Accelerated Sequential Deposition Reaction via Crystal Orientation Engineering for Low-Temperature,High-Efficiency Carbon-Electrode CsPbBr_(3) Solar Cells

Low-temperature,ambient processing of high-quality CsPbBr_(3)films is demanded for scalable production of efficient,low-cost carbon-electrode perovskite solar cells(PSCs).Herein,we demonstrate a crystal orientation engineering strategy of PbBr_(2)precursor film to accelerate its reaction with CsBr precursor during two-step sequential deposition of CsPbBr_(3)films.Such a novel strategy is proceeded by adding CsBr species into PbBr_(2)precursor,which can tailor the preferred crystal orientation of PbBr_(2)film from[020]into[031],with CsBr additive staying in the film as CsPb_(2)Br_(5)phase.Theoretical calculations show that the reaction energy barrier of(031)planes of PbBr_(2)with CsBr is lower about 2.28 eV than that of(O2O)planes.Therefore,CsPbBr_(3)films with full coverage,high purity,high crystallinity,micro-sized grains can be obtained at a low temperature of 150℃.Carbon-electrode PSCs with these desired CsPbBr_(3)films yield the record-high efficiency of 10.27%coupled with excellent operation stability.Meanwhile,the 1 cm^(2)area one with the superior efficiency of 8.00%as well as the flexible one with the champion efficiency of 8.27%and excellent mechanical bending characteristics are also achieved.

Effects of orientation on the fatigue crack growth behaviors of the ZK60 magnesium alloy in air and PBS

Strong anisotropic corrosion and mechanical properties caused by specimen orientations greatly limit the applications of wrought magnesium alloys.To investigate the influences of specimen orientation,the corrosion tests and(corrosion)fatigue crack growth tests were conducted.The rolled and transverse surfaces of the materials show distinct corrosion rate differences in the stable corrosion stage,but the truth is the opposite for the initial stage of corrosion.In air,specimen orientations have a significant influence on the plastic deformation mechanisms near the crack tip,which results in different fatigue fracture surfaces and cracking paths.Compared with R-T specimens,N-T specimens show a slower fatigue crack growth(FCG)rate in air,which can be attributed to crack closure effects and deformation twinning near the crack tip.The corrosion environment will not significantly change the main plastic deformation mechanisms for the same type of specimen.However,the FCG rate in phosphate buffer saline(PBS)is one order of magnitude higher than that in air,which is caused by the combined effects of hydrogen-induced cracking and anodic dissolution.Owing to the similar corrosion rates at crack tips,the specimens with different orientations display close FCG rates in PBS.

Evaluation of New Graduate Nursing Orientation Program

The study site is a holistic patient-centered organization that has developed a 16-week long orientation program for new graduate nurses entering the hospital setting. The purpose of the program is for new graduate nurses to gain the confidence, competence, and critical thinking skills for providing safe patient care. The issue occurring within the organization is that there is an increasing rise in the number of turnover rates of new graduates leaving the hospital, thus making evaluating the program a necessity to problem-solving. There has been no evaluation of the program in the past five years to reveal why the increase in the recent turnover rates. The data collected during the interview process was coded and categorized into three main sections: organizational, substantive, and theoretical. The evaluator used an organizational category to investigate for board areas or issues within the problem attempting to be solved. The evaluator concluded from the results and findings that the issue, a poor preceptor-preceptee relationship was seen by all stakeholders involved. The literature presented concludes that continuous evaluation of orientation programs is crucial for the professional and personal growth of new graduate nurses in the hospital.

