Xinggui Zhou 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第8期133-143,共11页
Au sites supported on Ti-containing materials(Au/Ti-containing catalyst)are currently considered as a promising catalyst for the propylene epoxidation owing to the synergistic effect that hydrogen peroxide species for... Au sites supported on Ti-containing materials(Au/Ti-containing catalyst)are currently considered as a promising catalyst for the propylene epoxidation owing to the synergistic effect that hydrogen peroxide species formed on Au sites diffuses to the Ti sites to form the Ti-hydroperoxo intermedi-ates and contributes to the formation of propylene oxide(PO).In principle,thermal treatment will significantly affect the chemical and physical structures of Ti-containing materials.Consequently,the synergy between tailored Ti sites with different surface properties and Au sites is highly expected to enhance the catalytic performance for the reaction.Herein,we systematically studied the intrinsic effects of different microenvironments around Ti sites on the PO adsorption/desorption and conversion,and then effectively improved the catalytic performance by tailoring the number of surface hydroxyl groups.The Ti^(Ⅵ) material with fewer hydroxyls stimulates a remarkable enhancement in PO selectivity and H_(2) efficiency compared to the Ti^(Ⅵ) material that possessed more hydroxyls,offering a 7-fold and 4-fold increase,respectively.As expected,the Ti^(Ⅵ+Ⅳ) and Ti^(Ⅳ) materials also exhibit a similar phenomenon to the Ti^(Ⅵ) materials through the same thermal treatment,which strongly supports that the Ti sites microenvironment is an important factor in suppressing PO con-version and enhancing catalytic performance.These insights could provide guidance for the rational preparation and optimization of Ti-containing materials synergizing with Au catalysts for propylene epoxidation. 展开更多
关键词 Propylene epoxidation MICROENVIRONMENT Ti-containing material Au-Ti synergy Hydroxyl group
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Trade-offs and synergies between ecosystem services in Yutian County along the Keriya River Basin,Northwest China
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作者 ZUBAIDA Muyibul 《Journal of Arid Land》 SCIE CSCD 2024年第7期943-962,共20页
The Keriya River Basin is located in an extremely arid climate zone on the southern edge of the Tarim Basin of Northwest China,exhibiting typical mountain-oasis-desert distribution characteristics.In recent decades,cl... The Keriya River Basin is located in an extremely arid climate zone on the southern edge of the Tarim Basin of Northwest China,exhibiting typical mountain-oasis-desert distribution characteristics.In recent decades,climate change and human activities have exerted significant impacts on the service functions of watershed ecosystems.However,the trade-offs and synergies between ecosystem services(ESs)have not been thoroughly examined.This study aims to reveal the spatiotemporal changes in ESs within the Keriya River Basin from 1995 to 2020 as well as the trade-offs and synergies between ESs.Leveraging the Integrated Valuation of Ecosystem Services and Trade-offs(InVEST)and Revised Wind Erosion Equation(RWEQ)using land use/land cover(LULC),climate,vegetation,soil,and hydrological data,we quantified the spatiotemporal changes in the five principal ESs(carbon storage,water yield,food production,wind and sand prevention,and habitat quality)of the watershed from 1995 to 2020.Spearman correlation coefficients were used to analyze the trade-offs and synergies between ES pairs.The findings reveal that water yield,carbon storage,and habitat quality exhibited relatively high levels in the upstream,while food production and wind and sand prevention dominated the midstream and downstream,respectively.Furthermore,carbon storage,food production,wind and sand prevention,and habitat quality demonstrated an increase at the watershed scale while water yield exhibited a decline from 1995 to 2020.Specifically,carbon storage,wind and sand prevention,and habitat quality presented an upward trend in the upstream but downward trend in the midstream and downstream.Food production in the midstream showed a continuously increasing trend during the study period.Trade-off relationships were identified between water yield and wind and sand prevention,water yield and carbon storage,food production and water yield,and habitat quality and wind