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Cokriging of Soil Cation Exchange Capacity Using the First Principal Component Derived from Soil Physico-Chemical Properties 被引量:4
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作者 LIAO Kai-hua XU Shao-hui +2 位作者 WU Ji-chun JI Shu-hua LIN Qing 《Agricultural Sciences in China》 CAS CSCD 2011年第8期1246-1253,共8页
As soil cation exchange capacity (CEC) is a vital indicator of soil quality and pollutant sequestration capacity,a study was conducted to evaluate cokriging of CEC with the principal components derived from soil phy... As soil cation exchange capacity (CEC) is a vital indicator of soil quality and pollutant sequestration capacity,a study was conducted to evaluate cokriging of CEC with the principal components derived from soil physico-chemical properties.In Qingdao,China,107 soil samples were collected.Soil CEC was estimated by using 86 soil samples for prediction and 21 soil samples for test.The first two principal components (PC1 and PC2) together explained 60.2% of the total variance of soil physico-chemical properties.The PC1 was highly correlated with CEC (r=0.76,P0.01),whereas there was no significant correlation between CEC and PC2 (r=0.03).The PC1 was then used as an auxiliary variable for the prediction of soil CEC.Mean error (ME) and root mean square error (RMSE) of kriging for the test dataset were-1.76 and 3.67 cmolc kg-1,and ME and RMSE of cokriging for the test dataset were-1.47 and 2.95 cmolc kg-1,respectively.The cross-validation R2 for the prediction dataset was 0.24 for kriging and 0.39 for cokriging.The results show that cokriging with PC1 is more reliable than kriging for spatial interpolation.In addition,principal components have the highest potential for cokriging predictions when the principal components have good correlations with the primary variables. 展开更多
关键词 soil cation exchange capacity spatial interpolation root mean square error GEOSTATISTICS
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Cat Swarm with Fuzzy Cognitive Maps for Automated Soil Classification
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作者 Ashit Kumar Dutta Yasser Albagory +2 位作者 Manal Al Faraj Majed Alsanea Abdul Rahaman Wahab Sait 《Computer Systems Science & Engineering》 SCIE EI 2023年第2期1419-1432,共14页
Accurate soil prediction is a vital parameter involved to decide appro-priate crop,which is commonly carried out by the farmers.Designing an auto-mated soil prediction tool helps to considerably improve the efficacy of... Accurate soil prediction is a vital parameter involved to decide appro-priate crop,which is commonly carried out by the farmers.Designing an auto-mated soil prediction tool helps to considerably improve the efficacy of the farmers.At the same time,fuzzy logic(FL)approaches can be used for the design of predictive models,particularly,Fuzzy Cognitive Maps(FCMs)have involved the concept of uncertainty representation and cognitive mapping.In other words,the FCM is an integration of the recurrent neural network(RNN)and FL involved in the knowledge engineering phase.In this aspect,this paper introduces effective fuzzy cognitive maps with cat swarm optimization for automated soil classifica-tion(FCMCSO-ASC)technique.The goal of the FCMCSO-ASC technique is to identify and categorize seven different types of soil.To accomplish this,the FCMCSO-ASC technique incorporates local diagonal extrema pattern(LDEP)as a feature extractor for producing a collection of feature vectors.In addition,the FCMCSO model is applied for soil classification and the weight values of the FCM model are optimally adjusted by the use of CSO algorithm.For exam-ining the enhanced soil classification outcomes of the FCMCSO-ASC technique,a series of simulations were carried out on benchmark dataset and the experimen-tal outcomes reported the enhanced performance of the FCMCSO-ASC technique over the recent techniques with maximum accuracy of 96.84%. 展开更多
