Mechanical reliable,NIR light-induced rapid self-healing hydrogel electrolyte towards flexible zinc-ion hybrid supercapacitors with low-temperature adaptability and long service life

Hydrogel electrolytes hold great potential in flexible zinc ion supercapacitors(ZICs)due to their high conductivity,good safety,and flexibility.However,freezing of electrolytes at low temperature(subzero)leads to drastic reduction in ionic conductivity and mechanical properties that deteriorates the performance of flexible ZICs.Besides,the mechanical fracture during arbitrary deformations significantly prunes out the lifespan of the flexible device.Herein,a Zn^(2+)and Li^(+)co-doped,polypyrrole-dopamine decorated Sb_(2)S_(3)incorporated,and polyvinyl alcohol/poly(N-(2-hydroxyethyl)acrylamide)double-network hydrogel electrolyte is constructed with favorable mechanical reliability,anti-freezing,and self-healing ability.In addition,it delivers ultra-high ionic conductivity of 8.6 and 3.7 S m^(-1)at 20 and−30°C,respectively,and displays excellent mechanical properties to withstand tensile stress of 1.85 MPa with tensile elongation of 760%,together with fracture energy of 5.14 MJ m^(-3).Notably,the fractured hydrogel electrolyte can recover itself after only 90 s of infrared illumination,while regaining 83%of its tensile strain and almost 100%of its ionic conductivity during−30–60°C.Moreover,ZICs coupled with this hydrogel electrolyte not only show a wide voltage window(up to 2 V),but also provide high energy density of 230 Wh kg^(-1)at power density of 500 W kg^(-1)with a capacity retention of 86.7%after 20,000 cycles under 20°C.Furthermore,the ZICs are able to retain excellent capacity even under various mechanical deformation at−30°C.This contribution will open up new insights into design of advanced wearable flexible electronics with environmental adaptability and long-life span.

Self-Healing Liquid Metal Magnetic Hydrogels for Smart Feedback Sensors and High-Performance Electromagnetic Shielding

Hydrogels exhibit potential applications in smart wearable devices because of their exceptional sensitivity to various external stimuli.However,their applications are limited by challenges in terms of issues in biocompatibility,custom shape,and self-healing.Herein,a conductive,stretchable,adaptable,self-healing,and biocompatible liquid metal GaInSn/Ni-based composite hydrogel is developed by incorporating a magnetic liquid metal into the hydrogel framework through crosslinking polyvinyl alcohol(PVA)with sodium tetraborate.The excellent stretchability and fast self-healing capability of the PVA/liquid metal hydrogel are derived from its abundant hydrogen binding sites and liquid metal fusion.Significantly,owing to the magnetic constituent,the PVA/liquid metal hydrogel can be guided remotely using an external magnetic field to a specific position to repair the broken wires with no need for manual operation.The composite hydrogel also exhibits sensitive deformation responses and can be used as a strain sensor to monitor various body motions.Additionally,the multifunctional hydrogel displays absorption-dominated electromagnetic interference(EMI)shielding properties.The total shielding performance of the composite hydrogel increases to~62.5 dB from~31.8 dB of the pure PVA hydrogel at the thickness of 3.0 mm.The proposed bioinspired multifunctional magnetic hydrogel demonstrates substantial application potential in the field of intelligent wearable devices.

A Self-Healing Optoacoustic Patch with High Damage Threshold and Conversion Efficiency for Biomedical Applications

Compared with traditional piezoelectric ultrasonic devices,optoacoustic devices have unique advantages such as a simple preparation process,anti-electromagnetic interference,and wireless long-distance power supply.However,current optoacoustic devices remain limited due to a low damage threshold and energy conversion efficiency,which seriously hinder their widespread applications.In this study,using a self-healing polydimethylsiloxane(PDMS,Fe-Hpdca-PDMS)and carbon nanotube composite,a flexible optoacoustic patch is developed,which possesses the self-healing capability at room temperature,and can even recover from damage induced by cutting or laser irradiation.Moreover,this patch can generate high-intensity ultrasound(>25 MPa)without the focusing structure.The laser damage threshold is greater than 183.44 mJ cm^(-2),and the optoacoustic energy conversion efficiency reaches a major achievement at 10.66×10^(-3),compared with other carbon-based nanomaterials and PDMS composites.This patch is also been successfully examined in the application of acoustic flow,thrombolysis,and wireless energy harvesting.All findings in this study provides new insight into designing and fabricating of novel ultrasound devices for biomedical applications.