and sand prevention.Prominent temporal and spatial synergistic relationships were observed between different ESs,notably between carbon storage and habitat quality,carbon storage and food production,food production and wind and sand prevention,and food production and habitat quality.Water resources emerged as a decisive factor for the sustainable development of the basin,thus highlighting the intricate trade-offs and synergies between water yield and the other four services,particularly the relationship with food production,which warrants further attention.This research is of great significance for the protection and sustainable development of river basins in arid areas. 展开更多
关键词 ecosystem services trade-offs SYNERGIES water yield food production habitat quality wind and sand prevention Tarim Basin
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Trade-Offs and Synergie Effects of Regulating Ecosystem Services along an Climatic Gradient in Slovakia
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作者 Jarmila Makovníková Stanislav Kološta Boris Pálka 《Journal of Geoscience and Environment Protection》 2024年第6期135-150,共16页
This study aims to assess the synergies and trade-offs of regulating ecosystem services. Ecosystem services are non-linearly interconnected and changes in one service can positively or negatively affect another. We ev... This study aims to assess the synergies and trade-offs of regulating ecosystem services. Ecosystem services are non-linearly interconnected and changes in one service can positively or negatively affect another. We evaluated ecosystem services based on biophysical indicators using an expert scoring system that determines the corresponding soil functions and is part of the existing databases available in Slovakia. This methodological combination enabled us to provide unique mapping and assessment of ecosystem services within Slovakia. Correlation analysis between individual regulating ecosystem services and climate regions, slope, texture, and altitude confirm the statistically significant influence of climate and slope in all agricultural land, arable land, and grassland ecosystems. Statistically significant synergistic effects were established between the regulation of the water regime and the regulation of soil erosion within each climate region, apart from the very warm climate region. Only in a very warm climate region was potential of regulating ecosystem services mutually beneficial for soil erosion control and soil cleaning potential (immobilization of inorganic pollutants). 展开更多
关键词 Agroecosystem Services Climatic Zone MAPPING Trade-Offs SYNERGIES
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医科达Synergy医用电子直线加速器故障维修六例
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作者 张成刚 《医疗装备》 2024年第10期94-96,共3页
放射治疗是利用放射线治疗肿瘤的医疗方式[1]。医用电子直线加速器作为医院开展放射治疗的重要医疗设备,在肿瘤治疗中发挥重要作用。同时,医用电子直线加速器的技术结构复杂,组成模块、系统、零部件多,集成度高,设备具有“唯一性”、故... 放射治疗是利用放射线治疗肿瘤的医疗方式[1]。医用电子直线加速器作为医院开展放射治疗的重要医疗设备,在肿瘤治疗中发挥重要作用。同时,医用电子直线加速器的技术结构复杂,组成模块、系统、零部件多,集成度高,设备具有“唯一性”、故障风险大等特点,如出现故障不能及时解决,可影响患者治疗效果,严重时甚至会造成不可逆性的重大损伤[2]。目前,医科达Synergy医用电子直线加速器的市场占有率较高,其通信模块较多、运动结构相对复杂,故障率较高。本研究以我院在用的医科达Synergy医用电子直线加速器为例,对其结构原理及6例故障维修过程进行总结分析,以供同行借鉴和参考。 展开更多
关键词 synergy医用电子直线加速器 故障 维修
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Spatiotemporal variations in ecosystem services and their trade-offs and synergies against the background of the gully control and land consolidation project on the Loess Plateau,China
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作者 WANG Jing WEI Yulu +2 位作者 PENG Biao LIU Siqi LI Jianfeng 《Journal of Arid Land》 SCIE CSCD 2024年第1期131-145,共15页
Studying the spatiotemporal variations in ecosystem services and their interrelationships on the Loess Plateau against the background of the gully control and land consolidation(GCLC)project has significant implicatio... Studying the spatiotemporal variations in ecosystem services and their interrelationships on the Loess Plateau against the background of the gully control and land consolidation(GCLC)project has significant implications for ecological protection and quality development of the Yellow River Basin.Therefore,in this study,we took Yan'an City,Shaanxi Province of China,as the study area,selected four typical ecosystem services,including soil conservation service,water yield service,carbon storage service,and habitat quality service,and quantitatively evaluated the spatiotemporal variation