关键词 soil classification intelligent models fuzzy cognitive maps cat swarm optimization fuzzy logic
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Changes of Soil Water, Organic Matter, and Exchangeable Cations Along a Forest Successional Gradient in Southern China 被引量:6
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作者 YAN Jun-Hua ZHOU Guo-Yi ZHANG De-Qiang CHU Guo-Wei 《Pedosphere》 SCIE CAS CSCD 2007年第3期397-405,共9页
Information on the distribution patterns of soil water content (SWC), soil organic matter (SOM), and soil exchangeable cations (SEC) is important for managing forest ecosystems in a sustainable manner. This stud... Information on the distribution patterns of soil water content (SWC), soil organic matter (SOM), and soil exchangeable cations (SEC) is important for managing forest ecosystems in a sustainable manner. This study investigated how SWC, SOM, and SEC were influenced in forests along a successional gradient, including a regional climax (monsoon evergreen broad-leaved forest, or MEBF), a transitional forest (coniferous and broad-leaved mixed forest, or MF), and a pioneer forest (coniferous Masson pine (Pinus rnassoniana) forest, or MPF) of the Dinghushan Biosphere Reserve in the subtropical region of southern China. SWC, SOM, and SEC excluding Ca^2+ were found to increase in the soil during forest succession, being highest in the top soil layer (0 to 15 cm depth) except for Na^+. The differences between soil layers were largest in MF. This finding also suggested that the nutrients were enriched in the topsoil when they became increasingly scarce in the soil. There were no significant differences (P = 0.05) among SWC, SOM, and SEC. A linear, positive correlation was found between SWC and SOM. The correlation between SOM and cation exchange capacity (CEC) was statistically significant, which agreed with the theory that the most important factor determining SEC is SOM. The ratio of K^+ to Na^+ in the topsoil was about a half of that in the plants of each forest. MF had the lowest exchangeable Ca^2+ concentration among the three forests and Ca^2+:K^+ in MPF was two times higher than that in MF. Understanding the changes of SWC, SOM, and CEC during forest succession would be of great help in protecting all three forests in southern China. 展开更多
关键词 forest succession soil exchangeable cations soil organic matter soil water content
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Effect of natural and anthropogenic acidifi cation on aluminium distribution in forest soils of two regions in the Czech Republic 被引量:1
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作者 Lenka Pavlů LubošBorůvka +1 位作者 Ondřej Drábek Antonín Nikodem 《Journal of Forestry Research》 SCIE CAS CSCD 2021年第1期363-370,共8页
To elucidate the dynamics of aluminium(Al),an element potentially toxic and strongly aff ected by acidifi cation processes,in soils,we selected two regions that were similar in relief,soil types,and vegetation cover b... To elucidate the dynamics of aluminium(Al),an element potentially toxic and strongly aff ected by acidifi cation processes,in soils,we selected two regions that were similar in relief,soil types,and vegetation cover but diff ered markedly in their history of acid precipitation:the JizerskéMountains(anthropogenically acidifi ed)and the NovohradskéMountains(naturally acidifi ed)in the Czech Republic.The levels of Al forms(exchangeable and organically bound)associated with