Dietary polyphenols reduced the allergenicity ofβ-lactoglobulin via non-covalent interactions:a study on the structure-allergenicity relationship

Studies showed that complexation of polyphenols with milk allergens reduced their immunogenic potential.However,the relationship between structures of polyphenols and their hypoallergenic effects on milk allergens in association with physiological and conformational changes of the complexes remain unclear.In this study,polyphenols from eight botanical sources were extracted to prepare non-covalent complexes withβ-lactoglobulin(β-LG),a major allergen in milk.The dominant phenolic compounds bound toβ-LG with a diminished allergenicity were identified to investigate their respective role on the structural and allergenic properties ofβ-LG.Extracts from Vaccinium fruits and black soybeans were found to have great inhibitory effects on the IgE-and IgG-binding abilities ofβ-LG.Among the fourteen structure-related phenolic compounds,flavonoids and tannins with larger MWs and multi-hydroxyl substituents,notably rutin,EGCG,and ellagitannins were more potent to elicit changes on the conformational structures ofβ-LG to decrease the allergenicity of complexedβ-LG.Correlation analysis further demonstrated that a destabilized secondary structure and protein depolymerization caused by polyphenol-binding were closely related to the allergenicity property of formed complexes.This study provides insights into the understanding of structure-allergenicity relationship ofβ-LG-polyphenol interactions and would benefit the development of polyphenol-fortified matrices with hypoallergenic potential.

Control of light-matter interactions in two-dimensional materials with nanoparticle-on-mirror structures

Light–matter interactions in two-dimensional(2D)materials have been the focus of research since the discovery of graphene.The light–matter interaction length in 2D materials is,however,much shorter than that in bulk materials owing to the atomic nature of 2D materials.Plasmonic nanostructures are usually integrated with 2D materials to enhance the light–matter interactions,offering great opportunities for both fundamental research and technological applications.Nanoparticle-on-mirror(NPo M)structures with extremely confined optical fields are highly desired in this aspect.In addition,2D materials provide a good platform for the study of plasmonic fields with subnanometer resolution and quantum plasmonics down to the characteristic length scale of a single atom.A focused and up-to-date review article is highly desired for a timely summary of the progress in this rapidly growing field and to encourage more research efforts in this direction.In this review,we will first introduce the basic concepts of plasmonic modes in NPo M structures.Interactions between plasmons and quasi-particles in 2D materials,e.g.,excitons and phonons,from weak to strong coupling and potential applications will then be described in detail.Related phenomena in subnanometer metallic gaps separated by 2D materials,such as quantum tunneling,will also be touched.We will finally discuss phenomena and physical processes that have not been understood clearly and provide an outlook for future research.We believe that the hybrid systems of2D materials and NPo M structures will be a promising research field in the future.

RETRACTED: Nuclear Structure Study of Odd-Odd Yttrium Nuclei within Interacting-Boson Fermi-Fermion Model (IBFFM)

Short Retraction NoticeThe paper does not meet the standards of "Journal of Applied Mathematics and Physics". This article has been retracted to straighten the academic record. In making this decision the Editorial Board follows COPE's Retraction Guidelines. The aim is to promote the circulation of scientific research by offering an ideal research publication platform with due consideration of internationally accepted standards on publication ethics. The Editorial Board would like to extend its sincere apologies for any inconvenience this retraction may have caused.Editor guiding this retraction: Prof. Wen-Xiu Ma (EiC of JAMP)The full retraction notice in PDF is preceding the original paper, which is marked "RETRACTED".