characteristics and trade-offs and synergies of ecosystem services from 2010 to 2018 using the Integrated Valuation of Ecosystem Services and Trade-offs(InVEST)model.We also analysed the relationship between the GCLC project and regional ecosystem service changes in various regions(including 1 city,2 districts,and 10 counties)of Yan'an City and proposed a coordinated development strategy between the GCLC project and the ecological environment.The results showed that,from 2010 to 2018,soil conservation service decreased by 7.76%,while the other three ecosystem services changed relatively little,with water yield service increasing by 0.56% and carbon storage service and habitat quality service decreasing by 0.16% and 0.14%,respectively.The ecological environment of Yan'an City developed in a balanced way between 2010 and 2018,and the four ecosystem services showed synergistic relationships,among which the synergistic relationships between soil conservation service and water yield service and between carbon storage service and habitat quality service were significant.The GCLC project had a negative impact on the ecosystem services of Yan'an City,and the impact on carbon storage service was more significant.This study provides a theoretical basis for the scientific evaluation of the ecological benefits of the GCLC project and the realization of a win-win situation between food security and ecological security. 展开更多
关键词 ecosystem services trade-offs and synergies gully control and land consolidation habitat quality Integrated Valuation of Ecosystem Services and Trade-offs(InVEST)model Loess Plateau
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Trade-off and Synergy of Rural Functions Under County Depopulation in the Typical Black Soil Region of Northeast China 被引量:2
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作者 LI Dongmei WEN Qing +1 位作者 QI Yue ZHANG Pingyu 《Chinese Geographical Science》 SCIE CSCD 2023年第4期616-633,共18页
As the population continues to shrink in the black soil region of Northeast China since 2000,it is critical to master the impact of population shrinkage on rural functions to realize rural revitalization and sustainab... As the population continues to shrink in the black soil region of Northeast China since 2000,it is critical to master the impact of population shrinkage on rural functions to realize rural revitalization and sustainable development.In this study,we focused on the impacts of depopulation on the evolution and interrelationship of rural subfunctions.Based on the rural function indexes system,the TOPSIS(Technique for Order Preference by Similarity to an Ideal Solution)method,spatial analysis method,and mathematical statistics analysis method were used to summarize the spatial and temporal characteristics of rural function development,as well as the effect of population shrinkage in the typical black soil region of Northeast China.The results showed that depopulation varied in the extent and duration between the forested region and plain areas,which both impacted the trajectories of rural subfunctions evolution.For the economic development function and ecological conservation function,the effect of continuous slight depopulation was beneficial,while the effect of rapid depopulation was adverse,which was exactly opposite to the agricultural production function.All forms of population shrinkage were conducive to the development of the social security function.With the deepening population shrinkage,depopulation mainly promoted the collaborative development between subfunctions in this study,except the relationship between agricultural production and social security function.But effects of depopulation on the interrelationship of rural subfunctions varied between the forested region and plain areas in some cases.The results provided evidence for the cognition that population shrinkage had complicated effects on rural subfunctions. 展开更多
关键词 rural function depopulation trade-off and synergy typical black soil region Northeast China
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Long-range electron synergy over Pt_(1)-Co_(1)/CN bimetallic single-atom catalyst in enhancing charge separation for photocatalytic hydrogen production 被引量:2
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作者 Man Yang Jing Mei +3 位作者 Yujing Ren Jie Cui Shuhua Liang Shaodong Sun 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第6期502-509,I0011,共9页