Multifunctional phase change film with high recyclability, adjustable thermal responsiveness, and intrinsic self-healing ability for thermal energy storage

Phase change materials(PCMs) present promising potential for guaranteeing safety in thermal management systems.However,most reported PCMs have a single application in energy storage for thermal management systems,which does not meet the growing demand for multi-functional materials.In this paper,the flexible material and hydrogen-bonding function are innovatively combined to design and prepare a novel multi-functional flexible phase change film(PPL).The 0.2PPL-2 film exhibits solid-solid phase change behavior with energy storage density of 131.8 J/g at the transition temperature of42.1℃,thermal cycling stability(500 cycles),wide-temperature range flexibility(0-60℃) and selfhealing property.Notably,the PPL film can be recycled up to 98.5% by intrinsic remodeling.Moreover,the PPL film can be tailored to the desired colors and configurations and can be cleverly assembled on several thermal management systems at ambient temperature through its flexibility combined with shape-memory properties.More interestingly,the transmittance of PPL will be altered when the ambient temperature changes(60℃),conveying a clear thermal signal.Finally,the thermal energy storage performance of the PPL film is successfully tested by human thermotherapy and electronic device temperature control experiments.The proposed functional integration strategy provides innovative ideas to design PCMs for multifunctionality,and makes significant contributions in green chemistry,highefficiency thermal management,and energy sustainability.

Flexible,thermal processable,self-healing,and fully bio-based starch plastics by constructing dynamic imine network

The serious environmental threat caused by petroleum-based plastics has spurred more researches in developing substitutes from renewable sources.Starch is desirable for fabricating bioplastic due to its abundance and renewable nature.However,limitations such as brittleness,hydrophilicity,and thermal properties restrict its widespread application.To overcome these issues,covalent adaptable network was constructed to fabricate a fully bio-based starch plastic with multiple advantages via Schiff base reactions.This strategy endowed starch plastic with excellent thermal processability,as evidenced by a low glass transition temperature(T_(g)=20.15℃).Through introducing Priamine with long carbon chains,the starch plastic demonstrated superior flexibility(elongation at break=45.2%)and waterproof capability(water contact angle=109.2°).Besides,it possessed a good thermal stability and self-adaptability,as well as solvent resistance and chemical degradability.This work provides a promising method to fabricate fully bio-based plastics as alternative to petroleum-based plastics.

High performance photodegradation resistant PVA@TiO_(2)/carboxyl-PES self-healing reactive ultrafiltration membrane

The occurrence of ultrafiltration(UF)membrane fouling frequently hampers the sustainable advancement of UF technology.Reactive self-cleaning UF membranes can effectively alleviate the problem of membrane fouling.Nevertheless,the self-cleaning process may accelerate membrane aging.Addressing these concerns,we present an innovative design concept for composite self-healing materials based on self-cleaning UF membranes.To begin,TiO_(2)nanoparticles were incorporated into the polymer molecular structure via molecular design,resulting in the synthesis of TiO_(2)/carboxyl-polyether sulfone(PES)hybrid materials.Subsequently,the nonsolvent-induced phase inversion technique was employed to prepare a novel of UF membrane.Lastly,a polyvinyl alcohol(PVA)hydrogel coating was applied to the hybrid UF membrane surface to create PVA@TiO_(2)/carboxyl-PES self-healing reactive UF membranes.By establishing a covalent bond,the TiO_(2)nanoparticles were effectively and uniformly dispersed within the UF membrane,leading to exceptional self-cleaning properties.Furthermore,the water-absorbing and swelling properties of PVA hydrogel,along with its capacity to form hydrogen bonds with water molecules,resulted in UF membranes with improved hydrophilicity and active self-healing abilities.The results demonstrated that the water contact angle of PVA@5%TiO_(2)/carboxyl-PES UF membrane was 43.1°.Following a 1-h exposure to simulated solar exposure,the water flux recovery ratio increased from 48.16%to 81.03%.Moreover,even after undergoing five cycles of 12-h simulated sunlight exposure,the UF membranes exhibited a consistent retention rate of over 97%,thus fully demonstrating their exceptional self-cleaning,antifouling,and selfhealing capabilities.We anticipate that the self-healing reactive UF membrane system will serve as a pioneering and comprehensive solution for the self-cleaning antifouling challenges encountered in UF membranes while also effectively mitigating the aging effects of reactive UF membranes.