Effects of mesoclimate and microclimate variations mediated by high altitude and row orientation on sucrose metabolism and anthocyanin synthesis in grape berries

Climate change and extreme weather pose significant challenges to the traditional viticulture regions.Emerging high-altitude grape-producing regions with diverse orientations have shown great potential in coping with this challenge.Stable,high-quality wine grape production may be achieved by synchronizing the meso-and microclimate.To clarify the role of high altitude and row orientation in meso-and microclimate and the response of berries to it,we evaluated seven years(2012-2018)of climate data,two years of basic grape(Cabernet Sauvignon,Vitis vinifera L.)quality,and one-year microclimate from veraison to harvest.By comparing two locations(Sidon 2047 m,Sinon 2208 m)in Yunnan Province,China,we found that the average temperature has been stable at approximately 15℃ for seven years,with no extreme weather or,noticeable global warming.The light intensity(LI)in the north-south(NS)was more balanced than the east-west(EW)direction,and the east-west to the south(EW-S)canopy side was almost higher than the other sides.High LI was associated with high photosynthetically active radiation(PAR),ultraviolet(UV),and infrared(IR)light and vice versa.The north-south to the east(NS-E)and east-west to the north(EWN)sides were characterized by lower LI and higher UV and IR light,and higher total anthocyanin content.Most anthocyanin synthesis-related genes,for example,VvF3'H and VvF3'5'H,were highly expressed in NS-E from veraison to maturity.Perhaps UV and IR light induced their expression.This study provides new insights on the role of differently orientated rows in controlling grape quality due to varied light quality.The findings are globally significant,particularly in the context of climate change,and offer fresh insights into berry physiological responses and decision-making for the management of existing vineyards.

Alleviating the anisotropic microstructural change and boosting the lithium ions diffusion by grain orientation regulation for Ni-rich cathode materials

Generally,layered Ni-rich cathode materials exhibit the morphology of polycrystalline secondary sphere composed of numerous primary particles.While the arrangement of primary particles plays a very important role in the properties of Ni-rich cathodes.The disordered particle arrangement is harmful to the cyclic performance and structural stability,yet the fundamental understanding of disordered structure on the structural degradation behavior is unclarified.Herein,we have designed three kinds of LiNi_(0.83)Co_(0.06)Mn_(0.11)O_(2) cathode materials with different primary particle orientations by regulating the precursor coprecipitation process.Combining finite element simulation and in-situ characterization,the Li^(+)transport and structure evolution behaviors of different materials are unraveled.Specifically,the smooth Li^(+)diffusion minimizes the reaction heterogeneity,homogenizes the phase transition within grains,and mitigates the anisotropic microstructural change,thereby modulating the crack evolution behavior.Meanwhile,the optimized structure evolution ensures radial tight junctions of the primary particles,enabling enhanced Li^(+)diffusion during dynamic processes.Closed-loop bidirectional enhancement mechanism becomes critical for grain orientation regulation to stabilize the cyclic performance.This precursor engineering with particle orientation regulation provides the useful guidance for the structural design and feature enhancement of Ni-rich layered cathodes.

Nonlinear Time History Analysis for the Different Column Orientations under Seismic Wave Synthetic Approach

The significant impact of earthquakes on human lives and the built environment underscores the extensive human and economic losses caused by structural collapses. Over the years, researchers have focused on improving seismic design to mitigate earthquake-induced damages and enhance structural performance. In this study, a specific reinforced concrete (RC) frame structure at Kyungpook National University, designed for educational purposes, is analyzed as a representative case. Utilizing SAP 2000, the research conducts a nonlinear time history analysis to assess the structural performance under seismic conditions. The primary objective is to evaluate the influence of different column section designs, while maintaining identical column section areas, on structural behavior. The study employs two distinct seismic waves from Abeno (ABN) and Takatori (TKT) for the analysis, comparing the structural performance under varying seismic conditions. Key aspects examined include displacement, base shear force, base moment, joint radians, and layer displacement angle. This research is anticipated to serve as a valuable reference for seismic restraint reinforcement work on RC buildings, enriching the methods used for evaluating structures through nonlinear time history analysis based on the synthetic seismic wave approach.