Synthesis and Crystal Structure of a Mixed-ligand Manganese(Ⅱ) Complex Containing Abundant Hydrogen-bonding Interactions

A new mixed-ligand Mn（II）complex,namely [Mn（bipy）2（Huca）]·5H2O（1,bipy = 2,2＇-bipyridine,and H3uca = uracil-5-carboxylic acid）has been prepared and characterized by single-crystal X-ray diffraction,FT-IR spectroscopy and thermogravimetric analysis.It crystallizes in monoclinic,space group C2/c with a = 23.597（8）,b = 16.434（5）,c = 15.531（6）,β = 112.785（6）o,C25H28MnN6O9,Mr = 611.47,V = 5553（3）3,Z = 8,μ = 0.538,Dc = 1.463 g/cm3,F（000）= 2536,R = 0.0441 and wR = 0.1230 for all 5227 observed reflections（I 2σ（I））.The manganese（II）center is surrounded by three bidentate chelating ligands,and it displays a severely distorted octahedral geometry,with cis angles ranging from 72.14（6）to 109.78（6）o.Extensive intermolecular hydrogen bonds link the [Mn（bipy）2（Huca）] monomers and lattice water molecules to yield a three-dimensional supramolecular framework.TGA shows complete removal of all lattice water molecules above 270 ℃.

Trophic interactions, ecosystem structure and function in the southern Yellow Sea

The southem Yellow Sea is an important fishing ground, providing abundant fishery resources. However, overfishing and climate change have caused a decline in the resource and damaged the ecosystem. We developed an ecosystem model to analyze the trophic interactions and ecosystem structure and function to guide sustainable development of the ecosystem. Atrophic mass-balance model of the southern Yellow Sea during 2000-2001 was constructed using Ecopath with Ecosim software. We defined 22 important functional groups and studied their diet composition. The trophic levels of fish, shrimp, crabs, and cephalopods were between 2.78 and 4.39, and the mean trophic level of the fisheries was 3.24. The trophic flows within the food web occurred primarily in the lower trophic levels. The mean trophic transfer efficiency was 8.1%, of which 7.1% was from primary producers and 9.3% was from detritus within the ecosystem. The transfer efficiency between trophic levels II to III to IV to V to 〉V was 5.0%, 5.7%, 18.5%, and 19.7%-20.4%, respectively. Of the total flow, phytoplankton contributed 61% and detritus contributed 39%. Fishing is defined as a top predator within the ecosystem, and has a negative impact on most commercial species. Moreover, the ecosystem had a high gross efficiency of the fishery and a high value of primary production required to sustain the fishery. Together, our data suggest there is high fishing pressure in the southern Yellow Sea. Based on analysis of Odum＇s ecological parameters, this ecosystem was at an immature stage. Our results provide some insights into the structure and development of this ecosystem.

Gradient structure induced simultaneous enhancement of strength and ductility in AZ31 Mg alloy with twin-twin interactions

Gradient nanostructure was introduced to enhance the strength and ductility via deformation incompatibility accommodated by geometrical necessary dislocations for most metallic materials recently.However,few intensive researches were carried out to investigate the effect of gradient structure on the deformation twin evolution and resulting performance improvements.In the present paper,we produced gradient-structured AZ31 Mg alloy with fine-grain layers,parallel twin laminates and a coarse-grain core from two upmost surfaces to the center of plate.Surprisingly,this architected Mg alloy exhibited simultaneous enhancement of strength and ductility.Subsequent microstructural observations demonstrated that abundant twin-twin interactions resulting from higher strength and multi-axial stress state could make great contributions to the increase of work-hardening capability.This was further proved by the measurement of full-field strain evolution during the plastic deformation.Such a design strategy may provide a new path for producing advanced structure materials in which the deformation twinning works as one of the dominant plasticity mechanisms.

Thermal Stability Improved by π–π Stacking Interactions: Synthesis, Crystal Structure and Thermal Decomposition of Sodium Nitroformate

An energetic salt, sodium nitroformate （NaNF）, was synthesized and characterized by elemental analysis, IR and UV spectra, and its crystal structure was first determined by single crystal X-ray diffraction. The structure exhibits two types of π-π stacking interactions between the nitroformate anions, i e, the parallel-displaced and T-shaped confgurafions. Furthermore, the thermal decomposition mechanism was investigated by DSC, TG-DTG and FTIR techniques. The kinetic parameters of the thermal decomposition were also calculated by using Kissinger＇s and Ozawa-Doyle＇s methods. The results show that NaNF has a good thermal stability, which is attributed to the π-π stacking interactions.