An intrinsically self-healing and anti-freezing molecular chains induced polyacrylamide-based hydrogel electrolytes for zinc manganese dioxide batteries

The anti-freezing strategy of hydrogels and their self-healing structure are often contradictory,it is vital to break through the molecular structure to design and construct hydrogels with intrinsic anti-freezing/self-healing for meeting the rapid development of flexible and wearable devices in diverse service conditions.Herein,we design a new hydrogel electrolyte(AF/SH-Hydrogel)with intrinsic anti-freezing/self-healing capabilities by introducing ethylene glycol molecules,dynamic chemical bonding(disulfide bond),and supramolecular interaction(multi-hydrogen bond)into the polyacrylamide molecular chain.Thanks to the exceptional freeze resistance(84%capacity retention at-20℃)and intrinsic self-healing capabilities(95%capacity retention after 5 cutting/self-healing cycles),the obtained AF/SH-Hydrogel makes the zinc||manganese dioxide cell an economically feasible battery for the state-of-the-art applications.The Zn||AF/SH-Hydrogel||MnO_(2)device offers a near-theoretical specific capacity of 285 m A h g^(-1)at 0.1 A g^(-1)(Coulombic efficiency≈100%),as well as good self-healing capability and mechanical flexibility in an ice bath.This work provides insight that can be utilized to develop multifunctional hydrogel electrolytes for application in next generation of self-healable and freeze-resistance smart aqueous energy storage devices.

“Smart”micro/nano container-based self-healing coatings on magnesium alloys:A review

Coating technologies are a commonly used way to protect metals against corrosion.However,with more and more severe service environments of materials,many protective coating systems often are not environmentally friendly or toxic as in the case of chromates.Based on the world’s abundant ideal magnesium(Mg)and its alloy,the smart self-healing anticorrosive coating can autonomously restore the damaged part of the coating according to the environmental changes,strengthen the corrosion protection ability,and prolong its service life.This paper reviews the research progress of smart self-healing coatings on Mg alloys.These coatings mostly contain suitable corrosion inhibitors encapsulated into micro/nano containers.Moreover,the different self-healing mechanisms and functionalities of micro/nano containers are discussed.The micro/nano containers range from inorganic nanocontainers such as mesoporous nanoparticles(silica(SiO_(2)),titanium dioxide(TiO_(2)),etc.),over inorganic clays(halloysite,hydrotalcite-like,zeolite),to organic nanocontainers such as polymer microcapsules,nanofibers,chitosan(CS)and cyclodextrin(CD),as well as,carbon materials such as graphene and carbon nanotubes and hybrids such as metal organic frameworks.The functioning of micro/nano containers can be divided in two principal groups:autonomous(based on defect filling and corrosion inhibition)and non-autonomous(based on dynamic bonds and shape memory polymers).Moreover,multi functionalities and composite applications of various micro/nano containers are summarized.At present,significant progress has been made in the preparation methods and technologies of micro/nano containers.Achieving long-term self-healing properties of coatings sensing of coating failure and early warning after self-healing function failure can be expected as the main development direction of self-healing corrosion protection coatings in the future.