diff erent environmental impacts were measured and univalent,divalent and trivalent Al species were quantifi ed using HPLC/IC.Exchangeable and organically bound Al concentrations were higher in the anthropogenically acidifi ed area.Only the concentrations of the leastdangerous species,the univalent,in organic soil horizons were similar for both mountains.The concentrations of exchangeable Al forms were correlated with Ca concentrations and with pH in the organic horizon.The known relationship of Al with soil pH was stronger in the mineral horizons.Relationships of exchangeable Al forms concentrations with sulphur concentrations or even more with the sulphur calcium molar ratio were found only in the JizerskéMountains,not in the Novohradské.Generally,the obtained results support the hypothesis that mechanisms diff ered between natural and anthropogenic acidifi cation. 展开更多
关键词 soil acidifi cation Spruce forest soil properties Aluminium forms Aluminium species
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Sheep manure application increases soil exchangeable base cations in a semi-arid steppe of Inner Mongolia 被引量:9
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作者 YuGe ZHANG Shan YANG +6 位作者 MingMing FU JiangPing CAI YongYong ZHANG RuZhen WANG ZhuWen XU YongFei BAI Yong JIANG 《Journal of Arid Land》 SCIE CSCD 2015年第3期361-369,共9页
The long-term productivity of a soil is greatly influenced by cation exchange capacity(CEC).Moreover,interactions between dominant base cations and other nutrients are important for the health and stability of grass... The long-term productivity of a soil is greatly influenced by cation exchange capacity(CEC).Moreover,interactions between dominant base cations and other nutrients are important for the health and stability of grassland ecosystems.Soil exchangeable base cations and cation ratios were examined in a 11-year experiment with sheep manure application rates 0–1,500 g/(m2?a) in a semi-arid steppe in Inner Mongolia of China,aiming to clarify the relationships of base cations with soil p H,buffer capacity and fertility.Results showed that CEC and contents of exchangeable calcium(Ca2+),magnesium(Mg2+),potassium(K+) and sodium(Na+) were significantly increased,and Ca2+ saturation tended to decrease,while K+ saturation tended to increase with the increases of sheep manure application rates.The Ca2+/Mg2+ and Ca2+/K+ ratios decreased,while Mg2+,K+ and Na+ saturations increased with increasing manure application rates.Both base cations and CEC were significantly and positively correlated with soil organic carbon(SOC) and soil p H.The increases of SOC and soil p H would be the dominant factors that contribute to the increase of cations in soil.On a comparison with the initial soil p H before the experiment,we deduced that sheep manure application could partly buffer soil p H decrease potentially induced by atmospheric deposition of nitrogen and sulfur.Our results indicate that sheep manure application is beneficial to the maintenance of base cations and the buffering of soil acidification,and therefore can improve soil fertility in the semi-arid steppes of northeastern China. 展开更多
关键词 base cation sheep manure soil p H soil fertility buffer capacity grassland conservation
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Adsorption of 2,4-dinitrophenol and 2,4-dichlorophenol on Cationic Surfactant Modified Red Soil 被引量:3
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作者 廖敏 《Chinese Journal Of Geochemistry》 EI CAS 2004年第4期301-308,共8页