The interactions between bloodstream and vascular structure on aortic dissecting aneurysmal model: A numerical study

Stent-graft implantation is an important means of clinical treatment for aortic dissecting aneurysm （ADA）. However, researches on fluid dynamics effects of stent were rare. Computer simulation was used to investigate the interactions between bloodstream and vascular structure in a stented ADA, which endures the periodic pulse velocity and pressure. We obtained and analyzed the flow velocity distribution, the wall displacement and wall stress in the ADA. By comparing the different results between a non-stented and a stented ADA, we found that the insertion of a vascular graft can make the location of maximum stress and displacement move from the aneurysm lumen wall to the artery wall, accompanied with a greatly decrease in value. These results imply that the placement of a stent-graft of any kind to oc-clude ADA will result in a decreased chance of rupture.

Weak Interactions and 2D Layer Structure of a New Ion-pair Complex Bis(1-benzyl-4-methylquinolinium)-bis(maleonitriledithiolato)nickel(Ⅱ)

A new ion-pair complex, [BzMeQ1]2[Ni（nmt）2]1（[BzMeQ1]^＋ = 1-benzyl-4-ntethylquino- linium, mnta- -- maleonitriledithiolate） has been synthesized and structurally characterized by IR, ESI-MS and X-ray diffraction methods. Complex 1 is of triclinic, space group PI, with a = 9.079（2）, b = 10.154（2）, c = 11.243（2）A, α= 81.58（1）, β= 69.63（1）, γ = 68.02（1）°, V= 940.1（3）A3, Dc = 1.427 g/cm^3, Z = 1, F（000） = 418 and R = 0.0442. A 2D layer structure is formed via the cation-cation π…π and C-H…π interactions observed in the solid state of the complex.

THE IMPACT OF AIR-SEA INTERACTIONS ON TYPHOON STRUCTURE

In this work,the results of a coupled experiment and an uncoupled experiment conducted in one of our former works are used to analyze the impact of air-sea interactions on the structure of typhoons.Results reveal that typhoon-induced SST decreases to reduce the latent heat fluxes transporting from the ocean to the atmosphere and cause the flux of sensible heat to transfer downward from the atmosphere to the ocean.Such SST reduction also has remarkable impacts on the typhoon structure by making the typhoon more axisymmetric,especially in the middle and high levels.This study also analyzes the basic characteristics of symmetric typhoon structure.

Experiment and numerical simulation on the characteristics of fluid–structure interactions of non-rigid airships

Fluid-structure interaction is an important issue for non-rigid airships with inflated envelopes. In this study, a wind tunnel test is conducted, and a loosely coupled procedure is correspondingly established for numerical simulation based on computational fluid dynamics and nonlinear finite element analysis methods. The typical results of the numerical simulation and wind tunnel experiment, including the overall lift and deformation, are in good agreement with each other. The results obtained indicate that the effect of fluid-structure interaction is noticeable and should be considered for non-rigid airships. Flow- induced deformation can further intensify the upward lift force and pitching moment, which can lead to a large deformation. Under a wind speed of 15 m/s, the lift force of the non-rigid model is increased to approximatelv 60% compared with that of the rigid model under a high angle of attack.

Fine-Structure Splittings of Nitrogen Isoelectronic Sequence： Competitions among Spin-Orbit Interactions, Breit Interactions and Electron Correlations

Using the multi-configuration Dirac-Fock self-consistent field method and the relativistic configuration interaction method with quantum-electrodynamics corrections performed by the GRASP code, we calculate the fine-structure energy levels of the ground-state configuration （1s^22s^22p^3） of the nitrogen isoelectronic sequence, according to the L-S coupling scheme with atomic number Z up to 22. Based on the calculated results, we elucidate the mechanism of the orderings of fine-structure energy levels of 2^ D3/2,5/2 and 2^P1/2,3/2 respectively, i.e. for 2^D3/2,5/2 orderings, the competition between the spin-orbit interactions and the Breit interactions; for 2^P1/2,3/2 orderings, the electron correlations, especially the electron correlations owing to the 2p^5 configuration interactions.