Effect of drying cracks on swelling and self-healing of bentonite-sand blocks used as engineered barriers for radioactive waste disposal

Experiments were conducted to evaluate the healing of drying cracks in air-dried bentonite-sand blocks after hydration and swelling in groundwater,providing justifications to simplify the protection of blocks prior to installation in a high-level radioactive waste repository.Synthetic groundwater was prepared to represent the geochemistry of Beishan groundwater,and was used to hydrate the blocks during the swelling pressure and swelling strain measurements,as Beishan is the most promising site for China's repository.Healing of the surface cracks was recorded by photography,and healing of the internal cracks was visualized by CT images and hydraulic conductivity of air-dried blocks.The results indicate that the maximum swelling pressure and swelling strain are primarily affected by the geochemistry of Beishan groundwater,but not affected by the drying cracks.The maximum swelling pressure and swelling strain of air-dried blocks are comparable to or even higher than the pressure and strain of fresh blocks.The maximum swelling pressure measured in strong(i.e.high ion strength)Beishan groundwater was 44%of the pressure measured in deionized(DI)water,and the maximum swelling strain was reduced to 23%of the strain measured in DI water.Nevertheless,the remained swelling of the blocks hydrated in strong Beishan groundwater was sufficient to heal the surface and internal drying cracks,as demonstrated by the pictures of surface cracks and CT images.The hydraulic conductivity of the air-dried block permeated with strong groundwater was comparable(3.7×higher)to the hydraulic conductivity of the fresh block,indicating the self-healing of drying cracks after hydration and swelling in groundwater.A simplified method of protecting the block with plastic wraps before installation is recommended,since the remained swelling of the block hydrated in Beishan groundwater is sufficient to heal the drying cracks.

复杂系统视角下数字领域“smart”概念的国际标准化共识构建及应用

进入数字时代,伴随大数据和人工智能技术快速发展和普遍应用,带有“smart”的指称不断涌现,然而关于“smart”概念的认知尚缺少跨领域和跨国际标准组织的标准化共识构建研究。采用ISO 704:2022的概念构建原则和方法,基于复杂系统论视角,对数字领域国际标准定义中涉及“smart”的概念特征进行了识别。基于跨领域国际标准组织专家的研讨、问卷调查和国际共识构建,提出了适应于复杂系统数字领域“smart”的通用概念,并将其用于指导《智慧城市城市智能服务体系构建指南》国家标准的制定过程。该研究对推进国家标准和国际标准兼容具有重要战略意义。

中国加入CPTPP的农产品贸易效应研究--基于WITS-SMART模型

粮食安全是国家安全的基石,面对国际市场不稳定性,加入CPTPP有望为中国夯实农产品贸易韧性提供新契机。在考察中国与CPTPP国家农产品贸易竞合关系的基础上,运用WITS-SMART模型建立局部均衡分析框架,研究中国加入CPTPP的农产品贸易效应,结果发现:第一,中国农产品竞争力整体不强,但与CPTPP国家依存关系较高,双边贸易潜力在关税完全削减时充分释放。第二,零关税情境下,贸易创造效应普遍大于转移效应,中国对CPTPP多数国家农产品贸易规模大幅扩张,进口增长主要源自种植业、畜牧业部门以及加拿大、澳大利亚、英国、日本等国家,出口增长主要集中于种植业部门以及日本、英国、马来西亚、墨西哥等国家。第三,加入CPTPP显著改善了双边经济福利,不过关税损失较为严重。因此,中国应破除部门利益障碍,加强与墨西哥、日本、英国等国经贸联系以充分挖掘CPTPP国家市场潜力,释放贸易自由化福利,持续提高农产品出口质量和国际竞争力以应对加入CPTPP带来的挑战。