Adsorption isotherms of 2,4-dinitrophenol and 2,4-dichlorophenol on hexadecyltrimethylammonium (HDTMA) bromide modified red soil under different ionic strength, divalent cation Cu 2+ or different pH conditions were st... Adsorption isotherms of 2,4-dinitrophenol and 2,4-dichlorophenol on hexadecyltrimethylammonium (HDTMA) bromide modified red soil under different ionic strength, divalent cation Cu 2+ or different pH conditions were studied. All the adsorption isotherms were well fitted to the Freundlich equation. The adsorption capacities of 2,4-dinitrophenol or 2,4-dichlorophenol were dramatically enhanced by HDTMA treatment of red soil. The increase of ionic strength and the addition of divalent heavy metal cation Cu 2+ significantly enhanced the adsorption of 2,4-dinitrophenol or 2,4-dichlorophenol on the HDTMA-modified red soil. Adsorption capacities of HDTMA-modified red soil for 2,4-dinitrophenol and 2,4-dichlorophenol gradually increased with decreasing pH in the aqueous phase. 展开更多
关键词 2 4-二硝基酚 2 4-二氢氯化 红土 阳离子表面活性剂
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Soil exchangeable base cations along a chronosequence of Caragana microphylla plantation in a semi-arid sandy land,China 被引量:13
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作者 YuGe ZHANG ZhuWen XU +1 位作者 DeMing JIANG Yong JIANG 《Journal of Arid Land》 SCIE CSCD 2013年第1期42-50,共9页
As a pioneer leguminous shrub species for vegetation re-establishment, Caragana microphylla is widely distributed in the semi-fixed and fixed sandy lands of the Horqin region, North China. C. microphylla planta- tions... As a pioneer leguminous shrub species for vegetation re-establishment, Caragana microphylla is widely distributed in the semi-fixed and fixed sandy lands of the Horqin region, North China. C. microphylla planta- tions modify organic carbon (SOC), nitrogen (N) and phosphorus dynamics, bulk density and water-holding capacity and biological activities in soils, but little is known with regard to soil exchange properties. Variation in soil ex- changeable base cations was examined under C. microphylla plantations with an age sequence of 0, 5, 10, and 22 years in the Horqin Sandy Land, and at the depth of 0-10, 10-20, and 20-30 cm, respectively. C. microphylla has been planted on the non-vegetated sand dunes with similar physical-chemical soil properties. The results showed that exchangeable calcium (Ca), magnesium (Mg), and potassium (K), and cation exchange capacity (CEC) were significantly increased, and Ca saturation tended to decrease, while Mg and K saturations were increased with the plantation years. No difference was observed for exchangeable sodium (Na) neither with plantation years nor at soil depths. Of all the base cations and soil layers, exchangeable K at the depth of 0-10 cm accumulated most quickly, and it increased by 1.76, 3.16, and 4.25 times, respectively after C. microphylla was planted for 5, 10, and 22 years. Exchangeable Ca, Mg, and K, and CEC were significantly (P〈0.001) and positively correlated with SOC, total N, pH and electrical conductivity (EC). Soil pH and SOC are regarded as the main factors influencing the variation in ex- changeable cations, and the preferential absorption of cations by plants and different leaching rates of base cations that modify cation saturations under C. microphylla plantation. It is concluded that as a nitrogen-fixation species, C. microphylla plantation is beneficial to increasing exchangeable base cations and CEC in soils, and therefore can improve soil fertility and create favorable microenvironments for plants and creatures in the semi-arid sandy land ecosystems. 展开更多
关键词 cation exchange capacity soil organic carbon soil pH soil fertility Caragana microphylla ecological restoration
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Base cation concentrations in forest litter and topsoil have different responses to climate and tree species along elevational gradients 被引量:2