Numerical Investigation on Fluid Structure Interaction Considering Rotor Deformation for a Centrifugal Pump

The existing research for unsteady flow field and the corresponding flow induced vibration analysis of centrifugal pump are mainly carried out respectively without considering the interaction between fluid and structure. The ignorance of fluid structure interaction （FSI） means that the energy transfer between fluid and structure is neglected. To some extent, the accuracy and reliability of unsteady flow and rotor deflection analysis should be affected by this interaction mechanism. In this paper, a combined calculation between two executables for turbulent flow and vibrating structure was established using two-way coupling method to study the effect of FSI. Pressure distributions, radial forces, rotor deflection and equivalent stress are analyzed. The results show that the FSI effect to pressure distribution in flow field is complex. The pressure distribution is affected not only around impeller outlet where different variation trends of pressure values with and without FSI appear according to different relative positions between blade and cutwater, but also in the diffusion section of volute. Variation trends of peak values of radial force amplitude calculated with and without FSI are nearly same under high flow rate and designed conditions while the peak value with FSI is slightly smaller, and differently, the peak value with FSI is larger with low flow rate. In addition, the effect of FSI on the angle of radial force is quite complex, especially under 0.5Q condition. Fluctuation of radial deflection of the rotor has obvious four periods, of which the extent is relatively small under design condition and is relatively large under off-design condition. Finally, fluctuations of equivalent stress with time are obvious under different conditions, and stress value is small. The proposed research establishes the FSI calculation method for centrifugal pump analysis, and ensures the existing affect by fluid structure interaction.

Effect of the Interaction of Different Scale Vortices on the Structure and Motion of Typhoons

Five numerical experiments have been performed in this paper by using a quasigtostrophic barotropical model to investigate the interaction of different scale vortiCes on the structure and motion of typhoons.Results show that this interaction may arouse the irregular changes of the asymmetric structure of typhoons,thus leading to anomalous Phenomena such as meandering tracks and sudden changes in the motion speed of typhoons;the ￣t Of this interaction on the strucure and motion may be quite different when the smaller vortex is situated in different Posihons of the typhoon circulation.

Experimental study on interaction between membrane structures and wind environment

The interaction between membrane structures and their environment can be either static or dynamic. Static interaction refers to interaction with static air, while dynamic interaction refers to wind and its effects. They can be evaluated by two parameters, added mass and radiation/aerodynamic damping, which are experimentally investigated in this study. The study includes the effects of both the static and dynamic interaction on structural dynamic characteristics, and the relationship between the interaction parameters and the covered area of a membrane structure for the static interaction and the relationship between the interaction parameters and wind direction and speed for the dynamic interaction. Experimental data show that the dynamic interaction is strongly correlated with the structural modes, i.e., the interaction of the symmetric modes is much larger than the anti-synmletric modes; and the influence of the dynamic interaction is significant in wind-induced response analysis and cannot be ignored. In addition, it is concluded that the structural natural frequency is remarkably decreased by this interaction, and the frequency band is significantly broadened.

Study of vibrating foundations considering soil-pile-structure interaction for practical applications

An investigation of soil-pile-structure interaction is carried out, based on a large reciprocating compressor installed on an elevated concrete foundation （table top structure）. A practical method is described for the dynamic analysis, and compared with a 3D finite element （FE） model. Two commercial software packages are used for dynamic analysis considering the soilpile-structure interaction （SPSI）. Stiffness and damping of the pile foundation are generated from a computer program, and then input into the FE model. To examine the SPSI thoroughly, three cases for the soil, piles and superstructure are considered and compared. In the first case, the interaction is fully taken into account, that is, both the superstructure and soil-pile system are flexible. In the second case, the superstructure is flexible but fixed to a rigid base, with no deformation in the base （no SSI）. In the third case, the dynamic soil-pile interaction is taken into account, but the table top structure is assumed to be rigid. From the comparison beteen the results of these three cases some conclusions are made, which could be helpful for engineering practice.