深度学习重建联合Smart去金属伪影算法在口腔金属植入物患者头颈CT血管成像中的应用

目的:探讨深度学习重建(DLR)联合Smart去金属伪影(MAR)算法在口腔金属植入物患者头颈CT血管成像(CTA)中的应用价值。方法:选择郑州大学第一附属医院2023年2月至6月口腔有不可拆卸金属植入物行头颈CTA的患者70例,采用以下3种方法重建图像:基于混合模型的自适应迭代重建(ASIR-V)50%算法(IR),ASIR-V50%联合Smart MAR算法(IR-S),高水平DLR联合Smart MAR算法(DLR-S)。测量不受伪影影响的颈内动脉C1段和头夹肌感兴趣区CT值的标准差(SD)2和SD4,作为图像噪声指标;计算颈内动脉C1段和舌部的金属伪影指数(AI)1和AI2;对颈内动脉C1段和口腔整体图像质量进行主观评分。结果:与IR组和IR-S组比较,DLR-S组SD2和SD4降低(P<0.05)。与IR组比较,IR-S组和DLR-S组AI1、AI2降低;与IR-S组比较,DLR-S组AI1、AT2降低(P<0.05)。与IR组比较,IR-S组和DLR-S组口腔整体和颈内动脉C1段图像质量主观评分均增高;与IR-S组比较,DLR-S组图像质量主观评分增高(P<0.05),9例患者舌部可见新的伪影。结论:Smart MAR联合DLR可减少口腔植入物造成的金属伪影,提高头颈CTA图像质量。但Smart MAR可能引入新的伪影,需联合未加入Smart MAR的图像进行分析。

基于SMART原则的三阶段教学法的中医院神经外科规培护士培训评价

目的探讨基于SMART原则的三阶段教学法对神经外科规范化培训(以下简称“规培”)护士的教学效果。方法选择2020年1月—2022年7月在广东省中医院神经外科规培的护士80人作为研究对象,采用随机数字表法分为对照组(40人)和观察组(40人)。观察组采用基于SMART原则的三阶段教学法,对照组使用常规规培方法;培训结束后比较两组理论考试、临床实践考试成绩及护士核心能力测评结果。结果观察组规培护士理论知识考核及临床实践得分均高于对照组(P<0.05);观察组与对照组在评判性思维/科研、临床护理能力、人际关系、专业发展能力、教育咨询能力及总分方面差异有统计学意义(P<0.05),而在法律/伦理实践、领导能力方面差异无统计学意义(P>0.05)。结论与传统教学方法相比,基于SMART原则的三阶段教学法更有助于提高神经外科规培护士的综合护理能力,尤其是在神经外科急危重症护理方面;另外,规培护士的领导能力培养易被忽略,今后应加强相关研究。

3D smart mA调控技术对不同BMI患者图像采集时间质量及辐射剂量的影响

目的:分析3D智能管电流(3D smart mA)调控技术对不同体质量指数(BMI)患者图像采集时间、质量及辐射剂量的影响。方法:择取的180例行胸部CT扫描患者选自西安交通大学第一附属医院2021年6月至2022年12月期间所收治,按照BMI将患者分为三组,A组(18.5 kg/m^(2)≤BMI≤23.9kg/m^(2),n=75)、B组(23.9kg/m^(2)0.05);两位医师对肺部不同层面图像质量(IQS)评分进行评价,Kappa一致性非常好(Kappa值=0.768、0.812、0.861);三组肺部不同层面IQS评分对比,差异无统计学意义(P>0.05);三组肺部不同层面CT对比,差异有统计学意义,且随着BMI增加而下降(P<0.05),三组肺部不同层面图像标准差(SD)值对比,差异无统计学意义(P>0.05);三组容积CT剂量指数(CTDIvol)对比,差异无统计学意义(P>0.05);A组DLP、ED均低于B、C组,B组DLP、ED低于C组(P<0.05)。结论:不同BMI患者应用3D smart mA调控技术,在保证图像质量的前提下,可有效降低辐射剂量。

二维同步插补算法及其在S7-200 Smart PLC上的应用

针对插补运动系统中存在机械振动较大的问题,提出一类基于恒定加加速度的二维直线插补算法。在确定加加速度的前提下,将直线插补的运动过程分为7个不同的阶段。利用运动学定律分析每个阶段的加速度、速度和位移的表达式,获取各运动阶段的初始条件。在基于二维系统的位移要求确定二维同步关系的基础上,实现了各阶段算法的离散化,最终完成了基于PLC(可编程逻辑控制器)的算法设计。实测效果表明,该算法同步精度小于0.5%,运行时间误差小于1 s,运行效果良好,满足应用场景的需求。