The development of novel single-atom catalysts with optimal electron configuration and economical noble-metal cocatalyst for efficient photocatalytic hydrogen production is of great importance,but still challenging.He... The development of novel single-atom catalysts with optimal electron configuration and economical noble-metal cocatalyst for efficient photocatalytic hydrogen production is of great importance,but still challenging.Herein,we fabricate Pt and Co single-atom sites successively on polymeric carbon nitride(CN).In this Pt_(1)-Co_(1)/CN bimetallic single-atom catalyst,the noble-metal active sites are maximized,and the single-atomic Co_(1)N_4sites are tuned to Co_(1)N_3sites by photogenerated electrons arising from the introduced single-atomic Pt_(1)N_4sites.Mechanism studies and density functional theory(DFT)calculations reveal that the 3d orbitals of Co_(1)N_3single sites are filled with unpaired d-electrons,which lead to the improved visible-light response,carrier separation and charge migration for CN photocatalysts.Thereafter,the protons adsorption and activation are promoted.Taking this advantage of long-range electron synergy in bimetallic single atomic sites,the photocatalytic hydrogen evolution activity over Pt_(1)-Co_(1)/CN achieves 915.8 mmol g^(-1)Pt h^(-1),which is 19.8 times higher than Co_(1)/CN and 3.5 times higher to Pt_(1)/CN.While this electron-synergistic effect is not so efficient for Pt nanoclusters.These results demonstrate the synergistic effect at electron-level and provide electron-level guidance for the design of efficient photocatalysts. 展开更多
关键词 Bimetallic single-atom catalyst Long-range electron synergy Charge separation/transfer Carbon nitride Hydrogen production
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Regulating the synergy coefficient of composite materials for alleviating self-discharge of supercapacitors
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作者 Siqi Jing Xiaohui Yan +6 位作者 Yige Xiong Taibai Li Junkai Xiong Tao Hu Zhongjie Wang Liang Lou Xiang Ge 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期34-40,共7页
Supercapacitor is an efficient energy storage device,yet its wider application is still limited by self-discharge.Currently,various composite materials have been reported to have improved inhibition on self-discharge,... Supercapacitor is an efficient energy storage device,yet its wider application is still limited by self-discharge.Currently,various composite materials have been reported to have improved inhibition on self-discharge,while the evaluation of the synergistic effect in composite materials is challenging.Herein,pairs of intercalation type pseudocapacitive niobium oxides are pre-lithiated and coupled to construct conjugatedly configured supercapacitors,within which the cathode and anode experience identical reaction environment with single type of charge carrier,thus providing ideal platform to quantify the synergistic effect of composite materials on the self-discharge process.By using titanium dioxide as the stabilizer,we have compared how the modes of forming composite would influence the selfdischarge performance of the active composite materials with similar ratio of the constituent materials.Specifically,core@shell Nb_(2)O_(5)@TiO_(2) composite using TiO_(2) as the shell shows significantly higher synergy coefficient(μ=0.61,defined as the value that evaluates the synergistic effect between composite materials,and can be quantified using the overall performance of the composite,performance of individual component as well as the ratio of the component.) than other control group samples,which corresponds to the highest retained energy of 63% at 100 h.This work is expected to provide a general method for quantifying the synergistic effect and guide the design of composite materials with specific mode of forming the composite. 展开更多
关键词 PSEUDOCAPACITIVE synergy coefficient Conjugated supercapacitor Niobium oxide SELF-DISCHARGE
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Recycling Spent LiCoO_(2)Battery as a High-efficient Lithiumdoped Graphitic Carbon Nitride/Co_(3)O_(4)Composite Photocatalyst and Its Synergistic Photocatalytic Mechanism
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作者 Bo Niu Jiefeng Xiao Zhenming Xu 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第2期45-53,共9页