Integrating Virtual Reality and Energy Analysis with BIM to Optimize Window-to-Wall Ratio and Building’s Orientation for Age-in-Place Design at the Conceptual Stage

This study unfolds an innovative approach aiming to address the critical role of building design in global energy consumption, focusing on optimizing the Window-to-Wall Ratio (WWR), since buildings account for approximately 30% of total energy consumed worldwide. The greatest contributors to energy expenditure in buildings are internal artificial lighting and heating and cooling systems. The WWR, determined by the proportion of the building’s glazed area to its wall area, is a significant factor influencing energy efficiency and minimizing energy load. This study introduces the development of a semi-automated computer model designed to offer a real-time, interactive simulation environment, fostering improving communication and engagement between designers and owners. The said model serves to optimize both the WWR and building orientation to align with occupants’ needs and expectations, subsequently reducing annual energy consumption and enhancing the overall building energy performance. The integrated model incorporates Building Information Modeling (BIM), Virtual Reality (VR), and Energy Analysis tools deployed at the conceptual design stage, allowing for the amalgamation of owners’ inputs in the design process and facilitating the creation of more realistic and effective design strategies.

Crystallization and Orientation Modulation Enable Highly Efficient Doctor-Bladed Perovskite Solar Cells

With the rapid rise in perovskite solar cells(PSCs)performance,it is imperative to develop scalable fabrication techniques to accelerate potential commercialization.However,the power conversion efficiencies(PCEs)of PSCs fabricated via scalable two-step sequential deposition lag far behind the state-of-the-art spin-coated ones.Herein,the additive methylammonium chloride(MACl)is introduced to modulate the crystallization and orientation of a two-step sequential doctorbladed perovskite film in ambient conditions.MACl can significantly improve perovskite film quality and increase grain size and crystallinity,thus decreasing trap density and suppressing nonradiative recombination.Meanwhile,MACl also promotes the preferred face-up orientation of the(100)plane of perovskite film,which is more conducive to the transport and collection of carriers,thereby significantly improving the fill factor.As a result,a champion PCE of 23.14%and excellent longterm stability are achieved for PSCs based on the structure of ITO/SnO_(2)/FA_(1-x)MA_xPb(I_(1-y)Br_y)_3/Spiro-OMeTAD/Ag.The superior PCEs of 21.20%and 17.54%are achieved for 1.03 cm~2 PSC and 10.93 cm~2 mini-module,respectively.These results represent substantial progress in large-scale two-step sequential deposition of high-performance PSCs for practical applications.

厄瓜多尔Oriente盆地白垩系Napo组LU亚段沉积模式

厄瓜多尔Oriente盆地北部白垩系Napo组LU亚段地层油气资源极其丰富,具有较大的油气勘探潜力,由于目前对LU亚段地层沉积模式认识不清晰,极大程度上限制了研究区进一步勘探开发。依据LU亚段岩芯观察、测井、成熟度分析以及镜下薄片等资料,通过岩芯岩性、结构等岩石学特征,沉积构造、生物遗迹化石、沉积韵律等沉积学特征,以及测井相标志认为,研究区LU亚段地层发育于潮汐作用为主的海陆过渡环境,并在前人研究基础上提出潮控河口湾与陆棚之间存在过渡带沉积,形成了潮控河口湾-过渡带-陆棚沉积体系,识别出潮汐水道、潮汐砂坝、砂坪、海绿石砂席、混合坪、陆棚泥和灰质滩共7种沉积微相,其中,优势储层相带为潮汐水道和潮汐砂坝,砂坪次之。建立研究区潮控河口湾-过渡带-陆棚沉积模式,以期对Oriente盆地白垩系Napo组油气勘探提供有利的科学依据。

Mutual impact of true triaxial stress, borehole orientation and bedding inclination on laboratory hydraulic fracturing of Lushan shale