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作者 XUE Feng ZHAO Ming-fei +6 位作者 WANG Yu-hang KANG Mu-yi XING Kai-xiong WANG Guo-yi SHI Jing-jing CHEN Chen JIANG Yuan 《Journal of Mountain Science》 SCIE CSCD 2019年第1期30-42,共13页
The forest litter is an essential reservoir of nutrients in forests, supplying a large part of absorbable base cations(BC) to topsoil, and facilitating plant growth within litter-soil system. To characterize elevation... The forest litter is an essential reservoir of nutrients in forests, supplying a large part of absorbable base cations(BC) to topsoil, and facilitating plant growth within litter-soil system. To characterize elevational patterns of base cation concentrations in the forest litter and topsoil, and explore the effects of climate and tree species, we measured microclimate and collected the forest litter and topsoil(0-10 cm) samples across an elevational range of more than 2000 m(1243 ~ 3316 m a.s.l.),and analyzed the concentrations of BC in laboratory. Results showed that: 1) litter Ca concentration displayed a hump-shaped pattern along the elevational gradients, but litter K and Mg showed saddle-shaped patterns. Soil Ca concentration increased with elevation, while soil K and Mg had no significant changes. 2) Ca concentration in the forest litter under aspen(Populus davidiana) was significantly higher than that in all other species, but in topsoil, Ca concentration was higher under coniferous larch and fir(Larix chinensis and Abies fargesii). Litter K and Mg concentrations was higher under coniferous larch and fir, whereas there were nosignificant differences among tree species in the concentrations of K and Mg in topsoil. 3) Climatic factors including mean annual temperature(MAT), growing season precipitation(GSP) and non-growing season precipitation(NGSP) determined BC concentrations in the forest litter and topsoil. Soil C/N and C/P also influenced BC cycling between litter and soil. Observation along elevations within different tree species implies that above-ground tree species can redistribute below-ground cations, and this process is profoundly impacted by climate. Litter and soil Ca, K and Mg with different responses to environmental variables depend on their soluble capacity and mobile ability. 展开更多
关键词 BASE cationS Elevations LARIX CHINENSIS Litter-soil system Carbon nitrogen ratio
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Study on Exchangeable Cation Determining Base Saturation Percentage of Soil in South China
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作者 Anqi Wang Xiangzhen Kong +2 位作者 Xiaodong Song Bing Ju Decheng Li 《Agricultural Sciences》 2020年第1期17-26,共10页
Base saturation percentage (BSP) is an important soil chemical index in soil fertility and soil taxonomy. However, it is still unclear what exchangeable cation dominates BSP of soil in south China. Therefore, in this ... Base saturation percentage (BSP) is an important soil chemical index in soil fertility and soil taxonomy. However, it is still unclear what exchangeable cation dominates BSP of soil in south China. Therefore, in this study, the data of BSPs and exchangeable H+, Al3+, Ca2+, Mg2+, K+ and Na+ of 109 and 45 horizon samples of 50 and 28 soil species in red soil and yellow soil groups in the Database of Chinese Soil Species were used to explore further the characteristics of BSPs and exchangeable cations as well as the correlation between BSPs and exchangeable cations. The results showed that the concentrations of exchangeable cations in both red soil and yellow soil groups were in an order of Al3+ (4.55 ± 1.47 and 4.22 ± 1.2 