Dynamic Analysis of Tension Leg Platform for Offshore Wind Turbine Support as Fluid-Structure Interaction

Tension leg platform （TLP） for offshore wind turbine support is a new type structure in wind energy utilization. The strong-interaction method is used in analyzing the coupled model, and the dynamic characteristics of the TLP for offshore wind turbine support are recognized. As shown by the calculated results： for the lower modes, the shapes are water＇s vibration, and the vibration of water induces the structure＇s swing; the mode shapes of the structure are complex, and can largely change among different members; the mode shapes of the platform are related to the tower＇s. The frequencies of the structure do not change much after adjusting the length of the tension cables and the depth of the platform; the TLP has good adaptability for the water depths and the environment loads. The change of the size and parameters of TLP can improve the dynamic characteristics, which can reduce the vibration of the TLP caused by the loads. Through the vibration analysis, the natural vibration frequencies of TLP can be distinguished from the frequencies of condition loads, and thus the resonance vibration can be avoided, therefore the offshore wind turbine can work normally in the complex conditions.

Seismic response of tall building considering soil-pile-structure interaction

The seismic behavior of tall buildings can he greatly affected by non-linear soil-pile interaction during strong earthquakes.In this study a 20-storey building is examined as a typical structure supported on a pile foundation for different conditions:(1) rigid base,i.e.no deformation in the foundation:(2) linear soil-pile system;and (3) nonlinear soil-pile system. The effects of pile foundation displacements on the behavior of tall building are investigated,and compared with the behavior of buildings supported on shallow foundation.With a model of non-reflective boundary between the near field and far field, Novak's method of soil-pile interaction is improved.The computation method for vibration of pile foundations and DYNAN computer program are introduced comprehensively.A series of dynamic experiments have been done on full-scale piles, including single pile and group,linear vibration and nonlinear vibration,to verify the validity of boundary zone model.

Interactive Multi-objective Optimization Design for the Pylon Structure of an Airplane

The pylon structure of an airplane is very complex, and its high-fidelity analysis is quite time-consuming. If posterior preference optimization algorithm is used to solve this problem, the huge time consumption will be unacceptable in engineering practice due to the large amount of evaluation needed for the algorithm. So, a new interactive optimization algorithm-interactive multi-objective particle swarm optimization （IMOPSO） is presented. IMOPSO is efficient, simple and operable. The decision-maker can expediently determine the accurate preference in IMOPSO. IMOPSO is used to perform the pylon structure optimization design of an airplane, and a satisfactory design is achieved after only 12 generations of IMOPSO evolutions. Compared with original design, the maximum displacement of the satisfactory design is reduced, and the mass of the satisfactory design is decreased for 22%.

Numerical modeling of deep-seated landslides interacting with man-made structures

This paper describes the interaction between deep-seated landslides and man-made structures such as dams, penstocks, viaducts, and tunnels. Selected case studies are reported first with the intent to gain insights into the complexities associated with the interaction of these structures with deep-seated landslides(generally referred to as deep-seated gravity slope deformations, DSGSDs). The main features, which characterize these landslides, are mentioned together with the interaction problems encountered in each case. Given the main objective of this paper, the numerical modeling methods adopted are outlined as means for increase in the understanding of the interaction problems being investigated. With the above in mind, the attention moves to an important and unique case history dealing with the interaction of a large-size twin-tunnel excavated with an earth pressure balance(EPB)tunnel boring machine(TBM) and a deep-seated landslide, which was reactivated due to the stress changes induced by tunnel excavation in landslide shear zone. The geological and geotechnical conditions are described together with the available monitoring data on the landslide movements, based on the advanced and conventional monitoring tools used. Numerical modeling is illustrated as an aid to back-analyze the monitored surface and subsurface deformations and to assist in finding the appropriate engineering solution for putting the tunnel into service and as a follow-up means for future understanding and control of the interaction problems. The simulation is based on a novel time-dependent model representing the landslide behavior.