Unconventional resources like shale gas has been the focus of intense research and development for two decades. Apart from intrinsic geologic factors that control the gas shale productivity (e.g. organic matter content, bedding planes, natural fractures, porosity and stress regime among others), external factors like wellbore orientation and stimulation design play a role. In this study, we present a series of true triaxial hydraulic fracturing experiments conducted on Lushan shale to investigate the interplay of internal factors (bedding, natural fractures and in situ stress) and external factors (wellbore orientation) on the growth process of fracture networks in cubic specimens of 200 mm in length. We observe relatively low breakdown pressure and fracture propagation pressure as the wellbore orientation and/or the maximum in situ stress is subparallel to the shale bedding plane. The wellbore orientation has a more prominent effect on the breakdown pressure, but its effect is tapered with increasing angle of bedding inclination. The shale breakdown is followed by an abrupt response in sample displacement, which reflects the stimulated fracture volume. Based on fluid tracer analysis, the morphology of hydraulic fractures (HF) is divided into four categories. Among the categories, activation of bedding planes (bedding failure, BF) and natural fractures (NF) significantly increase bifurcation and fractured areas. Under the same stress regime, a horizontal wellbore is more favorable to enhance the complexity of hydraulic fracture networks. This is attributed to the relatively large surface area in contact with the bedding plane for the horizontal borehole compared to the case with a vertical wellbore. These findings provide important references for hydraulic fracturing design in shale reservoirs.

基于改进Oriented R-CNN的旋转框麦穗检测与计数模型

为对干扰、遮挡等复杂的田野环境中麦穗进行精准定位与计数,该研究提出了一种改进的Oriented R-CNN麦穗旋转框检测与计数方法,首先在主干网络中引入跨阶段局部空间金字塔(spatial pyramid pooling cross stage partial networks,SPPCSPC)模块扩大模型感受野,增强网络感知能力;其次,在颈网络中结合路径聚合网络(PANet,path aggregation network)和混合注意力机制(E2CBAM,efficient two convolutional block attention module),丰富特征图包含的特征信息;最后采用柔性非极大值抑制算法(Soft-NMS,soft-non maximum suppression)优化预测框筛选过程。试验结果显示,改进的模型对复杂环境中的麦穗检测效果良好。相较原模型,平均精确度均值mAP提高了2.02个百分点,与主流的旋转目标检测模型Gliding vertex、R3det、Rotated Faster R-CNN、S2anet和Rotated Retinanet相比,mAP分别提高了4.99、2.49、3.94、2.25和4.12个百分点。该研究方法利用旋转框准确定位麦穗位置,使得框内背景区域面积大幅度减少,为实际观察麦穗生长状况和统计数量提供了一种有效的方法。

Impact of orientation of blast initiation on ground vibrations

The blast-induced ground vibrations can be significantly controlled by varying the location and orien-tation of point of interest from blast site.The blast waves generated due to individual holes get super-imposed and resultant peak particle velocity(PPV)generates.With the orientation sequence of holes blasts on site,the superimposition angle of wave changes and hence results in significant variation in resultant PPV.The orientation with respect to the initiation of blasts resulting in lowest PPV needs to be identified for any site.By knowing the PPV contour of vibration waves in mine sites,it is possible to reduce the vibration on the structures by changing the initiation sequence.In this paper,experimental blasts were conducted at two different mine sites and the PPV values were recorded at different ori-entations from the blast site and its initiation sequence.The PPV contours were drawn to identify the orientation with least and highest PPV generation line.It was found that by merely changing the initi-ation sequence of blasts with respect to the sensitive structure or point of interest,the PPV values can be reduced significantly up to 76.9%.

Phase-field-crystal simulation of nano-single crystal microcrack propagation under different orientation angles

The propagation mechanism of microcracks in nanocrystalline single crystal systems under uniaxial dynamic and static tension is investigated using the phase-field-crystal method.Both dynamic and static stretching results show that different orientation angles can induce the crack propagation mode,microscopic morphology,the free energy,crack area change,and causing fracture failure.Crack propagation mode depends on the dislocation activity near the crack tip.Brittle propagation of the crack occurs due to dislocation always at crack tip.Dislocation is emitted at the front end of the crack tip and plastic deformation occurs,which belongs to ductile propagation.The orientation angles of 9°and 14°are brittleductile mixed propagation,while the orientation angles of 19°and 30°are brittle propagation and no dislocation is formed under dynamic tension.The vacancy and vacancy connectivity phenomenon would appear when the orientation angle is14°under static tension,and the crack would be ductile propagation.While the orientation angle is 19°and 30°,the crack propagates in a certain direction,which is a kind of brittle propagation.This work has some practical significance in preventing material fracture failure and improving material performance.