cmol(+)/kg) > Ca2+ (0.32 ± 0.21 and 0.36 ± 0.24 cmol(+)/kg) > H+ (0.23 ± 0.13 and 0.19 ± 0.10 cmol(+)/kg) > K+ (0.16 ± 0.09 and 0.16 ± 0.11 cmol(+)/kg) > Mg2+ (0.13 ± 0.09 and 0.11 ± 0.08 cmol(+)/kg) > Na+ (0.08 ± 0.06 and 0.11 ± 0.06 cmol(+)/kg). For red soil group, Al3+ concentration was significantly higher than those of other exchangeable cations, Ca2+ and H+ concentrations were significantly higher than those of K+, Mg2+ and Na+;while for yellow soil group, Ca2+, H+ and K+ concentrations were significantly higher than those of Mg2+ and K+. BSP of red soil group was codetermined by Ca2+, Al3+, Mg2+ and Na+, with the contributions of 33.81%, 19.82% and 14.49%, respectively;while BSP of yellow soil group was codetermined by Al3+, Ca2+, Mg2+, K+ and Na+, with the contributions of 24.91%, 21.55%, 19.91% and 14.21%, respectively. A higher concentration of exchangeable cation does not mean the higher importance of the cation to soil BSP. 展开更多
关键词 Base Saturation PERCENTAGE (BSP) Exchangeable cationS Correlation Red soil Yellow soil South China
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乙二胺四乙酸-乙酸铵盐交换法测定阳离子交换量方法优化
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作者 王卓 郭全恩 +1 位作者 曹诗瑜 展宗冰 《化学分析计量》 CAS 2024年第2期87-92,共6页
针对乙二胺四乙酸(EDTA)-乙酸铵交换法测定土壤阳离子交换量耗时长的问题,对方法的搅拌方式、搅拌时间、蒸馏时间进行优化。优化后分析条件为:用磁力搅拌器代替人工橡皮头玻璃棒搅拌,确定搅拌时间为90 s,确定蒸馏时间为6 min。选择4个... 针对乙二胺四乙酸(EDTA)-乙酸铵交换法测定土壤阳离子交换量耗时长的问题,对方法的搅拌方式、搅拌时间、蒸馏时间进行优化。优化后分析条件为:用磁力搅拌器代替人工橡皮头玻璃棒搅拌,确定搅拌时间为90 s,确定蒸馏时间为6 min。选择4个不同地区不同阳离子交换量的土壤标准物质用优化前、后的方法分别进行7次测定,其检测结果相对标准偏差为1.53%~5.32%;28个实际样品进行成对二样本均值分析,优化前、优化后测定的土壤阳离子交换量结果无显著性差异;对优化前、后28个土壤样品阳离子交换量测定结果进行相关性分析,线性相关显著,相关系数r=0.998。结果表明,EDTA-乙酸铵交换法优化前、后均具有较好的精密度和准确度,结果无显著性差异,EDTA乙酸铵交换法优化后的方法检测时间(1人测定8个样品)由280 min缩短到130 min,提高了检测效率,适合批量石灰性土壤阳离子代换量的测定。 展开更多
关键词 土壤 阳离子交换量 乙二胺四乙酸-乙酸铵交换法 磁力搅拌器
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长期施用化肥对南方稻田土壤酸化和盐基离子损失的影响
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作者 冀建华 吕真真 +5 位作者 刘淑珍 侯红乾 刘益仁 刘秀梅 李絮花 蓝贤瑾 《中国农业科学》 CAS CSCD 北大核心 2024年第13期2599-2611,共13页
【目的】利用长期定位试验评估氮、磷、钾化肥配施对土壤酸化程度、交换性铝产生量和盐基离子损失量的影响,为维持土壤健康生产和农田可持续利用提供依据。【方法】采用始于1984年的肥料长期定位试验,选取不施肥(CK),磷钾肥配施(PK)、... 【目的】利用长期定位试验评估氮、磷、钾化肥配施对土壤酸化程度、交换性铝产生量和盐基离子损失量的影响,为维持土壤健康生产和农田可持续利用提供依据。【方法】采用始于1984年的肥料长期定位试验,选取不施肥(CK),磷钾肥配施(PK)、氮磷肥配施(NP)、氮钾肥配施(NK)和氮磷钾肥配施(NPK)5个处理,采集每个处理的0—10、10—20、20—40和40—60 cm土层土样,分析土壤pH、交换性酸、交换性盐基离子总量、交换性盐基离子累积量、酸碱缓冲容量和酸化速率等指标。【结果】经过连续33年不同施肥处理的定向培育后,CK、PK、NP、NK和NPK处理0—20 cm土层pH较试验前分别下降0.82、0.91、1.13、0.8和1.19个pH单位,导致表层土壤明显酸化,酸化速率分别达到了1.10、1.22、1.46、1.13和1.58 kmol·hm^(-2)·a^(-1)。与CK处理相比,NP和NPK处理的0—40 cm土层显著酸化,土壤pH分别下降0.28—0.38和0.35—0.46个单位,土壤交换性酸分别增加了35.5%—110.0%和30.4%—120.5%,特别是交换性铝分别增加56.2%—157.6%和73.7%—189.8%,土壤交换性盐基离子总量分别减少6.3%—14.9%和9.9%—13.2%,盐基饱和度降低2.9—14.9和2.6—15.4个百分点;NK处理的0—20 cm土层略有酸化,土壤交换性酸增加53.5%—55.0%,盐基饱和度降低6.0—7.1个百分点;PK处理的0—60 cm土壤酸化均不明显,土壤交换性酸增加和交换性盐基离子总量减少差异均不显著。【结论】长期施化肥对土壤酸化程度和盐基离子损失量的影响表现出明显差异。其中,NPK和NP长期处理加剧土壤酸化进程,且酸化深度到达40 cm,盐基离子损失量和交换性铝的产生量大幅增加,初步估算施用化肥导致土壤pH降低1个单位,土壤交换性盐基离子的损失量约是土壤交换性酸增加量的一倍左右;长期磷钾配施、氮钾配施对土壤酸化的影响较小,盐基离子损失量和交换性铝增加量相对较少。 展开更多
关键词 化肥 长期定位试验 稻田 土壤PH 土壤酸化 交换性盐基离子
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内蒙古平原灌区土壤固碳与养分吸附特征及秸秆还田调控 被引量:2
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作者 于博 刘雅梦 +6 位作者 杨哲 王佳乐 王钰艳 郭艳 马扬 任琴 穆俊祥 《华北农学报》 CSCD 北大核心 2024年第1期120-126,共7页
为内蒙古平原灌区春玉米连续高产稳产过程中秸秆培肥高产田和改良盐碱田提供理论依据。设置了玉米秸秆还田1~4 a(HT1~HT4)定位试验,以秸秆不还田作为对照(CK),测定了春播前和收获期土壤有机碳含量、全氮含量、有效氮含量、有效磷含量、... 为内蒙古平原灌区春玉米连续高产稳产过程中秸秆培肥高产田和改良盐碱田提供理论依据。设置了玉米秸秆还田1~4 a(HT1~HT4)定位试验,以秸秆不还田作为对照(CK),测定了春播前和收获期土壤有机碳含量、全氮含量、有效氮含量、有效磷含量、阳离子交换量、pH值和酸碱缓冲曲线。结果表明,HT1~HT4收获期与春播前相比土壤有机碳含量、全氮含量、有效氮含量、有效磷含量、阳离子交换量的相对变化率为1.34%~3.62%,0.20%~1.51%,-0.11%~0.78%,0.89%~6.36%,0.09%~0.41%,CK收获期与春播前相比土壤有机碳含量、全氮含量、有效氮含量、有效磷含量、阳离子交换量的相对变化率为1.57%,-0.02%,-0.45%,-0.15%,-0.05%;HT2、HT3、HT4比CK的土壤pH值显著降低;土壤对碱的缓冲能力依次为HT4>HT3>HT2>HT1>CK。综上所述,随秸秆还田年限的增加,土壤固碳能力、保肥能力和缓冲性能增大,有效抵御因施化肥等因素导致土壤pH值剧烈变化的能力增强,秸秆还田培肥改土措施显著提升了土壤质量。 展开更多