The ever-increasing quantity of spent lithium-ion batteries(LIBs)is both a potential environmental pollutant and a valuable resource.The spent LIBs recycling mainly aimed at the separation of valuable elements.Some is... The ever-increasing quantity of spent lithium-ion batteries(LIBs)is both a potential environmental pollutant and a valuable resource.The spent LIBs recycling mainly aimed at the separation of valuable elements.Some issues still exist in these processes such as high energy consumption and complex separation procedures.This study avoided element separation and proposed a facile approach to transform spent LiCoO_(2) electrode into a lithium(Li)-doped graphitic carbon nitride(g-C_(3)N_(4))/Co_(3)O_(4) composite photocatalyst through one-pot in situ thermal reduction.During the thermal process,melamine served as the reductant for LiCoO_(2) decomposition and the raw material for g-C_(3)N_(4) production.Li was in situ doped in g-C_(3)N_(4) and the generated Co_(3)O_(4) was in situ integrated,forming a Li-doped g-C_(3)N_(4)/Co_(3)O_(4) composite photocatalyst.This special composite exhibited an enhanced photocatalytic performance,and its photocatalytic H2 production and RhB degradation rates were 8.7 and 6.8 times higher than those of g-C_(3)N_(4).The experiments combined with DFT calculation revealed that such enhanced photocatalytic efficiency was ascribed to the synergy effect of Li doping and Co_(3)O_(4) integrating,which extended the visible light absorption(450-900 nm)and facilitated the charge transfer and separation.This study transforms waste into a high-efficient catalyst,realizing high-valued utilization of waste and environmental protection. 展开更多
关键词 composite photocatalyst environmental protection spent LIBs synergy mechanism waste utilization
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Conjugated polymerized bimetallic phthalocyanine based electrocatalyst with Fe-N_(4)/Co-N_(4) dual-sites synergistic effect for zinc-air battery
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作者 Shuaifeng Wang Zhongfang Li +5 位作者 Wenjie Duan Peng Sun Jigang Wang Qiang Liu Lei Zhang Yanqiong Zhuang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第11期41-53,I0002,共14页
The bifunctional oxygen catalyst is essential for zinc-air batteries(ZABs).Here,an efficient bifunctional oxygen catalyst,PPcFeCo/3D-G,is obtained throughπ-πinteraction between the conjugated polymerized iron-cobalt... The bifunctional oxygen catalyst is essential for zinc-air batteries(ZABs).Here,an efficient bifunctional oxygen catalyst,PPcFeCo/3D-G,is obtained throughπ-πinteraction between the conjugated polymerized iron-cobalt phthalocyanine(PPcFeCo)with excellent thermal stability and three-dimensional graphene(3D-G).The bimetallic synergistic effect of PPcFeCo,verified by DFT(Density functional theory)calculation,andπ-πinteractions enhances the catalytic activity and durability of the PPcFeCo/3D-G.Regarding electrochemical performance,the PPcFeCo/3D-G with a high electron transfer number(3.98,@0.768 V vs.RHE)has excellent half-wave potential(E_(1/2)=0.890 V vs.RHE)and exhibits outstanding reversibility(ΔE=0.700 V,ΔE=Ej=10-E_(1/2)).The liquid ZAB(LZAB)employed PPcFeCo/3D-G displays a high power density(222 m W cm^(-2)),a specific capacity(792 m A h g-1),and excellent durability(120 h).This work has guiding significance for the preparation of high-efficiency bifunctional catalysts. 展开更多
关键词 Zn-airbattery Bifunctional oxygen catalysts Polymerized iron-cobalt phthalocyanine Bimetallic synergy π-πinteraction
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Synergies and trade-offs of climate-smart agriculture(CSA)practices selected by smallholder farmers in Geshy watershed,Southwest Ethiopia
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作者 Girma TILAHUN Amare BANTIDER Desalegn YAYEH 《Regional Sustainability》 2023年第2期129-138,共10页