The Influence of Crystallographic Orientation and Grain Boundary on Nanoindentation Behavior of Inconel 718 Superalloy Based on Crystal Plasticity Theory

The crystal plasticity finite element method(CPFEM)is widely used to explore the microscopic mechanical behavior of materials and understand the deformation mechanism at the grain-level.However,few CPFEM simulation studies have been carried out to analyze the nanoindentation deformation mechanism of polycrystalline materials at the microscale level.In this study,a three-dimensional CPFEM-based nanoindentation simulation is performed on an Inconel 718 polycrystalline material to examine the influence of different crystallographic parameters on nanoindentation behavior.A representative volume element model is developed to calibrate the crystal plastic constitutive parameters by comparing the stress-strain data with the experimental results.The indentation force-displacement curves,stress distributions,and pile-up patterns are obtained by CPFEM simulation.The results show that the crystallographic orientation and grain boundary have little influence on the force-displacement curves of the nanoindentation,but significantly influence the local stress distributions and shape of the pile-up patterns.As the difference in crystallographic orientation between grains increases,changes in the pile-up patterns and stress distributions caused by this effect become more significant.In addition,the simulation results reveal that the existence of grain boundaries affects the continuity of the stress distribution.The obstruction on the continuity of stress distribution increases as the grain boundary angle increases.This research demonstrates that the proposed CPFEM model can well describe the microscopic compressive deformation behaviors of Inconel 718 under nanoindentation.

A General Strategy to Electrospin Nanofibers with Ultrahigh Molecular Chain Orientation

The degree of polymer chain orientation is a key structural parameter that determines the mechanical and physical properties of fibers.However,understanding and significantly tuning the orientation of fiber macromolecular chains remain elusive.Herein,we propose a novel electrospinning technique that can efficiently modulate molecular chain orientation by controlling the electric field.In contrast to the typical electrospinning method,this technique can piecewise control the electric field by applying high voltage to the metal ring instead of the needle.Benefiting from this change,a new electric field distribution can be realized,leading to a non-monotonic change in the drafting force.As a result,the macromolecular chain orientation of polyethylene oxide(PEO)nanofibers was significantly improved with a recordhigh infrared dichroic ratio.This was further confirmed by the sharp decrease in the PEO jet fineness of approximately 80%and the nanofiber diameter from 298 to 114 nm.Interestingly,the crystallinity can also be adjusted,with an obvious drop from 74.9%to 31.7%,which is different from the high crystallinity caused by oriented chains in common materials.This work guides a new perspective for the preparation of advanced electrospun nanofibers with optimal orientation–crystallinity properties,a merited feature for various applications.

Evaluation of elastic-viscoplastic self-consistent models for a rolled AZ31B magnesium alloy under monotonic loading along five different material orientations and free-end torsion

Comprehensive experiments including monotonic tension and monotonic compression of specimens taken from a rolled AZ31B Mg thick plate along five different material orientations with respect to the rolled direction(RD),and free-end torsion of a tubular specimen machined along the thickness direction(ND)were conducted.The experimental results were used to evaluate an elastic-viscoplastic self-consistent model with the consideration of twinning and detwinning(EVPSC-TDT)on magnesium(Mg)alloys.The EVPSC-TDT model provides stress-strain curves and the hardening rates in close agreement with the experimental results of all the 11 loading cases.The model adequately predicts the textures after fracture of all the 11 loading cases and the evolutions of tension twins with increasing strains for tension in the ND,compression in the RD,and torsion along the ND.The Swift effect was observed in the experiment and was properly simulated by the model.