关键词 秸秆还田 土壤有机碳 土壤养分吸附 土壤阳离子交换量 土壤酸碱缓冲曲线 盐碱田
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大春河小流域土壤有效硼和阳离子交换量变化特征研究
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作者 郭锁娜 脱云飞 +6 位作者 张丽娟 王倩 沈方圆 王飞 郑阳 杜文娟 向萍 《西南林业大学学报(自然科学)》 CAS 北大核心 2024年第1期48-55,共8页
为提高土壤保肥能力和构建合理耕层结构,以云南省昆明市大春河小流域林地、园地、草地、耕地和裸地为研究对象,采用固定深度法和等效质量法2种方法共同计算土壤有效硼(EB)储量,Franzluebbers法计算EB和阳离子交换量(CEC)层化率,分析土... 为提高土壤保肥能力和构建合理耕层结构,以云南省昆明市大春河小流域林地、园地、草地、耕地和裸地为研究对象,采用固定深度法和等效质量法2种方法共同计算土壤有效硼(EB)储量,Franzluebbers法计算EB和阳离子交换量(CEC)层化率,分析土壤有效硼和阳离子交换量随深度的变化特征及影响因素。结果表明:EB含量和储量随深度变化差异显著(P <0.05),林地和园地随深度的增加而降低,草地、耕地和裸地随深度的增加而增加;林地EB和CEC层化率SR2大于SR1;土壤CEC含量随土壤深度增加显著增加或降低;阳离子附着于土壤而流失,土壤CEC含量随土壤深度的增加而递减;有机质(OM)、总氮(TN)、含水率(MC)和容重(BD)对EB和CEC具有显著相关性(P <0.05),不同土地利用类型的OM、TN和MC与EB和CEC呈正相关关系,BD与土壤EB和CEC呈负相关关系;林地和园地保肥能力高于草地、耕地和裸地,0~20cm保肥能力最好;草地、耕地和裸地40~60 cm保肥能力最好。植被覆盖率和土壤侵蚀是影响EB和CEC变化的主要物理因素,OM、TN、MC和BD是影响EB和CEC变化的主要化学因素,需构建合理耕作层,提高保水保肥能力。 展开更多
关键词 小流域 土壤 阳离子交换量 养分
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皖南山区不同类型森林土壤阳离子交换性能差异
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作者 石晓芸 夏尚光 +2 位作者 孙庆业 李静 赵琼 《安徽农业大学学报》 CAS CSCD 2024年第2期284-290,共7页
为了解皖南山区不同类型森林土壤阳离子交换性能差异,为该区合理营林提供参考,选取皖南山区6种不同类型森林土壤(杉木林、马尾松林、栓皮栎林、外松林、天然阔叶林和杉木-栓皮栎混交林)为研究对象,比较森林土壤阳离子交换性能的差异。... 为了解皖南山区不同类型森林土壤阳离子交换性能差异,为该区合理营林提供参考,选取皖南山区6种不同类型森林土壤(杉木林、马尾松林、栓皮栎林、外松林、天然阔叶林和杉木-栓皮栎混交林)为研究对象,比较森林土壤阳离子交换性能的差异。结果表明:(1)研究区土壤呈强酸性,土壤有机质含量为33.84~91.50 g·kg^(-1),总氮含量为0.94~3.37 g·kg^(-1),碱解氮含量为131.58~203.62 mg·kg^(-1),总磷含量为0.22~0.77 g·kg^(-1),有效磷含量为0.17~0.32 mg·kg^(-1);土壤主要缺乏速效磷养分。(2)阳离子交换量在8.09~12.57 cmol·kg^(-1)之间,排序为:天然阔叶林>外松林>马尾松林>混交林>杉木林>栓皮栎林,不同森林土壤间阳离子交换量的差异主要由其土壤有机质的差异引起。(3)交换性盐基总量在1.74~2.72 cmol·kg^(-1)g之间,排序为:马尾松林>外松林>杉木林>栓皮栎林>混交林>天然阔叶林,Ca^(2+)和Mg^(2+)是主要的盐基离子,是成土过程中Ca、Mg优先固持形成的。(4)盐基饱和度在13.97%~28.98%之间,排序为:马尾松林>杉木林>栓皮栎林>外松林>混交林>天然阔叶林,该差异是由淋溶作用和树木对盐基离子的吸收共同作用形成的差异。综上,研究区土壤保肥和缓冲性能较低且供肥能力较差,尤其是土壤速效磷供应能力差。其中松林的供肥保肥能力及缓冲性能明显优于其他树种森林,混交林的速效养分含量更高,故可通过营造松类混交林以及施肥来提高森林土壤供肥保肥能力和缓冲性能。 展开更多
关键词 皖南山区 森林土壤 阳离子交换性能 盐基离子 土壤肥力
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酸沉降强度对马尾松土壤活性铝的影响
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作者 朱君琳 刘敏 +3 位作者 王云琦 李成 郑永林 张晓明 《森林与环境学报》 CSCD 北大核心 2024年第4期376-386,共11页
为探究长期自然环境中酸沉降强度对马尾松林下土壤活性铝的影响,以酸沉降强度依次增大的重庆四面山、缙云山、铁山坪为研究区,选取母质相同的马尾松土壤为研究对象,分析不同酸沉降强度下土壤pH值、营养元素含量、交换性阳离子含量、酶... 为探究长期自然环境中酸沉降强度对马尾松林下土壤活性铝的影响,以酸沉降强度依次增大的重庆四面山、缙云山、铁山坪为研究区,选取母质相同的马尾松土壤为研究对象,分析不同酸沉降强度下土壤pH值、营养元素含量、交换性阳离子含量、酶活性与土壤活性铝的相互作用关系。结果表明:随着酸沉降强度的增大,土壤pH值及全碳(TC)、全氮(TN)、交换性铝(Ex-Al)、单聚体羟基铝(Hy-Al)、酸溶无机铝(Ac-Al)含量显著下降(P<0.05),而交换性Mn^(2+)含量不断上升。研究区活性铝以Ac-Al和腐殖质酸铝(Hu-Al)为主,共占比77.1%~84.9%。酸沉降条件下,土壤各形态活性铝含量与TC含量、TN含量、全硫(TS)含量、铵态氮(NH_(4)^(+)-N)含量、脲酶(UE)活性显著相关(P<0.05),活性铝总量的主要影响因子为NH_(4)^(+)-N含量。酸沉降强度改变影响土壤活性铝的主导因子。在四面山,TC、TN、TS含量与各形态活性铝含量显著正相关(P<0.05);在缙云山,Mg^(2+)含量与Ac-Al含量显著正相关(P<0.05),与Ex-Al、Hy-Al、Hu-Al含量显著负相关(P<0.05);在铁山坪,硝态氮(NO_(3)^(-)-N)含量与Ex-Al含量极显著负相关(P<0.01),与Hy-Al、Ac-Al、Hu-Al含量极显著正相关(P<0.01)。随着酸沉降强度的增大,马尾松土壤碳氮元素流失,活性铝淋溶,交换性Mn^(2+)含量升高。经冗余分析可知,随酸沉降强度增大,影响土壤各形态活性含量的主要因子由TC、TN、TS含量转变为交换性Mg^(2+)含量,后为NO_(3)^(-)-N含量。 展开更多
关键词 酸沉降强度 土壤活性铝 土壤交换性阳离子 土壤酶活性
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模拟酸雨对烟田土壤酸化及烟草生长发育的影响
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作者 相雨晴 肖艳松 +6 位作者 刘明宏 郜军艺 李彩斌 高睿康 刘馥榕 张继光 彭玉龙 《中国烟草科学》 CSCD 北大核心 2024年第3期26-33,共8页
我国西南地区是全球酸沉降负荷最高的地区之一,为明确酸性降水给烟田生态系统产生的可能危害,在田间利用自动模拟酸雨监测仪,模拟自然降雨(CK,pH 6.3)、超纯水(T1,pH 6.8)和酸雨(T2,pH 3.5)3种条件,测定其对土壤酸化及阳离子特征、烟草... 我国西南地区是全球酸沉降负荷最高的地区之一,为明确酸性降水给烟田生态系统产生的可能危害,在田间利用自动模拟酸雨监测仪,模拟自然降雨(CK,pH 6.3)、超纯水(T1,pH 6.8)和酸雨(T2,pH 3.5)3种条件,测定其对土壤酸化及阳离子特征、烟草长势、生物量及氮磷钾积累量的影响。结果表明:(1)与CK和T1相比,T2土壤pH显著降低且随时间推移各处理之间差异逐渐增大;T2土壤交换性酸及铝离子含量显著增加,CEC和盐基总量下降;(2)T2显著抑制烟草生长发育,显著降低烟株株高、茎围、有效叶数及叶片长、宽,CK的茎和叶生物量最高,T1的根生物量最高;(3)根中氮和钾的积累量均为T2最低;茎和叶中氮的积累量表现为T2>T1>CK,茎和叶中钾的积累量表现为CK>T2>T1;磷的积累量在不同部位中差异不大,整体表现为T2最低。可见pH 3.5的酸雨能导致土壤明显酸化,显著抑制烟株生长发育,应采取有效措施控制其发生危害。 展开更多