Studies on mainstreaming climate-smart agriculture(CSA)practices can increase smallholder farmers’capacity and awareness to improve food security and establish sustainable livelihoods through resilient agricultural s... Studies on mainstreaming climate-smart agriculture(CSA)practices can increase smallholder farmers’capacity and awareness to improve food security and establish sustainable livelihoods through resilient agricultural systems,while achieving adaptation and mitigation benefits.Hence,valuable insights can be obtained from smallholder farmers in responding to present and forthcoming challenges of climate change impacts.However,there is little research work on trade-off and synergy assessments.Taking Geshy watershed in Southwest Ethiopia as a case study area,both quantitative and qualitative data analysis were undertaken in this study.The data were collected from 15 key informant interviews,6 focus group discussions,and 384 households to answer the following questions:(1)what are the top 5 preferred CSA practices for smallholder farmers in Geshy watershed when coping with the impacts of climate change?(2)What is the performance of the preferred CSA practices?And(3)which trade-offs and synergies are experienced upon the implementation of CSA practices?The study came up with the most preferred CSA practices such as the use of improved crop varieties,small-scale irrigation,improved animal husbandry,the use of efficient inorganic fertilizers,and crop rotation with legumes.The selected CSA practices showed that the productivity goal exhibit the best synergy,while the mitigation goal has trade-offs.The study also indicated that the use of improved crop varieties causes high synergies in all 3 goals of CSA practices;small-scale irrigation provides a medium synergy on productivity goal but high synergy for adaptation and mitigation goals;improved animal husbandry shows a high synergy with the adaptation goal,a relatively lower synergy with the productivity goal,and a trade-off with the mitigation goal;the use of efficient inorganic fertilizers shows maximum synergy for the productivity and adaptation goals;and crop rotation with legumes exhibits high synergy with the productivity and mitigation goals but a relatively lower synergy with the adaptation goal.These results can provide evidence to various stakeholder farmers in the value chain that the impacts of climate change can be addressed by the adoption of CSA practices.In general,CSA practices are considered indispensable.Smallholder farmers prefer CSA practices that help to increase crop productivity and household resilience to climate change impacts.The results generate a vital foundation for recommendations to smallholder farming decision-makers.It also sensitizes actions for innovative and sustainable methods that are able to upscale the preferred CSA practices in the agricultural system in Geshy watershed of Southwest Ethiopia and other regions. 展开更多
关键词 Climate-smart agriculture(CSA) Climate change SYNERGIES Trade-offs Productivity Adaptation Mitigation Geshy watershed
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Synergistic Effect of Nonionic Surfacants(Nonethoxylated Sorbitan Esters)on Herbicides in Paddy Fields
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作者 Tao Bo Zhang Qi +1 位作者 Han Yu-jun Guo Jing 《Journal of Northeast Agricultural University(English Edition)》 2023年第4期20-31,共12页
An uneven herbicide distribution can lead to reduced efficacy,and the release of herbicide residues and their transformation products into the environment through runoff increases their potential use risk.Understandin... An uneven herbicide distribution can lead to reduced efficacy,and the release of herbicide residues and their transformation products into the environment through runoff increases their potential use risk.Understanding the water distribution dynamics of commonly used paddy field herbicides,for example,oxadiazon,is imperative for the long-term management of weeds in paddy fields.To clarify the diffusion and sedimentation ability of oxadiazon with the addition of a nonionic surfactant—diffusion and settling agent(DSA)for subsequent commercial use in paddy field water layers,the synergistic mechanisms of DSA with butachlor and bensulfuron-methyl in paddy fields were studied.Bioassays,instrumental analysis and field experiments were conducted in this research to provide a relevant basis for improving the efficacy of paddy field herbicides.The field experiment results indicated that DSA could increase the plant and fresh weight control effects of oxadiazon(450 g a.i.·hm^(-2)),butachlor and bensulfuron-methyl to different degrees.These findings demonstrated that DSA could not only effectively improve oxadiazon diffusion and settling in water layers and significantly increase the control effects of butachlor and bensulfuron-methyl,but also promote crop growth and development to different degrees. 展开更多
关键词 green agriculture weed control synergy mechanism RICE
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煤炭工业数字智能绿色三化协同模式与新质生产力建设路径 被引量:11