Rapid and efficient characterization of cervical collagen orientation using linearly polarized colposcopic images

Collagen provides tissue strength and structural integrity.Quanti fication of the orientated dispersion of collagen fibers is an important factor when studying the mechanical properties of the cervix.In this study,for the first time,a new method for rapid characterization of the collagen fiber orientations of the cervix using linearly polarized light colposcopy is presented.A total of 24 colposcopic images were captured using a cross-polarized imaging system with white LED light sources.In the preprocessing stage,the Red channel of the RGB image was chosen,which contains no information of the blood vessels because of the low-absorption of blood cells in the red region.OrientationJ,which is an ImageJ plug-in,was used to estimate the local orientation of the collagen fibers.The result shows that in the nonpregnant cervix,the middle zone(Zone 2)has circumferentially aligned collagen fibers while the inner zone(Zone 1)has randomly arranged.The collagen fiber dispersion in Zone 2 is much smaller than that in Zone 1 at all four quadrants region(anterior,posterior,left,and right quadrant).This new analysis technique could potentially combine with diagnostic tools to provide a quantitative platform of collagen fibers in the clinic.

Deformation mechanism,orientation evolution and mechanical properties of annealed cross-rolled Mg-Zn-Zr-Y-Gd sheet during tension

Mg-6.75Zn-0.57Zr-0.4Y-0.18Gd(wt.%)sheet with typical basal texture was produced by cross rolling and annealing.Room temperature tensile tests were subsequently conducted along rolling direction(RD),transverse direction(TD),and diagonal direction(RD45).Deformation mechanism and orientation evolution during the tension were investigated by quasi-in-situ electron backscatter diffraction observation and in-grain misorientation axis analysis.The results indicate that the activation of deformation mechanism mainly depends on the initial grain orientation.For RD sample,prismatic<a>slip plays an important role in the deformation of grains with<0001>axis nearly perpendicular to the RD.With the<0001>axis gradually tilted towards the RD,basal<a>slip becomes the dominant deformation mode.After the tensile fracture,the initial concentrically distributed{0001}pole is split into double peaks extending perpendicular to the RD,and the randomly distributed{1010}pole becomes parallel to the RD.The evolution in{0001}and{1010}poles during tension is related to the lattice rotation induced by basal<a>slip and prismatic<a>slip,respectively.TD and RD45 samples exhibit similar deformation mechanism and orientation evolution as the RD sample,which results in the nearly isotropic mechanical properties in the annealed cross-rolled sheet.

A non-contact measurement method for rock mass discontinuity orientations by smartphone

Smartphones are usually packed with a large number of features.An increasing number of researchers are paying attention to the technological capabilities of smartphones,which is a new topic and research interest.This paper proposes a method using smartphones and digital photogrammetry to measure the discontinuity orientation of a rock mass.Smartphone photos satisfying a certain overlap rate provide an efficient method for generating point cloud models of rock outcrops based on image matching.Using the target and the generated point cloud model allows for determining actual geographic coordinates and the measurement of discontinuity orientations.The method proposed has been applied to two different study areas.The discontinuity orientations measured by the proposed method are compared with those measured by the manual method in two cases.The results show a good agreement,verifying the reliability and accuracy of the proposed method.The main contribution of this paper is to use knowledge of coordinate rotation to determine the actual geographic location of the model through a square target.The equipment used in this study is simple,and photogrammetric field surveys are easy to carry out.

Four new orientation relationships of Mg_(17)Al_(12) phase with magnesium matrix in Mg-8Al-0.5Zn alloys

Although the non-basal precipitates, those not parallel to the basal plane, are more effective to block basal slip in Mg-Al alloys, the crystallographic orientation relationship(OR) between these precipitates and the α-Mg matrix has not been well established. In this work, the crystallography of the non-basal Mg_(17)Al_(12) precipitates in AZ80 alloy was systematically investigated by transmission electron microscopy(TEM). By tilting to a suitable electron beam direction, different kinds of non-basal precipitates were recognized in TEM, and the following four new ORs between the non-basal Mg_(17)Al_(12) precipitates and the matrix were revealed: ■, and ■.Furthermore, these ORs and their habit planes were explained using the edge-to-edge matching model. The findings in this work can provide some guidelines for designing the microstructure of Mg-Al alloys to enhance their precipitation hardening potential.