基于Smart 3D软件的船舶二维与三维集成设计变更

船舶二维与三维集成设计流程复杂、变更需求大。梳理船舶设计变更研究现状。基于Smart 3D软件,从数据处理、二维与三维映射转换和设计变更管理等方面进行船舶二维与三维集成设计变更关键技术分析,并对船舶二维与三维集成设计变更的可行性进行实例验证。结果表明,基于Smart 3D软件进行船舶二维与三维集成设计变更可有效提升集成设计变更的精度与管理效率。

SMART精准护理联合康复护理对冠心病PCI术后二级预防及并发症的影响

目的探究在对冠心病PCI术后护理过程中开展SMART精准护理联合康复护理的作用。方法在2022年2月至2024年2月本院冠心病PCI手术患者中选择88例为对象,按照数字表随机排序划分对照组(44例,术后开展常规护理)和观察组(44例,开展SMART精准护理联合康复护理),针对两组术后心功能水平、并发症发生率、病症感知水平等对比。结果心功能水平检测,护理前无差异,护理后观察组左心室射血分数、心输出量、心脏指数较对照组高,差异有统计学意义(P<0.05)。对比两组病症感知水平,认知描绘维度、情绪描绘维度以及综合理解维度,干预前无差异,干预后观察组高于对照组,差异有统计学意义(P<0.05)。对比两组并发症发生率,观察组低于对照组,差异有统计学意义(P<0.05)。结论在对冠心病PCI手术患者术后护理时开展SMART精准护理联合康复护理,有助于增加患者对自身病症认知水平,提升心功能,降低并发症发生率。

工业机器人Smart组件夹具的应用研究

运用ABB RobotStudio,探究了ABB工业机器人的末端执行器在物料搬运工作站中的仿真应用。结合实际生产流程和需求,科学规划搬运工作站空间布局,并精确设置Smart组件信号与属性及传感器动作。通过精准调控搬运工作站逻辑设定,实现了物料搬运工作的精确仿真。该工作站不仅可以适应广泛的应用场景,还可以通过优化仿真环境,提升工作站效率与稳定性,为工业生产智能化、自动化升级提供有力支撑。

基于SMART原则的高校国有资产出租规范化管理研究

教育、科技、人才是全面建设社会主义现代化国家的基础性、战略性支撑。高校是教育、科技、人才工作的聚合点,推动高校高质量发展,离不开规范的管理和服务。随着高校后勤服务社会化、校属企业改革等高校改革工作的不断推进,规范高校国有资产出租管理成为推进高校管理改革的重要环节。目前,国家陆续出台了一系列有关国有资产出租的政策规定,但在实际工作中还存在一些问题。本文分析了高校在国有资产出租规范化管理过程中出现的问题,剖析了出现问题的原因,提出基于SMART原则的多项建议,以期规范高校国有资产出租管理,维护国有资产安全与完整,提升国有资产综合使用效益。

Self-Healing MXene-and Graphene-Based Composites:Properties and Applications

Today,self-healing graphene-and MXene-based composites have attracted researchers due to the increase in durability as well as the cost reduction in long-time applications.Different studies have focused on designing novel self-healing graphene-and MXenebased composites with enhanced sensitivity,stretchability,and flexibility as well as improved electrical conductivity,healing efficacy,mechanical properties,and energy conversion efficacy.These composites with self-healing properties can be employed in the field of wearable sensors,supercapacitors,anticorrosive coatings,electromagnetic interference shielding,electronic-skin,soft robotics,etc.However,it appears that more explorations are still needed to achieve composites with excellent arbitrary shape adaptability,suitable adhesiveness,ideal durability,high stretchability,immediate self-healing responsibility,and outstanding electromagnetic features.Besides,optimizing reaction/synthesis conditions and finding suitable strategies for functionalization/modification are crucial aspects that should be comprehensively investigated.MXenes and graphene exhibited superior electrochemical properties with abundant surface terminations and great surface area,which are important to evolve biomedical and sensing applications.However,flexibility and stretchability are important criteria that need to be improved for their future applications.Herein,the most recent advancements pertaining to the applications and properties of self-healing graphene-and MXene-based composites are deliberated,focusing on crucial challenges and future perspectives.