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作者 刘峰 郭林峰 +1 位作者 张建明 王蕾 《煤炭学报》 EI CAS CSCD 北大核心 2024年第1期1-15,共15页
煤炭工业是支撑我国经济社会高速发展和保障国家能源安全的压舱石与稳定器,承担着能源保供与支撑新能源稳定发展的时代使命,煤炭工业的高质量发展既是落实我国能源安全新战略与产业体系变革的关键,也是推进能源产业可持续发展与促进国... 煤炭工业是支撑我国经济社会高速发展和保障国家能源安全的压舱石与稳定器,承担着能源保供与支撑新能源稳定发展的时代使命,煤炭工业的高质量发展既是落实我国能源安全新战略与产业体系变革的关键,也是推进能源产业可持续发展与促进国家高质量发展的基础。当前我国煤炭工业高质量发展已取得阶段成效,能源保供成绩显著,产业结构不断优化,科技创新能力显著提高,绿色开发与清洁高效利用持续推进。但当前煤炭工业仍面临诸多挑战,发展水平与中国式现代化的国家需求差距较大,可持续发展受多重因素制约,数字技术与煤炭开发利用尚未深度融合,智能化建设仍处于示范培育阶段,绿色化发展不平衡且矛盾突出,煤炭工业的转型升级仍然任重道远。结合当前煤炭工业发展现状与挑战,提出了数字化、智能化、绿色化(三化)协同的发展模式,明确了煤炭新质生产力的核心内涵,构建了三化协同发展煤炭新质生产力的总体架构,阐述了通过数字化变革生产要素创新配置、智能化引领关键技术跨越突破、绿色化主导传统产业深度转型三大要素催生煤炭新质生产力的技术路径,提出了六大技术体系:通过研发全产业链数据高效采集与深度治理技术体系,打通煤炭产—运—储—销—用全流程的数据壁垒;通过研发构建煤炭行业知识图谱与智能决策管控技术体系,深度挖掘煤炭产业上下游各业务场景的关联关系与价值,为煤炭生产利用全流程的自主决策与智能控制奠定基础;开展煤炭资源智能-绿色-高效开发技术体系、煤炭产业安全协同保障技术体系、矿区生态智能监测-预警-修复技术体系、煤炭柔性开发与清洁低碳利用技术体系研究,实现煤炭开发利用全产业链、全流程的三化协同发展,培育形成煤炭新质生产力,为煤炭工业的整体形象带来根本性变革提升。 展开更多
关键词 数字化 智能化 绿色化 三化协同 煤炭新质生产力 “双碳”目标
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Evaluation of Disk Potentiation Test (DPT) and Double Disk Synergy Test (DDST) for The Detection of Metallo-β-Lactamases (MBLs) in Clinical Isolates of Bangladesh
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作者 Sumon Kumar Das Afzal Sheikh +4 位作者 Nikhat Ara Suma Mita Biswas Abhinandan Chowdhury Fatimah Az Zahra Chaman Ara Keya 《Advances in Infectious Diseases》 2023年第4期609-626,共18页
Objective: Increasing the emergence of Metallo-β-lactamase (MBL) producing gram-negative bacteria and their dexterous horizontal transmission demands rapid and accurate detection. This study was conducted to determin... Objective: Increasing the emergence of Metallo-β-lactamase (MBL) producing gram-negative bacteria and their dexterous horizontal transmission demands rapid and accurate detection. This study was conducted to determine a suitable method to promptly detect MBL-producing gram-negative bacteria. Methods: A total of 103 gram-negative bacteria were identified from various clinical samples at a tertiary care hospital in Dhaka city. MBL producers were detected by two phenotypic methods, the Disk Potentiation Test (DPT) and the Double Disk Synergy Test (DDST) based on β-lactam chelator combinations where EDTA/SMA has been used as an inhibitor and Imipenem, Ceftazidime as substrates. Results: 103 isolates which were identified as Escherichia coli spp, Klebsiella spp, Pseudomonas spp, Acinetobacter spp, Proteus spp, Providencia spp were found to be multidrug-resistant in antibiogram test. Isolates showed complete resistance (100%) to Imipenem, Meropenem, and Amoxiclav. The highest carbapenem-resistant etiological agents were Acinetobacter spp 40 (38.8%) followed by Pseudomonas spp 27 (26.2%), Klebsiella spp 26 (25.2%), Escherichia coli 8 (7.8%), Proteus spp 1 (1%) and Providencia spp 1 (1%). DPT method detected significantly (p = 0.000009) a higher number of MBL-producers (Imipenem with 0.5 M EDTA n = 61, 59.2% & Ceftazidime with 0.5 M EDTA n = 56, 54.4%) compared to the DDST method (Imipenem -0.5 M EDTA n = 43, 41.7%, Imipenem – SMA n = 38, 36.9% & Ceftazidime -0.5 M EDTA n = 15, 14.6%). Conclusion: Pieces of evidence suggest that DPT is a more sensitive method than DDST and could be recommended for identifying MBL-producing bacteria in Bangladeshi hospitals for the proper management of patients, to reduce time constraints and treatment costs. 展开更多
关键词 Disk Potentiation Test (DPT) Double Disk synergy Test (DDST) Metallo-β-Lactamase (MBL) Sodium Mercaptoacetate (SMA) and Ethylenediaminetetraacetic Acid (EDTA)
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Multimodal Synergistic Strategies in High School English Teaching
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作者 YUAN Zhi-qian 《Sino-US English Teaching》 2023年第11期423-429,共7页
This paper focuses on the multimodal synergistic strategy in high school English teaching.It first briefly reviews the relevant concepts and theories of multimodality and multimodal teaching.On this basis,it employs c... This paper focuses on the multimodal synergistic strategy in high school English teaching.It first briefly reviews the relevant concepts and theories of multimodality and multimodal teaching.On this basis,it employs cases from text books published by People’s Education Press to illustrate how to exert the synergistic effect of multimodal teaching to guide English teaching practice from the perspectives of the English core qualities-listening,speaking,reading,viewing,and writing.The introduction and application of multimodal theory into English teaching practice is conducive to further promoting the“student-centered”English teaching reform,and plays a positive role in the cultivation of high school students’thinking and the improvement of core literacy. 展开更多