关键词 酸雨 土壤酸化特性 土壤阳离子特性 农艺性状
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超声浸提-电感耦合等离子体发射光谱法测定石灰性土壤中的有效磷
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作者 杨青 孙晓慧 +2 位作者 黄尧 季佩高 李亮 《分析测试技术与仪器》 CAS 2024年第3期196-202,共7页
采用超声浸提-电感耦合等离子体发射光谱法(ICP-AES)实现了石灰性土壤中有效磷的快速、准确、批量化分析要求.将水土混合液在400 W超声功率下于25℃浸提10 min,用3.50 g苯乙烯阳离子交换树脂降低基体干扰.分析谱线P 214.914 nm,射频功率... 采用超声浸提-电感耦合等离子体发射光谱法(ICP-AES)实现了石灰性土壤中有效磷的快速、准确、批量化分析要求.将水土混合液在400 W超声功率下于25℃浸提10 min,用3.50 g苯乙烯阳离子交换树脂降低基体干扰.分析谱线P 214.914 nm,射频功率1150 W,载气流量0.6 L/min,采用ICP-AES测定有效磷.结果显示:磷在0~5.00 mg/L范围内校准曲线线性良好(相关系数0.9996),检出限为0.072 mg/kg.方法用于4种不同碱性土壤有效态标准物质的分析,测定值相对误差小于±7%,相对标准偏差小于10%,且和标准方法(NY/T 1121.7—2014)测定值接近. 展开更多
关键词 超声浸提 电感耦合等离子体发射光谱法 石灰性土壤 有效磷 苯乙烯阳离子交换树脂
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文山州土壤质地构成与肥力特征
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作者 茹瑞红 农全东 +6 位作者 李在辉 李雪萍 农传江 李春情 陈显梅 王瑞清 屈用函 《贵州农业科学》 CAS 2024年第6期54-60,共7页
【目的】探明文山州耕地土壤质地与肥力特征,为当地耕地土壤保护与改良提供参考。【方法】对文山州7县1市不同生态区共926个点进行土壤调查,测定土壤pH、有机质、全氮、有效磷及速效钾含量,分析主要土壤类型的肥力特征。【结果】文山州... 【目的】探明文山州耕地土壤质地与肥力特征,为当地耕地土壤保护与改良提供参考。【方法】对文山州7县1市不同生态区共926个点进行土壤调查,测定土壤pH、有机质、全氮、有效磷及速效钾含量,分析主要土壤类型的肥力特征。【结果】文山州土壤质地以壤土为主,占比达96.22%,砂壤土在壤土中占比最高,为32.44%。在单作玉米模式下,2020年文山酸性砂壤土以强酸性土壤为主,占比为55.71%;2022年土壤p H、有机质、全氮、速效钾和有效磷含量较2020年总体呈上升趋势;pH与有机质、全氮含量呈负相关关系,与有效磷、速效钾含量呈正相关关系。有机质与全氮、速效钾含量分别呈极显著和显著正相关关系,全氮与有效磷、速效钾含量分别呈极显著和显著正相关关系,有效磷与速效钾含量呈极显著正相关关系。pH与养分的最优回归方程为y=0.207-0.562 x_(1)+0.01 x_(2)(式中,y为土壤pH的增量、x_(1)和x_(2)分别为土壤全氮和速效钾含量的增量),pH与全氮含量呈负相关,与速效钾含量呈正相关。【结论】文山州96.22%的土壤为壤土,壤土中以砂壤土最多,占比32.44%。文山州砂壤土含氮量总体丰富,有机质、有效磷与速效钾含量各地差异大,中等含量水平居多。相比于2020年,2022年土壤pH总体呈上升趋势;pH与全氮含量呈负相关,与速效钾含量呈正相关。结合土壤酸化规律,建议文山州农户进一步优化施肥方式,适当减少氮肥的施用,重视磷钾肥的施用,避免施肥导致土壤进一步酸化。 展开更多
关键词 土壤 土壤质地 砂壤土 肥力特征 土壤理化性质 酸化成因 文山州
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积雪变化对东北农田黑土盐基离子及有效硅铝含量的影响
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作者 王子龙 滕怀淏 +3 位作者 姜秋香 刘传兴 单家珣 王凯 《水土保持学报》 CSCD 北大核心 2024年第2期147-156,164,共11页
[目的]为探究冬季积雪深度变化下东北农田黑土盐基离子及有效硅铝含量的季节性变化特征。[方法]采用人工控制积雪深度的方法,通过测定除雪处理组(SR)、减雪处理组(SL)、自然积雪对照组(C)、增雪处理组(SA)的东北农田黑土环境因子(温湿... [目的]为探究冬季积雪深度变化下东北农田黑土盐基离子及有效硅铝含量的季节性变化特征。[方法]采用人工控制积雪深度的方法,通过测定除雪处理组(SR)、减雪处理组(SL)、自然积雪对照组(C)、增雪处理组(SA)的东北农田黑土环境因子(温湿度、含水率、pH、总有机碳)、盐基离子、有效硅以及活性铝,分析土壤盐基离子及有效硅铝的含量变化过程,以及两者对土壤环境因子的响应关系。[结果]积雪深度的降低使季节性雪被覆盖下黑土受到积雪的保温作用减弱,0-30 cm土壤温度及湿度(未冻水含量)显著下降,使水盐运移过程中未冻水携带的HCO_(3)^(-)含量减少,土壤平均pH受HCO _(3)^(-)含量影响分别变化-0.06,-0.04,-0.02,0.01。土壤的碱性降低,低价阳离子对高价阳离子在土壤胶体吸附电位的置换能力增强,使得交换态一价阳离子(Na^(+)、K^(+))含量升高,同时使交换态及碳酸盐态二价阳离子(Ca ^(2+)、Mg^(2+))含量降低。碳酸盐态二价阳离子与交换态Na+分别对TOC含量构成正向和负向的影响,使土壤平均总有机碳(TOC)含量随积雪深度的降低分别增长0.87,1.09,1.32,1.48 g/kg。盐基离子与土壤pH、TOC的相互影响关系使在积雪深度降低的条件下土壤pH与TOC含量降低,进而对土壤有效硅铝含量构成间接影响。TOC含量的降低削弱了土壤对低活性腐殖酸铝(Al-HA)的固持作用,pH的降低促进低活性铝向高活性交换态铝(Ex-Al)与单聚体羟基铝(Hy-Al)的转化,土壤铝毒性提升,同时促进有效硅的溶解,造成土壤硅的流失。[结论]气候变暖引起的中高纬度地区季节性积雪覆盖面积减少将影响冬季东北地区农田黑土的物质能量分布状态,并由此改变生长季节农作物的生长发育环境,研究提示为冬季东北黑土区土壤矿质元素的季节性变化过程提供了一定的科学依据。 展开更多
关键词 积雪变化 农田黑土 盐基离子 有效硅 活性铝
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酸性土壤阳离子交换量和交换性钙、镁、钾、钠的方法探讨
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作者 孙连伟 宋娟娟 +4 位作者 于聪灵 陈超 杨利娟 冉卓 秦冲 《广州化工》 CAS 2024年第14期88-90,108,共4页
为了提高土壤中阳离子交换量检测的准确度和效率,针对国家标准方法的不足,在原理不变的条件下对空白、浸提、离心等实验步骤进行优化。结果表明:通过实验测试对试验进行重新定义,将国家标准方法中的浸提时间由120 min优化为30 min,大大... 为了提高土壤中阳离子交换量检测的准确度和效率,针对国家标准方法的不足,在原理不变的条件下对空白、浸提、离心等实验步骤进行优化。结果表明:通过实验测试对试验进行重新定义,将国家标准方法中的浸提时间由120 min优化为30 min,大大缩减了一个样品的测试时间,离心时间由5 min优化为10 min。本方法效率高、准确度和精密性良好,适用于大批量土壤中阳离子交换量的测定。 展开更多
关键词 土壤 阳离子交换量 浸提 离心 分光光度法 优化改进
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