关键词 MULTIMODE high school English teaching synergy
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Synergistic Treatment of Low-concentration Organic Waste Gas by Micro-nano Bubble Coordinated with Peroxymonosulfate
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作者 Peng ZHOU Yixin XU +1 位作者 Xiaosi LEI Mingjie WEI 《Meteorological and Environmental Research》 2023年第6期73-76,共4页
Continuous dynamic experiment was conducted for the treatment of low-concentration organic waste gas with xylene as a representative, using micro-nano bubble and peroxymonosulfate working in synergy. The degradation r... Continuous dynamic experiment was conducted for the treatment of low-concentration organic waste gas with xylene as a representative, using micro-nano bubble and peroxymonosulfate working in synergy. The degradation rule of xylene under different conditions such as the ORP value of the spray liquid, pH value of the spray liquid, liquid-gas ratio of the spray liquid, residence time of xylene, and initial concentration of xylene was investigated. The results showed that at a low concentration, the pH value of the spray liquid had little effect on the degradation rate of xylene. The degradation rate of xylene rose with the increase of the ORP value of the spray liquid, the liquid-gas ratio of the spray liquid, the residence time of xylene, and the initial concentration of xylene. 展开更多
关键词 Micro-nano bubble PEROXYMONOSULFATE synergy Low concentration Organic waste gas
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Exploring the Goal Synergy between the Ecological Carrying Capacity of Miyun District and the Development of the Ecological Home-stay Industry in Beijing
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作者 ZHANG Qilun CAO Jinglong XU Zhiyong 《Journal of Landscape Research》 2023年第2期45-48,53,共5页
Green construction in culture and environmental protection will be the development trend in a long run,the urban and suburban area will be ecologically developed as well.Rural revitalization must adhere to the positio... Green construction in culture and environmental protection will be the development trend in a long run,the urban and suburban area will be ecologically developed as well.Rural revitalization must adhere to the position of historical progress theory and modern concepts,innovate spatial layout,optimize ecological resources,and appropriately determine its historical significance and sustainable development responsibility with reasonable value orientation and environmental ecological carrying capacity for local ecological construction.In order to achieve this responsibility,the authors must expand the dimensions to consider more relevant factors.The guarantee of ecological carrying capacity is an important means to ensure the promotion of ecological civilization.This paper aims to integrate and regulate the goal synergy of the cultural development of the home-stay industry in Miyun District of Beijing by means of the innovative model of sustainable economic development of cultural ecology,ecological people,ecological health preservation and rich home-stay ecological elements.Assuming that the role of the former in promoting the latter can be expanded,then in the range of ecological and cultural towns(conceptual model)that maintain a certain tolerance of ecological carrying capacity,as a characteristic home-stay industry in Miyun,there will be some effective growth,so the integration and development of multiple cultural genes and elements must be the ecological and cultural town model under the enhanced multi-factor aggregation effect,(See the ecological environment carrying capacity development goal A:A=B12345+C1234567 later).This article will explain that the development goals of Miyun's ecological culture and the ecological homestay industry are coordinated,and the two are mutually raised in the same direction. 展开更多
关键词 Ecological carrying capacity Coordinated development goals of ecological home-stay industry Goal synergy
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